CN115347101A - Micro light-emitting diode structure - Google Patents
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Abstract
Description
技术领域technical field
本发明涉及一种发光结构,尤其涉及一种微型发光二极管结构。The invention relates to a light emitting structure, in particular to a micro light emitting diode structure.
背景技术Background technique
在现有技术中,微型发光二极管的主要制程是在磊晶基板上进行,制程完成后再移除磊晶基板,并被转移到暂时性的承载基板上。在上述制程中,微型发光二极管的表面会形成一层用于电性钝化的绝缘层(厚度约0.5微米至1微米不等),且绝缘层会从微型发光二极管结构的顶面沿着其周围表面延伸覆盖至磊晶基板的表面上。然而,由于绝缘层具有一定厚度,当进行激光剥离(Laser Lift-Off,LLO)程序以移除磊晶基板时,容易导致剥离后的微型发光二极管的周围表面残留外延的绝缘层,进而对转移后的制程造成不良影响。In the prior art, the main manufacturing process of micro light emitting diodes is carried out on the epitaxial substrate. After the manufacturing process is completed, the epitaxial substrate is removed and transferred to a temporary carrier substrate. In the above-mentioned process, an insulating layer (thickness ranging from about 0.5 micron to 1 micron) will be formed on the surface of the micro-LED structure for electrical passivation, and the insulating layer will start from the top surface of the micro-LED structure along its The surrounding surface extends to cover the surface of the epitaxial substrate. However, since the insulating layer has a certain thickness, when the laser lift-off (Laser Lift-Off, LLO) process is performed to remove the epitaxial substrate, it is easy to cause the epitaxial insulating layer to remain on the surrounding surface of the micro light emitting diode after stripping, thereby affecting the transfer Detrimental effects on subsequent processes.
发明内容Contents of the invention
本发明是针对一种微型发光二极管结构,其解决现有技术中剥离后的微型发光二极管的周围表面残留有外延绝缘层的问题,可具有较佳的结构可靠度,在兼顾发光效率的同时,可改善整体制程良率。The present invention is directed to a micro light emitting diode structure, which solves the problem in the prior art that the epitaxial insulating layer remains on the surrounding surface of the stripped micro light emitting diode, and can have better structural reliability, while taking into account the luminous efficiency, The overall process yield can be improved.
根据本发明的实施例,微型发光二极管结构包括磊晶结构、第一绝缘层以及第二绝缘层。磊晶结构包括第一型半导体层、发光层以及第二型半导体层。发光层位于第一型半导体层与第二型半导体层之间。第一型半导体层、发光层以及第二型半导体层的第一部分构成平台。平台具有顶面以及第一侧表面。第二型半导体层的第二部分相对于平台凹陷而形成平台面。第二型半导体层的第二部分具有第二侧表面。平台面位于第一侧表面与第二侧表面之间。第一绝缘层从平台的顶面沿着第一侧表面覆盖至平台面,且暴露出第二侧表面。第二绝缘层直接覆盖第二侧表面,其中第一绝缘层与第二绝缘层的厚度比值介于10至50之间。According to an embodiment of the present invention, the micro LED structure includes an epitaxial structure, a first insulating layer and a second insulating layer. The epitaxial structure includes a first type semiconductor layer, a light emitting layer and a second type semiconductor layer. The light emitting layer is located between the first type semiconductor layer and the second type semiconductor layer. The first type semiconductor layer, the light emitting layer and the first part of the second type semiconductor layer constitute a platform. The platform has a top surface and a first side surface. The second portion of the second-type semiconductor layer is recessed relative to the platform to form a platform surface. The second portion of the second type semiconductor layer has a second side surface. The platform surface is located between the first side surface and the second side surface. The first insulation layer covers from the top surface of the platform to the platform surface along the first side surface, and exposes the second side surface. The second insulating layer directly covers the second side surface, wherein a thickness ratio of the first insulating layer to the second insulating layer is between 10 and 50.
根据本发明的实施例,微型发光二极管结构包括磊晶结构、第一绝缘层以及第二绝缘层。磊晶结构包括第一型半导体层、发光层以及第二型半导体层。发光层位于第一型半导体层与第二型半导体层之间。第一型半导体层、发光层以及第二型半导体层的第一部分构成平台。平台具有顶面以及第一侧表面。第二型半导体层的第二部分相对于平台凹陷而形成平台面。第二型半导体层的第二部分具有第二侧表面。平台面位于第一侧表面与第二侧表面之间。第一绝缘层从平台的顶面沿着第一侧表面直接覆盖至平台面,且暴露出第二侧表面,其中覆盖第一侧表面的第一绝缘层与第二侧表面形成连续表面。第二绝缘层配置于第一绝缘层上,且直接覆盖连续表面,其中第一绝缘层与第二绝缘层直接接触。According to an embodiment of the present invention, the micro LED structure includes an epitaxial structure, a first insulating layer and a second insulating layer. The epitaxial structure includes a first type semiconductor layer, a light emitting layer and a second type semiconductor layer. The light emitting layer is located between the first type semiconductor layer and the second type semiconductor layer. The first type semiconductor layer, the light emitting layer and the first part of the second type semiconductor layer constitute a platform. The platform has a top surface and a first side surface. The second portion of the second-type semiconductor layer is recessed relative to the platform to form a platform surface. The second portion of the second type semiconductor layer has a second side surface. The platform surface is located between the first side surface and the second side surface. The first insulating layer directly covers the platform from the top surface of the platform along the first side surface and exposes the second side surface, wherein the first insulating layer covering the first side surface forms a continuous surface with the second side surface. The second insulating layer is disposed on the first insulating layer and directly covers the continuous surface, wherein the first insulating layer is in direct contact with the second insulating layer.
基于上述,在本发明的微型发光二极管结构的设计中,第一绝缘层从平台的顶面沿着第一侧表面覆盖至平台面,且暴露出第二型半导体层的第二部分的第二侧表面,而第二绝缘层直接覆盖此第二侧表面,其中第一绝缘层与第二绝缘层的厚度比值介于10至50之间。也就是说,厚度较厚的第一绝缘层不会延伸至基板上,可解决现有技术中剥离后的微型发光二极管的周围表面残留有外延绝缘层的问题,而厚度较薄且直接覆盖在第二侧表面上的第二绝缘层,可钝化第二侧表面,以提升发光效率。因此,本发明的微型发光二极管结构可具有较佳的结构可靠度与发光效率,同时改善整体制程良率。Based on the above, in the design of the micro light emitting diode structure of the present invention, the first insulating layer covers from the top surface of the platform to the platform surface along the first side surface, and exposes the second part of the second part of the second type semiconductor layer. side surface, and the second insulating layer directly covers the second side surface, wherein the thickness ratio of the first insulating layer to the second insulating layer is between 10 and 50. That is to say, the thicker first insulating layer will not extend to the substrate, which can solve the problem in the prior art that the epitaxial insulating layer remains on the surrounding surface of the stripped micro light emitting diode, while the thinner and directly covering the The second insulating layer on the second side surface can passivate the second side surface to improve luminous efficiency. Therefore, the micro light emitting diode structure of the present invention can have better structural reliability and luminous efficiency, while improving the overall process yield.
附图说明Description of drawings
图1是依照本发明的一实施例的一种微型发光二极管结构的剖面示意图;1 is a schematic cross-sectional view of a micro light emitting diode structure according to an embodiment of the present invention;
图2是依照本发明的另一实施例的一种微型发光二极管结构的剖面示意图;2 is a schematic cross-sectional view of a micro light emitting diode structure according to another embodiment of the present invention;
图3是依照本发明的另一实施例的一种微型发光二极管结构的剖面示意图;3 is a schematic cross-sectional view of a micro light emitting diode structure according to another embodiment of the present invention;
图4是依照本发明的另一实施例的一种微型发光二极管结构的剖面示意图;4 is a schematic cross-sectional view of a micro light emitting diode structure according to another embodiment of the present invention;
图5是依照本发明的另一实施例的一种微型发光二极管结构的剖面示意图;5 is a schematic cross-sectional view of a micro light emitting diode structure according to another embodiment of the present invention;
图6是依照本发明的另一实施例的一种微型发光二极管结构的剖面示意图;6 is a schematic cross-sectional view of a micro light emitting diode structure according to another embodiment of the present invention;
图7是依照本发明的另一实施例的一种微型发光二极管结构的剖面示意图;7 is a schematic cross-sectional view of a micro light emitting diode structure according to another embodiment of the present invention;
图8是依照本发明的另一实施例的一种微型发光二极管结构的剖面示意图;8 is a schematic cross-sectional view of a micro light emitting diode structure according to another embodiment of the present invention;
图9是依照本发明的另一实施例的一种微型发光二极管结构的剖面示意图;9 is a schematic cross-sectional view of a micro light emitting diode structure according to another embodiment of the present invention;
图10是依照本发明的另一实施例的一种微型发光二极管结构的剖面示意图。FIG. 10 is a schematic cross-sectional view of a micro LED structure according to another embodiment of the present invention.
附图标记说明Explanation of reference signs
100a、100b、100c、100d、100e、100f、100g、100h、100i、100j:微型发光二极管结构;100a, 100b, 100c, 100d, 100e, 100f, 100g, 100h, 100i, 100j: micro light emitting diode structure;
101:基板;101: substrate;
110:磊晶结构;110: epitaxy structure;
112:第一型半导体层;112: the first type semiconductor layer;
114:发光层;114: light-emitting layer;
116:第二型半导体层;116: the second type semiconductor layer;
117:第一部分;117: first part;
119:第二部分;119: the second part;
120a、120d:第一绝缘层;120a, 120d: the first insulating layer;
122:第一开口;122: first opening;
124:第二开口;124: second opening;
130a、130b、130c、130d、130e、130f、130g、130h、130i、130j:第二绝缘层;130a, 130b, 130c, 130d, 130e, 130f, 130g, 130h, 130i, 130j: second insulating layer;
131、133、135:膜层;131, 133, 135: film layer;
132e、132f:第三开口;132e, 132f: the third opening;
134e、134f:第四开口;134e, 134f: the fourth opening;
140a、140e、140f、140h:第一电极;140a, 140e, 140f, 140h: first electrodes;
150a、150d、150e、150f、150h:第二电极;150a, 150d, 150e, 150f, 150h: second electrodes;
160:电流分布层;160: current distribution layer;
170:贯孔;170: through hole;
B:底面;B: bottom surface;
CS:连续表面;CS: continuous surface;
D:平台面;D: platform surface;
G:距离;G: distance;
H:高度;H: height;
M:平台;M: platform;
P:平面;P: plane;
S1:第一侧表面;S1: first side surface;
S2、S2’:第二侧表面;S2, S2': the second side surface;
T、T1、T2:厚度;T, T1, T2: thickness;
U:顶面。U: top surface.
具体实施方式Detailed ways
现将详细地参考本发明的示范性实施例,示范性实施例的实例说明于附图中。只要有可能,相同元件符号在附图和描述中用来表示相同或相似部分。Reference will now be made in detail to the exemplary embodiments of the present invention, examples of which are illustrated in the accompanying drawings. Wherever possible, the same reference numbers will be used in the drawings and description to refer to the same or like parts.
图1是依照本发明的一实施例的一种微型发光二极管结构的剖面示意图。请参考图1,在本实施例中,微型发光二极管结构100a包括磊晶结构110、第一绝缘层120a以及第二绝缘层130a。磊晶结构110可配置于基板101上,且磊晶结构110包括第一型半导体层112、发光层114以及第二型半导体层116,其中发光层114位于第一型半导体层112与第二型半导体层116之间。第一型半导体层112、发光层114以及第二型半导体层116的第一部分117构成平台M。平台M具有顶面U以及第一侧表面S1,其中顶面U的延伸方向可垂直于第一侧表面S1的延伸方向。第二型半导体层116的第二部分119相对于平台M凹陷而形成平台面D,且第二型半导体层116的第二部分119具有第二侧表面S2,其中平台面D的延伸方向可垂直于第二侧表面S2的延伸方向。平台面D位于第一侧表面S1与第二侧表面S2之间,且平台面D可平行于顶面U。第一绝缘层120a从平台M的顶面U沿着第一侧表面S1覆盖至平台面D,且暴露出第二侧表面S2。第二绝缘层130a直接覆盖第二侧表面S2,其中第一绝缘层120a与第二绝缘层130a的厚度比值介于10至50之间。也就是说,本实施例的第一绝缘层120a没有覆盖在第二侧表面S2上,而第二侧表面S2也仅被第二绝缘层130a直接覆盖。FIG. 1 is a schematic cross-sectional view of a micro LED structure according to an embodiment of the present invention. Please refer to FIG. 1 , in the present embodiment, the
更进一步来说,在本实施例中,第一型半导体层112例如为P型半导体层,而发光层114例如是多重量子井(Multi Quantum Well,MWQ)结构,且第二型半导体层116例如为N型半导体层,但不以此为限。再者,本实施例的微型发光二极管结构100a还包括电流分布层160,配置于第一绝缘层120a与第一型半导体层112之间,其中电流分布层160与第一型半导体层112形成欧姆接触。于此,电流分布层160直接接触平台M的顶面U,且电流分布层160于顶面U上的正投影可等于顶面U,但不以此为限。电流分布层160的材质可例如是氧化铟锡、氧化铟、氧化锡、氧化铝锌、氧化镉锡、氧化锑锡、氧化锌或上述材料的组合。此处,平台M的厚度加上电流分布层160的厚度为高度H,其中高度H小于第二型半导体层116的第二部分119的厚度T。此处,高度H例如是1微米至2微米,而厚度T例如是3微米至5微米。Furthermore, in this embodiment, the first-
特别是,如图1所示,第一绝缘层120a直接覆盖平台面D,即平台面D仅接触第一绝缘层120a,且覆盖第一侧表面S1的第一绝缘层120a与第二侧表面S2形成连续表面CS。以剖面观之,此连续表面CS呈直线,例如是沿着基板101的法线方向延伸的直线,但不以此为限。第二绝缘层130a于连续表面CS直接覆盖第一绝缘层120a,并且沿着连续表面CS延伸覆盖至平台面D以及顶面U上的第一绝缘层120a,其中第二绝缘层130a的厚度T2小于第一绝缘层120a的厚度T1。此处,第一绝缘层120a的厚度T1例如是介于0.5微米至1微米之间,而第二绝缘层130a的厚度T2例如是介于20纳米至50纳米之间。于平台M与平台面D上,第一绝缘层120a与第二绝缘层130a呈共形设置,意即绝缘层的总厚度为第一绝缘层120a的厚度T1加上第二绝缘层130a的厚度T2,而于第二侧表面S2上,绝缘层的总厚度仅具有第二绝缘层130a的厚度T2。In particular, as shown in FIG. 1, the first insulating
再者,在本实施例中,第一绝缘层120a的材质实质上不同于第二绝缘层130a的材质。于一实施例中,第一绝缘层120a可例如为物理性沉积膜层,而第二绝缘层130a可例如为化学性沉积膜层。上述的物理性是指靶材(target)未经过化学反应,原材料直接借由外力等方式成膜在目标上;而化学性是指靶材在化学气体中或目标表面上经过反应,形成不同化合物并堆积成膜。于一实施例中,第一绝缘层120a与第二绝缘层130a可分别为单层膜层或多层膜层。于一实施例中,第一绝缘层120a可例如是利用溅镀沉积(Sputtering)形成的二氧化硅(SiO2)/二氧化钛(TiO2)交叠的分布式布拉格反射膜层,而第二绝缘层130a可例如是原子层沉积(Atomic Layer Deposition,ALD)镀膜的氧化铝(Al2O3)或二氧化铪(HfO2),或者是,化学气相沉积(Chemical vapor deposition,CVD)镀膜的二氧化硅(SiO2)/氮化硅(SiXNX)。当第二绝缘层130a采用原子层沉积或化学气相沉积来形成时,可具有较佳的阶梯覆盖(step coverage)覆盖于第二侧表面S2上,其中第二绝缘层130a的制程温度可略高于第一绝缘层120a的制程温度。于一实施例中,因制程与材料选择不同,第二绝缘层130a的致密度可高于第一绝缘层120a的致密度。Furthermore, in this embodiment, the material of the first insulating
如图1所示,本实施例较厚的第一绝缘层120a是直接覆盖在第一型半导体层112、发光层114以及第二型半导体层116的周围表面(即第一侧表面S1)上,可确保电性钝化的效果。再者,第二型半导体层116的第二部分119只直接覆盖厚度较薄的第二绝缘层130a,因此于进行激光剥离(LLO)程序时,沉积在基板上的第二绝缘层(未示出)会汽化或断裂,所以第二部分119的底部不会残留第二绝缘层130a。于此,第一绝缘层120a的设置除了具有电性隔绝的效果外,亦具有可将发光层114的光垂直反射至出光面的效果;而,较薄厚度的第二绝缘层130a直接覆盖在第二侧表面S2,因此第二绝缘层130a的设置可钝化第二侧表面S2,以减少非辐射复合的缺陷,进而可提高微型发光二极管结构100a的发光效率。简言之,本实施例的微型发光二极管结构100a同时具有厚度较厚的第一绝缘层120a与直接接触第一绝缘层120a且厚度较薄的第二绝缘层130a,可同时兼顾结构可靠度及转移良率。As shown in FIG. 1, the thicker first insulating
此外,请再参考图1,本实施例的微型发光二极管结构100a还包括第一电极140a以及第二电极150a。第一电极140a与第一型半导体层112电性连接。第二电极150a与第二型半导体层116电性连接,其中第一电极140a与部分第二电极150a位于同一平面P上。更详细来说,第一绝缘层120a以及第二绝缘层130a于顶面U暴露第一型半导体层112而形成第一开口122,并于平台面D暴露第二型半导体层116的第二部分119而形成第二开口124。第一电极140a配置于第一开口122内且延伸至第二绝缘层130a上。第二电极150a配置于第二绝缘层130a上且延伸至第二开口124内。因第二绝缘层130a在平台M及平台面D上与第一绝缘层120a呈共形设置,因此第二绝缘层130a亦会暴露出第一开口122所暴露出的电流分布层160以及第二开口124所暴露出的第二型半导体层116的第二部分119。In addition, please refer to FIG. 1 again, the
由于第一绝缘层120a从平台M的顶面U沿着第一侧表面S1覆盖至平台面D,且暴露出第二型半导体层116的第二部分119的第二侧表面S2,也就是说,第一绝缘层120a不会延伸至基板101上,因此可解决现有技术中剥离后的微型发光二极管的周围表面残留有外延绝缘层的问题,以避免对后续转移制程造成不良影响。此外,第一绝缘层120a与第二绝缘层130a的厚度比值介于10至50之间,表示较厚的第一绝缘层120a主要覆盖在发光层114的侧壁;而直接覆盖在第二侧表面S2上的第二绝缘层120a具有明显较薄的厚度,可钝化第二侧表面S2,以提升发光效率,并且不会影响微型发光二极管结构100a的后续转移步骤。Since the first insulating
在此必须说明的是,下述实施例沿用前述实施例的组件标号与部分内容,其中采用相同的标号来表示相同或近似的组件,并且省略了相同技术内容的说明。关于省略部分的说明可参考前述实施例,下述实施例不再重复赘述。It must be noted here that the following embodiments use the component numbers and partial content of the previous embodiments, wherein the same numbers are used to denote the same or similar components, and descriptions of the same technical content are omitted. For the description of omitted parts, reference may be made to the foregoing embodiments, and the following embodiments will not be repeated.
图2是依照本发明的另一实施例的一种微型发光二极管结构的剖面示意图。请同时参考图1及图2,本实施例的微型发光二极管结构100b与图1的微型发光二极管结构100a相似,两者的差异在于:本实施例的第二绝缘层130于第一开口122或第二开口124的位置处封闭第一绝缘层120a与部分电流分布层160上,以保护第一绝缘层120a。图2中示意地示出第二绝缘层130于第一开口122处的位置处封闭第一绝缘层120a,而其他未示出的实施例中,亦可以是第二绝缘层130于第二开口124处的位置处封闭第一绝缘层120a。此时,第一电极140a仅接触电流分布层160与第二绝缘层140a,而没有接触第一绝缘层120a。FIG. 2 is a schematic cross-sectional view of a micro LED structure according to another embodiment of the present invention. Please refer to FIG. 1 and FIG. 2 at the same time. The micro light emitting
图3是依照本发明的另一实施例的一种微型发光二极管结构的剖面示意图。请同时参考图1及图3,本实施例的微型发光二极管结构100c与图1的微型发光二极管结构100a相似,两者的差异在于:本实施例的第二绝缘层130c于第一开口122或第二开口124的位置处,相对于第一绝缘层120a内缩一距离G,以暴露出部分第一绝缘层120a,即暴露出较多的电流分布层160的接触面积来与第一电极140a接触,可具有较佳的欧姆接触。图3中示意地示出第二绝缘层130c于第一开口122的位置处相对于第一绝缘层120a内缩距离G,而其他未示出的实施例中,第二绝缘层130c也可以于第二开口124的位置处相对于第一绝缘层120a内缩距离G,使得第二型半导体层116的第二部分119(或未示出的另一电流分布层)可以完全暴露于第二开口124,以达到与第二电极150a更佳的欧姆接触。此处,第二绝缘层130c于磊晶结构110上的正投影不重叠于第一电极140a与电流分布层160的连接面于磊晶结构110上的正投影。FIG. 3 is a schematic cross-sectional view of a micro LED structure according to another embodiment of the present invention. Please refer to FIG. 1 and FIG. 3 at the same time. The micro light emitting
图4是依照本发明的另一实施例的一种微型发光二极管结构的剖面示意图。请同时参考图1及图4,本实施例的微型发光二极管结构100d与图1的微型发光二极管结构100a相似,两者的差异在于:在本实施例中,微型发光二极管结构100d还包括贯孔170,贯穿电流分布层160、第一型半导体层112、发光层114以及部分第二型半导体层116。第一绝缘层120d更延伸覆盖贯孔170的内壁,且第二电极150d延伸于贯孔170内与第二型半导体层116电性连接。此时,因第二绝缘层130d直接接触且共形于第一绝缘层120d,因此于第二开口124处,第二绝缘层130d也延伸至贯孔170内。FIG. 4 is a schematic cross-sectional view of a micro LED structure according to another embodiment of the present invention. Please refer to FIG. 1 and FIG. 4 at the same time. The
图5是依照本发明的另一实施例的一种微型发光二极管结构的剖面示意图。请同时参考图1及图5,本实施例的微型发光二极管结构100e与图1的微型发光二极管结构100a相似,两者的差异在于:在本实施例中,于平台M与平台面D上,部分的第二绝缘层130e没有直接接触第一绝缘层120a。详细来说,第一电极140e与第二电极150e位于第一绝缘层120a与第二绝缘层130e之间,意即第一电极140e与第二电极150e将第一绝缘层120a与第二绝缘层130e分隔开,可降低/避免后续焊料凸块溢流而造成第一电极140e与第二电极150e之间短路的机会。第二绝缘层130e是在形成第一电极140e与第二电极150e之后才形成,因此第二绝缘层130e可借由图形化蚀刻定义暴露出第一电极140e的第三开口132e以及暴露出第二电极150e的第四开口134e,以利后续焊料凸块可通过第三开口132e及第四开口134e分别与第一电极140e与第二电极150e电性连接。此处,微型发光二极管结构100e可例如是红色微型发光二极管结构。FIG. 5 is a schematic cross-sectional view of a micro LED structure according to another embodiment of the present invention. Please refer to FIG. 1 and FIG. 5 at the same time. The micro light emitting
图6是依照本发明的另一实施例的一种微型发光二极管结构的剖面示意图。请同时参考图4及图6,本实施例的微型发光二极管结构100f与图4的微型发光二极管结构100d相似,两者的差异在于:在本实施例中,于平台M与平台面D上,部分的第二绝缘层130f没有直接接触第一绝缘层120d。详细来说,第一电极140f与第二电极150f位于第一绝缘层120d与第二绝缘层130f之间,意即第一电极140f与第二电极150f将第一绝缘层120d与第二绝缘层130f分隔开,可降低/避免后续焊料凸块溢流而造成第一电极140f与第二电极150f之间短路的机会。在图6的实施例中,由于第二绝缘层130f是在形成第一电极140f与第二电极150f之后才形成,因此第二绝缘层130f没有延伸至贯孔170内,并且具有暴露出第一电极140f的第三开口132f以及暴露出第二电极150f的第四开口134f,以利后续焊料凸块可通过第三开口132f及第四开口134f分别与第一电极140f与第二电极150f电性连接。换言之,第二绝缘层130f于第一开口122以及第二开口124的位置处分别暴露出第一电极140f以及第二电极150f。此处,微型发光二极管结构100f可例如是红色微型发光二极管结构。FIG. 6 is a schematic cross-sectional view of a micro LED structure according to another embodiment of the present invention. Please refer to FIG. 4 and FIG. 6 at the same time. The micro light emitting
图7是依照本发明的另一实施例的一种微型发光二极管结构的剖面示意图。请同时参考图1及图7,本实施例的微型发光二极管结构100g与图1的微型发光二极管结构100a相似,两者的差异在于:在本实施例中,第一绝缘层120a与第二绝缘层130g至少其中的一者为分布式布拉格反射膜层。此处,第二绝缘层130g为分布式布拉格反射膜层,其包括交替堆栈且不同折射率的多个膜层131、133、135,可放大内部反射的临界角,以增加出光面的光萃取。膜层131、133、135可分别为氧化层或氮化物层,但不以此为限。膜层的厚度依据不同需求而设计,详细而言,依据薄膜干涉公式,膜厚d在建设性干涉下符合:2nfilm dcos(θ)=mλ;而当分布式布拉格反射膜层的设计需求为破坏性干涉时,表示膜层内的反射光被设计为存在相位差(此处未讨论发生相位反转的情况),则此时膜厚d符合其中,θ表示光线在膜层131、133、135等各层介质中入射到另一膜层的入射角度,n表示膜层的折射率,m表示任一正整数,λ表示发光层的发光波长。依据上述,膜厚d系取决于所选材料的折射率、以及针对微型发光二极管的出光角度范围的控制需求,并可借由上述薄膜干涉原理以实验方式来调整膜层131、133、135的厚度。由于薄膜干涉属于既有的光学知识,故此处不再深入说明。较佳地,每一膜层131、133、135的厚度可介于发光层114的发光波长的1/4倍至1/2倍之间,可改变微型发光二极管结构100g内部反射的路径,以减少光在内部的反射损耗。值得一提的是,于另一未示出的实施例中,亦可以是第一绝缘层为分布式布拉格反射膜层,或者是,第一绝缘层与第二绝缘层分别为分布式布拉格反射膜层,其中第一绝缘层中的膜层厚度可不同于第二绝缘层中的膜层厚度,上述仍属于本发明所欲保护的范围。FIG. 7 is a schematic cross-sectional view of a micro LED structure according to another embodiment of the present invention. Please refer to FIG. 1 and FIG. 7 at the same time. The micro light emitting
图8是依照本发明的另一实施例的一种微型发光二极管结构的剖面示意图。请同时参考图4及图8,本实施例的微型发光二极管结构100h与图4的微型发光二极管结构100d相似,两者的差异在于:在本实施例中,第二绝缘层130h不直接接触第一绝缘层120d。详细来说,第二型半导体层116的第二部分119更具有相对于平台面D的底面B,其中底面B可平行平台面D,且第二侧表面S2可垂直连接平台面D与底面B。第二绝缘层130h从第二侧表面S2延伸分布,并直接覆盖底面B,且第二绝缘层130h不重叠且不接触第一绝缘层120d。此时,第一绝缘层120d与第二绝缘层130h环绕磊晶结构110的周围表面,且于平台M与平台面D上仅具有第一绝缘层120d,而第二型半导体层116的第二部分119的底面B以及第二侧表面S2上仅具有第二绝缘层130h。第一电极140h直接接触第一绝缘层120d与电流分布层160,而第二电极150h直接接触第一绝缘层120d与被贯孔170所暴露出的第二型半导体层116。FIG. 8 is a schematic cross-sectional view of a micro LED structure according to another embodiment of the present invention. Please refer to FIG. 4 and FIG. 8 at the same time. The micro light emitting
图9是依照本发明的另一实施例的一种微型发光二极管结构的剖面示意图。请同时参考图8及图9,本实施例的微型发光二极管结构100i与图8的微型发光二极管结构100h相似,两者的差异在于:在本实施例中,第二绝缘层130i更延伸覆盖位于第一侧表面S1上的第一绝缘层120d,且与第一绝缘层120d在平台M的顶面U上齐平,因此于第一侧表面S1上,第一绝缘层120d与第二绝缘层130i直接接触。FIG. 9 is a schematic cross-sectional view of a micro LED structure according to another embodiment of the present invention. Please refer to FIG. 8 and FIG. 9 at the same time. The micro light emitting
图10是依照本发明的另一实施例的一种微型发光二极管结构的剖面示意图。请同时参考图1及图10,本实施例的微型发光二极管结构100j与图1的微型发光二极管结构100a相似,两者的差异在于:在本实施例中,第二绝缘层130j不直接接触第一绝缘层120a,且覆盖第一侧表面S1的第一绝缘层120a与第二侧表面S2’呈不连续面。详细来说,第二型半导体层116的第二部分119更具有相对于平台面D的底面B,其中底面B可平行平台面D,且第二侧表面S2’可倾斜连接平台面D与底面B。意即,第二侧表面S2’相对于底面B倾斜,可增加光反射,进而提升光出量。第二绝缘层130j直接覆盖第二侧表面S2’与底面B,且第二绝缘层130j不重叠且不接触第一绝缘层120a。此时,第一绝缘层120a与第二绝缘层130j环绕磊晶结构110的周围表面,且于平台M及平台面D上仅有第一绝缘层120a,而第二型半导体层116的第二部分119的底面B以及第二侧表面S2’上仅具有第二绝缘层130j。第一电极140j直接接触第一绝缘层120a与电流分布层160,而第二电极150j直接接触第一绝缘层120a与第二开口124所暴露出的第二型半导体层116。FIG. 10 is a schematic cross-sectional view of a micro LED structure according to another embodiment of the present invention. Please refer to FIG. 1 and FIG. 10 at the same time. The micro light emitting
值得一提的是,图8至图10的微型发光二极管结构中的第二绝缘层130h、130i、130j是从底面B朝向顶面U的方向延伸覆盖。在实际制程中,第二绝缘层130h、130i、130j与第一绝缘层120a、120d可以分别在不同的阶段形成。详细而言,第一绝缘层120a、120d是在磊晶晶圆上的制程阶段(chip on wafer)首先形成;而在图8至图10的实施例中,第二绝缘层130h、130i、130j是在微型发光二极管结构100h、100i、100j经过翻转而被转移到暂时性的承载基板后才形成,因此呈现与第一绝缘层120a、120d相对的覆盖方向。换言之,在磊晶晶圆上的制程阶段时,也可以仅形成第一绝缘层120a、120d,保留第二侧表面S2、S2’为暴露的状态。It is worth mentioning that the second insulating
在微型发光二极管结构100h、100i、100j翻转后,根据设计目的或是采取的成膜方法不同,第二绝缘层130h、130i、130j可以为多种实施态样。例如在图8中,第二绝缘层130h仅延伸覆盖至平台面D处;又如图9所示,第二绝缘层130i可以沿着连续表面CS继续覆盖,且最终与位在顶面U处的第一绝缘层120d齐平。另外,对于例如是图10的某些实施例而言,在转移制程后才形成的第二绝缘层130j也可以更好地覆盖倾斜的第二侧表面S2’,确保微型发光二极管结构100j的所有周围表面皆有良好的绝缘保护。After the miniature light emitting
如此一来,当转移微型发光二极管结构100h、100i、100j时,由于第二绝缘层130h、130i、130j尚未形成,因此可以完全避免激光剥离不完全所导致的残留问题。In this way, when the
综上所述,在本发明的微型发光二极管结构的设计中,第一绝缘层从平台的顶面沿着第一侧表面覆盖至平台面,且暴露出第二型半导体层的第二部分的第二侧表面,而第二绝缘层直接覆盖此第二侧表面,其中第一绝缘层与第二绝缘层的厚度比值介于10至50之间。也就是说,厚度较厚的第一绝缘层不会延伸至基板上,可解决现有技术中剥离后的微型发光二极管的周围表面残留有外延绝缘层的问题,而厚度较薄且直接覆盖在第二侧表面上的第二绝缘层,可钝化第二侧表面,以提升发光效率。因此,本发明的微型发光二极管结构可具有较佳的结构可靠度与发光效率。To sum up, in the design of the micro light emitting diode structure of the present invention, the first insulating layer covers from the top surface of the platform to the platform surface along the first side surface, and exposes the second part of the second type semiconductor layer. The second side surface, and the second insulating layer directly covers the second side surface, wherein the thickness ratio of the first insulating layer to the second insulating layer is between 10 and 50. That is to say, the thicker first insulating layer will not extend to the substrate, which can solve the problem in the prior art that the epitaxial insulating layer remains on the surrounding surface of the stripped micro light emitting diode, while the thinner and directly covering the The second insulating layer on the second side surface can passivate the second side surface to improve luminous efficiency. Therefore, the micro LED structure of the present invention can have better structural reliability and luminous efficiency.
最后应说明的是:以上各实施例仅用以说明本发明的技术方案,而非对其限制;尽管参照前述各实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分或者全部技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本发明各实施例技术方案的范围。Finally, it should be noted that: the above embodiments are only used to illustrate the technical solutions of the present invention, rather than limiting them; although the present invention has been described in detail with reference to the foregoing embodiments, those of ordinary skill in the art should understand that: It is still possible to modify the technical solutions described in the foregoing embodiments, or perform equivalent replacements for some or all of the technical features; and these modifications or replacements do not make the essence of the corresponding technical solutions deviate from the technical solutions of the various embodiments of the present invention. scope.
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