CN110556599A - Method for maintaining deteriorated battery in service process of energy storage battery pack - Google Patents

Method for maintaining deteriorated battery in service process of energy storage battery pack Download PDF

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CN110556599A
CN110556599A CN201910876028.4A CN201910876028A CN110556599A CN 110556599 A CN110556599 A CN 110556599A CN 201910876028 A CN201910876028 A CN 201910876028A CN 110556599 A CN110556599 A CN 110556599A
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energy
battery
energy storage
pack
capacity
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高云芳
徐新
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Zhejiang University of Technology ZJUT
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4207Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells for several batteries or cells simultaneously or sequentially
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Charge And Discharge Circuits For Batteries Or The Like (AREA)

Abstract

本发明公开了一种储能电池组服役过程中劣化电池的维护方法,过程如下:配制一系列不同电容量的能量包;在储能电池组的一个维护周期内,通过电池管理系统对正在运行的储能电池组中的一只或若干只劣化电池进行分析,获取所述劣化电池需要补充的电容量数据;若劣化电池需要补充的电容量达到其额定电容量的5%,则对劣化电池进行更换;若劣化电池需要补充的电容量小于其额定电容量的5%,则在储能电池组进行周期维护时,对劣化电池并联接入相对应电容量的能量包或能量包组合,所述能量包组合是由不同的能量包并联而成。本发明采用补充能量包的方法促使各单体电池的剩余能量趋于一致,使得各单体电池基本上同时放空、同时充满,提高系统储能效率。

The invention discloses a maintenance method for a deteriorated battery during service of an energy storage battery pack. The process is as follows: prepare a series of energy packs with different electric capacities; Analyze one or several degraded batteries in the energy storage battery pack, and obtain the electric capacity data that needs to be supplemented by the degraded battery; if the electric capacity to be supplemented by the degraded battery reaches 5% of its rated electric capacity, then Replace; if the capacity of the deteriorated battery to be supplemented is less than 5% of its rated capacity, during the periodic maintenance of the energy storage battery pack, connect the deteriorated battery in parallel with the energy pack or combination of energy packs with the corresponding capacity. The energy package combination is formed by connecting different energy packages in parallel. The invention adopts the method of supplementing the energy pack to make the residual energy of each single battery tend to be consistent, so that each single battery is basically emptied and fully charged at the same time, and the energy storage efficiency of the system is improved.

Description

一种储能电池组服役过程中劣化电池的维护方法A maintenance method for deteriorating batteries during service of an energy storage battery pack

技术领域technical field

本发明涉及一种储能电池组服役过程中劣化电池的维护方法。The invention relates to a maintenance method for a deteriorated battery during service of an energy storage battery pack.

背景技术Background technique

蓄电池在生产过程中因厂家技术、管理等因素影响,造成实际产品的性能存在一定的离散性。串联使用前一般通过筛选(所谓成组配对)把性能相近的蓄电池组合一起,使组合后的电池组平均放电容量达到单体电池最小平均放电容量值,以保证蓄电池组的性能及寿命。但经过若干充放电循环后,这种一致性不复存在,表现在单体电池间的剩余能量相差甚大。主要原因是电池内阻不一致及电池自放电造成的。电池内阻的变化与使用情况(温度、振动、电流、隔板性能)相关联的,每个电池的内阻差异是必然的,内阻不一致,热功率损失就不一样,同样电池自放电也各有差异,最终导致单体电池的剩余能量不一致。In the production process of the battery, due to factors such as manufacturer's technology and management, the performance of the actual product has a certain discreteness. Before being used in series, the batteries with similar performance are generally combined by screening (so-called group pairing), so that the average discharge capacity of the combined battery pack reaches the minimum average discharge capacity value of the single battery, so as to ensure the performance and life of the battery pack. However, after several charge-discharge cycles, this consistency no longer exists, which is manifested in the large difference in residual energy between single cells. The main reason is the inconsistent internal resistance of the battery and the self-discharge of the battery. The change of battery internal resistance is related to the usage (temperature, vibration, current, separator performance), the internal resistance difference of each battery is inevitable, the internal resistance is inconsistent, the thermal power loss is different, and the battery self-discharge is also Each is different, which eventually leads to inconsistency in the remaining energy of the single battery.

大规模储能电池系统中,电池性能差异更加明显。实际使用中,大规模的电池成组应用均配置电池管理系统 BMS ,通过BMS能采集电池组及单体电池的电压、温度等实时数据,并通过分析计算进行电池组热管理、SOC诊断、能量均衡等操作,提高电池组整体效率。In large-scale energy storage battery systems, the differences in battery performance are more obvious. In actual use, large-scale battery pack applications are equipped with battery management system BMS. Through BMS, real-time data such as voltage and temperature of battery packs and single cells can be collected, and battery pack thermal management, SOC diagnosis, and energy can be performed through analysis and calculation. Balance and other operations to improve the overall efficiency of the battery pack.

目前适合大规模、高容量电池组的均衡方式主要有二类:充电式,利用辅助电源对能量低的补充,向高的看齐。放电式,将能量高的放电,使其向低的看齐。由于充电式均衡对硬件要求高,且充电末期对电池补电效率低,实际效果不如充电式理想,现有电池均衡大都采用放电式。但放电式存在能量浪费,当电池组中存在特别劣化的单体电池时浪费更甚。At present, there are two main types of balancing methods suitable for large-scale, high-capacity battery packs: rechargeable, which uses auxiliary power to supplement low energy and align with high energy. Discharge type, discharge high energy to make it align with low energy. Due to the high hardware requirements of charging type equalization, and the low efficiency of battery replenishment at the end of charging, the actual effect is not as ideal as that of charging type. Most of the existing battery equalization uses discharge type. However, there is a waste of energy in the discharge type, and the waste is even worse when there are particularly deteriorated single cells in the battery pack.

发明内容SUMMARY OF THE INVENTION

针对现有技术存在的上述技术问题,本发明的目的在于提供一种储能电池组服役过程中劣化电池的维护方法。In view of the above technical problems existing in the prior art, the purpose of the present invention is to provide a maintenance method for the deteriorated battery during the service of the energy storage battery pack.

所述的一种储能电池组服役过程中劣化电池的维护方法,其特征在于包括以下步骤:The maintenance method for the deteriorated battery during the service process of the energy storage battery pack is characterized by comprising the following steps:

1)配制一系列不同电容量的能量包;1) Prepare a series of energy packs with different capacitances;

2)在储能电池组的一个维护周期内,通过电池管理系统对正在运行的储能电池组中的一只或若干只劣化电池进行分析,获取所述劣化电池需要补充的电容量数据;2) During a maintenance cycle of the energy storage battery pack, analyze one or several degraded batteries in the running energy storage battery pack through the battery management system, and obtain the electric capacity data that needs to be supplemented by the degraded battery;

3)若劣化电池需要补充的电容量达到其额定电容量的5%,则对劣化电池进行更换;若劣化电池需要补充的电容量小于其额定电容量的5%,则在储能电池组进行周期维护时,对劣化电池并联接入相对应的能量包或能量包组合,所述劣化电池需要补充的电容量与能量包或能量包组合的电容量相等,所述能量包组合是由若干能量包并联而成。3) If the capacity of the deteriorated battery to be supplemented reaches 5% of its rated capacity, the deteriorated battery shall be replaced; if the capacity of the deteriorated battery to be supplemented is less than 5% of its rated capacity, the battery shall be replaced in the energy storage battery pack. During periodic maintenance, the corresponding energy pack or combination of energy packs is connected in parallel to the degraded battery. The electric capacity that needs to be supplemented by the degraded battery is equal to the electric capacity of the energy pack or combination of energy packs. The combination of energy packs is composed of several energy packs. Packages are connected in parallel.

所述的一种储能电池组服役过程中劣化电池的维护方法,其特征在于步骤1)配制一系列不同电容量的能量包的过程为:以储能电池组中单只电池的额定电容量的1/10000记为C,所述C记为最小电容量;配制一系列电容量为1C、2C、5C、10C、20C、50C、100C的能量包。The method for maintaining a deteriorated battery during service of an energy storage battery pack is characterized in that in step 1) the process of preparing a series of energy packs with different electric capacities is: taking the rated electric capacity of a single battery in the energy storage battery pack 1/10000 of the 1/10000 is recorded as C, and the C is recorded as the minimum capacitance; a series of energy packs with capacitances of 1C, 2C, 5C, 10C, 20C, 50C, and 100C are prepared.

所述的一种储能电池组服役过程中劣化电池的维护方法,其特征在于步骤1)中,所述能量包由超级电容器、设置于超级电容器两端的插孔连接器以及设置于插孔连接器上的插片组成。The maintenance method for the deteriorated battery during the service of the energy storage battery pack is characterized in that in step 1), the energy pack is connected by a super capacitor, a jack connector arranged at both ends of the super capacitor, and a jack connector arranged on the jack. It consists of inserts on the device.

相对于现有技术,本发明取得的有益效果是:Compared with the prior art, the beneficial effects obtained by the present invention are:

(1)常规储能系统中,电池组放电受限于串联电池组中电压最低的电池,充电受限于电压最高的电池。充电时总有充不满的,放电时总有没法放空的。这就导致电池的“有效储能”总是低于“理论最大储能”。本发明采用补充能量包的方法促使各单体电池的剩余能量趋于一致,使得各单体电池基本上同时放空、同时充满,提高系统储能效率。(1) In a conventional energy storage system, the discharge of the battery pack is limited to the battery with the lowest voltage in the series battery pack, and the charging is limited to the battery with the highest voltage. When charging, there is always something that is not fully charged, and there is always something that cannot be emptied when discharging. This results in the "effective energy storage" of the battery being always lower than the "theoretical maximum energy storage". The invention adopts the method of supplementing the energy pack to make the residual energy of each single battery tend to be consistent, so that each single battery is basically emptied and fully charged at the same time, and the energy storage efficiency of the system is improved.

(2)采用本发明方法,能很好地避免因单只(或若干)电池性能落后或差异引起的电池组失效,最大程度延长电池组循环寿命。(2) By adopting the method of the present invention, the failure of the battery pack caused by the backward or different performance of a single (or several) batteries can be well avoided, and the cycle life of the battery pack can be extended to the greatest extent.

附图说明Description of drawings

图1为电池组及能量包的结构示意图;1 is a schematic structural diagram of a battery pack and an energy pack;

图2为能量包的结构示意图;Fig. 2 is the structural representation of the energy pack;

图中:1-电池组,2-能量包,201-超级电容器,202-插孔连接器,203-插片,3-劣化电池。In the picture: 1-battery pack, 2-energy pack, 201-supercapacitor, 202-jack connector, 203-insert, 3-degraded battery.

具体实施方式Detailed ways

下面结合具体实施例对本发明作进一步说明,但本发明的保护范围并不限于此。The present invention will be further described below with reference to specific embodiments, but the protection scope of the present invention is not limited thereto.

实施例1:Example 1:

一种储能电池组服役过程中劣化电池的维护方法,包括以下步骤:A maintenance method for a deteriorated battery during service of an energy storage battery pack, comprising the following steps:

1)配制一系列不同电容量的能量包;能量包的最小电容量为储能电池组中的单只电池额定电容量的1/10000,记为C。以此为基准,配置一系列电容量为1C、2C、5C、10C、20C、50C、100C的能量包。能量包的结构示意图如图2所示:能量包2是由超级电容器201、设置于超级电容器201两端的插孔连接器202以及设置于插孔连接器上的插片203组成,含不同超级电容器201的能量包2可以相互接插,能量包2相互插接并联能够形成不同电容量的能量包组合。1) Prepare a series of energy packs with different capacities; the minimum capacity of the energy pack is 1/10000 of the rated capacity of a single battery in the energy storage battery pack, denoted as C. Based on this, a series of energy packs with capacitances of 1C, 2C, 5C, 10C, 20C, 50C, and 100C are configured. The schematic diagram of the structure of the energy pack is shown in Figure 2: the energy pack 2 is composed of a supercapacitor 201, a jack connector 202 arranged at both ends of the supercapacitor 201, and a plug 203 arranged on the jack connector, including different supercapacitors. The energy packs 2 of 201 can be connected to each other, and the energy packs 2 can be connected to each other in parallel to form a combination of energy packs with different capacitances.

2)在储能电池组的一个维护周期内,通过电池管理系统对正在运行的储能电池组中的一只或若干只劣化电池进行分析,获取所述劣化电池需要补充的电容量数据(通过分析出劣化电池的实际电容量,则劣化电池需要进行补充的电容量=额定电容量-分析得到的实际电容量);2) During a maintenance cycle of the energy storage battery pack, use the battery management system to analyze one or several degraded batteries in the running energy storage battery pack, and obtain the capacity data that needs to be supplemented by the degraded batteries (via After analyzing the actual electric capacity of the deteriorated battery, the electric capacity that needs to be supplemented by the deteriorated battery = rated electric capacity - the actual electric capacity obtained by the analysis);

3)若劣化电池需要补充的电容量达到其额定电容量的5%(即劣化电池需要补充的电容量达到500C),则对劣化电池进行更换;若劣化电池需要补充的电容量小于其额定电容量的5%,则在储能电池组进行周期维护时,对劣化电池并联接入相对应的能量包或能量包组合,劣化电池需要补充的电容量与能量包或能量包组合的电容量相等。3) If the capacity of the deteriorated battery to be supplemented reaches 5% of its rated capacity (that is, the capacity of the deteriorated battery to be supplemented reaches 500C), replace the deteriorated battery; 5% of the capacity, then when the energy storage battery pack performs periodic maintenance, the degraded battery is connected in parallel with the corresponding energy pack or combination of energy packs. .

每个维护周期以上述方法对劣化电池进行能量包补充,如劣化电池需要补充的电容量为102C时,对劣化电池并联接入相对应的能量包组合是由一个100C的能量包和一个2C的能量包相互插接并联而成。In each maintenance cycle, the degraded battery is supplemented with energy packs by the above method. For example, when the capacity of the degraded battery to be supplemented is 102C, the corresponding energy pack combination for parallel connection of the degraded battery is composed of a 100C energy pack and a 2C energy pack. The energy packs are connected in parallel with each other.

其中,若需要补充的电容量达到500C以上,即该劣化电池相对电池组的其他电池的差异性达5%,该劣化电池进一步使用会使整个电池组的性能受损,此时应对该劣化电池直接进行更换新的电池。Among them, if the electric capacity that needs to be supplemented reaches more than 500C, that is, the difference between the degraded battery and other batteries in the battery pack is 5%, and further use of the degraded battery will damage the performance of the entire battery pack. At this time, the degraded battery should be dealt with. Just replace the battery with a new one.

本说明书所述的内容仅仅是对发明构思实现形式的列举,本发明的保护范围不应当被视为仅限于实施例所陈述的具体形式。The content described in this specification is only an enumeration of the realization forms of the inventive concept, and the protection scope of the present invention should not be regarded as being limited to the specific forms stated in the embodiments.

Claims (3)

1. A method for maintaining a degraded battery in the service process of an energy storage battery pack is characterized by comprising the following steps:
1) Preparing a series of energy packs with different capacitances;
2) In a maintenance cycle of the energy storage battery pack, analyzing one or more deteriorated batteries in the running energy storage battery pack through a battery management system to obtain electric capacity data which need to be supplemented by the deteriorated batteries;
3) If the capacity of the degraded battery which needs to be supplemented reaches 5% of the rated capacity, the degraded battery is replaced; if the electric capacity which needs to be supplemented by the degraded battery is less than 5% of the rated electric capacity of the degraded battery, when the energy storage battery pack is periodically maintained, the degraded battery is connected in parallel with a corresponding energy packet or energy packet combination, the electric capacity which needs to be supplemented by the degraded battery is equal to the electric capacity of the energy packet or the energy packet combination, and the energy packet combination is formed by connecting a plurality of energy packets in parallel.
2. The method of claim 1, wherein the step 1) of preparing a series of energy packs of different capacities comprises: recording 1/10000 of the rated capacity of a single battery in the energy storage battery pack as C, wherein the C is the minimum capacity; a series of energy packs with the capacitance of 1C, 2C, 5C, 10C, 20C, 50C and 100C are prepared.
3. the method according to claim 1, wherein in step 1), the energy pack comprises a super capacitor, receptacle connectors arranged at two ends of the super capacitor, and tabs arranged on the receptacle connectors.
CN201910876028.4A 2019-09-17 2019-09-17 Method for maintaining deteriorated battery in service process of energy storage battery pack Pending CN110556599A (en)

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