WO2008023605A1 - Light-reflecting body and light source comprising the same - Google Patents

Light-reflecting body and light source comprising the same Download PDF

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Publication number
WO2008023605A1
WO2008023605A1 PCT/JP2007/065842 JP2007065842W WO2008023605A1 WO 2008023605 A1 WO2008023605 A1 WO 2008023605A1 JP 2007065842 W JP2007065842 W JP 2007065842W WO 2008023605 A1 WO2008023605 A1 WO 2008023605A1
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WO
WIPO (PCT)
Prior art keywords
light
light source
layer
reflector
reflectance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2007/065842
Other languages
French (fr)
Japanese (ja)
Inventor
Kimihiko Saitoh
Eiji Hayashishita
Shin Fukuda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemicals Inc
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Mitsui Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Chemicals Inc filed Critical Mitsui Chemicals Inc
Priority to JP2008530865A priority Critical patent/JPWO2008023605A1/en
Publication of WO2008023605A1 publication Critical patent/WO2008023605A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/0001Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
    • G02B6/0011Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
    • G02B6/0013Means for improving the coupling-in of light from the light source into the light guide
    • G02B6/0023Means for improving the coupling-in of light from the light source into the light guide provided by one optical element, or plurality thereof, placed between the light guide and the light source, or around the light source
    • G02B6/0031Reflecting element, sheet or layer
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/0001Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
    • G02B6/0011Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
    • G02B6/0081Mechanical or electrical aspects of the light guide and light source in the lighting device peculiar to the adaptation to planar light guides, e.g. concerning packaging
    • G02B6/0085Means for removing heat created by the light source from the package
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/0001Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
    • G02B6/0011Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
    • G02B6/0081Mechanical or electrical aspects of the light guide and light source in the lighting device peculiar to the adaptation to planar light guides, e.g. concerning packaging
    • G02B6/0086Positioning aspects
    • G02B6/0091Positioning aspects of the light source relative to the light guide
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10HINORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80Constructional details
    • H10H20/85Packages
    • H10H20/855Optical field-shaping means, e.g. lenses
    • H10H20/856Reflecting means
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W90/00Package configurations
    • H10W90/701Package configurations characterised by the relative positions of pads or connectors relative to package parts
    • H10W90/721Package configurations characterised by the relative positions of pads or connectors relative to package parts of bump connectors
    • H10W90/724Package configurations characterised by the relative positions of pads or connectors relative to package parts of bump connectors between a chip and a stacked insulating package substrate, interposer or RDL

Definitions

  • Light reflector and light source including the same
  • the present invention relates to a light reflector and a light source including the light reflector. More specifically, the present invention relates to a light reflector having excellent reflection characteristics and bending workability. Background art
  • LCDs Liquid crystal displays
  • LCDs are displays that are aimed at reducing thickness and energy. LCDs are widely used as small displays such as mobile phone displays and digital camera displays, medium-sized displays such as computer monitors and car navigation displays, and large displays such as television displays.
  • An LCD is a non-light-emitting display that requires a separate light source, and image visibility may be low in some places.
  • a knock light that is, a surface light source device provided on the back surface of the liquid crystal panel is essential.
  • a cold cathode tube has been used as a light source for a backlight.
  • LEDs GaN-based light emitting diode (LED) technology has been remarkably reduced due to industrial progress. LEDs can be driven at a lower voltage than cold-cathode tubes and have a lifetime of more than 100,000 hours. In addition, it can be thinned structurally, and since it does not use mercury contained in cold cathode fluorescent lamps, it can also reduce environmental impact.
  • LEDs can be driven at a lower voltage than cold-cathode tubes and have a lifetime of more than 100,000 hours.
  • it can be thinned structurally, and since it does not use mercury contained in cold cathode fluorescent lamps, it can also reduce environmental impact.
  • backlight light sources using pseudo-white LEDs and three-color LEDs (a combination of three LEDs, red, green, and blue) has become active.
  • Backlight light sources that use three-color LEDs are capable of high color reproducibility with a single emission spectrum, and are therefore being actively developed for high-quality displays such as televisions.
  • Small and medium-sized LCDs have a surface light source device using an LED backlight, which is mainly called an edge light type.
  • the edge-light type LED backlight is a light source placed on the side of the light guide plate and mounted on a flexible circuit board (FPC) using a polyimide substrate. Having a light source including an LED. Since light emitted from the LED is directional, a device has been devised to introduce a uniform diffused light to the light guide plate by providing a white diffuse reflector around the LED to prevent uneven brightness and color on the display screen! /
  • a reflective function is given to the double-sided tape that fixes the FPC on which the LED is mounted and the light guide plate (see Patent Document 1), or a white resin tube with holes that match the shape of the LED is heated. It can be shrunk to make a reflector (see Patent Document 2), or the concave inner surface of a concave housing can be used as a light reflecting layer, and a diffuse reflecting sheet can be placed on the light reflecting layer, and the LED inside the housing It is proposed to arrange (see Patent Document 3)!
  • a new white reflective layer is provided on the substrate on which the LED is mounted, or a casing provided with the reflective layer is installed, so that a separate member is required, and the manufacturing process increases.
  • LED backlights with a large number of LEDs have the important issue of efficiently dissipating the generated heat.
  • the substrate on which the LED is mounted is fixed to a heat sink such as metal with double-sided tape or adhesive, so that the thermal resistance increases due to the double-sided tape or adhesive, resulting in a heat dissipation effect. May decrease. If the heat dissipation effect is reduced, the LED luminous efficiency may be reduced, the device life may be shortened, and the device may be destroyed.
  • a reflector in which a circuit pattern is formed with conductive ink on white glossy paper, polyethylene terephthalate resin, or polyester resin, and an LED is mounted on the circuit pattern (Patent Document 5). See).
  • This reflector also needs to be fixed to a metal housing with double-sided tape or adhesive to improve heat dissipation. For that reason, “Lead-free solder” such as SnAg alloy is generally used to reduce the environmental burden. Since soldering with lead-free solder requires a heating process of approximately 220 ° C to 280 ° C, the reflector is subject to thermal damage when mounting LEDs. There was a problem.
  • the backlight of a large LCD used in a television or the like is a backlight mainly called a direct type.
  • the direct type backlight has a light source arranged under the diffusion sheet or lighting curtain.
  • white is often formed by a mixture of LEDs based on the three colors of red, green, and blue. Therefore, the reflector of the direct type LED backlight needs to have high diffuse reflectivity.
  • the reflector itself since the number of LEDs mounted in the direct type LED backlight is very large, the reflector itself must have high heat resistance and heat dissipation.
  • a reflector made of a base material that can be bent is disclosed, in which an electric circuit layer is formed on the reflecting surface side through an insulating layer (see Patent Document 6). If a reflector that can be bent is used, for example, a flexible display can be obtained.
  • Patent Document 7 JP-A-2005-321586
  • Patent Document 2 JP 2005-123103 A
  • Patent Document 3 Japanese Unexamined Patent Publication No. 2005-135860
  • Patent Document 4 Japanese Patent Laid-Open No. 2001-133757
  • Patent Document 5 JP-A-9 115323
  • Patent Document 6 Japanese Unexamined Patent Publication No. 2003-185813
  • Patent Document 7 Japanese Unexamined Patent Publication No. 2005-268405
  • An object of the present invention is to provide a light reflector that has bending workability and diffuse reflectivity, and sufficiently dissipates heat generated by the LED even when the LED is mounted.
  • the A further object of the present invention is to provide a surface light source device for an LED backlight used in a liquid crystal display device. Means for solving the problem
  • the first of the present invention relates to the following light reflector.
  • a metal base a metal base; a light reflection layer provided on at least one surface of the metal base, having an electrical insulation, and containing an elastomer containing at least one of a pigment and an inorganic filler; and the light A light reflector including a conductive layer formed on a reflective layer.
  • a second aspect of the present invention relates to a light source shown below or a liquid crystal display device including the light source.
  • An edge light type backlight surface light source device having the light source according to [8] or [9] and a light guide plate into which light from the light source is introduced.
  • a direct-type backlight surface light source device having the light source according to [8] or [9] and a diffusion sheet or a lighting curtain arranged on the light emission side of the light source.
  • a liquid crystal display device having the surface light source device according to [10] as a backlight.
  • a liquid crystal display device having the surface light source device according to [11] as a backlight.
  • a light reflector having bending workability and diffuse reflectivity in which even if an LED is mounted on a reflection surface, the emitted heat is sufficiently dissipated. it can.
  • the light reflector of the present invention can be manufactured with a simple process as compared with the conventional light reflector. Furthermore, an LED backlight can be obtained using the light reflector of the present invention, and can be applied to a liquid crystal display device.
  • FIG. 1A is a cross-sectional view showing a laminated state of light reflectors.
  • FIG. 1B is a top view of the light reflector as viewed from the conductive layer side.
  • FIG. 2 is a cross-sectional view of a light source in which an LED is mounted on a light reflector.
  • FIG. 3A is a cross-sectional view of a light source in which a side view type LED is mounted on a light reflector.
  • FIG. 3B is a cross-sectional view of a light source in which a top view type LED is mounted on a concave light reflector.
  • FIG. 3C is a cross-sectional view of a light source in which a top view type LED is mounted on an L-shaped light reflector.
  • FIG. 3D is a cross-sectional view of a light source in which a top view type LED is mounted on a flat light reflector.
  • FIG. 4A is a cross-sectional view of a surface light source device for an edge light type backlight in which a light guide plate is attached to the light source of FIG. 3A.
  • FIG. 4B is a cross-sectional view of a surface light source device for an edge light type backlight in which a light guide plate is attached to the light source of FIG. 3B.
  • 4C is a cross-sectional view of a surface light source device for an edge light type backlight in which a light guide plate is attached to the light source of FIG. 3C.
  • 4D is a cross-sectional view of a surface light source device for a direct type backlight in which a diffusion sheet is attached to the light source of FIG. 3D.
  • FIG. 5A is a cross-sectional view of a liquid crystal display device having a surface light source device for the edge light type backlight of FIG. 4A.
  • 5B is a cross-sectional view of a liquid crystal display device having a surface light source device for the edge light type backlight of FIG. 4B.
  • FIG. 5C is a cross-sectional view of a liquid crystal display device having a surface light source device for the edge light type backlight of FIG. 4C.
  • 5D is a cross-sectional view of a liquid crystal display device having a surface light source device including the direct type backlight in FIG. 4D.
  • FIG. 6A A graph comparing the heat resistance of the reflector of the present invention (Example 2) and the conventional (Comparative Example 1) reflector and comparing the heat resistance before and after heating. Show.
  • FIG. 6B A graph comparing the heat resistance of the reflector of the present invention (Example 2) and the conventional (Comparative Example 1) reflector and comparing the heat resistance with time. Is shown.
  • FIG. 7 is a graph comparing the ultraviolet spring resistance of the reflector of the present invention (Example 2) and the conventional (Comparative Example 1) reflector, and comparing the resistance before and after the irradiation. Shows changes
  • FIG. 8 is a graph comparing the photothermal resistance of the reflector of the present invention (Example 2) and the conventional (Comparative Example 1) reflector and comparing the photothermal resistance. Changes.
  • the light reflector of the present invention includes 1) a metal substrate, 2) a light reflection layer provided on the metal substrate, and 3) a conductive layer provided on the light reflection layer.
  • 1A and 1B show the configuration of the light reflector of the present invention.
  • FIG. 1A shows the laminated state of the light reflectors
  • FIG. 1B is a top view of the light reflectors as viewed from the conductive layer side.
  • 10 is a metal substrate
  • 20 is a light reflecting layer having electrical insulation
  • 30 is a conductive layer.
  • suitable materials for the metal substrate include aluminum, aluminum alloy, magnesium alloy, stainless steel, copper, copper-zinc alloy, nickel, nickel-based alloy, titanium, titanium alloy and the like. From the viewpoint of weight reduction, an aluminum alloy or a magnesium alloy is preferably used. In general, silicon, magnesium, or copper is added to an aluminum alloy.
  • the metal base material may be stainless steel having both strength and corrosion resistance. The stainless steel is not particularly limited as long as it is ferritic containing chromium or austenitic containing chromium and nickel. Preferred stainless steel Maoka's concrete line (including SUS304, SUS316, etc.)
  • the metal substrate has a function of radiating heat generated by a light source (for example, LED) mounted on the light reflector. Therefore, the metal base material is preferably copper or copper alloy having high heat dissipation. Suitable examples of copper alloys include brass.
  • the thickness of the metal substrate be industrially bendable.
  • the thickness of the metal base material that can be bent industrially is preferably 0.03 mm to 1 mm, and more preferably 0.05 mm to 0.5 mm. If the metal substrate is too thin, the rigidity will be low, and there is a risk that when the light source is attached to the obtained light reflector, it will be fixed. On the other hand, if the metal substrate is too thick, bending may be difficult.
  • the light reflector of this invention contains the light reflection layer provided in the single side
  • the light reflecting layer is preferably made of an electrically insulating material, and is usually made of an electrically insulating polymer material. Examples of electrically insulating polymeric materials include epoxies, polyesters, polybutadienes, anoloxides, epoxyesterols, polyamides, silicones, and Teflon and blended materials thereof.
  • the light reflecting layer may be a single layer or a laminate of multiple layers.
  • the polymer material contained in the light reflection layer preferably has elasticity.
  • a polymer material having elasticity is called an elastomer.
  • elastomers include rubber and thermoplastic elastomers.
  • the elastomer is more preferably a silicone resin or a silicone rubber.
  • Silicone resin elastomer includes silicone thermoplastic elastomer
  • the light reflecting layer preferably also functions as an adhesive layer for bonding the metal substrate and the conductive layer. If an adhesive material is used for the light reflecting layer, the conductive layer can be easily formed on the light reflecting layer, and also functions as a bonding layer between the metal substrate and the conductive layer. Therefore, it is preferable that the polymer material contained in the light reflecting layer has high adhesion to the conductive layer (for example, a metal layer) and is a polymer material. High adhesion to conductive layer (metal layer), polymer material Examples of the material include an epoxy adhesive resin and a silicone adhesive resin, and a silicone adhesive resin is particularly preferable.
  • the light reflecting layer is also required to have high heat resistance.
  • the heat resistance required for the light reflecting layer is that, in practice, the reflectance of the light reflecting layer is hardly lowered even after a “soldering process” exposed to a high temperature (for example, 180 to 280 ° C.); It means that the insulation resistance value of the reflective layer hardly decreases; the adhesive strength between the base material and the light reflecting layer and the adhesive strength between the light reflective layer and the electric circuit layer hardly decrease. Therefore, the polymer material contained in the light reflecting layer is required to have little alteration due to thermal decomposition.
  • the weight reduction force of the polymer material due to thermal decomposition at 180 to 280 ° C. is preferably 10% or less, more preferably 5% or less, and even more preferably 3% or less.
  • the heat-resistant polymer material include silicone resin and silicone rubber.
  • the thickness of the light reflecting layer is appropriately selected depending on the desired light reflectance, but is usually 10 ⁇ m to 500 ⁇ m, more preferably 30 ⁇ m to 200 ⁇ m.
  • a pigment or an inorganic filler in the polymer material constituting the light reflecting layer.
  • a pigment and an inorganic filler may be contained, or any of them may be contained.
  • a silicone resin or silicone rubber containing a white pigment or an inorganic filler is preferably used.
  • the pigment is preferably a white pigment.
  • inorganic fillers can be arbitrarily selected from ceramics and other forces. Examples of preferred ceramics include diamond powder, aluminum oxide, silicon oxide, zirconium oxide, zinc oxide, titanium oxide, boron nitride, aluminum nitride, silicon nitride, titanium nitride and the like.
  • the thermal conductivity is improved as compared with the case of using a material composed only of the polymer material.
  • the thermal conductivity of the light reflecting layer increases, the heat generated from the light source provided on the light reflecting layer is efficiently transmitted to the metal substrate through the light reflecting layer and efficiently dissipated.
  • the kind, particle diameter, shape, and content of pigments and inorganic fillers contained in the polymer material constituting the light reflecting layer are determined by the diffuse reflecting performance, heat conduction performance, adhesive performance, etc. of the light reflecting layer. In view of this, it is appropriately selected.
  • the shape of the inorganic filler is needle-like, light reflection
  • the function of the layer as an adhesive layer (adhesiveness between the metal substrate and the conductive layer) can be enhanced.
  • the acicular filler has an average fiber diameter of 0.1 to 1 mm 111, preferably 0 .;! To 0.3 mm, and an average fiber length of 0.5 ⁇ 5 to 50 111, preferably 0. 5 ⁇ ; means filler that is 10 m. Shapes such as the average fiber diameter and average fiber length of the filler can be measured by observing the cross section of the light reflecting layer with a scanning electron microscope.
  • the polymer material constituting the light reflecting layer may contain an ultraviolet absorber, a stabilizer, and other additive agents.
  • the reflectance of the light reflecting layer is measured by making light incident from the conductive layer side.
  • the total light reflectance of the light reflecting layer is preferably 80% or more, more preferably 85% or more, more preferably 88% or more, and even more preferably 90% or more.
  • the total light reflectance is the sum of regular reflectance and diffuse reflectance.
  • the regular reflectance refers to the ratio of the amount of light reflected at a reflection angle equal to the incident angle with respect to the amount of incident light.
  • the diffuse reflectance is the ratio of the amount of light reflected at a reflection angle different from the incident angle with respect to the amount of incident light.
  • the total light reflectance can be easily measured with a general visible ultraviolet spectrophotometer equipped with an integrating sphere.
  • the total light reflectance may be the total light reflectance at a wavelength of 550 nm. More practically, the weight coefficient for calculating the visible light reflectance described in JIS R3106 may be used.
  • the diffuse reflectance of the light reflecting layer has an appropriate value depending on the position of the reflecting surface in the member and the purpose of use of the device equipped with the reflecting surface.
  • the diffuse reflectance may be preferably about 10 to 50%, or may be preferably 80% or more.
  • the diffuse reflectance can be measured with a general visible ultraviolet spectrophotometer equipped with an integrating sphere.
  • the light reflecting layer of the light reflector of the present invention preferably reflects light from a C light source and emits light that is nearly colorless.
  • the color of light may be indicated by a Hunter value.
  • Hunter value is a color system that uses a uniform color space, and is measured according to JIS Z8722.
  • X, Y and Z represent tristimulus values of the XYZ color system, 380 nm to 7
  • the absolute value of the! Is preferably 5 or less, more preferably 5 or less, and even more preferably 3 or less.
  • the light reflector of the present invention includes a conductive layer provided on the light reflection layer.
  • a conductive layer provided on the light reflection layer.
  • preferred metals that are preferably made of metal for the conductive layer include copper, aluminum, silver, gold, and platinum. Is included. These metal foils are preferably thin films.
  • the material of the conductive layer is preferably copper in consideration of electric resistance and etching characteristics, and is preferably aluminum or aluminum having low reflection characteristics and low color.
  • Metal foil is a metal thin film formed into a sheet before being provided on the light reflecting layer.
  • Metal thin film is formed on the light reflecting layer by a printing method, vapor deposition method or clinging method. It is a metal thin film.
  • the thickness of the conductive layer is appropriately determined depending on the power of the mounted LED.
  • the thickness of the metal foil is preferably in the range of 1 to 100 ⁇ m, and the thickness of the metal thin film is preferably in the range of 0.5 to 20 ⁇ m.
  • the conductive layer may be an electric circuit. A method for forming the conductive layer and the electric circuit will be described in detail later.
  • the light reflector of the present invention may have a resin film or an adhesive layer between the light reflection layer and the metal substrate.
  • the light reflector may have a configuration of conductive layer / light reflection layer / resin film / adhesive layer / metal substrate.
  • the total thickness (including the light reflection layer) of the members sandwiched between the conductive layer and the metal substrate is preferably 2 to 200111. If the thickness of these members is too large, the heat dissipation effect may be reduced.
  • the thickness of the light reflecting layer is preferably 30 to 200 Hm! /.
  • the surface of the light reflection layer is covered only with an electric circuit and other necessary conductive layers, and it is as wide as possible! ,. This is to increase the reflectivity of the light reflector.
  • the light reflector of the present invention is preferably bendable. Bending is possible, for example, by pressing, or other mechanical processing, with the light reflecting layer side facing inward and bending at a bending angle of 90 °. What you can do.
  • the light reflector of the present invention can be manufactured by a simple process because it is not necessary to separately form a light reflection layer for providing a reflection function on the circuit board.
  • the light reflecting layer is formed of an elastic resin, it can be bent.
  • the light-reflecting layer is made of a heat-resistant polymer material, LED mounting at high temperatures is possible.
  • the metal base material is used, the heat dissipation of the light reflector is high.
  • the light reflector of the present invention is used for indoor lighting, indoor lighting, and automobiles. It can be used as various reflectors for lighting such as lighting for lighting and decoration, and can also be used as a light reflector for a surface light source device of a display panel.
  • the light reflector of the present invention can be produced by any method as long as the effects of the present invention are not impaired. For example, 1) a method of applying a light reflecting layer having electrical insulation on a metal substrate, and further forming a conductive layer on the light reflecting layer; 2) preparing the light reflecting layer as an adhesive sheet; A method in which a metal substrate and a metal foil to be a conductive layer are bonded to each of the surfaces, 3) a polymer material (light reflecting layer) having electrical insulation properties on both the metal substrate and the metal foil to be a conductive layer There is a method of forming a light reflecting layer by applying the material (2) and pasting the coated surfaces of each other. Bonding may be performed by hot pressing, hot bonding, cold pressing, cold indirect bonding, or the like depending on the characteristics of the material.
  • the light reflecting layer preferably contains an adhesive resin. This is because the metal foil and the light reflection layer are easily bonded. On the other hand, the portion of the light reflecting layer exposed without attaching the metal foil may not have adhesiveness.
  • the metal thin film can be formed by a general method such as a vapor deposition method, a printing method, or a staking method.
  • a general method such as a vapor deposition method, a printing method, or a staking method.
  • a metal thin film on the light reflecting layer it is not particularly necessary to include an adhesive resin in the light reflecting layer, but in order to obtain adhesion, the surface of the light reflecting layer is plasma treated before forming the metal thin film. Adhesion can be given by corona treatment or UV ozone treatment.
  • the evaporation method include various methods such as a vacuum evaporation method by resistance heating, a vacuum evaporation method by electron beam heating, a sputtering method, and an ion plating method. One method may be used, or a plurality of methods may be used in combination.
  • the conductive layer may be an electric circuit.
  • the electric circuit can be formed by a general method.
  • An electric circuit may be formed by etching away a part of the conductive layer provided on the light reflecting layer. 2) An electric circuit is formed by directly drawing a conductive material on the light reflecting layer. Also good. Preferably, a part of the conductive layer provided in the light reflection layer is removed by etching to form an electric circuit. If the line width of the electric circuit is narrow, apply or bond a photosensitive resin to the formed conductive layer; expose it with a mask having an electric circuit pattern to remove unnecessary resin; Remove the conductive layer with a suitable etching material to form an electrical circuit To do.
  • a photosensitive resin is applied to the formed conductive layer in a circuit form by a printing method; the exposed conductive layer is exposed with an appropriate etching material. Remove to form an electrical circuit.
  • the photosensitive resin is not particularly limited and may be either a negative type or a positive type.
  • an electrical circuit of copper can be formed by wet etching using a ferric iron chloride aqueous solution or dry etching using plasma or the like.
  • the light reflector of the present invention can be used as a light source by mounting a light emitting diode (LED) on a conductive layer. LEDs that emit red, green, and blue light, and so-called pseudo white light-emitting LEDs are preferably used.
  • FIG. 2 shows a state in which the light emitting diode 100 is mounted on the light reflector (including the metal substrate 10, the light reflection layer 20, and the conductive layer 30) with the solder 40.
  • the LED may be either a side view type or a top view type.
  • FIG. 3A shows a light source in which a side view type LED 110 is mounted on a light reflector.
  • the side view type LED 110 is a type of LED whose light emitting surface is perpendicular to the mounting surface, and emits light parallel to the mounting surface from the light emitting section 130.
  • 3B to 3D show a light source in which a top view type LED 120 is mounted on a light reflector.
  • the top view type LED 120 is a type of LED whose light emitting surface is parallel to the mounting surface, and emits light perpendicular to the mounting surface from the light emitting unit 130.
  • Figures 3B and 3C show top-view type LEDs, but the side-view type LEDs may be applied depending on the light source design.
  • FIG. 3D it is preferable that a top view type LED is applied as shown in the figure.
  • Light sources for medium- and small-sized liquid crystal displays often use pseudo-white light-emitting LEDs.
  • Large-scale LCD light sources such as TV applications have red, green, and blue light emission characteristics. Often used in combination with existing LEDs. Even for small and medium-sized LCDs, it is preferable to use a combination of red, green, and blue LEDs as the light source for field sequential LCDs! /.
  • the ratio of the number of red, green, and blue LEDs may be determined according to the intensity of each light emitting diode. For example, the luminous efficiency of a blue LED is one-third that of a green or red LED. Then, mount blue LEDs at 3 times the density! /.
  • Blue-based LED semiconductor materials include GaN; blue-green and white LED semiconductor materials include InGaN; red-based LED semiconductor materials include AlInGaP.
  • LED semiconductor materials are not limited to these, and it is important to select them appropriately so that each color purity can be obtained.
  • the force S can be secured by fixing the LED with solder on the conductive layer at the desired position of the light reflector.
  • PbSn alloy solder with a melting point of about 180 ° C may be used as the solder material to be used, but from the viewpoint of environmental load reduction and environmental regulations in recent years, it is desired to use lead-free alloy solder. Yes.
  • the melting point is higher than PbSn alloy solder, from the viewpoint of mounting stability and reliability, AuSn-based alloy solder such as AuSnCu alloy solder (melting point: about 220 ° C), SnZnBi alloy solder (melting point: about 200 ° C) It is preferable to use SnZn alloy solder, SnSb alloy solder, SnCu alloy solder, etc.
  • a protective film may be attached to the surface of the light reflecting layer before these processing, and the protective film may be removed after processing.
  • a protective film having elongation characteristics and heat resistance characteristics is appropriately selected.
  • the thickness of the protective film is 10-200111.
  • the adhesion of the protective film is preferably from 0.01 to 0.3 kN / m, more preferably from 0.03 to 0.2 kN / m. If the adhesive force is too weak, the protective film peels off during processing, and if it is too strong, extra force is required to peel off the protective film to mount the LED.
  • the protective film is made of poly (vinyl chloride), polyolefin, polyester, etc.
  • protective films include Sanitect and PAC (manufactured by Sanei Kaken Co., Ltd.), E-MASK series (manufactured by Nitto Denko Corporation), etc. It is. [0056] It is possible to form a solder resist layer on the conductive layer (electric circuit) of the light reflector on which the LED is mounted. Since the exposed electrical circuit has a low reflectivity, it is possible to increase the reflectivity of the entire surface by covering it with a solder resist having diffuse reflectivity (for example, a white solder resist).
  • the white solder resist is, for example, a photo-curing solder resist containing a white pigment and a filler such as titanium oxide, zinc oxide, basic carbonate, basic lead sulfate, lead sulfate, zinc sulfide or antimony oxide. It is a thermosetting solder resist.
  • the photo-curing solder resist is a photo-curing solder resist that contains a photopolymerizable monomer composed of, for example, acrylates or the like, and a photosensitive polymer having both a carboxyl group and an ethylenically unsaturated bond in the molecule.
  • the thermosetting solder resist is a thermosetting solder resist containing, for example, a polyfunctional epoxy compound, a polyfunctional oxetane compound, a polyfunctional phenolic hydroxyl group-containing compound and the like.
  • the light reflector on which the LED is mounted can be applied to a surface light source device for a backlight of a display device (eg, LCD).
  • LCD backlights can be classified into edge light types and direct type.
  • the light source of the present invention can be applied to a surface light source device for any type of backlight with a force S.
  • a light source is attached to the end of the light guide plate, and in the case of a direct type backlight, a light source is attached to the lower part of the diffusion sheet or the lighting curtain.
  • FIGS. 4A to 4C show a surface light source device for an edge light type backlight.
  • the end of the light guide plate 200 is disposed near the LED of the light source, and LED light is introduced into the side surface of the light guide plate 200.
  • the LED of the surface light source device shown in Fig. 4A is a side view type, and is mounted on a flat light reflector.
  • the LED of the surface light source device shown in Fig. 4B and Fig. 4C is a top-view type (or a side-view type), which reflects light that is bent into a concave shape (Fig. 4B) or an L-shape (Fig. 4B). Implemented in the body.
  • the light reflector may be processed so that a part of the light reflector also serves as a reflection sheet under the light guide plate. .
  • the number of parts of the surface light source device can be reduced (for example, the reflector 210 in FIG. 4B is not required), and a metal substrate having a heat dissipation function can also be disposed under the light guide plate. Increases nature.
  • the means for bending the light reflector is not particularly limited.
  • examples of the material of the light guide plate used in the surface light source device for the edge light type backlight include acrylic resins such as polymethyl methacrylate and resins made of polycarbonate or polycarbonate'polystyrene composition. , Epoxy resin, cyclic polyolefin resin (Mappa Chemical Co., Ltd. Apell (registered trademark), Nippon Zeon Co., Ltd., ZEONOR (registered trademark), JSR Co., Ltd. Arton (registered trademark), etc.) and glass .
  • the material of the light guide plate is not necessarily limited to this as long as the material shows transparency in the wavelength region of 380 nm to 780 nm.
  • the thickness of the light guide plate may be appropriately selected depending on the purpose and size of use, the size of the light source, and the like. In order to make the in-plane luminance distribution uniform, various dot printings may be applied to the light guide plate surface.
  • FIG. 4D shows a surface light source device for a direct type backlight.
  • a diffusion sheet 220 is placed on top of the LED of the light source, and LED light is introduced from below the diffusion sheet 220.
  • the LED 120 of the surface light source device shown in FIG. 4D is a top view type, and is mounted on a flat light reflector.
  • the diffusion sheet and the lighting curtain used for the direct type backlight are, for example, a polyethylene terephthalate (PET) film or a PET film in which attalinole beads are coated with a binder.
  • PET polyethylene terephthalate
  • the thickness of the diffusion sheet or lighting curtain may be appropriately selected depending on the purpose and size of use, the size of the light source, and the like.
  • the liquid crystal display device of the present invention can be obtained by mounting a liquid crystal panel on a surface light source device for a backlight.
  • 5A to 5C are conceptual diagrams of a liquid crystal display device in which a liquid crystal panel 300 is mounted on a surface light source device for an edge light type backlight.
  • FIG. 5D is a conceptual diagram of a liquid crystal display device in which a liquid crystal panel 300 is mounted on a surface light source device for a direct type backlight.
  • the surface light source device can be suitably used for an active matrix liquid crystal panel equipped with a color filter and a thin film transistor (TFT) array or a thin film diode type (TFD). If red, green, and blue LEDs are emitted independently in time division as light sources, an intermediate color can be produced using the afterimage effect of liquid crystal panel switching without the need for a color filter. This method is called field sequential method!
  • Heat-curing silicone rubber adhesive product name: TSE3251H, manufactured by GE Toshiba Silicone Co., Ltd.
  • titanium oxide fine particles product name: Typeta R960, manufactured by Ishihara Sangyo Co., Ltd.
  • the silicone rubber adhesive mixed with titanium oxide fine particles was applied to an aluminum plate (thickness: 0.2 mm) of JIS 1000 series and a copper foil (thickness: 18 m) using an applicator.
  • the adhesive-coated surface of the aluminum plate and the adhesive-coated surface of the copper foil were bonded together and heated and pressed at 170 ° C for 1 hour.
  • the thickness of the adhesive layer of the resulting laminate is about 50 m.
  • a resist was applied to the copper foil surface by a printing method and etched!
  • An electric circuit was formed by removing unnecessary copper by a wet etching method using an iron chloride solution. After wet etching, the surface was washed with water and the resist was removed to obtain a light reflector as shown in FIGS. 1A and 1B.
  • the resin surface exposed by etching copper becomes a reflective surface.
  • the total light reflectance of the reflecting surface was measured with a visible ultraviolet spectrophotometer (manufactured by Shimadzu Corporation: UV-2450) using an integrating sphere.
  • a barium sulfate powder specified by a spectrophotometer manufacturer was packed in a holder attached to the spectrophotometer.
  • the standard plate is a standard made of hardened barium sulfate powder. Although a plate or an aluminum oxide standard plate may be used, a standard plate in which barium sulfate powder is hardened is used in this example.
  • the total light reflectance at a wavelength of 550 nm was 95%.
  • the diffuse reflectance at a wavelength of 550 nm measured with the same device was 92%.
  • the Hunter a value calculated from the total light reflection spectrum was 1.6 and the b value was 0.9.
  • the peel strength between the silicone rubber adhesive layer mixed with titanium oxide fine particles and the copper foil was measured under the following conditions, and the value was 0.6 kN / m.
  • the obtained light reflector was passed through a reflow furnace in a nitrogen atmosphere at 260 ° C over 1 minute. Thereafter, the reflectance of the reflecting surface and the peel strength between the adhesive layer and the copper foil were measured. There was no decrease in reflectance and peel strength compared with those before passing through the reflow furnace.
  • a white solder resist manufactured by Taiyo Ink: Photofiner PMR6000 was applied to the conductive layer of the obtained light reflector, and after UV exposure, it was heated and cured.
  • White solder The total light reflectance of the white surface of one resist was measured by the same method, and the reflectance at a wavelength of 550 nm was 88%.
  • Titanium oxide fine particles (product name: Typeta R 930, manufactured by Ishihara Sangyo Co., Ltd.) were mixed with the same silicone rubber adhesive as in Example 1 to make the content of titanium oxide fine particles 35% by weight. The resulting mixture was degassed by holding it in vacuum for 3 hours.
  • a white silicone rubber adhesive mixed with titanium oxide fine particles was applied to each of the same aluminum plate (thickness: 0.2 mm) and copper foil (thickness: 18 m) as in Example 1.
  • the adhesive coated surfaces were overlapped and heated and pressed at 170 ° C for 1 hour.
  • the thickness of the adhesive layer of the obtained laminate was about 50 am.
  • Example 2 In the same manner as in Example 1, the copper foil was removed by etching. The total light reflectance of the exposed reflecting surface was measured with a visible ultraviolet spectrophotometer (Hitachi: U-3010) using an integrating sphere. The standard for reflectance measurement was an aluminum oxide white plate (model number: 210-0740). Wavelength 550 The reflectivity at nm was 95%. The diffuse reflectance at a wavelength of 550 nm measured with the same device was 95%. The Hunter a value calculated from the total light reflection spectrum is-
  • the obtained light reflector was passed through a reflow furnace in a nitrogen atmosphere at 260 ° C three times (passing time).
  • the obtained light reflector was immersed in an alkaline aqueous solution or an organic solvent shown in the following 1) to 6) under predetermined conditions (temperature and time). The reflectivity and peel strength were measured before and after immersion, but no change was observed. Thus, it can be seen that the obtained light reflector has high alkali resistance and solvent resistance.
  • Example 3 Acicular titanium oxide fine particles (product name: Typeta FTL-110, manufactured by Ishihara Sangyo Co., Ltd.) were mixed with the same silicone rubber adhesive as in Example 1 to obtain acicular titanium oxide fine particles. The content was 35% by weight. The resulting mixture was degassed by holding it in vacuum for 3 hours.
  • the white silicone rubber adhesive mixed with acicular titanium oxide fine particles was applied to each of the aluminum plate (thickness: 0.2 mm) and copper foil (thickness: 18 m) as in Example 1. did.
  • the coated surfaces were overlapped and heated and pressed at 170 ° C for 1 hour. Adhesion of the resulting laminate The layer thickness was about 50 am.
  • the copper foil was removed by etching in the same manner as in Example 1.
  • the total light reflectance of the exposed reflecting surface measured with a visible ultraviolet spectrophotometer (Hitachi: U-3010) using an integrating sphere was 95% (measured at a wavelength of 550 nm).
  • the standard for reflectance measurement was an aluminum oxide white plate (model number: 210-0740).
  • the diffuse reflectance measured with the same device was 95% (measured at a wavelength of 550 nm).
  • the Hunter a value calculated from the total light reflection spectrum was 1.7, and the 1 ⁇ value was 1.7.
  • the peel strength between the white silicone rubber adhesive layer and the copper foil, measured under the same conditions as in Example 1, was 0.88 kN / m.
  • a white epoxy resin substrate was prepared by the following procedure. 50 parts by mass of alicyclic epoxy resin, 40 parts by mass of bisphenol A type epoxy resin, and 10 parts by mass of glycidyl methacrylate copolymer were dissolved in 50 parts by mass of methyl ethyl ketone (varnish A).
  • Varnish A and varnish B were mixed, and further, titanium oxide fine particles and 0.3 parts by weight of a brightening agent were mixed to obtain a white epoxy varnish.
  • the content of titanium oxide fine particles was 35% by weight.
  • the obtained white epoxy varnish was impregnated into a glass cloth, pre-dried at 150 ° C. for 5 minutes, and copper foil (thickness: 18 m) was superimposed on the upper and lower sides thereof and heated and pressed at 170 ° C.
  • the thickness of the epoxy resin layer was about 550 ⁇ m.
  • a part of the copper foil was removed by etching in the same manner as in Example 1 to expose the reflective surface.
  • the total light reflectance of the reflecting surface was 90% (measured at a wavelength of 550 nm) as measured with a visible ultraviolet spectrophotometer using an integrating sphere (manufactured by Hitachi, Ltd .: U-3010).
  • the diffuse reflectance measured with this device was 90% (measured at a wavelength of 550 nm).
  • the Hunter a value calculated from the total light reflection spectrum was 1 ⁇ 2, and the b value was 2.9.
  • Example 2 and Comparative Example 1 The copper foil of the reflector obtained in Example 2 and Comparative Example 1 was removed by etching in the same manner as in Example 1 to obtain a sample with the reflective surface exposed.
  • the total light reflectance of the exposed reflective surface was measured (untreated sample in Fig. 6A).
  • the reflective surface is exposed.
  • the samples were heated to 180 ° C for 10 hours and the change in the total light reflectance of the reflecting surface was measured (treated sample in Fig. 6A). The result of the measurement is shown in Figure 6A.
  • Figure 6B shows the time course of the reflectance of each sample with respect to the heating time for light with a wavelength of 550 nm.
  • the sample from Comparative Example 1 shows a significant deterioration in reflectance in the short wavelength region after heating for 10 hours.
  • the reflectance of the sample from Example 2 hardly changes even after heating for 10 hours.
  • the sample from Example 2 has excellent heat resistance!
  • Example 2 and Comparative Example 1 The copper foil of the reflector obtained in Example 2 and Comparative Example 1 was removed by etching in the same manner as in Example 1 to obtain a sample with the reflective surface exposed.
  • the total light reflectance of the exposed reflective surface was measured (untreated sample in Fig. 7).
  • the measurement results are shown in Fig. 7.
  • the sample from Comparative Example 1 has a low reflectivity even when it has not been processed, and the reflectivity in the short wavelength region is significantly reduced by the processing.
  • the sample from Example 2 has a high reflectivity from the untreated state and little degradation by treatment. Thus, it can be seen that the sample from Example 2 has excellent UV resistance.
  • Example 2 and Comparative Example 1 The copper foil of the reflector obtained in Example 2 and Comparative Example 1 was removed by etching in the same manner as in Example 1 to obtain a sample with the reflective surface exposed.
  • the total light reflectance of the exposed reflective surface was measured (untreated sample in Fig. 8).
  • simulated sunlight about 500 mW / cm 2
  • Simulated sunlight was obtained by attaching an air mass (A. M) filter 1.5 to a xenon lamp. Subsequent total light reflectance was measured (processed sample in Fig. 8).
  • the measurement results are shown in Fig. 8.
  • the sample from Comparative Example 1 has a reduced reflectance due to the irradiation treatment.
  • the reflectance from the sample from Example 2 is hardly deteriorated. .
  • the sample from Example 2 has excellent photothermal resistance.
  • Example 2 A sample of lOcm ⁇ 1 cm was cut out from the reflectors of Example 2 and Comparative Example 1, and a jig was applied to the center part, and the sample was bent 90 °.
  • the sample from Example 2 maintained its shape without peeling off both the resin and the copper foil even when bent by 90 °.
  • Comparative Example 1 when the sample from Comparative Example 1 was bent by 90 °, the resin layer broke and peeling occurred between the glass cloths.
  • Example 2 From the light reflector obtained in Example 1, a 19 cm ⁇ 27 cm sample was cut out. A protective film was laminated on the sample aluminum plate, and a dry film resist (AQ3058 manufactured by Asahi Kasei Co., Ltd.) was laminated on the copper foil. The dry film resist was irradiated with UV through a mask on which the LED mounting circuit pattern was drawn to cure the resist on the mounting circuit pattern. After the resist was cured, the sample was immersed in an aqueous sodium carbonate solution to remove the uncured resist.
  • a dry film resist (AQ3058 manufactured by Asahi Kasei Co., Ltd.) was laminated on the copper foil.
  • the dry film resist was irradiated with UV through a mask on which the LED mounting circuit pattern was drawn to cure the resist on the mounting circuit pattern. After the resist was cured, the sample was immersed in an aqueous sodium carbonate solution to remove the uncured resist.
  • the sample was immersed in a ferric chloride solution, and the copper foil in the region where the resist was removed was removed by etching, followed by washing with water.
  • the washed sample was immersed in an aqueous sodium hydroxide solution to remove all resist.
  • a white solder resist (manufactured by Taiyo Ink Manufacturing Co., Ltd .: Photofiner PMR-6000 W30 (main agent) and CA-40 G30 (curing agent) is applied to the entire surface on which the mounting circuit pattern is formed. And heated to 80 ° C. for 30 minutes and dried to form a 20 m thick film. Subsequently, the solder resist in the copper foil area, which is a mounting circuit pattern that excludes the area that needs to be soldered to mount the LED, was cured by irradiating UV through a mask. After the resist was cured, the sample was immersed in an aqueous sodium carbonate solution to remove the uncured solder resist and further washed with water. Thereafter, the solder resist was further cured by heating to 150 ° C. for 60 minutes.
  • a light source was obtained by mounting a side view type white LED on the light reflector obtained in Example 1 as shown in FIG. 3A by the method shown in Example 4.
  • a surface light source device was obtained by attaching a light guide plate made of talyl resin to the obtained light source as shown in FIG. 4A.
  • Example 1 The light reflector obtained in Example 1 was bent so that the diffuse reflection surface was concave. Using the method shown in Example 4, a light source was obtained by mounting a top view type or side view type white LED on a bent light reflector, as shown in Figs. 3B and 3C. A surface light source device was obtained by attaching an acrylic resin light guide plate to the light sources shown in FIGS. 3B and 3C, respectively, as shown in FIGS. 4B and 4C.
  • Example 4 Using the method shown in Example 4, a light source was obtained by mounting top view type red, green, and blue LEDs on the light reflector obtained in Example 1 as shown in FIG. 3D. A surface light source device was obtained by attaching a diffusion sheet of PET resin to the obtained light source as shown in FIG. 4D.
  • the light reflector of the present invention is suitably applied to light sources such as a surface light source device for a liquid crystal display, indoor lighting, indoor lighting, automobile lighting, and decoration lighting.
  • the light reflector, the light source, the surface light source device or the liquid crystal display device of the present invention can be applied to a small liquid crystal display such as a portable device or a computer monitor to a large liquid crystal display for TV use.

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  • General Physics & Mathematics (AREA)
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Abstract

Disclosed is a light-reflecting body having bending workability and diffuse reflection property, wherein sufficient heat dissipation is assured even when an LED, which emits heat, is mounted on a reflective surface. Specifically disclosed is a light-reflecting body comprising a metal base, a light-reflecting layer formed on at least one side of the metal base, having electrical insulation properties and containing an elastomer containing at least one of a pigment and an inorganic filler, and a conductive layer formed on the light-reflecting layer. A light source can be obtained by mounting a light-emitting diode on the light-reflecting body, and a liquid crystal display can be obtained by fixing the light source onto a liquid crystal panel as a surface light source device.

Description

明 細 書  Specification

光反射体、およびそれを含む光源  Light reflector and light source including the same

技術分野  Technical field

[0001] 本発明は、光反射体およびその光反射体を含む光源に関する。より具体的に本発 明は、優れた反射特性を有するとともに、曲げ加工性を有する光反射体に関する。 背景技術  [0001] The present invention relates to a light reflector and a light source including the light reflector. More specifically, the present invention relates to a light reflector having excellent reflection characteristics and bending workability. Background art

[0002] 画像を表示するディスプレイは、マルチメディアにおける最も重要なマシンインター フェースである。液晶ディスプレイ (LCD)は、薄型化および省エネルギー化を指向 するディスプレイである。 LCDは、携帯電話ディスプレイやデジタルカメラ用ディスプ レイなどの小型ディスプレイ、コンピューター用モニターやカーナビゲーシヨン用ディ スプレイなどの中型ディスプレイ、テレビ用ディスプレイなどの大型ディスプレイとして 、広範囲に利用されている。  [0002] A display for displaying an image is the most important machine interface in multimedia. Liquid crystal displays (LCDs) are displays that are aimed at reducing thickness and energy. LCDs are widely used as small displays such as mobile phone displays and digital camera displays, medium-sized displays such as computer monitors and car navigation displays, and large displays such as television displays.

[0003] LCDは別光源を必要とする非発光型ディスプレイであり、喑所において画像の視 認性が低いことがある。視認性を向上させるためには、ノ ックライト、すなわち液晶パ ネルの背面に設けられる面光源装置が必須となる。従来は、冷陰極管がバックライト の光源として使用されてきた。  [0003] An LCD is a non-light-emitting display that requires a separate light source, and image visibility may be low in some places. In order to improve the visibility, a knock light, that is, a surface light source device provided on the back surface of the liquid crystal panel is essential. Conventionally, a cold cathode tube has been used as a light source for a backlight.

[0004] 一方、 GaN系発光ダイオード (LED)の技術の進展は目覚しぐさらに産業進展に より低コスト化している。 LEDは冷陰極管に比べて低電圧で駆動でき、その寿命も 10 万時間以上である。また、構造的に薄型化が可能であり、冷陰極管に含まれる水銀 を使用しないため、環境負荷の低減も実現される。  [0004] On the other hand, the progress of GaN-based light emitting diode (LED) technology has been remarkably reduced due to industrial progress. LEDs can be driven at a lower voltage than cold-cathode tubes and have a lifetime of more than 100,000 hours. In addition, it can be thinned structurally, and since it does not use mercury contained in cold cathode fluorescent lamps, it can also reduce environmental impact.

そのため、擬似白色 LEDや、 3色 LED (赤、緑、青の 3つの LEDの組み合わせ)な どを用いたバックライト光源の開発が活発化している。 3色 LEDを用いたバックライト 光源は、単一発光スペクトルによる高い色再現性が可能なことから、特にテレビ等高 品位ディスプレイ向けに開発が活発化している。  For this reason, the development of backlight light sources using pseudo-white LEDs and three-color LEDs (a combination of three LEDs, red, green, and blue) has become active. Backlight light sources that use three-color LEDs are capable of high color reproducibility with a single emission spectrum, and are therefore being actively developed for high-quality displays such as televisions.

[0005] 小型および中型 LCDは、主にエッジライト型とよばれる LEDバックライトを用いた面 光源装置を有する。エッジライト型 LEDバックライトは、導光板の側面に配置された 光源であって、ポリイミド基板を使用したフレキシブル回路基板 (FPC)に実装された LEDを含む光源を有する。 LEDからの発光は指向性があるので、ディスプレイ画面 の輝度ムラや色ムラを防止するために、 LED周辺に白色の拡散反射体を設けて導 光板に均一な光を導入する工夫がなされて!/、る。 [0005] Small and medium-sized LCDs have a surface light source device using an LED backlight, which is mainly called an edge light type. The edge-light type LED backlight is a light source placed on the side of the light guide plate and mounted on a flexible circuit board (FPC) using a polyimide substrate. Having a light source including an LED. Since light emitted from the LED is directional, a device has been devised to introduce a uniform diffused light to the light guide plate by providing a white diffuse reflector around the LED to prevent uneven brightness and color on the display screen! /

たとえば、 LEDを実装される FPCと、導光板とを固定する両面テープに、反射機能 を付与したり(特許文献 1を参照)、 LEDの形状に合わせて孔を形成した白色樹脂チ ユーブを熱収縮させて反射体としたり(特許文献 2を参照)、凹型の筐体の凹内面を 光反射層として、さらに光反射層の上に拡散反射シートを配置して、その筐体の内部 に LEDを配置したり(特許文献 3を参照)することが提案されて!/、る。  For example, a reflective function is given to the double-sided tape that fixes the FPC on which the LED is mounted and the light guide plate (see Patent Document 1), or a white resin tube with holes that match the shape of the LED is heated. It can be shrunk to make a reflector (see Patent Document 2), or the concave inner surface of a concave housing can be used as a light reflecting layer, and a diffuse reflecting sheet can be placed on the light reflecting layer, and the LED inside the housing It is proposed to arrange (see Patent Document 3)!

[0006] さらに中型 LCD用バックライト(エッジライト型)では、輝度の均一化やモアレ防止の ため、導光板の下に配置される反射シートを、白色拡散反射シートとすると好ましい 場合がある。エッジライト型の LEDバックライトを用いた場合も、導光板の下に配置さ れる FPCの導光板側表面に白印刷反射部を設けて、 FPCに反射シートの機能を付 与することが提案されて!/、る(特許文献 4を参照)。  [0006] Further, in the case of a medium-size LCD backlight (edge light type), it may be preferable to use a white diffuse reflection sheet as the reflection sheet disposed under the light guide plate in order to make the luminance uniform and prevent moire. Even when an edge-light type LED backlight is used, it has been proposed to provide a function of a reflective sheet to the FPC by providing a white print reflector on the light guide plate side surface of the FPC placed under the light guide plate. Te! /, Ru (see Patent Document 4).

[0007] これらの提案では、 LEDを実装した基板に新たな白色反射層を設けたり、反射層 を設けた筐体を設置したりするため、別個の部材が必要とされたり、製造工程が増え たりするという問題がある。また、多数の LEDを設置する LEDバックライトは、発生す る熱を効率的に放熱しなければならないという重要な課題を有する。ところがこれらの 提案では、 LEDを実装した基板を、両面テープや接着剤などで金属などの放熱体 に固定しているので、その両面テープや接着剤などにより熱抵抗が上昇して放熱効 果が低下するおそれがある。放熱効果が低下すると、 LED発光効率の低下や、素子 寿命の短縮化、さらには素子破壊に至る恐れがある。  [0007] In these proposals, a new white reflective layer is provided on the substrate on which the LED is mounted, or a casing provided with the reflective layer is installed, so that a separate member is required, and the manufacturing process increases. There is a problem that. In addition, LED backlights with a large number of LEDs have the important issue of efficiently dissipating the generated heat. However, in these proposals, the substrate on which the LED is mounted is fixed to a heat sink such as metal with double-sided tape or adhesive, so that the thermal resistance increases due to the double-sided tape or adhesive, resulting in a heat dissipation effect. May decrease. If the heat dissipation effect is reduced, the LED luminous efficiency may be reduced, the device life may be shortened, and the device may be destroyed.

[0008] 白色で光沢のある紙、ポリエチレンテレフタレート樹脂や、ポリエステル系樹脂上に 、導電性インクで回路パターンを形成し、その回路パターンに LEDを実装する反射 体が開示されている(特許文献 5を参照)。この反射体も、両面テープや接着剤など で金属筐体などに固定して、熱放散性を高める必要がある。それだけでなぐ LEDの 実装は、現在、環境負荷の低減から、 SnAg合金系等の「鉛フリーはんだ」が一般的 に用いられている。鉛フリーはんだによるはんだ付けは、 220°C〜280°C程度の加熱 工程が必要であることから、 LEDを実装するときに反射体が熱ダメージを受けるという 問題があった。 [0008] A reflector is disclosed in which a circuit pattern is formed with conductive ink on white glossy paper, polyethylene terephthalate resin, or polyester resin, and an LED is mounted on the circuit pattern (Patent Document 5). See). This reflector also needs to be fixed to a metal housing with double-sided tape or adhesive to improve heat dissipation. For that reason, “Lead-free solder” such as SnAg alloy is generally used to reduce the environmental burden. Since soldering with lead-free solder requires a heating process of approximately 220 ° C to 280 ° C, the reflector is subject to thermal damage when mounting LEDs. There was a problem.

[0009] 一方、テレビなどで用いられる大型 LCDのバックライトは、主に直下型と称されるバ ックライトである。直下型バックライトは、拡散シートやライティングカーテンの下部に 配置された光源を有する。直下型 LEDバックライトでは、赤、緑、青の 3色を基本とす る LEDの混色により白色が形成されることが多い。そのため直下型 LEDバックライト の反射体は、高い拡散反射性を有する必要がある。また、直下型 LEDバックライトに おける LEDの実装数は非常に多いため、反射体自身の高い耐熱性や放熱性が求 められる。  [0009] On the other hand, the backlight of a large LCD used in a television or the like is a backlight mainly called a direct type. The direct type backlight has a light source arranged under the diffusion sheet or lighting curtain. In direct-type LED backlights, white is often formed by a mixture of LEDs based on the three colors of red, green, and blue. Therefore, the reflector of the direct type LED backlight needs to have high diffuse reflectivity. In addition, since the number of LEDs mounted in the direct type LED backlight is very large, the reflector itself must have high heat resistance and heat dissipation.

[0010] また、反射体に曲げ加工性を付与することも求められている。例えば、反射面側に 絶縁層を介して電気回路層が形成されていることを特徴とする、曲げ加工可能な基 材からなる反射体が開示されている(特許文献 6を参照)。曲げ加工可能な反射体を 用いれば、例えばフレキシブルディスプレイを得ることができる。  [0010] It is also required to impart bending workability to the reflector. For example, a reflector made of a base material that can be bent is disclosed, in which an electric circuit layer is formed on the reflecting surface side through an insulating layer (see Patent Document 6). If a reflector that can be bent is used, for example, a flexible display can be obtained.

[0011] さらに、紫外線領域から可視光領域の光に対して高い反射率を有するアルミニウム の物性を利用して、アルミニウム基板上に透明な絶縁層を介して回路を形成した回 路基板を、反射モジュールとして用いることが提案されて!/、る(特許文献 7を参照)。 特許文献 1 :特開 2005— 321586号公報 [0011] Further, a circuit board in which a circuit is formed on an aluminum substrate via a transparent insulating layer is reflected by utilizing the physical properties of aluminum having a high reflectance with respect to light in the ultraviolet region to the visible light region. It has been proposed to be used as a module! (See Patent Document 7). Patent Document 1: JP-A-2005-321586

特許文献 2 :特開 2005— 123103号公報  Patent Document 2: JP 2005-123103 A

特許文献 3:特開 2005— 135860号公報  Patent Document 3: Japanese Unexamined Patent Publication No. 2005-135860

特許文献 4 :特開 2001— 133757号公報  Patent Document 4: Japanese Patent Laid-Open No. 2001-133757

特許文献 5:特開平 9 115323号公報  Patent Document 5: JP-A-9 115323

特許文献 6 :特開 2003— 185813号公報  Patent Document 6: Japanese Unexamined Patent Publication No. 2003-185813

特許文献 7:特開 2005— 268405号公報  Patent Document 7: Japanese Unexamined Patent Publication No. 2005-268405

発明の開示  Disclosure of the invention

発明が解決しょうとする課題  Problems to be solved by the invention

[0012] 本発明は、曲げ加工性および拡散反射性を有する光反射体であって、 LEDが実 装されても、 LEDが発する熱を十分に放散する光反射体を提供することを目的とす る。さらに本発明は、液晶表示装置に用いられる LEDバックライト用の面光源装置を 提供することを目的とする。 課題を解決するための手段 [0012] An object of the present invention is to provide a light reflector that has bending workability and diffuse reflectivity, and sufficiently dissipates heat generated by the LED even when the LED is mounted. The A further object of the present invention is to provide a surface light source device for an LED backlight used in a liquid crystal display device. Means for solving the problem

[0013] すなわち本発明の第一は、以下に示す光反射体に関する。 [0013] That is, the first of the present invention relates to the following light reflector.

[I] 金属基材;前記金属基材の少なくとも片方の表面に設けられ、電気的絶縁性 を有し、顔料および無機フィラーの少なくともいずれかを含むエラストマ一を含有する 光反射層;ならびに前記光反射層上に形成された導電層を含む光反射体。  [I] a metal base; a light reflection layer provided on at least one surface of the metal base, having an electrical insulation, and containing an elastomer containing at least one of a pigment and an inorganic filler; and the light A light reflector including a conductive layer formed on a reflective layer.

[2] 前記エラストマ一がシリコーン樹脂またはシリコーンゴムを含む、 [1]に記載の 光反射体。  [2] The light reflector according to [1], wherein the elastomer includes silicone resin or silicone rubber.

[3] 前記無機フィラーが針状フィラーである、 [1]または [2]に記載の光反射体。  [3] The light reflector according to [1] or [2], wherein the inorganic filler is an acicular filler.

[4] 前記光反射層の全光線反射率が 88%以上である、 [1]〜[3]のいずれかに 記載の光反射体。  [4] The light reflector according to any one of [1] to [3], wherein the light reflection layer has a total light reflectance of 88% or more.

[5] 前記光反射層の拡散反射率が 80%以上である、 [1]〜[4]のいずれかに記 載の光反射体。  [5] The light reflector according to any one of [1] to [4], wherein the light reflection layer has a diffuse reflectance of 80% or more.

[6] 前記導電層が電気回路である、 [1]〜 [5]のいずれかに記載の光反射体。  [6] The light reflector according to any one of [1] to [5], wherein the conductive layer is an electric circuit.

[7] 前記電気回路は、エッチングで導電層の一部を除去することにより形成される 、 [6]に記載の光反射体。  [7] The light reflector according to [6], wherein the electric circuit is formed by removing a part of the conductive layer by etching.

[0014] 本発明の第二は、以下に示す光源、またはそれを含む液晶表示装置に関する。 A second aspect of the present invention relates to a light source shown below or a liquid crystal display device including the light source.

[8] [1]〜 [7]の!/、ずれかに記載の光反射体;前記電気回路層に実装された発 光ダイオード;および発光ダイオードが実装されて!/、な!/、電気回路を被覆するソルダ 一レジスト層を有する光源。  [8] The light reflector according to [1] to [7], or a light reflector according to any one of the above; a light emitting diode mounted on the electric circuit layer; and a light emitting diode mounted! /, N! / Solder covering the circuit A light source having a resist layer.

[9] 前記ソルダーレジスト層の表面における全光線反射率が 80%以上である、 [8 ]に記載の光源。  [9] The light source according to [8], wherein the total light reflectance on the surface of the solder resist layer is 80% or more.

[10] [8]または [9]に記載の光源、および前記光源からの光が導入される導光 板を有する、エッジライト型バックライト用面光源装置。  [10] An edge light type backlight surface light source device having the light source according to [8] or [9] and a light guide plate into which light from the light source is introduced.

[I I] [8]または [9]に記載の光源、および前記光源の発光側に配置された拡散 シートまたはライティングカーテンを有する、直下型バックライト用面光源装置。  [I I] A direct-type backlight surface light source device having the light source according to [8] or [9] and a diffusion sheet or a lighting curtain arranged on the light emission side of the light source.

[12] [10]に記載の面光源装置をバックライトとして有する液晶表示装置。  [12] A liquid crystal display device having the surface light source device according to [10] as a backlight.

[13] [11]に記載の面光源装置をバックライトとして有する液晶表示装置。  [13] A liquid crystal display device having the surface light source device according to [11] as a backlight.

発明の効果 [0015] 本発明により、曲げ加工性および拡散反射性を有する光反射体であって、反射面 に LEDを実装しても、発せられる熱が十分に放散される光反射体を提供することが できる。本発明の光反射体は、従来の光反射体と比較して簡便なプロセスで製造す ること力 Sできる。さらに本発明の光反射体を用いて LEDバックライトを得ることができ、 それを液晶表示装置に適用することができる。 The invention's effect [0015] According to the present invention, there is provided a light reflector having bending workability and diffuse reflectivity, in which even if an LED is mounted on a reflection surface, the emitted heat is sufficiently dissipated. it can. The light reflector of the present invention can be manufactured with a simple process as compared with the conventional light reflector. Furthermore, an LED backlight can be obtained using the light reflector of the present invention, and can be applied to a liquid crystal display device.

図面の簡単な説明  Brief Description of Drawings

[0016] [図 1A]光反射体の積層状態を示す断面図である。  FIG. 1A is a cross-sectional view showing a laminated state of light reflectors.

[図 1B]光反射体を導電層側からみた上面図である。  FIG. 1B is a top view of the light reflector as viewed from the conductive layer side.

[図 2]光反射体に LEDを実装した光源の断面図である。  FIG. 2 is a cross-sectional view of a light source in which an LED is mounted on a light reflector.

[図 3A]光反射体にサイドビュータイプ LEDを実装した光源の断面図である。  FIG. 3A is a cross-sectional view of a light source in which a side view type LED is mounted on a light reflector.

[図 3B]凹型の光反射体にトップビュータイプ LEDを実装した光源の断面図である。  FIG. 3B is a cross-sectional view of a light source in which a top view type LED is mounted on a concave light reflector.

[図 3C]L字型の光反射体にトップビュータイプ LEDを実装した光源の断面図である。  FIG. 3C is a cross-sectional view of a light source in which a top view type LED is mounted on an L-shaped light reflector.

[図 3D]平板型の光反射体にトップビュータイプ LEDを実装した光源の断面図である  FIG. 3D is a cross-sectional view of a light source in which a top view type LED is mounted on a flat light reflector.

[図 4A]図 3Aの光源に導光板を装着したエッジライト型バックライトのための面光源装 置の断面図である。 4A is a cross-sectional view of a surface light source device for an edge light type backlight in which a light guide plate is attached to the light source of FIG. 3A.

[図 4B]図 3Bの光源に導光板を装着したエッジライト型バックライトのための面光源装 置の断面図である。  4B is a cross-sectional view of a surface light source device for an edge light type backlight in which a light guide plate is attached to the light source of FIG. 3B.

[図 4C]図 3Cの光源に導光板を装着したエッジライト型バックライトのための面光源装 置の断面図である。  4C is a cross-sectional view of a surface light source device for an edge light type backlight in which a light guide plate is attached to the light source of FIG. 3C.

[図 4D]図 3Dの光源に拡散シートを装着した直下型バックライトのための面光源装置 の断面図である。  4D is a cross-sectional view of a surface light source device for a direct type backlight in which a diffusion sheet is attached to the light source of FIG. 3D.

[図 5A]図 4Aのエッジライト型バックライトのための面光源装置を有する液晶表示装置 の断面図である。  5A is a cross-sectional view of a liquid crystal display device having a surface light source device for the edge light type backlight of FIG. 4A.

[図 5B]図 4Bのエッジライト型バックライトのための面光源装置を有する液晶表示装置 の断面図である。  5B is a cross-sectional view of a liquid crystal display device having a surface light source device for the edge light type backlight of FIG. 4B.

[図 5C]図 4Cのエッジライト型バックライトのための面光源装置を有する液晶表示装置 の断面図である。 [図 5D]図 4Dの直下型バックライトを含む面光源装置を有する液晶表示装置の断面 図である。 FIG. 5C is a cross-sectional view of a liquid crystal display device having a surface light source device for the edge light type backlight of FIG. 4C. 5D is a cross-sectional view of a liquid crystal display device having a surface light source device including the direct type backlight in FIG. 4D.

[図 6A]本発明(実施例 2)の反射板と、従来(比較例 1)の反射板とを加熱処理して、 その耐熱性を比較したグラフであり、加熱前後の反射率の変化を示している。  [FIG. 6A] A graph comparing the heat resistance of the reflector of the present invention (Example 2) and the conventional (Comparative Example 1) reflector and comparing the heat resistance before and after heating. Show.

[図 6B]本発明(実施例 2)の反射板と、従来(比較例 1)の反射板とを加熱処理して、 その耐熱性を比較したグラフであり、加熱時間に対する反射率の経時変化を示して いる。  [FIG. 6B] A graph comparing the heat resistance of the reflector of the present invention (Example 2) and the conventional (Comparative Example 1) reflector and comparing the heat resistance with time. Is shown.

[図 7]本発明(実施例 2)の反射板と、従来 (比較例 1)の反射板とを紫外線照射処理 して、その耐紫外泉性を比較したグラフであり、照射前後の反射率の変化を示してい  FIG. 7 is a graph comparing the ultraviolet spring resistance of the reflector of the present invention (Example 2) and the conventional (Comparative Example 1) reflector, and comparing the resistance before and after the irradiation. Shows changes

[図 8]本発明(実施例 2)の反射板と、従来 (比較例 1)の反射板とを擬似太陽光照射 処理して、その耐光熱性を比較したグラフであり、照射前後の反射率の変化を示して いる。 FIG. 8 is a graph comparing the photothermal resistance of the reflector of the present invention (Example 2) and the conventional (Comparative Example 1) reflector and comparing the photothermal resistance. Changes.

発明を実施するための最良の形態  BEST MODE FOR CARRYING OUT THE INVENTION

[0017] 1.光反射体について  [0017] 1. About light reflector

本発明の光反射体は、 1)金属基材、 2)金属基材上に設けられた光反射層、 3)光 反射層上に設けられた導電層を含む。図 1Aおよび図 1Bは、本発明の光反射体の 構成を示している。図 1 Aは光反射体の積層状態を示しており、図 1Bは光反射体を 導電層の側から見た上面図である。 10は金属基材、 20は電気絶縁性を有する光反 射層、 30は導電層である。  The light reflector of the present invention includes 1) a metal substrate, 2) a light reflection layer provided on the metal substrate, and 3) a conductive layer provided on the light reflection layer. 1A and 1B show the configuration of the light reflector of the present invention. FIG. 1A shows the laminated state of the light reflectors, and FIG. 1B is a top view of the light reflectors as viewed from the conductive layer side. 10 is a metal substrate, 20 is a light reflecting layer having electrical insulation, and 30 is a conductive layer.

[0018] 金属基材について  [0018] Metal substrate

金属基材の好適な材料の例には、アルミニウム、アルミニウム合金、マグネシウム合 金、ステンレス鋼、銅、銅亜鉛合金、ニッケル、ニッケル系合金、チタン、チタン合金 などが含まれる。軽量化の観点からは、アルミニウム合金やマグネシウム合金が好ま しく用いられる。アルミニウム合金には、一般的に、珪素、マグネシウムまたは銅が添 カロされている。金属基材の材料は、強度や耐食性を兼ね備えているステンレス鋼で あってもよい。ステンレス鋼は、クロムを含有したフェライト系や、クロムとニッケルを含 有したオーステナイト系などいずれでもよぐ特に限定されない。好ましいステンレス ま岡の具体列 ίこ (ま、 SUS304, SUS316など含まれる。 Examples of suitable materials for the metal substrate include aluminum, aluminum alloy, magnesium alloy, stainless steel, copper, copper-zinc alloy, nickel, nickel-based alloy, titanium, titanium alloy and the like. From the viewpoint of weight reduction, an aluminum alloy or a magnesium alloy is preferably used. In general, silicon, magnesium, or copper is added to an aluminum alloy. The metal base material may be stainless steel having both strength and corrosion resistance. The stainless steel is not particularly limited as long as it is ferritic containing chromium or austenitic containing chromium and nickel. Preferred stainless steel Maoka's concrete line (including SUS304, SUS316, etc.)

[0019] また金属基材は、光反射体に装着された光源 (例えば LED)で発生した熱を放散 する機能を有する。したがって金属基材の材料は、放熱性の高い銅や銅合金である ことが好ましい。銅合金の好適な例には真鍮が含まれる。  [0019] The metal substrate has a function of radiating heat generated by a light source (for example, LED) mounted on the light reflector. Therefore, the metal base material is preferably copper or copper alloy having high heat dissipation. Suitable examples of copper alloys include brass.

[0020] 本発明の光反射体は、折り曲げ加工が可能であることが好ましい。したがって金属 基材の厚さは、工業的に折り曲げ可能な厚さとすることが好ましい。工業的に折り曲 げ加工可能な金属基材の厚さとは、好ましくは 0. 03mm〜; 1mmであり、より好ましく は 0. 05mm〜0. 5mmである。金属基材が薄すぎると剛性が低くなり、得られた光 反射体に光源を装着するときに、固定しに《なるおそれがある。一方、金属基材が 厚すぎると曲げ加工が困難になるおそれがある。  [0020] It is preferable that the light reflector of the present invention can be bent. Therefore, it is preferable that the thickness of the metal substrate be industrially bendable. The thickness of the metal base material that can be bent industrially is preferably 0.03 mm to 1 mm, and more preferably 0.05 mm to 0.5 mm. If the metal substrate is too thin, the rigidity will be low, and there is a risk that when the light source is attached to the obtained light reflector, it will be fixed. On the other hand, if the metal substrate is too thick, bending may be difficult.

[0021] 光反射層について  [0021] About the light reflection layer

本発明の光反射体は、金属基材の片面または両面に設けられた光反射層を含む。 光反射層は電気絶縁性材料で構成されることが好ましぐ通常は電気絶縁性の高分 子材料で構成される。電気絶縁性の高分子材料の例には、エポキシ、ポリエステル、 ポリブタジエン、ァノレキド、エポキシエステノレ、ポリアミド、シリコーン、およびテフロン( 登録商標)、ならびにこれらをブレンドした材料が含まれる。光反射層は単層でも複 数層の積層体であっても構わなレ、。  The light reflector of this invention contains the light reflection layer provided in the single side | surface or both surfaces of the metal base material. The light reflecting layer is preferably made of an electrically insulating material, and is usually made of an electrically insulating polymer material. Examples of electrically insulating polymeric materials include epoxies, polyesters, polybutadienes, anoloxides, epoxyesterols, polyamides, silicones, and Teflon and blended materials thereof. The light reflecting layer may be a single layer or a laminate of multiple layers.

[0022] 前述の通り本発明の光反射体は、折り曲げ加工が可能であることが好ましいので、 光反射層に含まれる高分子材料は弾性を有することが好ましい。弾性を有する高分 子材料を、エラストマ一と称する。エラストマ一の例には、ゴムや熱可塑性エラストマ 一などが含まれる。エラストマ一は、より好ましくはシリコーン樹脂またはシリコーンゴ ムである。シリコーン樹脂のエラストマ一とは、シリコーン熱可塑性エラストマ一を含む [0022] As described above, since the light reflector of the present invention is preferably foldable, the polymer material contained in the light reflection layer preferably has elasticity. A polymer material having elasticity is called an elastomer. Examples of elastomers include rubber and thermoplastic elastomers. The elastomer is more preferably a silicone resin or a silicone rubber. Silicone resin elastomer includes silicone thermoplastic elastomer

Yes

[0023] また光反射層は、金属基材と導電層とを接着させる接着層としても機能することが 好ましい。光反射層に、接着性を有する材料を使用すれば、光反射層上に導電層を 容易に形成することができ、かつ金属基材と導電層の接合層としても機能する。した がって、光反射層に含まれる高分子材料は、導電層(例えば金属層)との接着性が 高レ、高分子材料であることが好ましレ、。導電層 (金属層)との接着性が高レ、高分子材 料の例には、エポキシ系接着性樹脂やシリコーン系接着性樹脂などが含まれるが、 特にシリコーン接着性樹脂が好ましい。 [0023] The light reflecting layer preferably also functions as an adhesive layer for bonding the metal substrate and the conductive layer. If an adhesive material is used for the light reflecting layer, the conductive layer can be easily formed on the light reflecting layer, and also functions as a bonding layer between the metal substrate and the conductive layer. Therefore, it is preferable that the polymer material contained in the light reflecting layer has high adhesion to the conductive layer (for example, a metal layer) and is a polymer material. High adhesion to conductive layer (metal layer), polymer material Examples of the material include an epoxy adhesive resin and a silicone adhesive resin, and a silicone adhesive resin is particularly preferable.

[0024] さらに光反射層には、高い耐熱性も求められる。光反射層に求められる耐熱性とは 、実際上は、高温 (例えば 180〜280°C)に曝される「はんだ付け工程」を経ても、光 反射層の反射率がほとんど低下しないこと;光反射層の絶縁抵抗値がほとんど低下 しないこと;基材と光反射層間の接着強度および光反射層と電気回路層間の接着強 度がほとんど低下しないことなどを意味する。したがって、光反射層に含まれる高分 子材料には、熱分解による変質が少ないことが求められる。例えば、 180〜280°Cに おける熱分解による高分子材料の重量低下力 10%以下であることが好ましぐ 5% 以下であること力 り好ましく、 3%以下であることがさらに好ましい。耐熱性を有する 高分子材料の例にはシリコーン樹脂およびシリコーンゴムが含まれる。  [0024] Further, the light reflecting layer is also required to have high heat resistance. The heat resistance required for the light reflecting layer is that, in practice, the reflectance of the light reflecting layer is hardly lowered even after a “soldering process” exposed to a high temperature (for example, 180 to 280 ° C.); It means that the insulation resistance value of the reflective layer hardly decreases; the adhesive strength between the base material and the light reflecting layer and the adhesive strength between the light reflective layer and the electric circuit layer hardly decrease. Therefore, the polymer material contained in the light reflecting layer is required to have little alteration due to thermal decomposition. For example, the weight reduction force of the polymer material due to thermal decomposition at 180 to 280 ° C. is preferably 10% or less, more preferably 5% or less, and even more preferably 3% or less. Examples of the heat-resistant polymer material include silicone resin and silicone rubber.

[0025] 光反射層の厚さは、所望する光反射率などに応じて適宜選択されるが、通常は 10 μ m〜500 μ m、より望ましくは 30 μ m〜200 μ mである。  [0025] The thickness of the light reflecting layer is appropriately selected depending on the desired light reflectance, but is usually 10 μm to 500 μm, more preferably 30 μm to 200 μm.

[0026] さらに、光反射層を構成する高分子材料に、顔料または無機フィラーを含ませること により、拡散反射性を高めることが好ましい。顔料と無機フィラーの両方を含有しても 、いずれかを含有してもよい。光反射層を構成する高分子材料は、白色顔料や無機 フィラーを含有したシリコーン樹脂やシリコーンゴムが好適に使用される。  [0026] Further, it is preferable to enhance the diffuse reflectivity by including a pigment or an inorganic filler in the polymer material constituting the light reflecting layer. Either a pigment and an inorganic filler may be contained, or any of them may be contained. As the polymer material constituting the light reflection layer, a silicone resin or silicone rubber containing a white pigment or an inorganic filler is preferably used.

顔料は白色顔料であることが好ましい。一方、無機フイラ一は、セラミックなど力も任 意に選択されうる。好ましいセラミックの例には、ダイヤモンド粉、酸化アルミニウム、 酸化ケィ素、酸化ジルコニウム、酸化亜鉛、酸化チタン、窒化ホウ素、窒化アルミユウ ム、窒化珪素、窒化チタンなどが含まれる。無機フィラーを含有する高分子材料で光 反射層を形成すると、高分子材料のみからなる材料を用いる場合よりも、拡散反射性 の向上のほか、熱伝導率も向上する。光反射層の熱伝導率が高まると、光反射層上 に設けた光源から発生した熱が、光反射層を介して金属基材に効率よく伝わり、効率 的に放熱される。  The pigment is preferably a white pigment. On the other hand, inorganic fillers can be arbitrarily selected from ceramics and other forces. Examples of preferred ceramics include diamond powder, aluminum oxide, silicon oxide, zirconium oxide, zinc oxide, titanium oxide, boron nitride, aluminum nitride, silicon nitride, titanium nitride and the like. When the light reflecting layer is formed of a polymer material containing an inorganic filler, in addition to improving the diffuse reflectivity, the thermal conductivity is improved as compared with the case of using a material composed only of the polymer material. When the thermal conductivity of the light reflecting layer increases, the heat generated from the light source provided on the light reflecting layer is efficiently transmitted to the metal substrate through the light reflecting layer and efficiently dissipated.

[0027] 光反射層を構成する高分子材料に含有される顔料や無機フィラーの種類、粒子径 、形状、および含有量などは、光反射層の拡散反射性能、熱伝導性能や接着性能 などを鑑みて、適宜選択される。例えば、無機フィラーの形状を針状とすると、光反射 層の接着層としての機能 (金属基材と導電層との接着性)を高めることができる。針状 フィラーとは、その平均繊維径が 0. 1〜1〃111、好ましくは 0.;!〜 0. 3〃mであり、そ の平均繊維長が 0· 5〜50 111、好ましくは0. 5〜; 10 mであるフィラーを意味する 。フィラーの平均繊維径ゃ平均繊維長などの形状は、光反射層の断面を走査型電 子顕微鏡で観察することによって測定することができる。 [0027] The kind, particle diameter, shape, and content of pigments and inorganic fillers contained in the polymer material constituting the light reflecting layer are determined by the diffuse reflecting performance, heat conduction performance, adhesive performance, etc. of the light reflecting layer. In view of this, it is appropriately selected. For example, if the shape of the inorganic filler is needle-like, light reflection The function of the layer as an adhesive layer (adhesiveness between the metal substrate and the conductive layer) can be enhanced. The acicular filler has an average fiber diameter of 0.1 to 1 mm 111, preferably 0 .;! To 0.3 mm, and an average fiber length of 0.5 · 5 to 50 111, preferably 0. 5 ~; means filler that is 10 m. Shapes such as the average fiber diameter and average fiber length of the filler can be measured by observing the cross section of the light reflecting layer with a scanning electron microscope.

[0028] 光反射層を構成する高分子材料には、紫外線吸収剤や安定剤や、その他の添カロ 剤が含まれていてもよい。  [0028] The polymer material constituting the light reflecting layer may contain an ultraviolet absorber, a stabilizer, and other additive agents.

[0029] 光反射層の反射率は、導電層側から光を入射させて測定する。光反射層の全光線 反射率は、 80%以上であることが好ましぐ 85%以上であることがより好ましぐ 88% 以上であることがさらに好ましぐ 90%以上であればなお好ましい。全光線反射率と は、正反射率と拡散反射率を合わせたものである。ここで正反射率とは、入射光量に 対し、入射角と等しい反射角で反射した光量の割合をいう。光の入射面に凹凸があ る場合、入射光の入射角と異なる反射角で反射する光が発生する。拡散反射率とは 、入射光量に対し、この入射角と異なる反射角で反射する光量の割合をいう。  [0029] The reflectance of the light reflecting layer is measured by making light incident from the conductive layer side. The total light reflectance of the light reflecting layer is preferably 80% or more, more preferably 85% or more, more preferably 88% or more, and even more preferably 90% or more. . The total light reflectance is the sum of regular reflectance and diffuse reflectance. Here, the regular reflectance refers to the ratio of the amount of light reflected at a reflection angle equal to the incident angle with respect to the amount of incident light. When the light incident surface is uneven, light is reflected at a reflection angle different from the incident angle of the incident light. The diffuse reflectance is the ratio of the amount of light reflected at a reflection angle different from the incident angle with respect to the amount of incident light.

[0030] 全光線反射率は、積分球を取り付けた、一般の可視紫外分光光度計で容易に測 定できる。また全光線反射率は、波長 550nmにおける全光線反射率としてもよい。よ り実際的には、 JIS R3106に記載の可視光反射率を計算するための重価係数を用 いて算出してもよい。  [0030] The total light reflectance can be easily measured with a general visible ultraviolet spectrophotometer equipped with an integrating sphere. The total light reflectance may be the total light reflectance at a wavelength of 550 nm. More practically, the weight coefficient for calculating the visible light reflectance described in JIS R3106 may be used.

[0031] 光反射層の拡散反射率は、反射面の部材中での位置や、それを装機したデバイス の使用目的などによって、適当な値が異なる。例えば、波長 550nmにおける全光線 反射率に対して、拡散反射率は 10〜50%程度が好ましい場合もあれば、 80%以上 が好ましい場合もある。拡散反射率は、全光線反射率と同様に、積分球を取り付けた 一般の可視紫外分光光度計で測定できる。  [0031] The diffuse reflectance of the light reflecting layer has an appropriate value depending on the position of the reflecting surface in the member and the purpose of use of the device equipped with the reflecting surface. For example, with respect to the total light reflectance at a wavelength of 550 nm, the diffuse reflectance may be preferably about 10 to 50%, or may be preferably 80% or more. Similar to the total light reflectance, the diffuse reflectance can be measured with a general visible ultraviolet spectrophotometer equipped with an integrating sphere.

[0032] さらに本発明の光反射体の光反射層は、 C光源からの光を反射して、無色に近い 反射光を発することが好ましい。光の色はハンター値で示されることがある。ハンター 値とは、均等色空間を用いた表色系の一つであり、 JIS Z8722に準拠して測定され る。標準の光 Cで照明した表面色のハンター値 aおよび bは、以下の式で求められる。 [0033] [数 1] a = 17.5 (1.02X10-Y,oW Y,0 [0032] Further, the light reflecting layer of the light reflector of the present invention preferably reflects light from a C light source and emits light that is nearly colorless. The color of light may be indicated by a Hunter value. Hunter value is a color system that uses a uniform color space, and is measured according to JIS Z8722. The hunter values a and b of the surface color illuminated with the standard light C are obtained by the following equations. [0033] [Equation 1] a = 17.5 (1.02X 10 -Y, oW Y, 0

b = 7.0 (Y-0.847Z,0) /V"YI0 b = 7.0 (Y-0.847Z, 0 ) / V "Y I0

[0034] 上記数式において、 X 、Y 、Z は X Y Z 表色系の三刺激値を示し、 380nm〜7 [0034] In the above formula, X, Y and Z represent tristimulus values of the XYZ color system, 380 nm to 7

10 10 10 10 10 10  10 10 10 10 10 10

80nmの波長の光に対して、以下の式で求められる。  For light with a wavelength of 80 nm, the following equation is used.

[0035] [数 2]

Figure imgf000011_0001
Figure imgf000011_0002
[0035] [Equation 2]
Figure imgf000011_0001
Figure imgf000011_0002

Figure imgf000011_0003
Figure imgf000011_0003

S( X ):色の表示に用いる標準の光の分光分布  S (X): Spectral distribution of standard light used for color display

Χ( Λ δ(Λ )、 (λ ): Χ10Υ10Ζιο表色系における等色関数Χ (Λ δ (Λ), (λ): 等10 Υ 10 Ζιο Color matching function in the color system

R(^):分光 (立体角) 反射率 R (^): Spectral (solid angle) reflectance

[0036] 本発明の光反射体の光反射層が、 C光源からの光を反射した光の色を、ハンター の aおよび bで表現すると、 aおよび bの!/、ずれの絶対値も 7以下であることが好ましく 、 5以下であることがより好ましくは、 3以下であることがさらに好ましい。 [0036] When the light reflecting layer of the light reflector of the present invention expresses the color of the light reflected from the C light source by the hunter's a and b, the absolute value of the! Is preferably 5 or less, more preferably 5 or less, and even more preferably 3 or less.

[0037] 導電層について  [0037] Regarding the conductive layer

本発明の光反射体は、光反射層上に設けられた導電層を含む。導電層の材質は 金属であることが好ましぐ好ましい金属の例には銅、アルミニウム、銀、金、白金など が含まれる。これらの金属の箔ゃ薄膜が好ましい。さらに導電層の材質は、電気抵抗 とエッチング特性を考慮すると銅が好ましぐまた反射特性が低く色味が少なレ、アルミ ユウムも好ましい。「金属箔」とは、光反射層に設けられる前にシート状にされた金属 の薄膜であり、「金属薄膜」とは、光反射層に印刷法、蒸着法やめつき法により形成さ れた金属の薄膜である。 The light reflector of the present invention includes a conductive layer provided on the light reflection layer. Examples of preferred metals that are preferably made of metal for the conductive layer include copper, aluminum, silver, gold, and platinum. Is included. These metal foils are preferably thin films. In addition, the material of the conductive layer is preferably copper in consideration of electric resistance and etching characteristics, and is preferably aluminum or aluminum having low reflection characteristics and low color. "Metal foil" is a metal thin film formed into a sheet before being provided on the light reflecting layer. "Metal thin film" is formed on the light reflecting layer by a printing method, vapor deposition method or clinging method. It is a metal thin film.

[0038] 導電層の厚さは、実装される LEDの電力により適宜決定される。金属箔の厚さは 1 〜100 μ mの範囲であることが好ましぐ金属薄膜の厚さは 0· 5〜20 μ mの範囲で あることが好ましい。 [0038] The thickness of the conductive layer is appropriately determined depending on the power of the mounted LED. The thickness of the metal foil is preferably in the range of 1 to 100 μm, and the thickness of the metal thin film is preferably in the range of 0.5 to 20 μm.

[0039] また導電層は、電気回路であってもよい。導電層や電気回路の形成方法は、後に 詳細に説明する。  [0039] The conductive layer may be an electric circuit. A method for forming the conductive layer and the electric circuit will be described in detail later.

[0040] 本発明の光反射体は、光反射層と金属基材の間に、樹脂フィルムや接着層を有し ていてもよい。例えば光反射体は、導電層/光反射層/樹脂フィルム/接着層/金 属基材の構成を有していてもよい。導電層と金属基板とに挟まれる部材の厚さの合 計(光反射層を含む)は、 2〜200 111であることが好ましい。これらの部材の厚さが 大きすぎると、放熱効果が低下するおそれがある。前述の光反射率も考慮すると、光 反射層の厚みとしては 30〜200 H mであることが好まし!/、。  [0040] The light reflector of the present invention may have a resin film or an adhesive layer between the light reflection layer and the metal substrate. For example, the light reflector may have a configuration of conductive layer / light reflection layer / resin film / adhesive layer / metal substrate. The total thickness (including the light reflection layer) of the members sandwiched between the conductive layer and the metal substrate is preferably 2 to 200111. If the thickness of these members is too large, the heat dissipation effect may be reduced. Considering the light reflectance described above, the thickness of the light reflecting layer is preferably 30 to 200 Hm! /.

[0041] 光反射層の表面は、電気回路やその他必要な導電層のみによって覆われており、 できるだけ広!/、領域の光反射層が露出して!/、ること力 S好まし!/、。光反射体の反射性 を高めるためである。  [0041] The surface of the light reflection layer is covered only with an electric circuit and other necessary conductive layers, and it is as wide as possible! ,. This is to increase the reflectivity of the light reflector.

[0042] 本発明の光反射体は曲げ加工可能であることが好ましい。曲げ加工可能とは、例 えばプレス加工などの機械加工によって、光反射層側を内側にして曲げ角度 90° で屈曲させても構成部材の性能がほとんど低下せず、曲げ加工時の形状を保持でき ることをいう。  [0042] The light reflector of the present invention is preferably bendable. Bending is possible, for example, by pressing, or other mechanical processing, with the light reflecting layer side facing inward and bending at a bending angle of 90 °. What you can do.

[0043] 本発明の光反射体は、反射機能を付与するための光反射層を回路基板に別個に 形成する必要がないので、簡便な工程で製造できる。また、光反射層が弾性を有す る樹脂で形成されるので曲げ加工可能である。さらに、光反射層を耐熱性高分子材 料で形成すれば、高温での LED実装が可能である。また金属基材を用いているの で、光反射体の放熱性も高い。本発明の光反射体は、室内照明、屋内照明、自動車 用照明、装飾用照明など様々な照明用反射体として用いることができ、もちろん表示 パネルの面光源装置の光反射体として用いることもできる。 [0043] The light reflector of the present invention can be manufactured by a simple process because it is not necessary to separately form a light reflection layer for providing a reflection function on the circuit board. In addition, since the light reflecting layer is formed of an elastic resin, it can be bent. Furthermore, if the light-reflecting layer is made of a heat-resistant polymer material, LED mounting at high temperatures is possible. Moreover, since the metal base material is used, the heat dissipation of the light reflector is high. The light reflector of the present invention is used for indoor lighting, indoor lighting, and automobiles. It can be used as various reflectors for lighting such as lighting for lighting and decoration, and can also be used as a light reflector for a surface light source device of a display panel.

[0044] 2.光反射体の製造方法について [0044] 2. Manufacturing method of light reflector

本発明の光反射体は、本発明の効果を損なわない限り任意の方法で製造されうる 。例えば、 1)金属基材に電気絶縁性を有する光反射層を塗布形成し、さらに光反射 層上に導電層を形成する方法、 2)光反射層を接着シートとして準備して、シートの両 表面のそれぞれに金属基材と、導電層となる金属箔とを貼り合わせる方法、 3)金属 基材と、導電層となる金属箔の両方に、電気絶縁性を有する高分子材料 (光反射層 の材料)を塗布して、互!/、の塗布面を貼り合わせて光反射層を形成する方法などが ある。貼り合わせは、材料の特性に応じて、熱間圧着、熱間接着、冷間圧着、冷間接 着などで行えばよい。  The light reflector of the present invention can be produced by any method as long as the effects of the present invention are not impaired. For example, 1) a method of applying a light reflecting layer having electrical insulation on a metal substrate, and further forming a conductive layer on the light reflecting layer; 2) preparing the light reflecting layer as an adhesive sheet; A method in which a metal substrate and a metal foil to be a conductive layer are bonded to each of the surfaces, 3) a polymer material (light reflecting layer) having electrical insulation properties on both the metal substrate and the metal foil to be a conductive layer There is a method of forming a light reflecting layer by applying the material (2) and pasting the coated surfaces of each other. Bonding may be performed by hot pressing, hot bonding, cold pressing, cold indirect bonding, or the like depending on the characteristics of the material.

[0045] 導電層を金属箔とする場合には、光反射層には接着性を有する樹脂が含まれるこ とが好ましい。金属箔と光反射層を容易に接着させるためである。一方、金属箔を接 着させることなく露出させた部分の光反射層は、接着性を有していなくてもよい。  [0045] When the conductive layer is a metal foil, the light reflecting layer preferably contains an adhesive resin. This is because the metal foil and the light reflection layer are easily bonded. On the other hand, the portion of the light reflecting layer exposed without attaching the metal foil may not have adhesiveness.

[0046] 導電層を金属薄膜とする場合には、金属薄膜を蒸着法、印刷法やめつき法など、 一般的な方法で形成することができる。金属薄膜を光反射層に形成する場合に、光 反射層に接着性を有する樹脂を含ませる必要は特にないが、接着性を得るために、 金属薄膜形成前に、光反射層表面をプラズマ処理、コロナ処理や UVオゾン処理な どにより、接着性を与えることができる。蒸着法の例には抵抗加熱による真空蒸着法 、電子ビーム加熱による真空蒸着法、スパッタリング法、イオンプレーティング法など の種々の方法が含まれる。一つの方法で形成しても、複数の方法を併用してもよい。  [0046] When the conductive layer is a metal thin film, the metal thin film can be formed by a general method such as a vapor deposition method, a printing method, or a staking method. When forming a metal thin film on the light reflecting layer, it is not particularly necessary to include an adhesive resin in the light reflecting layer, but in order to obtain adhesion, the surface of the light reflecting layer is plasma treated before forming the metal thin film. Adhesion can be given by corona treatment or UV ozone treatment. Examples of the evaporation method include various methods such as a vacuum evaporation method by resistance heating, a vacuum evaporation method by electron beam heating, a sputtering method, and an ion plating method. One method may be used, or a plurality of methods may be used in combination.

[0047] 導電層は、電気回路であってもよい。電気回路は、一般的な方法で形成されうる。  [0047] The conductive layer may be an electric circuit. The electric circuit can be formed by a general method.

例えば、 1)光反射層に設けた導電層の一部をエッチング除去して電気回路を形成し てもよぐ 2)光反射層に、導電性材料を直接描画して電気回路を形成してもよい。 好ましくは、光反射層に設けた導電層の一部をエッチングで除去して電気回路を 形成する。電気回路の線幅が細い場合には、形成された導電層に感光性樹脂を塗 布または貼り合わせて;電気回路パターンを有するマスクをかけて露光して、不要な 樹脂を除去し;露出した導電層を適当なエッチング材で除去して、電気回路を形成 する。一方、電気回路の線幅がそれほど細くない場合には、形成された導電層上に 感光性樹脂を印刷法で回路状に塗布して;露出してレ、る導電層を適当なエッチング 材で除去して、電気回路を形成する。感光性樹脂は、ネガ型またはポジ型のいずれ でもよぐ特に制限されない。 For example, 1) An electric circuit may be formed by etching away a part of the conductive layer provided on the light reflecting layer. 2) An electric circuit is formed by directly drawing a conductive material on the light reflecting layer. Also good. Preferably, a part of the conductive layer provided in the light reflection layer is removed by etching to form an electric circuit. If the line width of the electric circuit is narrow, apply or bond a photosensitive resin to the formed conductive layer; expose it with a mask having an electric circuit pattern to remove unnecessary resin; Remove the conductive layer with a suitable etching material to form an electrical circuit To do. On the other hand, when the line width of the electric circuit is not so thin, a photosensitive resin is applied to the formed conductive layer in a circuit form by a printing method; the exposed conductive layer is exposed with an appropriate etching material. Remove to form an electrical circuit. The photosensitive resin is not particularly limited and may be either a negative type or a positive type.

[0048] 導電層が銅である場合には、第 II塩化鉄水溶液などを用いるウエットエッチングや、 プラズマなどを用いるドライエッチングなどによって、銅の電気回路を形成できる。  [0048] When the conductive layer is copper, an electrical circuit of copper can be formed by wet etching using a ferric iron chloride aqueous solution or dry etching using plasma or the like.

[0049] 3.光源について  [0049] 3. About the light source

本発明の光反射体は、導電層上に発光ダイオード (LED)を実装されることにより、 光源として用いられうる。赤、緑、青の発光をする LEDや、いわゆる擬似白色発光の LEDが好ましく使用される。図 2には、光反射体 (金属基材 10、光反射層 20および 導電層 30を含む)に、発光ダイオード 100をはんだ 40で実装した様子が示される。  The light reflector of the present invention can be used as a light source by mounting a light emitting diode (LED) on a conductive layer. LEDs that emit red, green, and blue light, and so-called pseudo white light-emitting LEDs are preferably used. FIG. 2 shows a state in which the light emitting diode 100 is mounted on the light reflector (including the metal substrate 10, the light reflection layer 20, and the conductive layer 30) with the solder 40.

[0050] LEDは、サイドビュータイプおよびトップビュータイプのいずれであってもよい。図 3 Aには、サイドビュータイプ LED110を光反射体に実装した光源が示される。サイドビ ユータイプ LED110は、発光面が実装面に垂直であるタイプの LEDであり、光出射 部 130から実装面に対して平行の光を発する。図 3B〜図 3Dには、トップビュータイ プ LED120を光反射体に実装した光源が示される。トップビュータイプ LED120は、 発光面が実装面に平行であるタイプの LEDであり、光出射部 130から実装面に対し て垂直の光を発する。図 3Bおよび図 3Cには、トップビュータイプの LEDが示されて いるが、サイドビュータイプの LEDを適用してもよぐ光源の設計に応じて適宜選ば れる。一方、図 3Dには、図に示されたようにトップビュータイプの LEDが適用されるこ とが好ましい。  [0050] The LED may be either a side view type or a top view type. FIG. 3A shows a light source in which a side view type LED 110 is mounted on a light reflector. The side view type LED 110 is a type of LED whose light emitting surface is perpendicular to the mounting surface, and emits light parallel to the mounting surface from the light emitting section 130. 3B to 3D show a light source in which a top view type LED 120 is mounted on a light reflector. The top view type LED 120 is a type of LED whose light emitting surface is parallel to the mounting surface, and emits light perpendicular to the mounting surface from the light emitting unit 130. Figures 3B and 3C show top-view type LEDs, but the side-view type LEDs may be applied depending on the light source design. On the other hand, in FIG. 3D, it is preferable that a top view type LED is applied as shown in the figure.

[0051] 中小型液晶ディスプレイ(LCD)の光源には、主に擬似白色発光の LEDが用いら れることが多ぐテレビ用途などの大型 LCDの光源には、赤、緑、青の発光特性を有 する LEDを組み合わせて用いることが多い。また、中小型 LCDであってもフィールド シーケンシャル駆動の LCDの光源には、赤、緑、青の発光特性を有する LEDを組 み合わせたものを用いることが好まし!/、。  [0051] Light sources for medium- and small-sized liquid crystal displays (LCDs) often use pseudo-white light-emitting LEDs. Large-scale LCD light sources such as TV applications have red, green, and blue light emission characteristics. Often used in combination with existing LEDs. Even for small and medium-sized LCDs, it is preferable to use a combination of red, green, and blue LEDs as the light source for field sequential LCDs! /.

[0052] 赤、緑、青の LEDの数の比率は、それぞれの発光ダイオードの強度に応じて決定 すればよい。例えば、青の LEDの発光効率が、緑や赤の LEDの発光効率の 3分の 1 であれば、青の LEDを他の 3倍の密度で実装すればよ!/、。 [0052] The ratio of the number of red, green, and blue LEDs may be determined according to the intensity of each light emitting diode. For example, the luminous efficiency of a blue LED is one-third that of a green or red LED. Then, mount blue LEDs at 3 times the density! /.

青系の LEDの半導体材料には GaN系があり;青 緑系および白系の LEDの半導 体材料には InGaN系があり;赤系の LEDの半導体材料には AlInGaP系などがある 。もちろん、 LEDの半導体材料がこれらに限定されるわけではなぐそれぞれの色純 度を得ることができるように、適宜選択することが重要である。  Blue-based LED semiconductor materials include GaN; blue-green and white LED semiconductor materials include InGaN; red-based LED semiconductor materials include AlInGaP. Of course, LED semiconductor materials are not limited to these, and it is important to select them appropriately so that each color purity can be obtained.

[0053] 光反射体の所望位置の導電層上に、はんだで LEDを固定して、電気的に接合さ せること力 Sできる。使用するはんだ材料は、融点が約 180°Cの PbSn合金はんだを用 いてもよいが、近年の環境負荷低減や環境規制の観点から、鉛を含まない合金はん だを用いることが望まれている。そこで、 PbSn合金はんだよりも融点は高いが、実装 安定性や信頼性の観点から、 AuSnCu合金はんだ(融点:約 220°C)などの AuSn 系合金はんだ、 SnZnBi合金はんだ(融点:約 200°C)などの SnZn系合金はんだ、 S nSb系合金はんだ、 SnCu系合金はんだなどを用いることが好ましい。  [0053] The force S can be secured by fixing the LED with solder on the conductive layer at the desired position of the light reflector. PbSn alloy solder with a melting point of about 180 ° C may be used as the solder material to be used, but from the viewpoint of environmental load reduction and environmental regulations in recent years, it is desired to use lead-free alloy solder. Yes. Therefore, although the melting point is higher than PbSn alloy solder, from the viewpoint of mounting stability and reliability, AuSn-based alloy solder such as AuSnCu alloy solder (melting point: about 220 ° C), SnZnBi alloy solder (melting point: about 200 ° C) It is preferable to use SnZn alloy solder, SnSb alloy solder, SnCu alloy solder, etc.

[0054] はんだごてを用いる手はんだで LEDを光反射体に実装することもできる力 S、工業的 には、リフロー炉を用いて、連続的かつ一の光反射体に多数の LEDを一括で実装 すること力 S好ましい。リフロー法では、例えば、はんだで仮固定された LEDを有する 光反射体を、窒素などの不活性ガス中で 220〜280°C程度に加熱したり、フロー炉 の中を数秒から数十秒かけて通過させたりすることにより、はんだでの LED実装を行 5。  [0054] The ability to mount LEDs on a light reflector by hand soldering using a soldering iron S. Industrially, using a reflow furnace, a large number of LEDs can be batched into a single light reflector. The power of mounting with S is preferable. In the reflow method, for example, a light reflector having an LED temporarily fixed with solder is heated to about 220 to 280 ° C in an inert gas such as nitrogen, or the flow furnace takes several seconds to several tens of seconds. LED mounting with solder by passing it through.

[0055] LEDの実装工程や、曲げ加工工程においては、反射面に傷をつけないようにする ことが重要である。例えば、これらの加工前に、光反射層の表面に保護フィルムを貼 り合わせて、加工後にその保護フィルムを除去してもよい。加工の種類に応じて、伸 び特性や耐熱特性を有する保護フィルムを適宜選択する。保護フィルムの厚さは 10 〜200 111カ好ましぃ。保護フィルムの付着力は 0. 01—0. 3kN/mが好ましぐ 0 . 03-0. 2kN/mであることがより好ましい。付着力が弱すぎると加工時に保護フィ ルムが剥離してしまい、強すぎると LEDを実装するために保護フィルムを剥離するた めに余分な力が必要になる。保護フィルムの材質はポリ塩化ビュル、ポリオレフインや 、ポリエステルなどであり、保護フィルムの例には、サニテクトおよび P AC (株式会社 サンエー化研製)、 E— MASKシリーズ(日東電工株式会社製)などが含まれる。 [0056] LEDが実装された光反射体の導電層(電気回路)には、ソルダーレジスト層を形成 すること力 Sできる。剥き出しにされた電気回路は反射率が低いので、拡散反射性を有 するソルダーレジスト(例えば白色のソルダーレジスト)で覆うことにより、面全体での 反射率を高めることができる。また、白色のソルダーレジストで導電層を覆うことにより 、導電層の反射色を抑制することができるので、反射ムラが低減される。ソルダーレジ スト層の表面における全光線反射率は 80%以上であることが好ましい。 白色のソル ダーレジストとは、例えば白色顔料や、酸化チタン、酸化亜鉛、塩基性炭酸塩、塩基 性硫酸鉛、硫酸鉛、硫化亜鉛または酸化アンチモンなどのフィラーを含有する、光硬 化型ソルダーレジストゃ熱硬化型ソルダーレジストである。光硬化型ソルダーレジスト は、例えばアタリレート類等からなる光重合性モノマーや分子中にカルボキシル基と エチレン性不飽和結合を併せ持つ感光性プレボリマーを含有する光硬化型ソルダ 一レジストである。熱硬化型ソルダーレジストは、例えば多官能エポキシ化合物、多 官能ォキセタン化合物、多官能フエノール性水酸基含有化合物等を含有する熱硬 化型ソルダーレジストである。 [0055] In the LED mounting process and the bending process, it is important not to damage the reflecting surface. For example, a protective film may be attached to the surface of the light reflecting layer before these processing, and the protective film may be removed after processing. Depending on the type of processing, a protective film having elongation characteristics and heat resistance characteristics is appropriately selected. The thickness of the protective film is 10-200111. The adhesion of the protective film is preferably from 0.01 to 0.3 kN / m, more preferably from 0.03 to 0.2 kN / m. If the adhesive force is too weak, the protective film peels off during processing, and if it is too strong, extra force is required to peel off the protective film to mount the LED. The protective film is made of poly (vinyl chloride), polyolefin, polyester, etc. Examples of protective films include Sanitect and PAC (manufactured by Sanei Kaken Co., Ltd.), E-MASK series (manufactured by Nitto Denko Corporation), etc. It is. [0056] It is possible to form a solder resist layer on the conductive layer (electric circuit) of the light reflector on which the LED is mounted. Since the exposed electrical circuit has a low reflectivity, it is possible to increase the reflectivity of the entire surface by covering it with a solder resist having diffuse reflectivity (for example, a white solder resist). Moreover, since the reflective color of a conductive layer can be suppressed by covering a conductive layer with a white solder resist, reflection unevenness is reduced. The total light reflectance on the surface of the solder resist layer is preferably 80% or more. The white solder resist is, for example, a photo-curing solder resist containing a white pigment and a filler such as titanium oxide, zinc oxide, basic carbonate, basic lead sulfate, lead sulfate, zinc sulfide or antimony oxide. It is a thermosetting solder resist. The photo-curing solder resist is a photo-curing solder resist that contains a photopolymerizable monomer composed of, for example, acrylates or the like, and a photosensitive polymer having both a carboxyl group and an ethylenically unsaturated bond in the molecule. The thermosetting solder resist is a thermosetting solder resist containing, for example, a polyfunctional epoxy compound, a polyfunctional oxetane compound, a polyfunctional phenolic hydroxyl group-containing compound and the like.

[0057] 面光源装置について  [0057] Surface light source device

LEDが実装された光反射体は、表示装置 (例えば LCD)のバックライトのための面 光源装置に適用されうる。 LCD用バックライトは、エッジライト型と直下型に分類されう る。本発明の光源は、いずれの方式のバックライトのための面光源装置にも適用する こと力 Sでさる。  The light reflector on which the LED is mounted can be applied to a surface light source device for a backlight of a display device (eg, LCD). LCD backlights can be classified into edge light types and direct type. The light source of the present invention can be applied to a surface light source device for any type of backlight with a force S.

[0058] エッジライト型バックライトの場合は、導光板の端部に光源が装着され、直下型バッ クライトの場合は、拡散シートやライティングカーテンの下部に光源が装着される。  In the case of an edge light type backlight, a light source is attached to the end of the light guide plate, and in the case of a direct type backlight, a light source is attached to the lower part of the diffusion sheet or the lighting curtain.

[0059] 図 4A〜図 4Cには、エッジライト型バックライトのための面光源装置が示される。導 光板 200の端部が光源の LEDの近傍に配置され、導光板 200の側面に LED光が 導入される。  4A to 4C show a surface light source device for an edge light type backlight. The end of the light guide plate 200 is disposed near the LED of the light source, and LED light is introduced into the side surface of the light guide plate 200.

図 4Aに示される面光源装置の LEDはサイドビュータイプであり、平板状の光反射 体に実装されている。図 4Bおよび図 4Cに示される面光源装置の LEDはトップビュ 一タイプ(サイドビュータイプでもよレ、)であり、凹型(図 4B)もしくは L字型(図 4B)に 曲げ加工された光反射体に実装されている。 [0060] エッジライト型バックライトのための面光源装置において、図 4Cに示されるように、 光反射体の一部分が導光板下の反射シートを兼ねるように、光反射体を加工しても よい。それにより、面光源装置の部品点数を低減する(例えば図 4Bの反射板 210が 不要にする)ことができ、さらに熱放散機能を有する金属基材を導光板下にも配置で きるので、放熱性が高まる。光反射体を曲げ加工する手段は特に限定されない。 The LED of the surface light source device shown in Fig. 4A is a side view type, and is mounted on a flat light reflector. The LED of the surface light source device shown in Fig. 4B and Fig. 4C is a top-view type (or a side-view type), which reflects light that is bent into a concave shape (Fig. 4B) or an L-shape (Fig. 4B). Implemented in the body. [0060] In the surface light source device for the edge light type backlight, as shown in FIG. 4C, the light reflector may be processed so that a part of the light reflector also serves as a reflection sheet under the light guide plate. . As a result, the number of parts of the surface light source device can be reduced (for example, the reflector 210 in FIG. 4B is not required), and a metal substrate having a heat dissipation function can also be disposed under the light guide plate. Increases nature. The means for bending the light reflector is not particularly limited.

[0061] さらにエッジライト型バックライトのための面光源装置に使用される導光板の材質の 例には、ポリメチルメタタリレートなどのアクリル系樹脂、ポリカーボネートやポリカーボ ネート'ポリスチレン組成物からなる樹脂、エポキシ系樹脂、環状ポリオレフイン系樹 脂(三井化学株式会社製ァペル (登録商標)、 日本ゼオン株式会社製ゼォノア (登録 商標)、 JSR株式会社製アートン (登録商標)など)や、ガラスが含まれる。ただし導光 板の材質は、 380nm〜780nmの波長領域において透明性を示す材料であれば、 必ずしもこれらに限定されない。導光板の厚さは、使用目的やサイズ、光源の大きさ などにより適宜選択すればよい。また、面内の輝度分布を均一化するために、導光 板表面に様々なドット印刷などを施してもよい。  [0061] Further, examples of the material of the light guide plate used in the surface light source device for the edge light type backlight include acrylic resins such as polymethyl methacrylate and resins made of polycarbonate or polycarbonate'polystyrene composition. , Epoxy resin, cyclic polyolefin resin (Mappa Chemical Co., Ltd. Apell (registered trademark), Nippon Zeon Co., Ltd., ZEONOR (registered trademark), JSR Co., Ltd. Arton (registered trademark), etc.) and glass . However, the material of the light guide plate is not necessarily limited to this as long as the material shows transparency in the wavelength region of 380 nm to 780 nm. The thickness of the light guide plate may be appropriately selected depending on the purpose and size of use, the size of the light source, and the like. In order to make the in-plane luminance distribution uniform, various dot printings may be applied to the light guide plate surface.

[0062] 一方、図 4Dには、直下型バックライトのための面光源装置が示される。拡散シート 2 20が光源の LEDの上部に配置され、拡散シート 220の下から LED光が導入される 。図 4Dに示される面光源装置の LED120はトップビュータイプであり、平板状の光 反射体に実装されている。  On the other hand, FIG. 4D shows a surface light source device for a direct type backlight. A diffusion sheet 220 is placed on top of the LED of the light source, and LED light is introduced from below the diffusion sheet 220. The LED 120 of the surface light source device shown in FIG. 4D is a top view type, and is mounted on a flat light reflector.

[0063] 直下型バックライトに使用される拡散シートやライティングカーテンは例えば、アタリ ノレビーズをバインダーでコートしたポリエチレンテレフタレート(PET)フィルムや PET フィルムなどである。拡散シートやライティングカーテンの厚さは、使用目的やサイズ 、光源の大きさなどにより適宜選択すればよい。  [0063] The diffusion sheet and the lighting curtain used for the direct type backlight are, for example, a polyethylene terephthalate (PET) film or a PET film in which attalinole beads are coated with a binder. The thickness of the diffusion sheet or lighting curtain may be appropriately selected depending on the purpose and size of use, the size of the light source, and the like.

[0064] 液晶表示装置について  [0064] Liquid crystal display device

本発明の液晶表示装置は、バックライトのための面光源装置に液晶パネルを装着 することで得ること力できる。図 5A〜図 5Cは、エッジライト型バックライトのための面 光源装置に、液晶パネル 300を装着した液晶表示装置の概念図である。  The liquid crystal display device of the present invention can be obtained by mounting a liquid crystal panel on a surface light source device for a backlight. 5A to 5C are conceptual diagrams of a liquid crystal display device in which a liquid crystal panel 300 is mounted on a surface light source device for an edge light type backlight.

一方、図 5Dは、直下型バックライトのための面光源装置に、液晶パネル 300を装着 した液晶表示装置の概念図である。 [0065] 液晶パネル 300に、偏光フィルム、拡散フィルム、プリズムシート、位相差フィルムな どを適宜設けることは、設計事項の範疇である。面光源装置は、カラーフィルターと 薄膜トランジスタ (TFT)アレイもしくは薄膜ダイオードタイプ (TFD)が装備されたァク ティブマトリックス方式の液晶パネルに好適に用いることができる。光源として赤、緑、 青の LEDを独立に時間分割で発光させれば、カラーフィルターを配置しなくても、液 晶パネルのスイッチングによる残像効果を利用して中間色を出すことができる。この 方式をフィールドシーケンシャル方式と!/、う。 On the other hand, FIG. 5D is a conceptual diagram of a liquid crystal display device in which a liquid crystal panel 300 is mounted on a surface light source device for a direct type backlight. [0065] It is in the category of design matters to appropriately provide the liquid crystal panel 300 with a polarizing film, a diffusion film, a prism sheet, a retardation film, and the like. The surface light source device can be suitably used for an active matrix liquid crystal panel equipped with a color filter and a thin film transistor (TFT) array or a thin film diode type (TFD). If red, green, and blue LEDs are emitted independently in time division as light sources, an intermediate color can be produced using the afterimage effect of liquid crystal panel switching without the need for a color filter. This method is called field sequential method!

実施例  Example

[0066] 本発明を、以下の実施例を参照してより具体的に説明する力 本発明の範囲は実 施例によって限定して解釈されない。  [0066] Power to explain the present invention more specifically with reference to the following examples. The scope of the present invention is not construed as being limited by the examples.

[0067] [実施例 1] [0067] [Example 1]

加熱硬化型のシリコーンゴム接着剤 (製品名: TSE3251H、 GE東芝シリコーン (株 )製)に、酸化チタン微粒子 (製品名:タイペータ R960、石原産業 (株)製)を混合して 、酸化チタン微粒子の含有率を 25重量%とした。得られた混合物を真空中にて 3時 間保持することにより脱泡した。  Heat-curing silicone rubber adhesive (product name: TSE3251H, manufactured by GE Toshiba Silicone Co., Ltd.) and titanium oxide fine particles (product name: Typeta R960, manufactured by Ishihara Sangyo Co., Ltd.) The content was 25% by weight. The resulting mixture was degassed by holding in vacuum for 3 hours.

[0068] 酸化チタン微粒子を混合したシリコーンゴム接着剤を、 JIS1000番台のアルミユウ ム板(厚み: 0· 2mm)、および銅箔(厚み: 18 m)のそれぞれに、アプリケーターを 用いて塗工した。アルミニウム板の接着剤塗工面と、銅箔の接着剤塗工面とを貼り合 わせて、 170°Cで 1時間加熱プレスした。得られた積層物の接着層の厚みは約 50 mであつに。 [0068] The silicone rubber adhesive mixed with titanium oxide fine particles was applied to an aluminum plate (thickness: 0.2 mm) of JIS 1000 series and a copper foil (thickness: 18 m) using an applicator. The adhesive-coated surface of the aluminum plate and the adhesive-coated surface of the copper foil were bonded together and heated and pressed at 170 ° C for 1 hour. The thickness of the adhesive layer of the resulting laminate is about 50 m.

[0069] 銅箔表面にレジストを印刷法で塗布して、エッチングした!/、部分を露出させた。塩 化鉄溶液によるウエットエッチング法により、不要な銅を除去して電気回路を形成した 。ウエットエッチング後、表面を水洗し、さらにレジストを除去して図 1Aおよび図 1Bに 示されるような光反射体を得た。  [0069] A resist was applied to the copper foil surface by a printing method and etched! An electric circuit was formed by removing unnecessary copper by a wet etching method using an iron chloride solution. After wet etching, the surface was washed with water and the resist was removed to obtain a light reflector as shown in FIGS. 1A and 1B.

[0070] 銅をエッチングして露出された樹脂面が反射面となる。この反射面の全光線反射率 を、積分球を用いた可視紫外分光光度計(島津製作所製: UV- 2450)で測定した 。反射率測定の標準は、分光光度計メーカー指定の硫酸バリウム粉末を分光光度計 付属のホルダーに詰めたものを用いた。標準板は、硫酸バリウム粉末を固めた標準 板でも、酸化アルミニウム標準板でもよいが、本実施例では硫酸バリウム粉末を固め た標準板を用いた。波長 550nmにおける全光線反射率は 95%であった。同装置で 測定した波長 550nmにおける拡散反射率は 92%であった。また、全光線反射スぺ タトルから算出したハンター a値は 1. 6, b値は 0. 9であった。 [0070] The resin surface exposed by etching copper becomes a reflective surface. The total light reflectance of the reflecting surface was measured with a visible ultraviolet spectrophotometer (manufactured by Shimadzu Corporation: UV-2450) using an integrating sphere. As a standard for reflectance measurement, a barium sulfate powder specified by a spectrophotometer manufacturer was packed in a holder attached to the spectrophotometer. The standard plate is a standard made of hardened barium sulfate powder. Although a plate or an aluminum oxide standard plate may be used, a standard plate in which barium sulfate powder is hardened is used in this example. The total light reflectance at a wavelength of 550 nm was 95%. The diffuse reflectance at a wavelength of 550 nm measured with the same device was 92%. The Hunter a value calculated from the total light reflection spectrum was 1.6 and the b value was 0.9.

[0071] さらに、酸化チタン微粒子を混合したシリコーンゴム接着剤層と銅箔との剥離強度 を次の条件で測定したところ、 0. 6kN/m値であった。 [0071] Further, the peel strength between the silicone rubber adhesive layer mixed with titanium oxide fine particles and the copper foil was measured under the following conditions, and the value was 0.6 kN / m.

[剥離強度測定条件]  [Peel strength measurement conditions]

使用機器:株式会社東洋精機製作所製 ストログラフ Ml  Equipment used: Strograph Ml manufactured by Toyo Seiki Seisakusho Co., Ltd.

測定条件:ロードセル 500N、セル移動速度 50mm/min、 90° 剥離  Measurement conditions: Load cell 500N, cell moving speed 50mm / min, 90 ° peeling

試料サイズ: 3· 2mm X 40mm  Sample size: 3 · 2mm X 40mm

[0072] 得られた光反射体を、 260°Cの窒素雰囲気のリフロー炉を 1分間かけて通過させた 。その後、反射面の反射率、および接着剤層と銅箔との剥離強度を計測した。リフロ ー炉通過前に比べて反射率、および剥離強度ともに低下は認められなかった。 [0072] The obtained light reflector was passed through a reflow furnace in a nitrogen atmosphere at 260 ° C over 1 minute. Thereafter, the reflectance of the reflecting surface and the peel strength between the adhesive layer and the copper foil were measured. There was no decrease in reflectance and peel strength compared with those before passing through the reflow furnace.

[0073] さらに得られた光反射体の導電層に、白色ソルダーレジスト (太陽インキ製:フォトフ アイナ一 PMR6000)を塗工し、 UV露光した後に加熱して硬化させた。 白色ソルダ 一レジストの白色面の全光線反射率を同様の方法で測定したところ、波長 550nmに おける反射率が 88%であった。 [0073] Further, a white solder resist (manufactured by Taiyo Ink: Photofiner PMR6000) was applied to the conductive layer of the obtained light reflector, and after UV exposure, it was heated and cured. White solder The total light reflectance of the white surface of one resist was measured by the same method, and the reflectance at a wavelength of 550 nm was 88%.

[0074] [実施例 2] [Example 2]

実施例 1と同様のシリコーンゴム接着剤に酸化チタン微粒子 (製品名:タイペータ R 930、石原産業 (株)製)を混合して、酸化チタン微粒子の含有率を 35重量%とした。 得られた混合物を真空中に 3時間保持することにより脱泡した。  Titanium oxide fine particles (product name: Typeta R 930, manufactured by Ishihara Sangyo Co., Ltd.) were mixed with the same silicone rubber adhesive as in Example 1 to make the content of titanium oxide fine particles 35% by weight. The resulting mixture was degassed by holding it in vacuum for 3 hours.

[0075] 酸化チタン微粒子を混合した白色シリコーンゴム接着剤を、実施例 1と同様のアル ミニゥム板 (厚み:0· 2mm)、および銅箔 (厚み: 18 m)のそれぞれに塗工した。接 着剤塗工面同士を重ねて、 170°Cで 1時間加熱プレスした。得られた積層物の接着 層の厚みは約 50 a mであった。  [0075] A white silicone rubber adhesive mixed with titanium oxide fine particles was applied to each of the same aluminum plate (thickness: 0.2 mm) and copper foil (thickness: 18 m) as in Example 1. The adhesive coated surfaces were overlapped and heated and pressed at 170 ° C for 1 hour. The thickness of the adhesive layer of the obtained laminate was about 50 am.

[0076] 実施例 1と同様に銅箔をエッチングで除去した。露出された反射面の全光線反射 率を、積分球を用いた可視紫外分光光度計(日立製作所製: U— 3010)で測定した 。反射率測定の標準を、酸化アルミニウム白板 (型番: 210— 0740)とした。波長 550 nmにおける反射率が 95%であった。同装置で測定した波長 550nmにおける拡散 反射率は 95%であった。また、全光線反射スペクトルから算出したハンター a値は—[0076] In the same manner as in Example 1, the copper foil was removed by etching. The total light reflectance of the exposed reflecting surface was measured with a visible ultraviolet spectrophotometer (Hitachi: U-3010) using an integrating sphere. The standard for reflectance measurement was an aluminum oxide white plate (model number: 210-0740). Wavelength 550 The reflectivity at nm was 95%. The diffuse reflectance at a wavelength of 550 nm measured with the same device was 95%. The Hunter a value calculated from the total light reflection spectrum is-

1. 9、 b値は 0. 7であった。 The 1.9 and b values were 0.7.

[0077] さらに、白色シリコーンゴム接着剤層と銅箔との剥離強度を、実施例 1と同様の条件 で測定したところ、 0. 45kN/mであった。 [0077] Further, the peel strength between the white silicone rubber adhesive layer and the copper foil was measured under the same conditions as in Example 1. As a result, it was 0.45 kN / m.

[0078] 得られた光反射体を 260°Cの窒素雰囲気のリフロー炉を 3回通過させて(通過時間 [0078] The obtained light reflector was passed through a reflow furnace in a nitrogen atmosphere at 260 ° C three times (passing time).

1分間)、反射面の反射率および接着層と銅箔との剥離強度を計測したところ、リフロ ー炉通過前に比べて、反射率および剥離強度とも低下は認められなかった。  1 minute), the reflectivity of the reflecting surface and the peel strength between the adhesive layer and the copper foil were measured. As a result, neither the reflectivity nor the peel strength was reduced compared with that before passing through the reflow furnace.

[0079] また得られた光反射体を、雰囲気温度 60°C、相対湿度 90%の耐湿熱試験環境下 で 500時間放置した後に、反射率およびピール強度を測定したところ、耐湿熱試験 前後で反射率および剥離強度の低下は認められなかった。 [0079] Further, after the obtained light reflector was allowed to stand for 500 hours in a humidity and heat resistance test environment at an ambient temperature of 60 ° C and a relative humidity of 90%, the reflectance and peel strength were measured. No decrease in reflectance and peel strength was observed.

[0080] 得られた光反射体を、以下の 1)〜6)に示すアルカリ水溶液または有機溶媒に、所 定の条件 (温度および時間)で浸漬させた。浸漬の前後で反射率および剥離強度を 測定したが、変化は見られなかった。このように、得られた光反射体の耐アルカリ性 および耐溶剤性は高!/、ことがわかる。 [0080] The obtained light reflector was immersed in an alkaline aqueous solution or an organic solvent shown in the following 1) to 6) under predetermined conditions (temperature and time). The reflectivity and peel strength were measured before and after immersion, but no change was observed. Thus, it can be seen that the obtained light reflector has high alkali resistance and solvent resistance.

[0081] l) NaOH (3重量%水溶液) 50°C, 30秒 変化なし [0081] l) NaOH (3 wt% aqueous solution) 50 ° C, 30 seconds No change

2) KOH (3重量%水溶液) 50°C, 30秒 変化なし  2) KOH (3 wt% aqueous solution) 50 ° C, 30 seconds No change

3) NaOH (5重量%水溶液) 25°C, 15分 変化なし 3) N a OH (5 wt% aqueous solution) 25 ° C, 15 min no change

4) 1^« (5重量%水溶液) 25°C, 15分 変化なし  4) 1 ^ «(5 wt% aqueous solution) 25 ° C, 15 minutes No change

5) MEK (メチルェチルケトン) 25°C, 15分 変化なし  5) MEK (methyl ethyl ketone) 25 ° C, 15 minutes, no change

6) IPA (イソプロピルアルコール) 25°C, 15分 変化なし  6) IPA (isopropyl alcohol) 25 ° C, 15 minutes, no change

[0082] [実施例 3] 実施例 1と同様のシリコーンゴム接着剤に針状酸化チタン微粒子 (製品 名:タイペータ FTL— 110、石原産業 (株)製)を混合し、針状酸化チタン微粒子の含 有率を 35重量%とした。得られた混合物を、真空中に 3時間保持することにより脱泡 した。  [0082] [Example 3] Acicular titanium oxide fine particles (product name: Typeta FTL-110, manufactured by Ishihara Sangyo Co., Ltd.) were mixed with the same silicone rubber adhesive as in Example 1 to obtain acicular titanium oxide fine particles. The content was 35% by weight. The resulting mixture was degassed by holding it in vacuum for 3 hours.

[0083] 針状酸化チタン微粒子を混合した白色シリコーンゴム接着剤を、実施例 1と同様の アルミニウム板 (厚さ:0· 2mm)、および銅箔 (厚さ: 18 m)のそれぞれに塗工した。 塗工面同士を重ねて、 170°Cで 1時間加熱プレスを行った。得られた積層物の接着 層の厚みは、約 50 a mであった。 [0083] The white silicone rubber adhesive mixed with acicular titanium oxide fine particles was applied to each of the aluminum plate (thickness: 0.2 mm) and copper foil (thickness: 18 m) as in Example 1. did. The coated surfaces were overlapped and heated and pressed at 170 ° C for 1 hour. Adhesion of the resulting laminate The layer thickness was about 50 am.

[0084] 実施例 1と同様に銅箔をエッチングで除去した。積分球を用いた可視紫外分光光 度計(日立製作所製: U— 3010)で測定された、露出した反射面の全光線反射率は 95%であった(波長を 550nmとして測定した)。反射率測定の標準を、酸化アルミ二 ゥム白板 (型番: 210— 0740)とした。また、同装置で測定された拡散反射率は 95% であった(波長を 550nmとして測定した)。また、全光線反射スペクトルから算出した ハンター a値は 1. 7、1^値は1. 7であった。さらに、実施例 1と同様の条件で測定さ れた、白色シリコーンゴム接着剤層と銅箔との剥離強度は 0. 88kN/mであった。  [0084] The copper foil was removed by etching in the same manner as in Example 1. The total light reflectance of the exposed reflecting surface measured with a visible ultraviolet spectrophotometer (Hitachi: U-3010) using an integrating sphere was 95% (measured at a wavelength of 550 nm). The standard for reflectance measurement was an aluminum oxide white plate (model number: 210-0740). The diffuse reflectance measured with the same device was 95% (measured at a wavelength of 550 nm). The Hunter a value calculated from the total light reflection spectrum was 1.7, and the 1 ^ value was 1.7. Furthermore, the peel strength between the white silicone rubber adhesive layer and the copper foil, measured under the same conditions as in Example 1, was 0.88 kN / m.

[0085] [比較例 1] 以下の手順で白色エポキシ樹脂基板を作製した。メチルェチルケトン 5 0質量部に、脂環式エポキシ樹脂 50質量部、ビスフエノール A型エポキシ樹脂 40質 量部、グリシジルメタクリレートコポリマー 10質量部を溶解させた(ワニス A)。  [Comparative Example 1] A white epoxy resin substrate was prepared by the following procedure. 50 parts by mass of alicyclic epoxy resin, 40 parts by mass of bisphenol A type epoxy resin, and 10 parts by mass of glycidyl methacrylate copolymer were dissolved in 50 parts by mass of methyl ethyl ketone (varnish A).

また、ジメチルホルムアミド 25質量部に、硬化剤としてジシアンジアミド 3質量部、硬 化促進剤として 1ーシァノエチルー 2—ゥンデシルイミダゾール 0. 1質量部を溶解さ せた(ワニス B)。  Further, 3 parts by mass of dicyandiamide as a curing agent and 0.1 part by mass of 1-cyanoethyl-2-undecylimidazole as a curing accelerator were dissolved in 25 parts by mass of dimethylformamide (varnish B).

[0086] ワニス Aとワニス Bを混合し、さらに酸化チタン微粒子および蛍光増白剤 0.3重量部 を混合して白色エポキシワニスを得た。酸化チタン微粒子の含有率は 35重量%とな つた。得られた白色エポキシワニスを、ガラスクロスに含浸させて、 150°Cで 5分間予 備乾燥し、その上下に銅箔 (厚さ: 18 m)を重ねて、 170°Cで加熱プレスした。ェポ キシ樹脂層の厚みは約 550 μ mとなった。  [0086] Varnish A and varnish B were mixed, and further, titanium oxide fine particles and 0.3 parts by weight of a brightening agent were mixed to obtain a white epoxy varnish. The content of titanium oxide fine particles was 35% by weight. The obtained white epoxy varnish was impregnated into a glass cloth, pre-dried at 150 ° C. for 5 minutes, and copper foil (thickness: 18 m) was superimposed on the upper and lower sides thereof and heated and pressed at 170 ° C. The thickness of the epoxy resin layer was about 550 μm.

[0087] 実施例 1と同様の方法で銅箔の一部をエッチングで除去して、反射面を露出させた 。積分球を用いた可視紫外分光光度計(日立製作所製: U— 3010)にて測定された 、反射面の全光線反射率は 90%であった(波長を 550nmとして測定した)。同装置 で測定された拡散反射率は 90%であった(波長を 550nmとして測定した)。全光線 反射スペクトルから算出したハンター a値は一 2· 2、b値は 2. 9であった。  [0087] A part of the copper foil was removed by etching in the same manner as in Example 1 to expose the reflective surface. The total light reflectance of the reflecting surface was 90% (measured at a wavelength of 550 nm) as measured with a visible ultraviolet spectrophotometer using an integrating sphere (manufactured by Hitachi, Ltd .: U-3010). The diffuse reflectance measured with this device was 90% (measured at a wavelength of 550 nm). The Hunter a value calculated from the total light reflection spectrum was 1 · 2, and the b value was 2.9.

[0088] 1)耐熱性試験  [0088] 1) Heat resistance test

実施例 2および比較例 1で得られた反射体の銅箔を、実施例 1と同様の方法で、ェ ツチングにより除去して、反射面が露出したサンプルを得た。露出した反射面の全光 線反射率を測定した(図 6Aにおける未処理サンプル)。さらに、反射面が露出したサ ンプルを 10時間 180°Cに加熱して、反射面の全光線反射率の変化を測定した(図 6 Aにおける処理サンプル)。測定の結果が図 6Aに示される。またそれぞれのサンプ ルの反射率の、波長 550nmの光に対する、加熱時間に対する経時変化を図 6Bに 示す。 The copper foil of the reflector obtained in Example 2 and Comparative Example 1 was removed by etching in the same manner as in Example 1 to obtain a sample with the reflective surface exposed. The total light reflectance of the exposed reflective surface was measured (untreated sample in Fig. 6A). In addition, the reflective surface is exposed. The samples were heated to 180 ° C for 10 hours and the change in the total light reflectance of the reflecting surface was measured (treated sample in Fig. 6A). The result of the measurement is shown in Figure 6A. Figure 6B shows the time course of the reflectance of each sample with respect to the heating time for light with a wavelength of 550 nm.

図 6Aに示されるように、比較例 1からのサンプルは、 10時間加熱後の短波長領域 での反射率の劣化が著しい。これに対して、実施例 2からのサンプルは、 10時間加 熱後のサンプルも、反射率がほとんど変化してないことがわかる。このように、実施例 2からのサンプルは、耐熱性が優れて!/、ること力 Sわ力、る。  As shown in FIG. 6A, the sample from Comparative Example 1 shows a significant deterioration in reflectance in the short wavelength region after heating for 10 hours. On the other hand, it can be seen that the reflectance of the sample from Example 2 hardly changes even after heating for 10 hours. Thus, the sample from Example 2 has excellent heat resistance!

[0089] 2)耐紫外線性試験 [0089] 2) UV resistance test

実施例 2および比較例 1で得られた反射体の銅箔を、実施例 1と同様の方法で、ェ ツチングにより除去して、反射面が露出したサンプルを得た。露出した反射面の全光 線反射率を測定した(図 7における未処理サンプル)。さらに高圧水銀灯光(照射強 度 =約 90mW/cm2)で、紫外線を 1分間照射した反射面の全光線反射率を測定し た(図 7における処理サンプル)。 The copper foil of the reflector obtained in Example 2 and Comparative Example 1 was removed by etching in the same manner as in Example 1 to obtain a sample with the reflective surface exposed. The total light reflectance of the exposed reflective surface was measured (untreated sample in Fig. 7). Furthermore, the total light reflectivity of the reflective surface irradiated with ultraviolet light for 1 minute was measured with a high-pressure mercury lamp (irradiation intensity = approximately 90 mW / cm 2 ) (treated sample in Fig. 7).

測定結果が図 7に示される。比較例 1からのサンプルは、未処理であっても反射率 が低ぐかつ処理によって短波長領域での反射率が著しく低下している。一方、実施 例 2からのサンプルは、未処理の状態から反射率が高ぐかつ処理によっても劣化が 少ない。このように、実施例 2からのサンプルは、耐紫外線性が優れていることがわか  The measurement results are shown in Fig. 7. The sample from Comparative Example 1 has a low reflectivity even when it has not been processed, and the reflectivity in the short wavelength region is significantly reduced by the processing. On the other hand, the sample from Example 2 has a high reflectivity from the untreated state and little degradation by treatment. Thus, it can be seen that the sample from Example 2 has excellent UV resistance.

[0090] 3)耐光熱性試験 [0090] 3) Photothermal resistance test

実施例 2および比較例 1で得られた反射体の銅箔を、実施例 1と同様の方法で、ェ ツチングにより除去して、反射面が露出したサンプルを得た。露出した反射面の全光 線反射率を測定した(図 8における未処理サンプル)。さらにサンプルを 100°Cに加 熱保持した状態で、擬似太陽光(約 500mW/cm2)を 150時間照射した。キセノン ランプにエアマス (A. M)フィルター 1. 5を取り付けて擬似太陽光を得た。その後の 全光線反射率を測定した(図 8における処理サンプル)。 The copper foil of the reflector obtained in Example 2 and Comparative Example 1 was removed by etching in the same manner as in Example 1 to obtain a sample with the reflective surface exposed. The total light reflectance of the exposed reflective surface was measured (untreated sample in Fig. 8). Furthermore, with the sample kept heated at 100 ° C, simulated sunlight (about 500 mW / cm 2 ) was irradiated for 150 hours. Simulated sunlight was obtained by attaching an air mass (A. M) filter 1.5 to a xenon lamp. Subsequent total light reflectance was measured (processed sample in Fig. 8).

測定結果が図 8に示される。比較例 1からのサンプルは、照射処理により反射率が 低下している。一方、実施例 2からのサンプルでは反射率がほとんど劣化していない 。このように、実施例 2からのサンプルは耐光熱性が優れているのがわかる。 The measurement results are shown in Fig. 8. The sample from Comparative Example 1 has a reduced reflectance due to the irradiation treatment. On the other hand, the reflectance from the sample from Example 2 is hardly deteriorated. . Thus, it can be seen that the sample from Example 2 has excellent photothermal resistance.

[0091] 4)曲げ加工性試験 [0091] 4) Bending workability test

実施例 2および比較例 1の反射体から lOcmX 1cmのサンプルを切り出し、中央部 に冶具を当てて、 90° 折り曲げた。実施例 2からのサンプルは、 90° 屈曲されても 樹脂および銅箔ともに剥離することなく形状を維持した。一方、比較例 1からのサンプ ノレは、 90° 屈曲されると樹脂層が破断してガラスクロス間で剥離が生じた。  A sample of lOcm × 1 cm was cut out from the reflectors of Example 2 and Comparative Example 1, and a jig was applied to the center part, and the sample was bent 90 °. The sample from Example 2 maintained its shape without peeling off both the resin and the copper foil even when bent by 90 °. On the other hand, when the sample from Comparative Example 1 was bent by 90 °, the resin layer broke and peeling occurred between the glass cloths.

[0092] [実施例 4] [0092] [Example 4]

LEDの実装  LED mounting

実施例 1で得られた光反射体から、 19cm X 27cmのサンプルを切り出した。サンプ ルのアルミニウム板上に保護フィルムを、さらに銅箔上にドライフィルムレジスト(旭化 成株式会社製: AQ3058)をラミネートした。 LEDの実装回路パターンを描画したマ スクを介してドライフィルムレジストに UVを照射し、実装回路パターン部のレジストを 硬化させた。レジスト硬化後、サンプルを炭酸ナトリウム水溶液に浸して、硬化されて いないレジストを除去した。  From the light reflector obtained in Example 1, a 19 cm × 27 cm sample was cut out. A protective film was laminated on the sample aluminum plate, and a dry film resist (AQ3058 manufactured by Asahi Kasei Co., Ltd.) was laminated on the copper foil. The dry film resist was irradiated with UV through a mask on which the LED mounting circuit pattern was drawn to cure the resist on the mounting circuit pattern. After the resist was cured, the sample was immersed in an aqueous sodium carbonate solution to remove the uncured resist.

[0093] その後、サンプルを塩化第二鉄溶液に浸して、レジストを除去された領域の銅箔を エッチング除去した後、水洗した。水洗後のサンプルを水酸化ナトリウム水溶液に浸 して、すべてのレジストを除去した。  Thereafter, the sample was immersed in a ferric chloride solution, and the copper foil in the region where the resist was removed was removed by etching, followed by washing with water. The washed sample was immersed in an aqueous sodium hydroxide solution to remove all resist.

[0094] 実装回路パターンが形成された面全域に、白色のソルダーレジスト(太陽インキ製 造株式会社製:フォトファイナー PMR-6000 W30 (主剤)と CA-40 G30 (硬化剤 )との 70 : 30の割合の混合物)をコートして、 30分間 80°Cに加熱して乾燥させ、 20 mの厚さの膜を形成した。続いて、マスクを介して UVを照射して、 LEDを実装するた めのはんだ付けが必要な領域を除ぐ実装回路パターンである銅箔のある領域のソ ルダーレジストを硬化させた。レジスト硬化後、サンプルを炭酸ナトリウム水溶液に浸 して、硬化されていないソルダーレジストを除去して、さらに水洗した。その後、 60分 間 150°Cに加熱してソルダーレジストをさらに硬化させた。  [0094] A white solder resist (manufactured by Taiyo Ink Manufacturing Co., Ltd .: Photofiner PMR-6000 W30 (main agent) and CA-40 G30 (curing agent) is applied to the entire surface on which the mounting circuit pattern is formed. And heated to 80 ° C. for 30 minutes and dried to form a 20 m thick film. Subsequently, the solder resist in the copper foil area, which is a mounting circuit pattern that excludes the area that needs to be soldered to mount the LED, was cured by irradiating UV through a mask. After the resist was cured, the sample was immersed in an aqueous sodium carbonate solution to remove the uncured solder resist and further washed with water. Thereafter, the solder resist was further cured by heating to 150 ° C. for 60 minutes.

[0095] ソルダーレジストが除去された領域(はんだ付けが必要な領域)を、純粋で洗浄した 。さらにその領域に、スクリーン印刷機を用いて Sn— Ag— Cu (Ag3%、 CuO. 5%) のクリームはんだを印刷した。次に、クリームはんだが印刷された領域に、 LEDチッ プをリフロー処理により実装した。具体的にはサンプルを、最高温度 260°Cのリフロ ー炉を 10秒間かけて通過させた。 [0095] The area where the solder resist was removed (area where soldering was necessary) was cleaned with pure water. Further, Sn-Ag-Cu (Ag3%, CuO. 5%) cream solder was printed on the area using a screen printer. Next, in the area where the cream solder is printed, Was implemented by reflow processing. Specifically, the sample was passed through a reflow furnace with a maximum temperature of 260 ° C over 10 seconds.

[0096] [実施例 5] [0096] [Example 5]

実施例 4に示された手法で、実施例 1で得られた光反射体に、サイドビュータイプの 白色 LEDを図 3Aに示すように実装することにより光源を得た。得られた光源にアタリ ル樹脂の導光板を図 4Aに示すように装着することで面光源装置を得た。  A light source was obtained by mounting a side view type white LED on the light reflector obtained in Example 1 as shown in FIG. 3A by the method shown in Example 4. A surface light source device was obtained by attaching a light guide plate made of talyl resin to the obtained light source as shown in FIG. 4A.

[0097] [実施例 6] [0097] [Example 6]

実施例 1で得られた光反射体の拡散反射面が凹面になるように曲げ加工した。実 施例 4に示された手法で、曲げ加工した光反射体に、トップビュータイプもしくはサイ ドビュータイプの白色 LEDを、図 3Bおよび図 3Cに示すように実装することにより光源 を得た。得られた図 3Bおよび図 3Cに示す光源に、アクリル樹脂の導光板を、図 4B および図 4Cに示すように各々装着することで面光源装置を得た。  The light reflector obtained in Example 1 was bent so that the diffuse reflection surface was concave. Using the method shown in Example 4, a light source was obtained by mounting a top view type or side view type white LED on a bent light reflector, as shown in Figs. 3B and 3C. A surface light source device was obtained by attaching an acrylic resin light guide plate to the light sources shown in FIGS. 3B and 3C, respectively, as shown in FIGS. 4B and 4C.

[0098] [実施例 7] [Example 7]

実施例 4に示された手法で、実施例 1で得られた光反射体に、トップビュータイプの 赤色、緑色、青色の LEDを図 3Dに示すように実装することにより光源を得た。得られ た光源に、 PET樹脂の拡散シートを図 4Dに示すように装着することで面光源装置を 得た。  Using the method shown in Example 4, a light source was obtained by mounting top view type red, green, and blue LEDs on the light reflector obtained in Example 1 as shown in FIG. 3D. A surface light source device was obtained by attaching a diffusion sheet of PET resin to the obtained light source as shown in FIG. 4D.

産業上の利用可能性  Industrial applicability

[0099] 本発明の光反射体は、液晶ディスプレイの面光源装置をはじめとして、室内照明、 屋内照明、 自動車用照明や装飾用照明などの光源に好適に適用される。特に、本 発明の光反射体、光源、面光源装置または液晶表示装置は、携帯機器やコンビユー タモニターなどの中小型からテレビ用途等の大型液晶ディスプレイへの適用が可能 である。 The light reflector of the present invention is suitably applied to light sources such as a surface light source device for a liquid crystal display, indoor lighting, indoor lighting, automobile lighting, and decoration lighting. In particular, the light reflector, the light source, the surface light source device or the liquid crystal display device of the present invention can be applied to a small liquid crystal display such as a portable device or a computer monitor to a large liquid crystal display for TV use.

[0100] 本出願は、 2006年 8月 23日出願の出願番号 JP2006— 226400 (特願 2006— 22 6400)に基づく優先権を主張する。当該出願明細書および図面に記載された内容 は、すべて本願明細書に援用される。  [0100] This application claims priority based on application number JP2006-226400 filed on August 23, 2006 (Japanese Patent Application No. 2006-22-6400). The contents described in the application specification and the drawings are all incorporated herein.

符号の説明  Explanation of symbols

[0101] 10 金属基材 電気的絶縁性を有する光反射層 導電層 [0101] 10 Metal substrate Electrically insulating light reflecting layer Conductive layer

はんだ Solder

発光ダイオード  Light emitting diode

サイドビュータイプの発光ダイオード トップビュータイプの発光ダイオード 発光ダイオードの光出射部 導光板  Side-view type light-emitting diode Top-view type light-emitting diode Light-emitting part of light-emitting diode Light guide plate

反射シート  Reflective sheet

拡散シート  Diffusion sheet

液晶パネル  LCD panel

Claims

請求の範囲 The scope of the claims [I] 金属基材;  [I] metal substrate; 前記金属基材の少なくとも片方の表面に設けられ、電気的絶縁性を有し、顔料およ び無機フィラーの少なくともいずれかを含むエラストマ一を含有する光反射層;ならび に  A light reflecting layer which is provided on at least one surface of the metal substrate and has an electrical insulation property and contains an elastomer containing at least one of a pigment and an inorganic filler; and 前記光反射層上に形成された導電層;  A conductive layer formed on the light reflecting layer; を含む光反射体。  Including light reflector. [2] 前記エラストマ一がシリコーン樹脂またはシリコーンゴムを含む、請求項 1に記載の 光反射体。  2. The light reflector according to claim 1, wherein the elastomer includes a silicone resin or a silicone rubber. [3] 前記無機フィラーが針状フィラーである、請求項 1に記載の光反射体。  [3] The light reflector according to [1], wherein the inorganic filler is an acicular filler. [4] 前記光反射層の全光線反射率が 88%以上である、請求項 1に記載の光反射体。  [4] The light reflector according to [1], wherein the light reflection layer has a total light reflectance of 88% or more. [5] 前記光反射層の拡散反射率が 80%以上である、請求項 1に記載の光反射体。  [5] The light reflector according to [1], wherein the diffuse reflectance of the light reflection layer is 80% or more. [6] 前記導電層が電気回路である、請求項 1に記載の光反射体。  6. The light reflector according to claim 1, wherein the conductive layer is an electric circuit. [7] 前記電気回路は、エッチングで導電層の一部を除去することにより形成される、請 求項 6に記載の光反射体。  [7] The light reflector according to claim 6, wherein the electric circuit is formed by removing a part of the conductive layer by etching. [8] 請求項 1に記載の光反射体、 [8] The light reflector according to claim 1, 前記電気回路層に実装された発光ダイオード、および  A light emitting diode mounted on the electrical circuit layer, and 発光ダイオードが実装されてレ、な!/、電気回路を被覆するソルダーレジスト層を有す る光源。  A light source with a light-emitting diode mounted and a solder resist layer covering the electrical circuit. [9] 前記ソルダーレジスト層の表面における全光線反射率が 80%以上である、請求項  [9] The total light reflectance on the surface of the solder resist layer is 80% or more. 8に記載の光源。  8. The light source according to 8. [10] 請求項 8に記載の光源、および前記光源からの光が導入される導光板を有する、 エッジライト型バックライト用面光源装置。  10. An edge light type backlight surface light source device comprising the light source according to claim 8, and a light guide plate into which light from the light source is introduced. [I I] 請求項 8に記載の光源、および前記光源の発光側に配置された拡散シートまたは ライティングカーテンを有する、直下型バックライト用面光源装置。  [I I] A direct-type backlight surface light source device having the light source according to claim 8 and a diffusion sheet or a lighting curtain arranged on a light emitting side of the light source. [12] 請求項 10に記載の面光源装置をバックライトとして有する液晶表示装置。  12. A liquid crystal display device having the surface light source device according to claim 10 as a backlight. [13] 請求項 11に記載の面光源装置をバックライトとして有する液晶表示装置。 13. A liquid crystal display device having the surface light source device according to claim 11 as a backlight.
PCT/JP2007/065842 2006-08-23 2007-08-14 Light-reflecting body and light source comprising the same Ceased WO2008023605A1 (en)

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JP2021085808A (en) * 2019-11-29 2021-06-03 シーシーエス株式会社 Light irradiation device

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