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ANALISIS SIFAT MEKANIK KOMPOSIT Al 2075 REINFORCEMENT DENGAN ELECTROLESS ABU DASAR BATUBARA Setiawan, Adhi; Nilasari, Arita Rochma; Ari, M.
Journal of Research and Technology Vol 2, No 2 (2016)
Publisher : Universitas Nahdlatul Ulama Sidoarjo

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (131.711 KB) | DOI: 10.5281/zenodo.2581996

Abstract

Aluminium composite 2075 manufacturing required a strenghthener such as bottom ash which has been through the electroless plating process that serves coating the bottom ash and sticks to aluminium casting process. The oxidation of 100oC produce 0,0126 µm Mg thickness oxidation, 200oC produce 0,0146 µm Mg thickness oxidation, and 300oC produces 0,0506 µm Mg thickness oxidation. Mechanical properties were tested by using worn-out test and hardness test based on new material function that will be used to replace existing disc brake material. Harness test showed that castings are using oxidized ash powder with higher temperature and produce resistant material than in low temperature. Casting mixture with oxidized bottom ash 100oC produce specific abrasion of 2,008 x 10-6 mm2/kg, produce of 1,814 x 10-6 mm2/kg for oxidized 200oC, and produce of 1,675 x 10-6 mm2/kg for oxidized 300oC.
ANALISIS POTENSI DAN DAMPAK KEBOCORAN GAS HIDROGEN PADA HYDROGEN PLANT DI INDUSTRI PELUMAS Setiawan, Adhi; Hanifah, Dian Nur; Nugroho, Agung; Dermawan, Denny
Journal of Research and Technology Vol 3, No 2 (2017)
Publisher : Universitas Nahdlatul Ulama Sidoarjo

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (402.575 KB) | DOI: 10.5281/zenodo.2581773

Abstract

Increasing the need for pure hydrogen in the industry is growing. One of its roles is in purification of petroleum industry. High purity hydrogen (99.99%) was obtained from methane using the steam methane reforming method in the hydrogen plant unit. Hydrogen is a very dangerous chemical element with its flammable properties. This research is conducted especially on purification system. Quantitative analysis is used to determine the frequency of hydrogen leakage, consequence modeling, and risk estimation that will be generated. The results of the analysis show that the highest frequency occurs in unignited release events. The jet fire scenario produces the longest fire length in the HPU about 27 meters. The jet fire scenario impact produces the farthest secure distance in the case of a leak in the HPU section of 60 meters. The flash fire produces the farthest distance loss in a leakage case in the HPU of 80 meters, and explosion at a radius of 200 meters will have a blast overpressure 7.62 psig with 22% fatality estimation of the population.
KOROSI BAJA KARBON API 5L GRADE B SEBAGAI FLOWLINE PRODUKSI GAS ALAM Setiawan, Adhi; Fajrin, Alfinura; Munir, M. Miftahul; Ari, M.
Journal of Research and Technology Vol 4, No 1 (2018)
Publisher : Universitas Nahdlatul Ulama Sidoarjo

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (948.636 KB) | DOI: 10.5281/zenodo.2580434

Abstract

Corrosion that occurs in a gas flowline is a serious problem because it can cause leaks that lead to material loss and environmental pollution. The aims of this research were to analyze the corrosion occurred in gas flowline of carbon steel 5l Grade B and the effect of inhibitor TIC-8002 GCI to the corrosion rate of metal. This research was conducted using SEM-EDX to analyze and produce various types of metals and corrosion crust. Metals corrosion test and the effect of inhibitors on the corrosion rate of metals were carried out by linear polarization methods. The result of SEM-EDX showed that inner pipe surface occurred pitting corrosion caused by dissolved chloride ions in the electrolite that flows in the pipeline. The result of XRD showed that corrosion products of carbon steel were Fe2O3 and FeOOH. The result of linear polarization showed that the corrosion rate of steel about 0.642 mmy without using inhibitor. The addition of an inhibitor can reduce the corrosion rate in carbon steel. The increase in inhibitor concentration from 10 ppm to 50 ppm can reduce the corrosion rate from 0.633 mmy to 0.394 mmy along with an increase in inhibition efficiency from 1.32% to 38.6%.
ANALISIS REMOVAL SCALING SILIKA PADA JALUR RE-INJEKSI BRINE PEMBANGKIT LISTRIK ENERGI PANAS BUMI DENGAN MENGGUNAKAN ASAM FLUORIDA Setiawan, Adhi; Saputro, Deris Eko; Nugroho, Agung
Journal of Research and Technology Vol 3, No 1 (2017)
Publisher : Universitas Nahdlatul Ulama Sidoarjo

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (537.228 KB) | DOI: 10.5281/zenodo.2581843

Abstract

Silica scale formation on the brine re-injection lines of geothermal power plants can lead to serious problems because it increased pressure drop and failure of the safety devices. One of the most effective methods to solve the problem is acidification of silica scaling using hydroflouric acid (HF). HF has a unique characteristic that is highly reactive with SiO2, easily obtained in the market and cheap. The use of HF can increase the rate of material corrosion in re-injection lines material. The use of HF should be adjusted to the appropriate concentration so it can dissolve silica scale optimally without shortening its life service. The concentration of HF used in the experiment were 5, 10, and 15% wt. The results showed that the optimum concentration of HF in dissolving silica at 15%. This is due to its ability to dissolve the crust mostly greatest than most other concentration that is equal to 21% of the total dissolved silica. The rate of corrosion on the material re-injection line with a concentration of 15% is equal to 0.647 mm/y and provide about 4.63 years life time of pipe.
Sintesis dan Karakterisasi ZnO sebagai Coating Antikorosi ZnO/Al(OH)3 Pada Material Baja Karbon Setiawan, Adhi
TEKNIK Vol 39, No 1 (2018): (July 2018)
Publisher : Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (929.895 KB) | DOI: 10.14710/teknik.v39i1.15659

Abstract

ZnO seringkali digunakan sebagai aplikasi pigmen anti korosi pada logam karena tidak beracun, ramah lingkungan, murah serta memiliki ketahanan korosi yang relatif baik. Partikel ZnO dalam penelitian ini disintesis dengan menggunakan metode presipitasi dengan ZnCl2 dan NaOH sebagai prekursor. Partikel ZnO yang dihasilkan dengan metode tersebut memiliki morfologi berbentuk batang dengan ujung lancip. Hasil SEM menunjukkan bahwa semakin rendah konsentrasi NaOH maka ukuran partikel ZnO yang dihasilkan akan semakin kecil. Pada konsentrasi NaOH sebesar 0,5 M dihasilkan ZnO dengan ukuran terkecil sebesar 123 nm. Hasil XRD menunjukkan bahwa ZnO memiliki kristalinitas tinggi dengan ukuran kristal mencapai 47 nm pada konsentrasi NaOH sebesar 0,5 M. Penggunaan pigmen ZnO/Al(OH)3 menunjukkan ketahanan korosi yang baik pada larutan NaCl 3,5% dengan specimen baja karbon. Hasil penelitian menunjukkan bahwa pada komposisi ZnO/Al(OH)3 sebesar 1:3 memiliki ketahanan korosi yang terbaik karena memberikan nilai laju korosi terendah yaitu sebesar 0,86 mpy.
Analisis Proximate Briket Tempurung Kelapa dan Ampas Tebu Setiani, Vivin; Setiawan, Adhi; Dhani, Mey Rohma; Maulidya, Risya Dwi
Jurnal Presipitasi : Media Komunikasi dan Pengembangan Teknik Lingkungan Vol 16, No 2 (2019): Juli 2019
Publisher : Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (328.318 KB) | DOI: 10.14710/presipitasi.v16i2.91-96

Abstract

Fossil fuels are a non-renewable energy source and their existence will be depleted. An alternative is needed that can reduce fossil fuels by using biomass. Biomass waste in the form of bagasse and coconut shell can be used as an alternative fuel in the form of biobriquette. This study aims to analyze the quality value of briquettes from the proximate test of the composition of bagasse and coconut shell produced with briquette quality standards that refer to SNI 01-6235-2000 about wood charcoal briquettes. The variables in this study consisted of five variables. The variables in this study were mass ratio coconut shells to bagasse were 90%: 10%, 80%: 20%, 70%; 30%, 60%: 40% and 50%: 50% respectively. The results of the test of water content, ash content, and volatile matter of the best quality briquettes of five variables were 90% coconut shell and 10% bagasse.
Biosorpsi Logam Berat Cu(II) Menggunakan Limbah Saccharomyces Cereviseae Setiawan, Adhi; Basyiruddin, Fariz; Dermawan, Denny
Jurnal Presipitasi : Media Komunikasi dan Pengembangan Teknik Lingkungan Vol 16, No 1 (2019): Maret 2019
Publisher : Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (765.095 KB) | DOI: 10.14710/presipitasi.v16i1.29-35

Abstract

Biosorpsi merupakan salah satu jenis bentuk pengolahan limbah logam berat dengan menggunakan mikroorganisme, seperti bakteri, alga dan ragi (yeast). Penelitian ini  menggunakan ragi (yeast) dari industri bir. Proses preparasi biosorben meliputi pengendapkan, pengeringan, dan pengayakan untuk memperoleh ukuran homogen. Biosorben yang terbentuk kemudian dikontakkan dengan larutan Cu (II) dengan konsentrasi 25 mg/L dan diteliti pengaruh pH (3, 4, 5), waktu kontak (1, 2, 3 jam) dan berat biosorben (0,25, 0,5, 0,75 gr) terhadap kemampuan biosorben dalam menurunkan konsentrasi logam Cu. Selanjutnya pada persen removal tertinggi dilakukan regenerasi menggunakan HNO3. Konsentrasi Cu yang setelah biosorpsi diuji menggunakan spektrofotometer Uv-Vis. Hasil penelitian menunjukkan bahwa pada pH 5, waktu kontak 1 jam dan berat biosorben 0,75 gr memiliki persen removal yang tertinggi yaitu sebesar 55,36%. Biosorben yang telah diregenerasi mengalami penurunan persen removal logam Cu (II) dari 55,36% menjadi 48,2%.
PENGARUH TREATMENT ALKALI TERHADAP KARAKTERISTIK FIBER SABUT KELAPA SAWIT DAN PELEPAH PISANG SEBAGAI BAHAN KOMPOSIT POLIMER Setiawan, Adhi; Setiani, Vivin; Hardiyanti, Fitri; Puspitasari, Devina
Journal of Research and Technology Vol 5, No 2 (2019)
Publisher : Universitas Nahdlatul Ulama Sidoarjo

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Abstract

The use of synthetic fibers in the fabrication of polymer composite materials has a negative impact on the environment. Natural fibers such as palm oil waste and banana pseudostem can be an alternative material for synthetic fibers because they are more economical, high specific strength, and environmentally friendly. The alkali treatment needs to be carried out on fibers for removal of lignin, hemicellulose, and impurity so that they can improve interfacial bonding between the fiber and the polymer matrix. The alkali treatment was carried out through fiber immersion in conditions without NaOH, 5% wt NaOH solution, and 10% wt for 24 hours. Fiber before and after alkalization were analyzed using Scanning Electron Microscope (SEM), X-Ray Difraction (XRD), Fourier Transform Infrared (FTIR), and Thermogravimetric  Analysis (TGA) methods. The results showed that alkali treatment was effective in removing the components of lignin, hemicellulose, and impurities in fiber. The result of the SEM was showed that the treated fiber surface has a cleaner surface than treatment without fiber. The alkali treatment process can improve the crystallinity and crystallinity index of the fiber due to amorphous component removal of lignin and hemicellulose. The TGA showed that palm oil fiber with alkali treatment and without alkali treatment a produced weight loss of 88,2% and 98,4% respectively. This showed that the alkali treatment can increase the thermal resistance of the palm oil fiber.
Sintesis dan Karakterisasi Zeolit dari Abu Bagasse Sebagai Adsorben Logam Berat Cu(II) Setiawan, Adhi; Hanun, Jihan Nabillah; Afiuddin, Ahmad Erlan
Jurnal Presipitasi : Media Komunikasi dan Pengembangan Teknik Lingkungan Vol 17, No 1 (2020): Maret 2020
Publisher : Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1051.515 KB) | DOI: 10.14710/presipitasi.v17i1.85-95

Abstract

The relatively high silica content in bagasse ash can be used as raw material for making zeolite. Zeolite can be used as a heavy metal adsorbent in industrial wastewater treatment. This study aims to synthesize zeolite from bagasse ash and to apply zeolite as an adsorbent of Cu(II) in a continuous system reactor. The effects of contact time, zeolite size, and concentration of Cu(II) solution on the removal efficiency of metals have been studied in this research. The synthesis of zeolite was carried out using the hydrothermal method at 100°C for 7 hours. The synthesized zeolite was characterized using SEM-EDX, XRD, FTIR, and BET The adsorption process was carried out using a continuous reactor with a flow rate of 0.4 L/min and flowed for 60 minutes with sampling at 15-minute intervals. The zeolite size used was 100 and 200 mesh. The results of SEM-EDX analysis showed that Zeolite has an irregular morphology and contains Si at 35.15%. The XRD results show that the zeolite crystallinity is relatively low. The specific surface area of zeolite at size 100 mesh and 200 mesh were 439.48 m2 /g and 697.76 m2/g respectively. The best Cu(II) waste adsorption test results were obtained under zeolite conditions with a particle size of 200 mesh, the concentration of Cu(II) wastewater of 25 mg/L, and an operational time of 60 minutes with a removal efficiency of Cu(II) of 41.57%
Pengolahan Logam Pb(II) pada Limbah Cair Menggunakan Metode Kombinasi Elektrokoagulasi−Adsorpsi Karbon Aktif Setiawan, Adhi; Ramadani, Tarikh Azis; Hanastasia, Rizka Lutfita
Jurnal Presipitasi : Media Komunikasi dan Pengembangan Teknik Lingkungan Vol 17, No 2 (2020): Juli 2020
Publisher : Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (548.925 KB) | DOI: 10.14710/presipitasi.v17i2.96-103

Abstract

Logam berat Pb(II) merupakan jenis polutan yang menyebabkan pencemaran air serta berdampak terhadap kerusakan ekosistem. Limbah logam Pb(II) bersifat racun serta biomagnifikasi sehingga berdampak negatif terhadap kesehatan manusia. Kombinasi proses elektrokoagulasi dan adsorpsi merupakan salah satu alternatif yang efisien serta efektif dalam menghilangkan logam Pb(II) di dalam air limbah. Pada penelitian ini, proses pengolahan air limbah dilakukan secara batch menggunakan elektrokoagulasi dengan elektroda aluminium dan dilanjutkan dengan adsorpsi karbon aktif. Penelitian ini bertujuan menganalisis pengaruh tegangan elektrokoagulasi, waktu kontak adsorpsi, dan dosis adsorben terhadap penurunan konsentrasi Pb(II). Proses elektrokoagulasi dan adsorpsi menggunakan variasi tegangan (10, 20, 30 V), waktu adsorpsi (15, 30, 45 menit), serta dosis adsorben (2,5, 3,3, 4,1, 5 g/L). Hasil penelitian menunjukkan bahwa kombinasi elektrokoagulasi dan adsorpsi dapat menurunkan konsentrasi Pb(II) dalam air limbah secara signifikan. Peningkatan tegangan listrik, waktu adsorpsi, dan dosis adsorben menyebabkan meningkatnya efisiensi penyisihan Pb(II). Efisiensi penyisihan logam Pb(II) maksimal diperoleh pada kondisi tegangan 30 V, waktu adsorpsi 45 menit, serta dosis adsorben 5 g/L. Pada kondisi tersebut diperoleh efisiensi penyisihan Pb(II) sebesar 96,01%.
Co-Authors Achmad Fatoni Agung Nugroho Agung Nugroho Agung Nugroho Agung Nugroho Agung Nugroho Ahmad Erlan Afiuddin Aisyah Nur Rahmadania Alfinura Fajrin Amilia Kristina Dewi Ananda Augista Firtsanti Anggara Trisna Nugraha Anggraini, Febby Dwi Melanny Ari, M. Arianingtyas, Nadya Ayu Arita Rochma Nilasari Azzahro, Annisa Basyiruddin, Fariz Bawafi, Muhammad Iqbal Ali Cahyono, Luqman Catur Rini Widyastuti, Catur Rini Chelvin Sugiarto Citra Eripramita Yunus Denny Dermawan Denny Dermawan Deris Eko Saputro Devina Puspitasari Devina Puspitasari Dewi, Tanti Utami Utami Dhani, Mey Rohma Dian Nur Hanifah Dika R. Widiana Dwi Rasy Mujiyanti Dzulfikar, Muhammad Hanif Endang Pudji Purwanti Fajrin, Alfinura Falenia Firdatul Jannah Fariha, Chandra Nur Firnandi, Rahmad Fitri Hardiyanti Gunawan, Karina Larasati Hanastasia, Rizka Lutfita Hanifah, Dian Nur Hanifah, Dian Nur Hanoni Hanun, Jihan Nabillah Inayatul Wulandari Indri Santiasih Lintang Indra Liuqil Mahfudz Luqman Cahyono M. Ari M. Miftahul Munir Maulidya, Risya Dwi Mirna Apriani Mochamad Yusuf Santoso Mochammad Choirul Rizal Muhamad Ari Muhamad Ari Muhammad Asrul Nizam Muhammad Luqman Ashari Mukhlis Mukhlis Munir, M. Miftahul Nilasari, Arita Rochma Nora Amelia Novitrie Novi Eka Mayangsari Novitrie, Nora Amelia Nugroho, Agung Nurhidayati, Dyah Isna Pawitra, Tiane Prianto, Haekal Irfan Titan Prima Astuti Handayani Priyambodo N. A. Nugroho Puguh Pribadhi Puspitasari, Devina Putri, Desita Ramadona Syah Qurrotul Aini Rahmawati, Devi Ayu Rizki Medy Prasetyo Rizki Noviana Damayanti Saputro, Deris Eko Satriavi, Aulia Diva Setiani, Vivin Siti Muthi’ah Tanti Utami Dewi Tarikh Azis Ramadani Tri Bagus Setiawan Utomo, Agung Prasetyo Vira Fadilah Qurani Vivin Setiani Vivin Setiani Widiyastuti Widiyastuti Widiyastuti Widiyastuti Winardi, Sugeng Wiwik Dwi Pratiwi