WO2016066382A1 - A water purifier and a process of cleaning the membrane - Google Patents

A water purifier and a process of cleaning the membrane Download PDF

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Publication number
WO2016066382A1
WO2016066382A1 PCT/EP2015/073029 EP2015073029W WO2016066382A1 WO 2016066382 A1 WO2016066382 A1 WO 2016066382A1 EP 2015073029 W EP2015073029 W EP 2015073029W WO 2016066382 A1 WO2016066382 A1 WO 2016066382A1
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WIPO (PCT)
Prior art keywords
water
valve
membrane module
pump
membrane
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Ceased
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PCT/EP2015/073029
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French (fr)
Inventor
Jaideep Chatterjee
Shailendra Pratap
Senthilmurugan Subbiah
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Unilever NV
Conopco Inc
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Unilever NV
Conopco Inc
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Publication of WO2016066382A1 publication Critical patent/WO2016066382A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D65/00Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/02Membrane cleaning or sterilisation ; Membrane regeneration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/04Feed pretreatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/12Controlling or regulating
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2311/00Details relating to membrane separation process operations and control
    • B01D2311/04Specific process operations in the feed stream; Feed pretreatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2313/00Details relating to membrane modules or apparatus
    • B01D2313/24Specific pressurizing or depressurizing means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2313/00Details relating to membrane modules or apparatus
    • B01D2313/48Mechanisms for switching between regular separation operations and washing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2313/00Details relating to membrane modules or apparatus
    • B01D2313/50Specific extra tanks
    • B01D2313/501Permeate storage tanks
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/04Backflushing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/40Automatic control of cleaning processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/442Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by nanofiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/06Contaminated groundwater or leachate
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/002Construction details of the apparatus
    • C02F2201/005Valves
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/003Downstream control, i.e. outlet monitoring, e.g. to check the treating agents, such as halogens or ozone, leaving the process
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/03Pressure
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/42Liquid level
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/44Time
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/06Pressure conditions
    • C02F2301/066Overpressure, high pressure
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/16Regeneration of sorbents, filters

Definitions

  • the present invention relates to a water purifier and a process of cleaning the membrane. Particularly the invention relates to a process for enhancing the recovery of purified water by a process of cleaning the membrane module.
  • Water purifiers based on membrane module systems is the most popular technology for water purification as it can remove biological, colloidal, organic and dissolved salts from water.
  • the main drawback of such purifiers is that for example more than 50 % of the input water cannot be recovered and is rejected during the purification process such as by reverse osmosis.
  • the process of water purification by reverse osmosis and similarly other membrane module based systems involve extracting pure water with no or minimal dissolved salts from an input water which contains a significantly higher level of dissolved salts and may contain other impurities like dissolved organic compounds as well as colloids and microorganisms.
  • the reverse osmosis process produces concentrated reject water, which has a significantly higher salt concentration compared to the input water. Higher the recovery of pure water the higher is the concentration of the dissolved salts in the reject.
  • water purification by reverse osmosis necessarily produces a concentrate water stream which is wasted and it would be highly beneficial to reduce this water wastage.
  • EP 07681 12 A1 shows that the permeate can be used to clean the membrane by flowing the permeate backwards through the membrane.
  • the driving force for the permeate is the osmotic pressure difference between the permeate and the water on the reject side of the membrane. This method however is time consuming as it is based on the natural principal of difference in osmotic pressure.
  • JP 201 1 1 10439 shows that the permeate can be used to backwash the membrane module, by using a second pump to pump the permeate in the reverse direction.
  • This system thus requires a second pump and additional instrumentation for powering and controlling the same.
  • US3786924 B1 (Delro Inc, 1974) discloses a reverse osmosis unit further having a concentrate outlet which is upstream from the membrane structure in fluid communication with the feed water inlet. In such a configuration, the concentrate outlet point is upstream of the membrane module when the system is in operation.
  • the permeate holding chamber has at least one valve upstream of the chamber and two valves and downstream of the chamber, which makes the system a bit complicated.
  • DE10302014 A1 and EP07681 12 A1 both disclose a separate chamber for holding a part of the permeate to be used for backwashing. There is a branch line to the backwash permeate tank with associated valve system. Therefore, there is a need to provide an efficient device and a process for cleaning a water purifier membrane which works faster than the dynamics of cleaning based on osmotic pressure difference.
  • the object of the present invention is also to provide a process for cleaning membrane module in a membrane based water purifier.
  • Another object of the present invention is to enhance recovery of purified water.
  • Yet another object of the present invention is to provide a process for enhancing the life of a water purifier membrane.
  • Another object of the present invention is to provide a process for cleaning a water purifier membrane module by avoiding the use of an additional mechanical fluid pressurizing device such as a pump for backwash cleaning and thus reducing power consumption.
  • Yet another object is to provide a process to reduce scaling and fouling of the membrane module and yet achieve higher purified water recovery.
  • a water purifier comprising, a pump; a membrane module where the membrane is spiral wound membrane including reverse osmosis, nanofilter, ultrafilter and microfilter membranes; a first valve to control the water flow into the membrane module; and a permeate line for purified water and a reject line for discarded water; wherein the reject line comprises a valve; and wherein the water purifier comprises a closed chamber and a second valve in sequence downstream the membrane module in the permeate line and wherein said reject line is downstream of said membrane module.
  • a process for cleaning the membrane module of a water purifier comprising, a pump; a membrane module where the membrane is spiral wound membrane including reverse osmosis, nanofilter, ultrafilter and microfilter membranes; a first valve to control the water flow into the membrane module; and a permeate line for purified water and a reject line for discarded water; wherein the reject line comprises a valve; and wherein the water purifier comprises a closed chamber and a second valve in sequence downstream the membrane module in the permeate line and wherein said reject line is downstream of said membrane module; said process comprising, operating the purifier with the pump powered and the first and second valves open; closing the second valve to initiate shut-down of the purifier and to allow a pressure build up in the closed chamber; allowing the pump to continue operation with the first valve open; and shutting off the pump and the first valve to force purified water in the closed chamber through the membrane module in the reverse direction until the pressure in the closed chamber dissipates to ⁇ 1 psig
  • the present invention relates to a water purifier and a process for cleaning the membrane.
  • the invention also provides a method for enhancing the recovery of purified water by the process of cleaning the membrane module.
  • the membrane can be fouled by bio-films, organics or colloids deposited on its surface.
  • scales which are usually deposits of calcium salts on the membrane surface. This leads to a decline in the flow of permeate as well as the total flow through the system. This may lead to an increase in pure water recovery due to a higher drop in the reject water flow rate, leading to a higher salt flux through the membrane. This also leads to an increase in the concentration of salt in the pure water.
  • concentration of salt in the same demonstrates that the membrane surfaces are clean and the system is operated optimally.
  • the present invention provides a membrane based water purifier with a membrane cleaning apparatus and a membrane cleaning process thereof.
  • the word 'control' is used in a general sense of the word to describe the apparatus or device or process which connotes the experimental control which is similar to the device and the process of the present invention but without the key features and proposition which is/are tested.
  • the term 'closed chamber' preferably refers to the chamber downstream the membrane module and upstream the second valve where the purified water flows in from the membrane module and which is closed to enable the pressure to build up in the chamber.
  • 'reverse direction' means the flow of water in the direction opposite to that of the flow of the purified water or opposite to the direction of flow of the permeate in the permeate line from the water purification device.
  • the term 'reject line' means the line for flow of waste water or discarded water from the water purification device.
  • 'permeate line' means the line for flow of purified water recovered from the water purification device.
  • the present invention provides a water purifier comprising, a pump; a membrane module; a first valve to control the water flow into the membrane module where the membrane is spiral wound membrane including reverse osmosis, nanofilter, ultrafilter and microfilter membranes; and a permeate line for purified water and a reject line for discarded water; wherein the reject line comprises a valve; and wherein the water purifier comprises a closed chamber and a second valve in sequence downstream the membrane module in the permeate line and wherein said reject line is downstream of said membrane module.
  • a preferred embodiment of the present invention provides a water purifier (200) comprising, a pump (203); a membrane module (205); a first valve (204) to control the water flow into the membrane module (205); and a permeate line (206) for purified water and a reject line (207) for discarded water; wherein the reject line (207) comprises a valve (208); and wherein the water purifier (200) comprises a closed chamber (209) and a second valve (210) in sequence downstream the membrane module (205) in the permeate line (206) and wherein said reject line is downstream of said membrane module.
  • the inlet water enters a spiral wound filter at one end and exits through the other end. During its journey from the one end to the other end, the water slows down, as some fraction of it permeates into the central core of the filter element. The water in the membrane outside the core gets concentrated significantly during this journey. Hence the end of the membrane near the other end, it is significantly more fouled with scale than the end at which it enters.
  • the water purifier and process in accordance with the invention is configured such the maximum pressure of the permeate used for backwash is available at the other end where the scaling is the maximum.
  • the pump may be selected from the standard types of commercially available pumps and preferably from a positive displacement pump.
  • the water purifier has the valve selected from on-off, solenoid or throttle type valve. More preferably the first and second valves are solenoid type valve and the valve provided at the reject line is a throttle type valve.
  • the membrane is spiral wound membrane modules including reverse osmosis, nanofilter, ultrafilter and microfilter membranes.
  • the first valve is operably connected to pump such that the first valve is open when the pump is powered and closed when the pump is switched off.
  • the water purifier comprises volume sensor operably connected to the second valve and the output of purified water from the permeate line.
  • the water purifier comprises a pressure switch operably connected to the closed chamber and the pump. Any standard type pressure switch can be employed.
  • the water purifier comprises a timer operably connected to the second valve and the pump.
  • An embodiment of the present invention provides a method of purifying water using the water purifier of the invention.
  • the present invention also provides for a process for cleaning the membrane module of a water purifier comprising, a pump; a membrane module; a first valve to control the water flow into the membrane module; and a permeate line for purified water and a reject line for discarded water; wherein the reject line comprises a valve; and wherein the water purifier comprises a closed chamber and a second valve in sequence downstream the membrane module in the permeate line and wherein said reject line is downstream of said membrane module; said process comprising, operating the purifier with the pump powered and the first and second valves open; closing the second valve to initiate shut-down of the purifier and to allow a pressure build up in the closed chamber; allowing the pump to continue operation with the first valve open; and shutting off the pump and the first valve to force purified water in the closed chamber through the membrane module in the reverse direction until the pressure in the closed chamber dissipates to ⁇ 1 psig ( ⁇ 0.0
  • the point at which the second valve is closed to start the process of cleaning the membrane module is preferably determined by the volume of output of purified water from the permeate line or the pump running time taken for obtaining a predetermined volume of purified water. It is more preferable to use the output volume of purified water from the permeate line as the parameter for closing the second valve to start the process of cleaning the membrane module.
  • a purified water chamber is placed downstream the second valve and more preferably a liquid float sensor which senses the volume of the purified water is located inside the purified water chamber. Therefore, it is preferred that the predetermined volume at which the second valve closes is dependent on the capacity of the purified water chamber. This predetermined volume is designed depending on the capacity of the purified water chamber.
  • the second valve is closed when the volume sensor located downstream of the second valve senses a predetermined output volume of purified water. In a more preferred embodiment the second valve is closed after the volume sensor senses predetermined output volume of purified water in the range of 2 to 200 litres.
  • the second valve is closed after a predetermined time period of 10 minutes to 20 days of operation of the purifier. It is preferred that the time is determined depending on the output volume of purified water.
  • the pump is allowed to continue operation with the first valve open preferably until a predetermined pressure is built up in the closed chamber or a predetermined volume of water is collected in the closed chamber or by pre-determining the time required for the pressure build up or for the predetermined volume of water collection in the closed chamber.
  • the time required to close the pump after the closure of the second valve depends on the pressure build up in the closed chamber. More preferably the pressure which is required to be achieved in the closed chamber is selected and the time is recorded which takes to reach to that pressure and the timer is then set at this predetermined time to achieve the desired pressure.
  • the pump is allowed to continue operation with the first valve open more preferably until a predetermined pressure is built up in the closed chamber.
  • the pump is allowed to continue operation with the first valve open by pre-determining the time required for the pressure build up in the closed chamber.
  • the pump after closing of second valve the pump is allowed to continue operation until the pressure switch senses a predetermined pressure in the closed chamber in the range of 1 (0.068 bar) to 180 psig (12.41 bar). More preferably the pump is allowed to continue operation untill the pressure in the closed chamber is in the range of 5 to 100 psig (0.34 bar to 6.89 bar) and yet more preferably 20 to 100 psig (1.37 bar to 6.89 bar) and most preferably the pump is allowed to continue operation until the pressure in the closed chamber is in the range of 30 to 50 psig (2.06 bar to 3.44 bar).
  • the pump is allowed to continue operation until the timer senses a predetermined time period of 0.30 minutes to 120 minutes more preferably from 0.5 minute to 60 minutes.
  • the pump is allowed to continue operation until 10 ml to 2 liters more preferably 100 ml to 500ml of water is collected in the closed chamber. This water is utilised to clean the membrane module.
  • the purified water is driven through the membrane module in the reverse direction till the built-up pressure in the closed chamber dissipates to ⁇ 1 psig ( ⁇ 0.068 bar) pressure or more preferably pressure of 0 to 0.99 psig.
  • first and second valves may be efficiently controlled using electronic control systems.
  • the purified water recovery is at least 50% of the input water. In a more preferred embodiment, the purified water recovery is in the range from 50% - 85% of the input water.
  • the present invention provides a process for cleaning the membrane module wherein preferably the life of the membrane module is increased by 2 to 10 times.
  • the process of the present invention is suitable for membrane based water purifiers with spiral wound membrane modules including reverse osmosis, nanofilter, ultrafilter and microfilter membranes.
  • Typical home use reverse osmosis devices reject ⁇ 70% of the input water while recovering only 30%. This is done as increasing the recovery of water in membrane filtration / separation introduces the following complexities. Higher the recovery of pure water, the more concentrated is the reject water. Higher concentration of dissolved salts in water leads to more scale formation. Higher the scale formation, shorter will be the life of the membrane. Hence low recovery of pure water is practiced to ensure high life of the membrane, which is the critical and expensive component in a reverse osmosis based water purifier.
  • the object of the invention is aimed at maintaining membrane and providing simple sustainable ways to prevent scaling and fouling while maintaining high recovery. Brief description of drawings
  • Fig.1 is a schematic representation of the control apparatus
  • Fig.2 is a schematic depiction of the apparatus of the present invention
  • Figure 1 shows a control water purifier system (100). Under the operation of a powered pump (103), the raw water/ input stream (101 ) enters a pre-filter (102) and is made to pass through the membrane module (105) via a valve (104). The water flows out of the membrane module (105) as a permeate water line (106) and a reject (107) water line.
  • FIG 2 shows the membrane cleaning apparatus (200) of the present invention.
  • the raw water/ input stream (201 ) enters a pre-filter (202) and is made to pass through the membrane module (205) via a valve (204).
  • the water flows out of the membrane module (205) as a permeate water line (206) and made to pass through a closed chamber (209), the permeate line from the closed chamber (209) is further made to pass via another solenoid valve (210).
  • the reject water flows out of the membrane module (205) passing through a valve (208) through a reject line (207).
  • the pressure switch (21 1 ) is operably connected to the pump (203) and the closed chamber (209.
  • the timer (212) is operably connected to the second valve (210) and the pump (203).
  • the volume sensor (213) is located downstream of the second valve and is operably connected to the output of purified water and the second valve (203).
  • the reject line (207) is downstream of the membrane module (205). In other words, water flows out of the reject line in the direction of the flow of the purified water or along the direction of flow of the permeate in the permeate line.
  • the input water (101 ) was made to enter the pre-filter (102) and then pass through the membrane module (105).
  • Dow's Filmtec 75 GPD membranes were used as a membrane module.
  • Hi Tech's Pre-carbon filter (Max Flow-1 .0 GPM, Max Pressure 125 psi), and Hi- Tech's Sediment Filter ( Max Flow-1.0 GPM, Max Pressure 125 psi) were used as pre-filters.
  • the experiments were initially setup to operate at -70 % recovery by regulating the reject flow rate through a flow regulator (Throttle valve - TV) (108).
  • the pressure in the input water line (101 ) and reject water line (106) were measured with pressure gauges.
  • TDS Total dissolved salt concentration
  • flow rate and water hardness of the input water (101 ), permeate stream (106) and the reject stream (107) were measured at regular intervals of every -35 liters of permeate (purified water) collected.
  • the TDS of input water (101 ) varied from 800-1000 ppm.
  • Figure 1 shows the schematic representation of the control apparatus.
  • the input water (201 ) from the pre-filter (202) was passed through a first solenoid valve (204) and allowed to enter the membrane module (205).
  • Dow's Filmtec 75 GPD membranes were used as a membrane module.
  • Hi Tech's Pre-carbon filter (Max Flow- 1.0 GPM, Max Pressure 125 psi), and Hi- Tech's Sediment Filter were used as pre-filters.
  • the permeate line (206) for water coming out of the membrane (205) was made to pass through a closed chamber (209). This permeate line (206) was further connected to a second solenoid valve (210).
  • the set-up was operated in such a way that initially both first and second solenoid valves (204) and (210) were open and the whole set-up was operated as a conventional membrane based water purifier.
  • the second valve (210) was closed.
  • purified water started to accumulate in the closed chamber (209) and pressure started to build up.
  • the pressure in the closed chamber (209) raised to -35 psig and the pump (203) was switched off.
  • Delta's Hydraulic Pressure Gauge (Range- 0 to 150 psig) was used.
  • the TDS, flow rate and water hardness of the feed water, permeate stream (206) and the reject stream (207) were measured at regular intervals of every -35 liters of permeate (purified water) collected.
  • the TDS of input water (201 ) varied from 800-1000 ppm.
  • Figure 2 shows the schematic representation of the water purifier with a membrane cleaning system of the present invention.
  • Control system and the water purifier of the invention were operated at permeate recovery of 70%: The control was operated without any system for cleaning of the membrane, or any other scale prevention technology.
  • the input water used was ground water which had a very high level of hardness of around 75 FH and a total salt concentration of - 850 ppm. This constitutes a "torture" test for the membrane since both total dissolved salts and hardness are very high.
  • TDS Salt cone- salt concentration in the purified water
  • Salt cone- salt concentration in the pure water The data in table 2 show that the permeate water flow rate through the system dropped slightly from 320 ml/min, when the membrane was new, to 247 ml/min by the time 1076 liters of purified water had been obtained from the system. Although the recovery of purified water was maintained at 70% which was approximately double of the recovery used in typical home-use reverse osmosis based purifiers, the salt concentration in the pure water stream was only 34 ppm, which is very low for such high recovery, indicating excellent membrane condition. Even after 2389 Liters of pure water extracted from the system, the flow rate of pure water was 238 ml/min, signifying a clean, "as good as new" membrane.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nanotechnology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The present invention provides a water purifier (200) comprising, a pump (203); a membrane module (205) where the membrane is spiral wound membrane including reverse osmosis, nanofilter, ultrafilter and microfilter membranes; a first valve (204) to control the water flow into the membrane module (205); and a permeate line for purified water and a reject line for discarded water; wherein the reject line comprises a valve (208); and wherein the water purifier comprises a closed chamber (209) and a second valve (210) in sequence downstream the membrane module (205) in the permeate line and wherein said reject line is downstream of said membrane module (205). The invention also provides a process for cleaning the membrane module (205) of the water purifier (200), said process comprising, operating the purifier (200) with the pump (204) powered and the first (204) and second valves (210) open; closing the second valve (210) to initiate shut-down of the purifier (200) and to allow a pressure build up in the closed chamber (209); allowing the pump (203) to continue operation with the first valve (204) open; and shutting off the pump (203) and the first valve (204) to force purified water in the closed chamber (209) through the membrane module (205) in the reverse direction until the pressure in the closed chamber (209) dissipates to<l psig pressure.

Description

A WATER PURIFIER AND A PROCESS OF CLEANING THE MEMBRANE Field of the invention
The present invention relates to a water purifier and a process of cleaning the membrane. Particularly the invention relates to a process for enhancing the recovery of purified water by a process of cleaning the membrane module.
Background of the invention
Any discussion of the prior art throughout the specification should in no way be considered as an admission that such prior art is widely known or forms part of the common general knowledge in the field. A large population of people in the world live in developing and under-developed countries where there is a severe shortage of hygienic potable water. A high percentage of these people live in rural areas where there are no water purification systems like the ones provided by urban municipal drinking water treatment plants. Many people have to depend directly on ground and/or surface water sources like wells, tube-wells, ponds and rivers. Often these water sources are contaminated by sewage, industrial and agricultural wastes.
A large number of physical and chemical methods of purifying water have been known and used at municipal, local and domestic levels.
Water purifiers based on membrane module systems is the most popular technology for water purification as it can remove biological, colloidal, organic and dissolved salts from water. The main drawback of such purifiers is that for example more than 50 % of the input water cannot be recovered and is rejected during the purification process such as by reverse osmosis.
The process of water purification by reverse osmosis and similarly other membrane module based systems involve extracting pure water with no or minimal dissolved salts from an input water which contains a significantly higher level of dissolved salts and may contain other impurities like dissolved organic compounds as well as colloids and microorganisms. In the process of extracting relatively salt free water, the reverse osmosis process produces concentrated reject water, which has a significantly higher salt concentration compared to the input water. Higher the recovery of pure water the higher is the concentration of the dissolved salts in the reject. In essence water purification by reverse osmosis necessarily produces a concentrate water stream which is wasted and it would be highly beneficial to reduce this water wastage. If water recovery is increased without increasing energy consumption, the energy efficiency of the system improves significantly which would have a positive environmental impact. In reverse osmosis and other devices that involve membranes for the purposes of water purification, it is essential to clean the membrane by removing the particles that get deposited on the membrane and retard the buildup of scale. This is generally ensured by changing the membrane or by frequent washing of the membrane by pressurized input water.
EP 07681 12 A1 (Christ AG, 1995) shows that the permeate can be used to clean the membrane by flowing the permeate backwards through the membrane. However the driving force for the permeate is the osmotic pressure difference between the permeate and the water on the reject side of the membrane. This method however is time consuming as it is based on the natural principal of difference in osmotic pressure.
JP 201 1 1 10439 (Toray Industries, 2009) shows that the permeate can be used to backwash the membrane module, by using a second pump to pump the permeate in the reverse direction. This system thus requires a second pump and additional instrumentation for powering and controlling the same.US3786924 B1 (Delro Inc, 1974) discloses a reverse osmosis unit further having a concentrate outlet which is upstream from the membrane structure in fluid communication with the feed water inlet. In such a configuration, the concentrate outlet point is upstream of the membrane module when the system is in operation. This publication is primarily addressing the technical problems of fiber modules or bundles. In addition, the permeate holding chamber has at least one valve upstream of the chamber and two valves and downstream of the chamber, which makes the system a bit complicated.
DE10302014 A1 and EP07681 12 A1 , both disclose a separate chamber for holding a part of the permeate to be used for backwashing. There is a branch line to the backwash permeate tank with associated valve system. Therefore, there is a need to provide an efficient device and a process for cleaning a water purifier membrane which works faster than the dynamics of cleaning based on osmotic pressure difference.
There is also a need to provide an efficient high flux backwash process for cleaning a water purifier membrane which avoids employment of additional equipment like a backwash pump and the extra power required to operate it, or other additional pumps and control system components for the membrane cleaning.
There is also a need to provide a process for cleaning a water purifier membrane with a controlled backwash frequency as too frequent backwash can lead to water wastage and infrequent backwash can lead to irreversible scaling and fouling thereby reducing the life of the membrane.
Also, there is a need to provide a process for cleaning a water purifier membrane which can be used for cleaning both spiral-wound and hollow fiber membrane modules.
The object of the present invention is also to provide a process for cleaning membrane module in a membrane based water purifier.
Another object of the present invention is to enhance recovery of purified water.
Yet another object of the present invention is to provide a process for enhancing the life of a water purifier membrane.
Another object of the present invention is to provide a process for cleaning a water purifier membrane module by avoiding the use of an additional mechanical fluid pressurizing device such as a pump for backwash cleaning and thus reducing power consumption.
Yet another object is to provide a process to reduce scaling and fouling of the membrane module and yet achieve higher purified water recovery. Summary of the invention
According to an aspect of the present invention is provided a water purifier comprising, a pump; a membrane module where the membrane is spiral wound membrane including reverse osmosis, nanofilter, ultrafilter and microfilter membranes; a first valve to control the water flow into the membrane module; and a permeate line for purified water and a reject line for discarded water; wherein the reject line comprises a valve; and wherein the water purifier comprises a closed chamber and a second valve in sequence downstream the membrane module in the permeate line and wherein said reject line is downstream of said membrane module.
According to another aspect of the present invention is provided a process for cleaning the membrane module of a water purifier comprising, a pump; a membrane module where the membrane is spiral wound membrane including reverse osmosis, nanofilter, ultrafilter and microfilter membranes; a first valve to control the water flow into the membrane module; and a permeate line for purified water and a reject line for discarded water; wherein the reject line comprises a valve; and wherein the water purifier comprises a closed chamber and a second valve in sequence downstream the membrane module in the permeate line and wherein said reject line is downstream of said membrane module; said process comprising, operating the purifier with the pump powered and the first and second valves open; closing the second valve to initiate shut-down of the purifier and to allow a pressure build up in the closed chamber; allowing the pump to continue operation with the first valve open; and shutting off the pump and the first valve to force purified water in the closed chamber through the membrane module in the reverse direction until the pressure in the closed chamber dissipates to <1 psig pressure.
Detailed description of the invention
The present invention relates to a water purifier and a process for cleaning the membrane. The invention also provides a method for enhancing the recovery of purified water by the process of cleaning the membrane module.
The membrane based water purifiers over a period of time see decline in pure water flow rate or the permeate flow rate and the salt concentration in this permeate is a measure of the "health" of the membrane. The membrane can be fouled by bio-films, organics or colloids deposited on its surface. However the most significant reason for permeate flow-rate decline is the formation of scales, which are usually deposits of calcium salts on the membrane surface. This leads to a decline in the flow of permeate as well as the total flow through the system. This may lead to an increase in pure water recovery due to a higher drop in the reject water flow rate, leading to a higher salt flux through the membrane. This also leads to an increase in the concentration of salt in the pure water. Hence high permeate water flow rate in combination with a low
concentration of salt in the same demonstrates that the membrane surfaces are clean and the system is operated optimally.
The present invention provides a membrane based water purifier with a membrane cleaning apparatus and a membrane cleaning process thereof.
Throughout the description of the invention, the word 'control' is used in a general sense of the word to describe the apparatus or device or process which connotes the experimental control which is similar to the device and the process of the present invention but without the key features and proposition which is/are tested. Throughout the description of the invention, the term 'closed chamber' preferably refers to the chamber downstream the membrane module and upstream the second valve where the purified water flows in from the membrane module and which is closed to enable the pressure to build up in the chamber.
Throughout the description of the invention, the term 'reverse direction' means the flow of water in the direction opposite to that of the flow of the purified water or opposite to the direction of flow of the permeate in the permeate line from the water purification device.
Throughout the description of the invention, the term 'reject line' means the line for flow of waste water or discarded water from the water purification device. Throughout the description of the invention, the term 'permeate line' means the line for flow of purified water recovered from the water purification device.
The present invention provides a water purifier comprising, a pump; a membrane module; a first valve to control the water flow into the membrane module where the membrane is spiral wound membrane including reverse osmosis, nanofilter, ultrafilter and microfilter membranes; and a permeate line for purified water and a reject line for discarded water; wherein the reject line comprises a valve; and wherein the water purifier comprises a closed chamber and a second valve in sequence downstream the membrane module in the permeate line and wherein said reject line is downstream of said membrane module.
A preferred embodiment of the present invention provides a water purifier (200) comprising, a pump (203); a membrane module (205); a first valve (204) to control the water flow into the membrane module (205); and a permeate line (206) for purified water and a reject line (207) for discarded water; wherein the reject line (207) comprises a valve (208); and wherein the water purifier (200) comprises a closed chamber (209) and a second valve (210) in sequence downstream the membrane module (205) in the permeate line (206) and wherein said reject line is downstream of said membrane module.
The inlet water enters a spiral wound filter at one end and exits through the other end. During its journey from the one end to the other end, the water slows down, as some fraction of it permeates into the central core of the filter element. The water in the membrane outside the core gets concentrated significantly during this journey. Hence the end of the membrane near the other end, it is significantly more fouled with scale than the end at which it enters. The water purifier and process in accordance with the invention is configured such the maximum pressure of the permeate used for backwash is available at the other end where the scaling is the maximum.
The pump may be selected from the standard types of commercially available pumps and preferably from a positive displacement pump.
Preferably the water purifier has the valve selected from on-off, solenoid or throttle type valve. More preferably the first and second valves are solenoid type valve and the valve provided at the reject line is a throttle type valve.
The membrane is spiral wound membrane modules including reverse osmosis, nanofilter, ultrafilter and microfilter membranes.
It is preferable that the first valve is operably connected to pump such that the first valve is open when the pump is powered and closed when the pump is switched off. In a preferred embodiment the water purifier comprises volume sensor operably connected to the second valve and the output of purified water from the permeate line.
In another preferred embodiment the water purifier comprises a pressure switch operably connected to the closed chamber and the pump. Any standard type pressure switch can be employed.
It is also preferred that the water purifier comprises a timer operably connected to the second valve and the pump.
An embodiment of the present invention provides a method of purifying water using the water purifier of the invention. The present invention also provides for a process for cleaning the membrane module of a water purifier comprising, a pump; a membrane module; a first valve to control the water flow into the membrane module; and a permeate line for purified water and a reject line for discarded water; wherein the reject line comprises a valve; and wherein the water purifier comprises a closed chamber and a second valve in sequence downstream the membrane module in the permeate line and wherein said reject line is downstream of said membrane module; said process comprising, operating the purifier with the pump powered and the first and second valves open; closing the second valve to initiate shut-down of the purifier and to allow a pressure build up in the closed chamber; allowing the pump to continue operation with the first valve open; and shutting off the pump and the first valve to force purified water in the closed chamber through the membrane module in the reverse direction until the pressure in the closed chamber dissipates to <1 psig (<0.068 bar) and more preferably 0-0.99 psig A preferred embodiment of the present invention provides a process for cleaning the membrane module of a water purifier comprising, (200) comprising, a pump (203); a membrane module (205); a first valve (204) to control the water flow into the membrane module (205); and a permeate line (206) for purified water and a reject line (207) for discarded water; wherein the reject line (207) comprises a valve (208);and wherein the water purifier (200) comprises a closed chamber (209) and a second valve (210) in sequence downstream the membrane module (205) in the permeate line (206) and wherein said reject line is downstream of said membrane module; said process comprising, operating the purifier (200) with the pump (203) powered and the first (204) and second (210) valves open; closing the second valve (210) to initiate shut-down of the purifier and to allow a pressure build up in the closed chamber (209); allowing the pump (203) to continue operation with the first valve (204) open; and shutting off the pump (203) and the first valve (204) to force purified water in the closed chamber (209) through the membrane module (205) in the reverse direction until the pressure in the closed chamber dissipates to <1 psig pressure.
The point at which the second valve is closed to start the process of cleaning the membrane module is preferably determined by the volume of output of purified water from the permeate line or the pump running time taken for obtaining a predetermined volume of purified water. It is more preferable to use the output volume of purified water from the permeate line as the parameter for closing the second valve to start the process of cleaning the membrane module.
Preferably a purified water chamber is placed downstream the second valve and more preferably a liquid float sensor which senses the volume of the purified water is located inside the purified water chamber. Therefore, it is preferred that the predetermined volume at which the second valve closes is dependent on the capacity of the purified water chamber. This predetermined volume is designed depending on the capacity of the purified water chamber.
In a preferred embodiment of the process of the present invention, the second valve is closed when the volume sensor located downstream of the second valve senses a predetermined output volume of purified water. In a more preferred embodiment the second valve is closed after the volume sensor senses predetermined output volume of purified water in the range of 2 to 200 litres.
In an alternative embodiment of the process for cleaning the membrane module wherein the second valve is closed after a predetermined time period of 10 minutes to 20 days of operation of the purifier. It is preferred that the time is determined depending on the output volume of purified water.
After the closure of the second valve the pump is allowed to continue operation with the first valve open preferably until a predetermined pressure is built up in the closed chamber or a predetermined volume of water is collected in the closed chamber or by pre-determining the time required for the pressure build up or for the predetermined volume of water collection in the closed chamber.
Preferably the time required to close the pump after the closure of the second valve depends on the pressure build up in the closed chamber. More preferably the pressure which is required to be achieved in the closed chamber is selected and the time is recorded which takes to reach to that pressure and the timer is then set at this predetermined time to achieve the desired pressure.
After the closure of the second valve, the pump is allowed to continue operation with the first valve open more preferably until a predetermined pressure is built up in the closed chamber. In a more preferred embodiment the pump is allowed to continue operation with the first valve open by pre-determining the time required for the pressure build up in the closed chamber.
In a preferred embodiment, after closing of second valve the pump is allowed to continue operation until the pressure switch senses a predetermined pressure in the closed chamber in the range of 1 (0.068 bar) to 180 psig (12.41 bar). More preferably the pump is allowed to continue operation untill the pressure in the closed chamber is in the range of 5 to 100 psig (0.34 bar to 6.89 bar) and yet more preferably 20 to 100 psig (1.37 bar to 6.89 bar) and most preferably the pump is allowed to continue operation until the pressure in the closed chamber is in the range of 30 to 50 psig (2.06 bar to 3.44 bar).
In another preferred embodiment of the process of present invention, the pump is allowed to continue operation until the timer senses a predetermined time period of 0.30 minutes to 120 minutes more preferably from 0.5 minute to 60 minutes.
In another preferred embodiment of the process of the present invention, the pump is allowed to continue operation until 10 ml to 2 liters more preferably 100 ml to 500ml of water is collected in the closed chamber. This water is utilised to clean the membrane module.
Preferably the purified water is driven through the membrane module in the reverse direction till the built-up pressure in the closed chamber dissipates to <1 psig (<0.068 bar) pressure or more preferably pressure of 0 to 0.99 psig.
It is preferred that the operation of the first and second valves may be efficiently controlled using electronic control systems.
In another preferred embodiment, the purified water recovery is at least 50% of the input water. In a more preferred embodiment, the purified water recovery is in the range from 50% - 85% of the input water.
The present invention provides a process for cleaning the membrane module wherein preferably the life of the membrane module is increased by 2 to 10 times.
In another embodiment of the present invention, it preferably takes at least 2 minutes to complete the membrane cleaning process and more preferably 5 to 15 minutes Yet another embodiment of the present invention provides that the process of the present invention is suitable for membrane based water purifiers with spiral wound membrane modules including reverse osmosis, nanofilter, ultrafilter and microfilter membranes.
Typical home use reverse osmosis devices reject ~ 70% of the input water while recovering only 30%. This is done as increasing the recovery of water in membrane filtration / separation introduces the following complexities. Higher the recovery of pure water, the more concentrated is the reject water. Higher concentration of dissolved salts in water leads to more scale formation. Higher the scale formation, shorter will be the life of the membrane. Hence low recovery of pure water is practiced to ensure high life of the membrane, which is the critical and expensive component in a reverse osmosis based water purifier. The object of the invention is aimed at maintaining membrane and providing simple sustainable ways to prevent scaling and fouling while maintaining high recovery. Brief description of drawings
Fig.1 is a schematic representation of the control apparatus
Fig.2 is a schematic depiction of the apparatus of the present invention
Detailed description of drawings Figure 1 shows a control water purifier system (100). Under the operation of a powered pump (103), the raw water/ input stream (101 ) enters a pre-filter (102) and is made to pass through the membrane module (105) via a valve (104). The water flows out of the membrane module (105) as a permeate water line (106) and a reject (107) water line.
Figure 2 shows the membrane cleaning apparatus (200) of the present invention. Under the operation of a powered pump (203), the raw water/ input stream (201 ) enters a pre-filter (202) and is made to pass through the membrane module (205) via a valve (204). The water flows out of the membrane module (205) as a permeate water line (206) and made to pass through a closed chamber (209), the permeate line from the closed chamber (209) is further made to pass via another solenoid valve (210). The reject water flows out of the membrane module (205) passing through a valve (208) through a reject line (207). The pressure switch (21 1 ) is operably connected to the pump (203) and the closed chamber (209. The timer (212) is operably connected to the second valve (210) and the pump (203). The volume sensor (213) is located downstream of the second valve and is operably connected to the output of purified water and the second valve (203). The reject line (207) is downstream of the membrane module (205). In other words, water flows out of the reject line in the direction of the flow of the purified water or along the direction of flow of the permeate in the permeate line.
Examples Control water purifier system
The input water (101 ) was made to enter the pre-filter (102) and then pass through the membrane module (105). Dow's Filmtec 75 GPD membranes were used as a membrane module. Hi Tech's Pre-carbon filter (Max Flow-1 .0 GPM, Max Pressure 125 psi), and Hi- Tech's Sediment Filter ( Max Flow-1.0 GPM, Max Pressure 125 psi) were used as pre-filters. The experiments were initially setup to operate at -70 % recovery by regulating the reject flow rate through a flow regulator (Throttle valve - TV) (108). The pressure in the input water line (101 ) and reject water line (106) were measured with pressure gauges. Delta's Hydraulic Pressure Gauge (Range- 0 to 150 psig) was used. The total dissolved salt concentration (TDS), flow rate and water hardness of the input water (101 ), permeate stream (106) and the reject stream (107) were measured at regular intervals of every -35 liters of permeate (purified water) collected. The TDS of input water (101 ) varied from 800-1000 ppm. Figure 1 shows the schematic representation of the control apparatus.
Water purifier of the Invention
Setting the predetermined volume for closure of second valve depends on the capacity of the purified water chamber. In the experimental set up the purified water chamber had a capacity of 30 liters. Therefore the volume sensor (213) was set at a
predetermined value of 25 liters for closure of second valve (210).
Setting the predetermined time for allowing pump (203) to operate after the closure of second valve (210) was timed so that a pressure of ~35psig was achieved. Therefore a value of two minutes was set in the timer (212) for allowing the pump (203) to run after the closure of second valve (210).
The input water (201 ) from the pre-filter (202) was passed through a first solenoid valve (204) and allowed to enter the membrane module (205). Dow's Filmtec 75 GPD membranes were used as a membrane module. Hi Tech's Pre-carbon filter (Max Flow- 1.0 GPM, Max Pressure 125 psi), and Hi- Tech's Sediment Filter ( Max Flow-1.0 GPM, Max Pressure 125 psi) were used as pre-filters. The permeate line (206) for water coming out of the membrane (205) was made to pass through a closed chamber (209). This permeate line (206) was further connected to a second solenoid valve (210). The set-up was operated in such a way that initially both first and second solenoid valves (204) and (210) were open and the whole set-up was operated as a conventional membrane based water purifier. After the output of every -25 liters of permeate (treated water) (206), the second valve (210) was closed. As a result purified water started to accumulate in the closed chamber (209) and pressure started to build up. After 2 minutes of the closure of the second valve (210) based on the predetermined time set in the timer (212), the pressure in the closed chamber (209) raised to -35 psig and the pump (203) was switched off. As a result the purified water (206) at higher pressure in the closed chamber (209) started flowing in the reverse direction towards the reject side through the membrane module (205) thereby resulting in cleaning of the membrane from within. It took ~ 5 minutes for the pure water collected in the closed chamber (209), which was roughly 0.25 L, to completely drain out. In this way for ~ every 25 liters of treated water one cycle of permeate back-flushing took place. The experiments were initially set-up to operate at -70 % recovery by regulating the reject flow rate through a valve (208) after which no change was made to the regulator setting. The pressure in the input water line, reject water line and pressurizing space/closed chamber (209) were measured with pressure gauges. Delta's Hydraulic Pressure Gauge (Range- 0 to 150 psig) was used. The TDS, flow rate and water hardness of the feed water, permeate stream (206) and the reject stream (207) were measured at regular intervals of every -35 liters of permeate (purified water) collected. The TDS of input water (201 ) varied from 800-1000 ppm. Figure 2 shows the schematic representation of the water purifier with a membrane cleaning system of the present invention.
Example 1
Control system and the water purifier of the invention were operated at permeate recovery of 70%: The control was operated without any system for cleaning of the membrane, or any other scale prevention technology. The input water used was ground water which had a very high level of hardness of around 75 FH and a total salt concentration of - 850 ppm. This constitutes a "torture" test for the membrane since both total dissolved salts and hardness are very high.
Table 1- Recovery of purified water in the control system
*Permeate/ (L) Qp (ml/min) Qt (ml/min) Salt cone, (ppm)
20 290 410 45 356 210 309 49
775 190 279 54
1 125 175 249 55
1510 55 65.5 109
*Permeate- the total volume of permeate obtained from the system
Qp- the flow-rate of the permeate obtained from the system
Qt- the total flow rate entering the membrane module
Salt cone- salt concentration in the purified water (TDS)
The data in table 1 show that the permeate water flow rate through the system dropped steadily from 290 ml/min, when the membrane is new, to 175 ml/min by the time 1 125 liters of pure water was obtained from the system. Since the recovery of purified water was maintained at 70% which was approximately double of the recovery used in typical home-use reverse osmosis based purifiers, the salt concentration in the purified water stream was slightly higher than normal i.e., 55 ppm. However, after 1510 liters of purified water was extracted from the system, the flow rate of permeate dropped to 55 ml/min, signifying end of useful life of the membrane. This was coupled with an increase in TDS of the purified water to 109 ppm, confirming the above.
Table 2- Recovery of purified water in the water purifier of the invention
Figure imgf000016_0001
*Permeate- the total volume of permeate obtained from the system
Qp- the flow-rate of the permeate obtained from the system
Qt- the total flow rate entering the membrane module
Salt cone- salt concentration in the pure water (TDS) The data in table 2 show that the permeate water flow rate through the system dropped slightly from 320 ml/min, when the membrane was new, to 247 ml/min by the time 1076 liters of purified water had been obtained from the system. Although the recovery of purified water was maintained at 70% which was approximately double of the recovery used in typical home-use reverse osmosis based purifiers, the salt concentration in the pure water stream was only 34 ppm, which is very low for such high recovery, indicating excellent membrane condition. Even after 2389 Liters of pure water extracted from the system, the flow rate of pure water was 238 ml/min, signifying a clean, "as good as new" membrane. This coupled with the TDS of the pure water of 29 ppm confirms the above. With further testing it was observed that even after 5439 liters of pure water extracted from the membrane, the flow rate of permeate water was still 208 ml/min and the salt concentration was 27 ppm, both of which indicate very good membrane condition. In summary, the data in tables 1 and 2 which were obtained under identical experimental conditions, show that the membrane life in the control is only ~ 1500 L of pure water, while the water purifier with the membrane cleaning system disclosed herein has lasted at least 5500 L, which represents a minimum enhancement of life by 3.5 times.

Claims

Claims
1. A water purifier (200) comprising,
a. a pump (203);
b. a membrane module (205) where the membrane is spiral wound
membrane including reverse osmosis, nanofilter, ultrafilter and microfilter membranes;
c. a first valve (204) to control the water flow into the membrane module (205); and
d. a permeate line (206) for purified water and a reject line (207) for
discarded water; wherein the reject line (207) comprises a valve (208); and
wherein the water purifier (200) comprises a closed chamber (209) and a second valve (210) in sequence downstream the membrane module (205) in the permeate line (206) and wherein said reject line is downstream of said membrane module.
2. A water purifier (200) as claimed in claim 1 , wherein the first valve (204) is
operably connected to pump (203).
3. A water purifier (200) as claimed in claims 1 and 2, wherein the valve is selected from on-off, solenoid or throttle type valve.
4. A water purifier (200) as claimed in any of the preceding claims, wherein the water purifier (200) comprises volume sensor (213) operably connected to the second valve (210) and the output of purified water from the permeate line 206.
5. A water purifier (200) as claimed in any of the preceding claims, wherein the water purifier (200) comprises a pressure switch (21 1 ) operably connected to the closed chamber (209) and the pump (203).
6. A water purifier (200) as claimed in any of the preceding claims, wherein the water purifier (200) comprises a timer (212) operably connected to the second valve (209) and the pump (203).
7. A process of purifying water using the water purifier (200) as claimed in any of the preceding claims.
8. A process for cleaning the membrane module (205) of a water purifier (200) as claimed in claim 1 , said process comprising:
i. operating the purifier (200) with the pump (203) powered and the first
(204) and second (210) valves open;
ii. closing the second valve (210) to initiate shut-down of the purifier (200) and to allow a pressure build up in the closed chamber (209);
iii. allowing the pump (203) to continue operation with the first valve (204) open; and
iv. shutting off the pump (203) and the first valve (204) to force purified water in the closed chamber (209) through the membrane module
(205) in the reverse direction until the pressure in the closed chamber dissipates to <1 psig (<0.068 bar) pressure.
9. A process for cleaning the membrane module (205) as claimed in claim 8, wherein the second valve (210) is closed after the volume sensor (213) senses
predetermined output volume of purified water from the permeate line (206) in the range of 2 to 200 litres.
10. A process for cleaning the membrane module (205) as claimed in claim 8, wherein the pump (203) is allowed to continue operation until the pressure switch (21 1 ) senses a predetermined pressure in the closed chamber (209) in the range of 1 (0.068 bar) to 180 psig (12.41 bar).
1 1. A process for cleaning the membrane module (205) as claimed in claim 8, wherein the pump (203) is allowed to continue operation after the closing of second valve until the timer (212) senses a predetermined time period of 0.30 minutes to 120 minutes.
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