TWI800097B - A curved plastic panel and method and device for fabricating the same - Google Patents
A curved plastic panel and method and device for fabricating the same Download PDFInfo
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/002—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor characterised by the choice of material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/52—Heating or cooling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/0288—Controlling heating or curing of polymers during moulding, e.g. by measuring temperatures or properties of the polymer and regulating the process
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/02—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
- B29C43/04—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles using movable moulds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/02—Combined thermoforming and manufacture of the preform
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/08—Deep drawing or matched-mould forming, i.e. using mechanical means only
- B29C51/082—Deep drawing or matched-mould forming, i.e. using mechanical means only by shaping between complementary mould parts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/14—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor using multilayered preforms or sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/26—Component parts, details or accessories; Auxiliary operations
- B29C51/30—Moulds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/26—Component parts, details or accessories; Auxiliary operations
- B29C51/46—Measuring, controlling or regulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
- B29C2035/0827—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using UV radiation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/02—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
- B29C43/14—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles in several steps
- B29C43/146—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles in several steps for making multilayered articles
- B29C2043/147—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles in several steps for making multilayered articles by compressing after the laying of further material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/36—Moulds for making articles of definite length, i.e. discrete articles
- B29C43/361—Moulds for making articles of definite length, i.e. discrete articles with pressing members independently movable of the parts for opening or closing the mould, e.g. movable pistons
- B29C2043/3615—Forming elements, e.g. mandrels or rams or stampers or pistons or plungers or punching devices
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/58—Measuring, controlling or regulating
- B29C2043/5816—Measuring, controlling or regulating temperature
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/58—Measuring, controlling or regulating
- B29C2043/5891—Measuring, controlling or regulating using imaging devices, e.g. cameras
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2007/00—Flat articles, e.g. films or sheets
- B29L2007/002—Panels; Plates; Sheets
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Thermal Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Press Drives And Press Lines (AREA)
Abstract
Description
本發明是關於一種曲面塑膠面板及其加工方法與加工裝置,尤指一種將平面塑膠基板先設置硬質層和光學功能層後再施以熱壓加工成為曲面塑膠面板的一種加工方法與加工裝置。 This invention relates to a curved plastic panel and its processing method and apparatus, particularly to a processing method and apparatus for first depositing a rigid layer and an optical functional layer on a flat plastic substrate and then hot-pressing it to form a curved plastic panel.
傳統的汽車大多使用玻璃來作為天窗、擋風玻璃、與車載顯示器前面板的板材,但因為玻璃有重量大、易碎、不易塑形等缺點,所以,近年來有人開發出塑膠材質的可透光板材來取代傳統的玻璃,用以製作汽車天窗、擋風玻璃、與車載顯示器前面板等。其中,由於車載顯示器需要更符合車內流線內裝的曲面設計,因此近年來開始有業者發想具曲面的車載顯示器來取代傳統平面車載顯示器。然而,具曲面的車載顯示器於產品設計上的最大困難點之一,即是覆蓋於曲面車載顯示器前方之曲面面板材料及其製作工藝。 Traditional automobiles mostly use glass for sunroofs, windshields, and the front panel of in-vehicle displays. However, due to the disadvantages of glass, such as its weight, fragility, and difficulty in shaping, translucent plastic sheets have been developed in recent years to replace traditional glass in the manufacture of sunroofs, windshields, and in-vehicle display front panels. In particular, because in-vehicle displays need to better fit the curved design of the vehicle's interior, some manufacturers have begun to explore curved in-vehicle displays to replace traditional flat displays. However, one of the biggest challenges in designing curved in-vehicle displays is the material and manufacturing process of the curved panel covering the front of the display.
傳統的曲面玻璃面板需要先將平面玻璃以超高溫熱成型加工為曲面玻璃,然後再進行曲面玻璃之表面研磨拋光,最後再進行光學表面處理(例如抗眩光或抗反射塗佈等)。由於在曲面基材上進行光學表面處理非常難以控制塗佈均勻性,尤其以抗反射塗層的厚度均勻性須達到+/- 10nm之塗佈公差規格,才可達成車載前面板反射率<1%之要求。在平面式面板塗佈要達成此規格已相當不容易,在曲面面板上更幾乎不可能達成。 Traditional curved glass panels require first thermoforming flat glass into curved glass using ultra-high temperature thermoforming, followed by surface grinding and polishing, and finally optical surface treatment (such as anti-glare or anti-reflective coatings). Controlling the uniformity of the coating distribution is extremely difficult on curved substrates, especially for anti-reflective coatings which require a thickness uniformity of +/- 10nm to meet the requirement of <1% reflectivity for automotive front panels. Achieving this specification is already quite difficult on flat panels, and it is almost impossible on curved panels.
當然,近年來也有使用塑膠材料來製作車載顯示器面板的技術被開發出來。塑膠的種類有許多種,其中,由聚碳酸酯(簡稱PC)所構成的工程塑膠由於具有高度透明性及自由染色性、高強度及彈性係數、高衝擊強度、使用溫度範圍廣、成形收縮率低、尺寸安定性良好、耐候性佳、 無味無臭對人體無害符合衛生安全、易塑形等優點,所以較適於被用來製作具曲面或特殊構造的透明基板,以取代易碎且不易塑形的玻璃板材。然而,聚碳酸酯(PC)卻也具有不耐磨、與在紫外線照射下易黃化等缺點。所以,在習知技術中,會藉由在聚碳酸酯(PC)基板外表面增設耐磨的硬質層以及光學功能層的方式,來提高其耐磨性、耐紫外光、抗眩光、以及抗反射等能力。 Of course, in recent years, technologies for using plastic materials to manufacture automotive display panels have also been developed. There are many types of plastics, among which engineering plastics made of polycarbonate (PC) are particularly suitable for manufacturing transparent substrates with curved surfaces or special structures, replacing fragile and difficult-to-shape glass sheets, due to their high transparency, free colorability, high strength and elasticity, high impact strength, wide operating temperature range, low molding shrinkage, good dimensional stability, good weather resistance, and being odorless, tasteless, and harmless to the human body, meeting hygiene and safety requirements, as well as being easily moldable. However, polycarbonate (PC) also has disadvantages such as poor abrasion resistance and a tendency to yellow under ultraviolet radiation. Therefore, in the prior art, a wear-resistant hard layer and an optical functional layer are added to the outer surface of a polycarbonate (PC) substrate to improve its wear resistance, UV resistance, glare resistance, and anti-reflection capabilities.
只不過,習知技術在製作具曲面的塑膠面板的技術上仍遭遇很艱難的困境。如圖一所示,為一典型具曲面的塑膠面板的結構示意圖。一般來說,適用於曲面車載顯示器的曲面塑膠面板於結構上是包括有:一塑膠基板、一硬質層(Hard Coating;簡稱HC)、一光學功能層、以及一印刷層。其中,該塑膠基板通常是由聚碳酸酯(Polycarbonate,簡稱PC)板材做為主層,並在PC板材的上、下表面分別設置一聚甲基丙烯酸甲酯(Polymethyl Methacrylate,簡稱PMMA)板材以強化其物理特性。硬質層通常是形成於該塑膠基板的外表面上,用於提高塑膠面板的耐磨性。光學功能層通常是形成於硬質層上,用於提高塑膠面板的光學表現,例如但不侷限於:耐紫外光、抗眩光、以及抗反射等等。印刷層通常是印刷於該塑膠基板內表面上,用於表現車載顯示器的功能指標。 However, conventional technology still faces significant challenges in manufacturing curved plastic panels. Figure 1 shows a typical structural diagram of a curved plastic panel. Generally, curved plastic panels suitable for curved automotive displays consist of: a plastic substrate, a hard coating (HC), an optical functional layer, and a printing layer. The plastic substrate is typically made of polycarbonate (PC) sheet as the main layer, with polymethyl methacrylate (PMMA) sheets deposited on the upper and lower surfaces of the PC sheet to enhance its physical properties. The hard coating is usually formed on the outer surface of the plastic substrate to improve the wear resistance of the plastic panel. Optical functional layers are typically formed on a rigid layer to improve the optical performance of the plastic panel, such as, but not limited to, UV resistance, glare reduction, and anti-reflection. Printed layers are usually printed on the inner surface of the plastic substrate to display the functional specifications of the automotive display.
如圖二所示,為習知具曲面的塑膠面板的加工方法示意圖,其包含以下步驟:步驟21:以塑膠押出成型方式製作平面的塑膠基板(俗稱生板);此塑膠基板可能是單層PC板材、也可能是PMMA/PC雙層複合板材、或是PMMA/PC/PMMA三層複合板材:步驟22:以熱壓曲面成型方式將該平面的塑膠基板熱壓成為具曲面的塑膠基板;步驟23:對該具曲面的塑膠基板進行HC表面處理,以便在具曲面的塑膠基板的上表面形成HC硬質層;然因曲面塑膠基板很難進行HC表面處理,所以良率不佳;步驟24:對該具曲面的塑膠基板進行光學表面處理,以便在具曲面的塑膠基板的HC硬質層上形成光學功能層;然因曲面塑膠基板很難進行光學表面處理,所以良率不佳; 步驟25:對該具曲面的塑膠基板進行印刷處理,以便在具曲面的塑膠基板的下表面上形成印刷層;然因曲面塑膠基板很難進行印刷處理,所以良率不佳;步驟26:對該具曲面的塑膠基板以平面電腦數值控制(Computer Numerical Control;簡稱CNC)加工機進行切削加工,以將具曲面的塑膠基板切削成預定的外型輪廓;然因曲面塑膠基板很難進行平面CNC切削處理,所以良率不佳;步驟27:完成具曲面的塑膠面板成品;由於步驟23至步驟26的不良率有累加效果,直接導致最後完成的成品良率很低,故仍有改善空間。 Figure 2 shows a schematic diagram of a conventional processing method for curved plastic panels, which includes the following steps: Step 21: A flat plastic substrate (commonly known as a raw board) is produced by plastic extrusion molding; this plastic substrate may be a single-layer PC board, a PMMA/PC double-layer composite board, or a PMMA/PC/PMMA triple-layer composite board; Step 22: The flat plastic substrate is hot-pressed into a curved plastic substrate by hot pressing; Step 23: The curved plastic substrate is subjected to HC surface treatment to form an HC hard layer on the upper surface of the curved plastic substrate; then... Because curved plastic substrates are difficult to surface-treat with HC, the yield is poor; Step 24: Perform optical surface treatment on the curved plastic substrate to form an optical functional layer on the HC hard layer of the curved plastic substrate; however, because curved plastic substrates are difficult to surface-treat with optical surface, the yield is poor; Step 25: Perform printing processing on the curved plastic substrate to form a printed layer on the lower surface of the curved plastic substrate; however, because curved plastic substrates are difficult to print, the yield is poor; Step 26: Use planar computer numerical control (Computer) to process the curved plastic substrate. Numerical Control (CNC) machining is used to cut the curved plastic substrate into a predetermined shape. However, curved plastic substrates are difficult to machine using planar CNC machining, resulting in poor yield. Step 27: The finished curved plastic panel is completed. Due to the cumulative effect of the defect rates from steps 23 to 26, the final yield is very low, indicating room for improvement.
如圖三A、圖三B及圖三C所示,為習知將平面塑膠基板熱壓成為具曲面的塑膠基板的方法示意圖。習知將平面塑膠基板221熱壓成為具曲面的塑膠基板的方法,是先以烤箱把平面塑膠基板221加熱至一預定溫度使其軟化後,再把加熱軟化後的平面塑膠基板搬移至一壓模機台。該壓模機台具有固定形狀、曲率不可變的上、下模具222、223。將加熱後的平面塑膠基板221放置在上、下模具222、223之間(如圖三A),再以油壓缸驅動上、下模具222、223疊合並壓迫位於其中的塑膠基板221a(如圖三B),使塑膠基板221a外型也因此變形成為配合上、下模具的具曲面的塑膠基板221a後再將其取出(如圖三C)。此種習知熱壓技術,不僅會有塑膠基板221溫度不均勻的問題,於外圍區域散熱快所以在壓模時溫度較低、但中央區域則散熱慢、溫度較高,而且在塑膠基板221a曲率較大的彎折處229會有應力集中的問題;所以,倘若是把已形成硬質層與光學功能層的平面塑膠基板使用此習知技術加以熱壓的話,在曲率較大的彎折處229將會造成硬質層脆裂、光學功能層厚度不均勻的重大缺失,致使熱壓過的具曲面的塑膠基板221a產品不堪使用,無法通過產品測試。 Figures 3A, 3B, and 3C illustrate a conventional method for hot-pressing a planar plastic substrate into a curved plastic substrate. The conventional method for hot-pressing a planar plastic substrate 221 into a curved plastic substrate involves first heating the planar plastic substrate 221 to a predetermined temperature in an oven to soften it, and then transferring the softened planar plastic substrate to a molding machine. This molding machine has upper and lower molds 222 and 223 with fixed shapes and invariable curvature. The heated flat plastic substrate 221 is placed between the upper and lower molds 222 and 223 (as shown in Figure 3A). Then, the upper and lower molds 222 and 223 are driven by a hydraulic cylinder to overlap and press the plastic substrate 221a located therein (as shown in Figure 3B). This causes the plastic substrate 221a to be deformed into a curved plastic substrate 221a that matches the upper and lower molds. Then, it is removed (as shown in Figure 3C). This conventional hot-pressing technique not only suffers from uneven temperature distribution on the plastic substrate 221 (with faster heat dissipation in the outer areas resulting in lower temperatures during molding, while the central area experiences slower heat dissipation and higher temperatures), but also exhibits stress concentration at the bends 229 of the plastic substrate 221a where curvature is significant. Therefore, if a planar plastic substrate with pre-formed hard and optical functional layers is hot-pressed using this conventional technique, significant defects will occur at the bends 229 where curvature is significant, leading to hard layer brittleness and uneven thickness of the optical functional layer. This renders the hot-pressed curved plastic substrate 221a unusable and unable to pass product testing.
傳統之高分子基材曲面成型是先將高分子基板加熱至高於高分子之軟化點(Tg;玻璃轉化溫度)後,再將高分子基板移載至熱壓成型模具內進行曲面熱壓成型。移載過程因室溫空氣之熱對流所造成的基板溫度變化,將影響熱壓成型的曲率及輪廓度精度。移載時間越長則冷卻時間越長,越不利於控制基板的均溫性,則對於熱壓成型的曲率及輪廓度精度之 控制越差。因此,降低移載時間及降低冷卻時間,則越有利於曲率及輪廓度之精度控制。而最理想之製程設計為高溫加熱與曲率成型同步於自動化模具內進行。本發明的重點為可即時監控局部溫度及監控局部曲率的感測元件,並反饋回加熱機構及熱壓機構,即時調整至板材達到最適成型溫度及成型目標曲率。 Traditional polymer substrate curvature forming involves first heating the polymer substrate to a temperature higher than the polymer's softening point (Tg; glass transition temperature), then transferring the substrate into a hot press mold for curvature hot pressing. Temperature variations in the substrate caused by heat convection from room temperature air during the transfer process affect the curvature and contour accuracy of the hot press. Longer transfer times lead to longer cooling times, making it more difficult to control substrate temperature uniformity, and consequently, worsening the control over curvature and contour accuracy. Therefore, reducing transfer and cooling times is more beneficial for controlling curvature and contour accuracy. The ideal process design involves simultaneous high-temperature heating and curvature forming within an automated mold. The key feature of this invention is the sensing element that can monitor local temperature and curvature in real time, and provide feedback to the heating and hot-pressing mechanisms to adjust them in real time until the sheet material reaches the optimal molding temperature and target curvature.
本發明之主要目的是在於提供一種曲面塑膠面板的加工方法,其係將平面的塑膠基板先形成硬質層、光學功能層及印刷層,並以CNC切削機將平面的塑膠基板加以切削成為預定外型後,再以一曲面熱壓裝置將其進行曲面熱壓加工,使其成為一具曲面且具有該硬質層、該光學功能層與該印刷層且具有該預定外型的曲面塑膠基板。本發明的加工方法除可製作部分曲面或全曲面之顯示器的多功能高分子材料面板之外,並同時兼具光學功能(抗反射或抗眩光)及安全不破裂之優點。並且,由於硬質層、光學功能層、印刷層及CNC切削的加工處理都是在平面塑膠基板上進行,所以良率很高,克服了習知技術的種種缺失。 The main objective of this invention is to provide a processing method for curved plastic panels. This method involves first forming a rigid layer, an optical functional layer, and a printed layer on a flat plastic substrate. Then, a CNC cutting machine is used to cut the flat plastic substrate into a predetermined shape. Finally, a curved hot pressing device is used to perform curved hot pressing processing, resulting in a curved plastic substrate with the rigid layer, optical functional layer, and printed layer, and the predetermined shape. This processing method can not only produce multifunctional polymer material panels for partially or fully curved displays, but also possesses the advantages of optical functionality (anti-reflection or anti-glare) and safety against cracking. Furthermore, since the hard layer, optical functional layer, printed layer, and CNC machining are all performed on a planar plastic substrate, the yield rate is very high, overcoming various shortcomings of conventional technologies.
本發明之另一目的是在於提供一種曲面塑膠面板的加工裝置,其包括一獨創的曲面熱壓裝置,可於加熱過程中同步進行熱壓成型,並且具有即時監控局部溫度及即時監控局部曲率成型狀態之功能、進而再回饋至加熱局部機構調整。溫度及曲率之監控可區分為多個階段,逐一階段監控並進行加溫或曲率成型調整,藉以提高將已具有硬質層、光學功能層與印刷層的平面塑膠基板熱壓成型為曲面塑膠面板的生產良率,更能實現全曲面或部分曲面塑膠面板之熱壓成型加工。 Another objective of this invention is to provide a processing apparatus for curved plastic panels, comprising an original curved hot pressing device capable of simultaneous hot pressing during heating. This device features real-time monitoring of local temperature and curvature forming status, providing feedback to the heating mechanism for adjustment. Temperature and curvature monitoring can be divided into multiple stages, with each stage monitored and adjusted for heating or curvature forming. This improves the production yield of hot pressing curved plastic panels from planar plastic substrates with rigid layers, optical functional layers, and printed layers, and enables the hot pressing of fully curved or partially curved plastic panels.
本發明之再一目的是在於提供一種適用於本發明加工方法的曲面塑膠面板的硬質層與光學功能層的材料組成。透過高分子材料配方、塗料配方設計與精密塗佈技術,可將高分子表面可延展特性提升至可熱彎加工之水準,並可通過各項耐候性測試後維持原有光學及物理特性。 Another objective of this invention is to provide a material composition for the rigid layer and optical functional layer of curved plastic panels suitable for the processing method of this invention. Through polymer material formulation, coating formulation design, and precision coating technology, the surface extensibility of the polymer can be improved to a level suitable for hot bending, and the original optical and physical properties can be maintained after passing various weather resistance tests.
為達上述之目的,本發明揭露了一種曲面塑膠面板的加工方法,包括:提供一平面的塑膠基板;在該平面的塑膠基板的至少一表面上 形成平面的一硬質層(Hard Coating,簡稱HC);在該平面的塑膠基板的該硬質層上形成平面的一光學功能層;在該平面的塑膠基板的至少一表面上形成平面的一印刷層;藉由一切削機對該平面的塑膠基板加以切削成為具一預定外型的該平面的塑膠基板;以及,以一曲面熱壓裝置將已形成有該硬質層、該光學功能層與該印刷層且具有該預定外型的該平面的塑膠基板進行曲面熱壓加工,使其成為一具曲面且具有該硬質層、該光學功能層與該印刷層且具有該預定外型的曲面塑膠基板;其中,該曲面熱壓裝置具有包括:一可變曲率的上模具、一可變曲率的下模具、複數個上加熱器、複數個上感溫器、複數個下加熱器、以及複數個下感溫器;複數個該上加熱器和複數個該上感溫器是分佈設於該上模具的各個區域,複數個該下加熱器和複數個該下感溫器是分佈設於該下模具的各個區域;該上模具與該下模具是相對應配合且都至少可以局部調整其曲率;該曲面熱壓裝置是以下列步驟來對該平面的塑膠基板進行曲面熱壓加工:將該上模具與該下模具的曲率調整為平面,並將該平面的塑膠基板夾置於該上模具與該下模具之間,並且藉由複數個該上加熱器和複數個該下加熱器將該平面的塑膠基板的溫度加熱至一預定溫度,且使用複數個該上感溫器和複數個該下感溫器來感測並確認該平面的塑膠基板的該各個區域的溫度都是維持在該預定溫度;將該上模具與該下模具的曲率調整為一第一曲率,使得夾置於該上模具與該下模具之間的該平面的塑膠基板被該上模具與該下模具加工成為具該第一曲率的該曲面塑膠基板;同時,複數個該上感溫器和複數個該下感溫器仍持續感測並確認具該第一曲率的該曲面塑膠基板的該各個區域的溫度都是維持在該預定溫度;以及將該上模具與該下模具的曲率調整為一第二曲率,使得夾置於該上模具與該下模具之間的該曲面塑膠基板被該上模具與該下模具加工成為具該第二曲率的該曲面塑膠基板;同時,複數個該上感溫器和複數個該下感溫器仍持續感測並確認具該第二曲率的該曲面塑膠基板的該各個區域的溫度都是維持在該預定溫度;其中,該第二曲率的曲率是大於該第一曲率。 To achieve the above objectives, this invention discloses a method for processing a curved plastic panel, comprising: providing a planar plastic substrate; forming a planar hard layer on at least one surface of the planar plastic substrate. Coating (abbreviated as HC); forming a planar optical functional layer on the rigid layer of the planar plastic substrate; forming a planar printed layer on at least one surface of the planar plastic substrate; cutting the planar plastic substrate by a cutting machine to form a planar plastic substrate with a predetermined shape; and performing a curved hot pressing process on the planar plastic substrate with the rigid layer, the optical functional layer and the printed layer formed thereon and having the predetermined shape using a curved hot pressing device, so as to form a curved plastic substrate having the rigid layer, the optical functional layer and the printed layer and having the predetermined shape; wherein, the A curved hot pressing apparatus includes: an upper mold with variable curvature, a lower mold with variable curvature, a plurality of upper heaters, a plurality of upper temperature sensors, a plurality of lower heaters, and a plurality of lower temperature sensors; the plurality of upper heaters and the plurality of upper temperature sensors are distributed in various areas of the upper mold, and the plurality of lower heaters and the plurality of lower temperature sensors are distributed in various areas of the lower mold; the upper mold and the lower mold are correspondingly fitted and each can at least partially adjust its curvature; the curved hot pressing apparatus performs curved hot pressing processing on a flat plastic substrate by adjusting the curvature of the upper mold and the lower mold to be flat, The planar plastic substrate is sandwiched between the upper mold and the lower mold, and the temperature of the planar plastic substrate is heated to a predetermined temperature by a plurality of upper heaters and a plurality of lower heaters. A plurality of upper temperature sensors and a plurality of lower temperature sensors are used to sense and confirm that the temperature of each area of the planar plastic substrate is maintained at the predetermined temperature. The curvature of the upper mold and the lower mold is adjusted to a first curvature, so that the planar plastic substrate sandwiched between the upper mold and the lower mold is processed by the upper mold and the lower mold into a curved plastic substrate with the first curvature. Simultaneously, the plurality of upper temperature sensors and... The plurality of lower temperature sensors continue to sense and confirm that the temperature of each region of the curved plastic substrate with the first curvature is maintained at the predetermined temperature; and the curvature of the upper mold and the lower mold is adjusted to a second curvature, such that the curved plastic substrate sandwiched between the upper mold and the lower mold is processed by the upper mold and the lower mold into a curved plastic substrate with the second curvature; simultaneously, the plurality of upper temperature sensors and the plurality of lower temperature sensors continue to sense and confirm that the temperature of each region of the curved plastic substrate with the second curvature is maintained at the predetermined temperature; wherein the curvature of the second curvature is greater than the first curvature.
較佳者,該曲面熱壓裝置更包括複數個攝像器,用於擷取該上模具與該下模具的曲率影像,藉以判斷該曲面塑膠基板的曲率是否已達到一預定曲率。 Preferably, the curved hot pressing apparatus further includes a plurality of cameras for capturing curvature images of the upper mold and the lower mold, thereby determining whether the curvature of the curved plastic substrate has reached a predetermined curvature.
較佳者,該上模具至少包括有一第一上模板、一第二上模板及一第三上模板;該第一上模板與該第二上模板之間是以一第一上關節連結,使得該第一上模板可藉由該第一上關節進行相對於該第二上模板的曲率調整運動;該第二上模板與該第三上模板之間是以一第二上關節連結,使得該第三上模板可藉由該第二上關節進行相對於該第二上模板的曲率調整運動;該下模具至少包括有一第一下模板、一第二下模板及一第三下模板;該第一下模板與該第二下模板之間是以一第一下關節連結,使得該第一下模板可藉由該第一下關節進行相對於該第二下模板的曲率調整運動;該第二下模板與該第三下模板之間是以一第二下關節連結,使得該第三下模板可藉由該第二下關節進行相對於該第二下模板的曲率調整運動;其中,該第一上模板的外型和位置是對應於該第一下模板,該第二上模板的外型和位置是對應於該第二下模板,該第三上模板的外型和位置是對應於該第三下模板。 Preferably, the upper mold includes at least a first upper template, a second upper template, and a third upper template; the first upper template and the second upper template are connected by a first upper joint, allowing the first upper template to perform curvature adjustment relative to the second upper template via the first upper joint; the second upper template and the third upper template are connected by a second upper joint, allowing the third upper template to perform curvature adjustment relative to the second upper template via the second upper joint; the lower mold includes at least a first lower template, a second lower template, and a third lower template; the first lower... The first lower template and the second lower template are connected by a first lower joint, allowing the first lower template to adjust its curvature relative to the second lower template via the first lower joint; the second lower template and the third lower template are connected by a second lower joint, allowing the third lower template to adjust its curvature relative to the second lower template via the second lower joint; wherein the shape and position of the first upper template correspond to the first lower template, the shape and position of the second upper template correspond to the second lower template, and the shape and position of the third upper template correspond to the third lower template.
較佳者,於該第一上模板、該第二上模板及該第三上模板中都分別設有該上加熱器及該上感溫器;於該第一下模板、該第二下模板及該第三下模板中都分別設有該下加熱器及該下感溫器;該第一上關節、該第二上關節、該第一下關節及該第二下關節都分別各包括一線性滑軌,藉由該線性滑軌帶動力矩的方式來調整相鄰兩模板之間的曲率。 Preferably, the upper heater and the upper temperature sensor are respectively provided in the first upper template, the second upper template, and the third upper template; the lower heater and the lower temperature sensor are respectively provided in the first lower template, the second lower template, and the third lower template; each of the first upper joint, the second upper joint, the first lower joint, and the second lower joint includes a linear slide rail, and the curvature between adjacent templates is adjusted by means of the torque driven by the linear slide rail.
較佳者,該平面的塑膠基板的材料組成是以下其中之一:聚甲基丙烯酸甲酯(Polymethyl Methacrylate,簡稱PMMA)板材、聚碳酸酯(Polycarbonate,簡稱PC)板材、PMMA/PC雙層複合板材、或是PMMA/PC/PMMA三層複合板材;該硬質層的組成至少包含以下其中之一:有機無機混成紫外光寡聚物/單體、無機粒子材料、或是高延伸特性(延伸率>200%)之紫外光固化長鏈寡聚物/單體;其中,該有機無機混成紫外光寡聚物/單體包含以下其中之一:高玻璃轉移溫度(Glass Transition Temperature,簡稱Tg)且其Tg120℃之紫外光固化彈性寡聚物、或是高Tg單體(Tg240℃);該光學功能層組成至少包含以下其中之一:高折射率(Refractive Index;簡稱RI)之紫外光固化寡聚物/單體、高RI無機材料、低RI之紫外光固化寡聚物/單體、或是低RI無機材料;其中,該高RI無機材料是包含以下其中之一:二氧化鈦(TiO2)或五氧化二铌(Nb2O5);該低RI無機材料是包含以下其中之一:二氧化矽(SiO2)或氟化鎂(MgF2);其中,該高折射率(RI)之紫外光固化寡聚物/單體的RI值範圍為:RI=1.55~1.75;該低RI之紫外光固化寡聚物/單體的RI值範圍為:RI=1.4~1.48;該高RI無機材料的RI值範圍為:RI=1.8~2.5;該低RI無機材料的RI值範圍為:RI=1.2~1.45。 Preferably, the material composition of the plastic substrate of the plane is one of the following: polymethyl methacrylate (PMMA) sheet, polycarbonate (PC) sheet, PMMA/PC double-layer composite sheet, or PMMA/PC/PMMA triple-layer composite sheet; the composition of the rigid layer includes at least one of the following: organic-inorganic hybrid UV-curable oligomers/monomers, inorganic particle materials, or UV-curable long-chain oligomers/monomers with high elongation characteristics (elongation >200%); wherein the organic-inorganic hybrid UV-curable oligomers/monomers include one of the following: high glass transition temperature (Tg) and its Tg UV-curable elastic oligomers at 120℃, or high Tg monomers (Tg 240℃); the optical functional layer comprises at least one of the following: high refractive index (Refractive) The term "index" (RI) refers to UV-curable oligomers/monomers, high-RI inorganic materials, low-RI UV-curable oligomers/monomers, or low-RI inorganic materials. The high-RI inorganic material comprises one of the following: titanium dioxide (TiO2) or niobium pentoxide (Nb2O5); the low-RI inorganic material comprises one of the following: silicon dioxide (SiO2) or magnesium fluoride (MgF2); the RI value range of the high-refractive-index (RI) UV-curable oligomers/monomers is RI = 1.55~1.75; the RI value range of the low-RI UV-curable oligomers/monomers is RI = 1.4~1.48; the RI value range of the high-RI inorganic material is RI = 1.8~2.5; and the RI value range of the low-RI inorganic material is RI = 1.2~1.45.
10:塑膠面板 10: Plastic Panels
11:塑膠基板 11: Plastic substrate
111:PC板材 111: PC Sheet
112、113:PMMA板材 112, 113: PMMA sheets
12:硬質層 12: Hard layer
13:光學功能層 13: Optical functional layer
14:印刷層 14: Printing Layer
21~27、31~37、3611~3614、3621~3624、3631~3634:步驟 Steps 21-27, 31-37, 3611-3614, 3621-3624, 3631-3634:
221、221a:塑膠基板 221, 221a: Plastic substrate
222、223:模具 222, 223: Molds
229:彎折處 229: Bend
361~364:階段 361~364: Stage
41:塑膠基板 41: Plastic substrate
42、43:模具 42, 43: Molds
420a、420b、430a、430b:關節 420a, 420b, 430a, 430b: Joints
4201、4301:線性滑軌 4201, 4301: Linear guide rails
421、431:加熱器 421, 431: Heaters
422、432:感溫器 422, 432: Temperature Sensors
49:彎折處 49: Bend
50:曲面熱壓裝置 50: Curved Surface Hot Press Device
51:機台本體 51: Machine Body
52:門板 52: Door panel
53、54:油壓裝置 53, 54: Hydraulic Devices
531、541:模具鎖附機構 531, 541: Mold locking mechanism
55:攝像器 55: Camera
60:控制單元 60: Control Unit
61:加熱模組 61: Heating Module
62:溫度感測模組 62: Temperature Sensing Module
63:驅動裝置 63: Drive unit
64:影像擷取模組 64: Image Capture Module
65:資料庫 65:Database
66:分析模組 66: Analysis Module
67:控制模組 67: Control Module
68:電源模組 68: Power Module
69:人機介面 69: Human-Computer Interface
圖一為一典型具曲面的塑膠面板的結構示意圖。 Figure 1 is a schematic diagram of a typical curved plastic panel.
圖二為為習知具曲面的塑膠面板的加工方法示意圖。 Figure 2 is a schematic diagram illustrating the processing method for learning to use curved plastic panels.
圖三A、圖三B及圖三C分別為習知將平面塑膠基板熱壓成為具曲面的塑膠基板的方法的三個步驟示意圖。 Figures 3A, 3B, and 3C are schematic diagrams of three steps in a conventional method for hot-pressing a planar plastic substrate into a curved plastic substrate.
圖四為本發明之具曲面的塑膠面板的加工方法的流程示意圖。 Figure 4 is a flowchart illustrating the processing method of the curved plastic panel of this invention.
圖五A、圖五B、圖五C及圖五D分別為本發明將平面塑膠基板熱壓成為具曲面的塑膠基板的數個流程的示意圖。 Figures 5A, 5B, 5C, and 5D are schematic diagrams illustrating several processes of hot-pressing a planar plastic substrate into a curved plastic substrate according to the present invention.
圖五E是本發明所述曲面熱壓裝置的上模具(或下模具)的俯視示意圖 Figure 5E is a top view of the upper (or lower) mold of the curved surface hot pressing device described in this invention.
圖六為本發明所述曲面熱壓裝置進行即時監控局部溫度及即時監控局部曲率成型狀態的流程示意圖。 Figure 6 is a schematic flowchart illustrating the real-time monitoring of local temperature and curvature forming status of the curved surface hot pressing device described in this invention.
圖七A及圖七B分別為本發明之曲面塑膠面板的加工裝置的一實施例於門板開啟及門板關閉狀態下的示意圖。 Figures 7A and 7B are schematic diagrams of an embodiment of the processing apparatus for curved plastic panels of the present invention in the open and closed states of the door panel, respectively.
圖八A及圖八B分別為本發明之曲面熱壓裝置的可變曲率的上、下模具於平面狀態與彎曲狀態時的示意圖。 Figures 8A and 8B are schematic diagrams of the variable curvature upper and lower molds of the curved surface hot pressing device of the present invention in a planar state and a bent state, respectively.
本發明提供一種曲面塑膠面板的加工方法,其係將平面的塑膠基板先形成硬質層、光學功能層及印刷層,並以CNC切削機將平面的塑 膠基板加以切削成為預定外型後,再以一曲面熱壓裝置將其進行曲面熱壓加工,使其成為一具曲面且具有該硬質層、該光學功能層與該印刷層且具有該預定外型的曲面塑膠基板。本發明的加工方法除可製作部分曲面或全曲面之顯示器的多功能高分子材料面板之外,並同時兼具光學功能(抗反射或抗眩光)及安全不破裂之優點。並且,由於硬質層、光學功能層、印刷層及CNC切削的加工處理都是在平面塑膠基板上進行,所以良率很高,克服了習知技術的種種缺失。本發明的曲面熱壓裝置可於加熱過程中同步進行熱壓成型,並且具有即時監控局部溫度及即時監控局部曲率成型狀態之功能、進而再回饋至加熱局部機構調整。溫度及曲率之監控可區分為多個階段,逐一階段監控並進行加溫或曲率成型調整,藉以提高將已具有硬質層、光學功能層與印刷層的平面塑膠基板熱壓成型為曲面塑膠面板的生產良率,更能實現全曲面或部分曲面塑膠面板之熱壓成型加工。本發明還提供一種塑膠面板之硬質層與光學功能層的材料組成。透過高分子材料配方、塗料配方設計與精密塗佈技術,可將高分子表面可延展特性提升至可熱彎加工之水準,並可通過各項耐候性測試後維持原有光學及物理特性。 This invention provides a method for processing curved plastic panels. The method involves first forming a rigid layer, an optical functional layer, and a printed layer on a flat plastic substrate. Then, a CNC cutting machine is used to cut the flat plastic substrate into a predetermined shape. Finally, a curved hot pressing device is used to perform curved hot pressing processing, resulting in a curved plastic substrate with the rigid layer, optical functional layer, and printed layer, and the predetermined shape. This processing method can produce multifunctional polymer material panels for partially or fully curved displays, and also possesses the advantages of optical functionality (anti-reflection or anti-glare) and safety against cracking. Furthermore, since the processing of the hard layer, optical functional layer, printed layer, and CNC cutting is all performed on a planar plastic substrate, the yield rate is very high, overcoming various shortcomings of prior art. The curved hot pressing device of this invention can perform hot pressing simultaneously during the heating process, and has the function of real-time monitoring of local temperature and real-time monitoring of local curvature forming status, and then feeding back to the heating local mechanism for adjustment. Temperature and curvature monitoring can be divided into multiple stages, with each stage monitored and adjusted for heating or curvature forming. This improves the production yield of hot-pressing a planar plastic substrate with a rigid layer, optical functional layer, and printed layer into a curved plastic panel, and enables hot-pressing of fully curved or partially curved plastic panels. This invention also provides the material composition of the rigid layer and optical functional layer of the plastic panel. Through polymer material formulation, coating formulation design, and precision coating technology, the surface extensibility of the polymer can be enhanced to a level suitable for hot bending, and the original optical and physical properties can be maintained after passing various weather resistance tests.
為了能更清楚地描述本發明所提出之具曲面的可透光塑膠板結構及其製造方法,以下將配合圖式詳細說明之。 To more clearly describe the curved, translucent plastic sheet structure and its manufacturing method proposed in this invention, a detailed explanation with accompanying drawings will follow.
本發明中所述的具曲面的塑膠面板,於結構上亦如圖一所示之一般適用於曲面車載顯示器的典型的塑膠面板10,其同樣包括有:一塑膠基板11、一硬質層12(Hard Coating;簡稱HC)、一光學功能層13、以及一印刷層14。該塑膠基板11於材料組成上可以是單層的PC板材、單層的PMMA板材、共押出(coextrusion)成型的PMMA/PC雙層複合板材、共押出成型的PMMA/PC/PMMA三層複合板材、或是其他習知的塑膠板材結構。於本實施例中,該塑膠基板11是由聚碳酸酯(PC)板材111做為主層,並在PC板材111的上、下表面分別設置一聚甲基丙烯酸甲酯(PMMA)板材112、113以強化其物理特性。硬質層12通常是形成於該塑膠基板11的外表面(上表面)上、或是在外、內表面(上、下表面)都設置硬質層12,用於提高塑膠面板10的耐磨性。於本實施例中,該硬質層12的組成至少包含以下其中之一:有機無機混成紫外光寡聚物/單體、無機粒子材料、或是高延伸特性(延伸率>200%)之紫外光固化長鏈寡聚物/單體;其中,該有機無機混 成紫外光寡聚物/單體包含以下其中之一:高玻璃轉移溫度(Glass Transition Temperature,簡稱Tg)且其Tg120℃之紫外光固化彈性寡聚物、或是高Tg單體(Tg240℃)。光學功能層13通常是形成於硬質層12的外表面上,用於提高塑膠面板10的光學表現,例如但不侷限於:耐紫外光、抗眩光、以及抗反射等等功能。於本實施例中,該光學功能層13組成至少包含以下其中之一:高折射率(Refractive Index;簡稱RI)之紫外光固化寡聚物/單體、高RI無機材料、低RI之紫外光固化寡聚物/單體、或是低RI無機材料;其中,該高RI無機材料是包含以下其中之一:二氧化鈦(TiO2)或五氧化二铌(Nb2O5);該低RI無機材料是包含以下其中之一:二氧化矽(SiO2)或氟化鎂(MgF2)。印刷層14通常是以有顏色的油墨印刷於該塑膠基板11內表面上,用於表現車載顯示器的功能指標。本發明的塑膠面板10於結構上雖和習知技術類似,但是本發明在硬質層12和光學功能層13的材料選擇上則特別獨創使用具高Tg值(Tg120℃)和高延伸特性的材料配方(延伸率>200%)。藉由在硬質層12使用高Tg值(Tg120℃)的紫外光固化彈性寡聚物或高Tg單體(Tg240℃)材料配方可提供可成型之具曲面的塑膠面板10具有高耐衝性、高可撓曲性、以及高溫狀態下之穩定性,可提升高溫環測或高溫高濕環測時之信賴性。藉由在硬質層12使用高延伸特性(延伸率>200%)之紫外光固化長鏈寡聚物或單體的材料配方,可提供可成型之具曲面的塑膠面板10有高延伸特性以及高溫可成型性,避免在熱壓成型的過程中產生龜裂或是造成光學功能層13的厚度不均。 The curved plastic panel described in this invention, structurally similar to the typical plastic panel 10 used in curved automotive displays as shown in Figure 1, also includes: a plastic substrate 11, a hard coating 12 (HC), an optical functional layer 13, and a printed layer 14. The plastic substrate 11 can be made of a single-layer PC sheet, a single-layer PMMA sheet, a co-extruded PMMA/PC double-layer composite sheet, a co-extruded PMMA/PC/PMMA triple-layer composite sheet, or other known plastic sheet structures. In this embodiment, the plastic substrate 11 is made of polycarbonate (PC) sheet 111 as the main layer, and polymethyl methacrylate (PMMA) sheets 112 and 113 are respectively disposed on the upper and lower surfaces of the PC sheet 111 to enhance its physical properties. The rigid layer 12 is usually formed on the outer surface (upper surface) of the plastic substrate 11, or the rigid layer 12 is disposed on both the outer and inner surfaces (upper and lower surfaces) to improve the wear resistance of the plastic panel 10. In this embodiment, the rigid layer 12 comprises at least one of the following: an organic-inorganic hybrid ultraviolet-cured oligomer/monomer, an inorganic particle material, or an ultraviolet-cured long-chain oligomer/monomer with high elongation (elongation >200%); wherein the organic-inorganic hybrid ultraviolet-cured oligomer/monomer comprises one of the following: a high glass transition temperature (Tg) and its Tg UV-curable elastic oligomers at 120℃, or high Tg monomers (Tg (240℃). The optical functional layer 13 is typically formed on the outer surface of the rigid layer 12 to improve the optical performance of the plastic panel 10, such as, but not limited to, functions such as UV resistance, anti-glare, and anti-reflection. In this embodiment, the optical functional layer 13 comprises at least one of the following: a high refractive index (RI) UV-curable oligomer/monomer, a high RI inorganic material, a low RI UV-curable oligomer/monomer, or a low RI inorganic material; wherein the high RI inorganic material comprises one of the following: titanium dioxide ( TiO2 ) or niobium pentoxide ( Nb2O5 ); and the low RI inorganic material comprises one of the following: silicon dioxide ( SiO2 ) or magnesium fluoride ( MgF2 ). The printed layer 14 is typically printed with colored ink on the inner surface of the plastic substrate 11 to represent the functional indicators of the in-vehicle display. While the plastic panel 10 of this invention is structurally similar to the prior art, this invention is particularly unique in its choice of materials for the rigid layer 12 and the optical functional layer 13, using materials with high Tg values (Tg... A material formulation with high elongation properties (elongation > 200%) and a temperature of 120℃. This is achieved by using a high Tg value (Tg) in the hard layer 12. UV-curable elastic oligomers or high Tg monomers (Tg) at 120℃ The material formulation (240℃) provides a moldable curved plastic panel 10 with high impact resistance, high flexibility, and stability under high temperature conditions, which can improve the reliability of high-temperature environmental testing or high-temperature and high-humidity environmental testing. By using a material formulation of UV-curable long-chain oligomers or monomers with high elongation characteristics (elongation rate >200%) in the rigid layer 12, the moldable curved plastic panel 10 can be provided with high elongation characteristics and high-temperature moldability, avoiding cracking or uneven thickness of the optical functional layer 13 during hot pressing.
於本發明中,硬質層12(HC)的材料配方組成包含有機無機混成紫外光寡聚物,相對於傳統高交聯密度之HC配方具有相對較低之交聯密度,可形成收縮率較低及可撓性佳之耐磨硬質層12。其中,無機材料可貢獻表面物理特性,使塗層具有高硬度及高耐磨耗性。另,本發明硬質層12(HC)配方組成包含高Tg紫外光彈性體寡聚物與高Tg單體,相對於傳統高交聯密度之HC配方具有較佳之高溫穩定性,因此在高溫製程時具有較佳之熱可成型性,可將UV硬化後的可成型高分子前面板材料彎曲為自由曲率。本發明硬質層12(HC)配方組成包含高延伸特性(>200%)之紫外光固化長鏈寡聚物或單體,相對於傳統高交聯密度之HC配方具有較佳之高延伸性,因此在熱壓製程中具有較佳之熱可成型性,可將UV硬化後的可成型高 分子前面板材料彎曲為自由曲率。本發明之具硬質層12與光學功能層13的平面塑膠面板10在進行熱壓加工前,會先進行平面油墨印刷及平面外型CNC加工,之後再結合本發明之曲面熱壓製程,可於熱壓後直接產出具有光學功能之曲面成品。有別於一般曲面前面板生產過程都是先進行曲面熱壓、再進行曲面表面處理及曲面光學處理、曲面印刷、曲面外型CNC加工,各站因曲面製程加工不易之良率不佳,直通率降低導致生產成本過高。本發明因各項加工工藝皆於平面完成,各站良率及直通率皆高,因此有較低之加工成本。於本實施例中,該高折射率(RI)之紫外光固化寡聚物/單體的RI值範圍為:RI=1.55~1.75;該低RI之紫外光固化寡聚物/單體的RI值範圍為:RI=1.4~1.48;該高RI無機材料的RI值範圍為:RI=1.8~2.5;該低RI無機材料的RI值範圍為:RI=1.2~1.45。抗反射定義為:反射率Reflection<2%;抗眩光定義為:光澤度<100。 In this invention, the hard layer 12 (HC) is formulated with a mixture of organic and inorganic UV-cured oligomers. Compared to traditional high-crosslink-density HC formulations, it has a relatively low crosslink-density, resulting in a wear-resistant hard layer 12 with lower shrinkage and better flexibility. The inorganic materials contribute to the surface physical properties, giving the coating high hardness and high wear resistance. Furthermore, the hard layer 12 (HC) formulation of this invention includes high-Tg UV-cured elastomer oligomers and high-Tg monomers, exhibiting better high-temperature stability compared to traditional high-crosslink-density HC formulations. Therefore, it has better thermoformability during high-temperature processes, allowing the UV-cured moldable polymer front panel material to be bent into a free curvature. The rigid layer 12 (HC) of this invention comprises UV-curable long-chain oligomers or monomers with high elongation (>200%). Compared to traditional HC formulations with high cross-linking density, it exhibits superior elongation, thus providing better thermoformability during hot pressing. This allows the UV-cured moldable polymer front panel material to be bent into a free curvature. Before hot pressing, the flat plastic panel 10 of this invention, consisting of the rigid layer 12 and the optical functional layer 13, undergoes planar ink printing and planar CNC machining. Then, combined with the curved hot pressing process of this invention, a curved finished product with optical functions can be directly produced after hot pressing. Unlike conventional curved front panel production processes, which involve hot pressing, surface treatment, optical processing, printing, and CNC machining, where each stage of the process suffers from poor yield and low first-pass yield, leading to high production costs, this invention achieves higher yield and first-pass yield because all processing steps are completed on a flat surface. In this embodiment, the RI value range of the high refractive index (RI) UV-curable oligomer/monomer is RI=1.55~1.75; the RI value range of the low RI UV-curable oligomer/monomer is RI=1.4~1.48; the RI value range of the high RI inorganic material is RI=1.8~2.5; and the RI value range of the low RI inorganic material is RI=1.2~1.45. Anti-reflection is defined as: Reflectance < 2%; Anti-glare is defined as: Glossiness < 100.
請參閱圖四,為本發明之具曲面的塑膠面板的加工方法的示意圖,其包含以下步驟:步驟31:以塑膠押出成型方式製作平面的塑膠基板(俗稱生板);此塑膠基板可能是單層PC板材、單層PMMA板材、也可能是PMMA/PC雙層複合板材、或是PMMA/PC/PMMA三層複合板材;步驟32:對該平面的塑膠基板進行HC表面處理,以便在具平面的塑膠基板的上表面形成HC硬質層;因平面塑膠基板容易進行HC表面處理,所以良率很高;步驟33:對該平面的塑膠基板進行光學表面處理,以便在具平面的塑膠基板的HC硬質層上形成光學功能層;因平面塑膠基板容易進行光學表面處理,所以良率很高;步驟34:對該平面的塑膠基板進行印刷處理,以便在平面的塑膠基板的下表面上形成印刷層;因平面塑膠基板容易進行印刷處理,所以良率很高;步驟35:對該平面的塑膠基板以平面電腦數值控制(CNC)加工機(切削機)進行切削加工,以將平面的塑膠基板切削成具一預定外型輪廓的平面塑膠基板;因平面塑膠基板很容易進行平面CNC切削處理,所以良率很高; 步驟36:以一曲面熱壓裝置將已形成有該硬質層、該光學功能層與該印刷層且具有該預定外型的該平面的塑膠基板進行曲面熱壓加工,使其成為一具曲面且具有該硬質層、該光學功能層與該印刷層且具有該預定外型的曲面塑膠基板;步驟37:完成具曲面的塑膠面板成品;由於步驟32至步驟35的加工良率都很高,所以最後完成的成品良率與精度也都很高、且能通過後續的產品測試。 Please refer to Figure 4, which is a schematic diagram of the processing method of the curved plastic panel of the present invention, including the following steps: Step 31: A flat plastic substrate (commonly known as a raw board) is produced by plastic extrusion molding; this plastic substrate may be a single-layer PC board, a single-layer PMMA board, a PMMA/PC double-layer composite board, or a PMMA/PC/PMMA triple-layer composite board; Step 32: The flat plastic substrate is subjected to HC surface treatment. To form an HC hard layer on the upper surface of the planar plastic substrate; because planar plastic substrates are easy to surface treat with HC, the yield is very high; Step 33: Perform an optical surface treatment on the planar plastic substrate to form an optical functional layer on the HC hard layer of the planar plastic substrate; because planar plastic substrates are easy to surface treat with optical, the yield is very high; Step 34: Perform a printing process on the planar plastic substrate to form an optical functional layer on the planar plastic substrate. A printed layer is formed on the lower surface; because the planar plastic substrate is easy to print on, the yield is very high; Step 35: The planar plastic substrate is machined using a planar computer numerical control (CNC) machining machine (cutting machine) to cut the planar plastic substrate into a planar plastic substrate with a predetermined outline; because the planar plastic substrate is easy to machine using planar CNC cutting, the yield is very high; Step 36: The already formed layer is pressed onto the lower surface using a curved hot pressing device. The planar plastic substrate, comprising the rigid layer, the optical functional layer, and the printed layer, and having the predetermined shape, undergoes curved hot pressing processing to form a curved plastic substrate with the rigid layer, the optical functional layer, and the printed layer, and having the predetermined shape; Step 37: The finished curved plastic panel is completed; Because the processing yields of steps 32 to 35 are very high, the final finished product also has high yield and precision, and can pass subsequent product testing.
如圖五A、圖五B、圖五C及圖五D所示,分別為本發明將平面塑膠基板熱壓成為具曲面的塑膠基板的數個流程的示意圖。本發明的加工方法,是使用一曲面熱壓裝置將已形成有該硬質層、該光學功能層與該印刷層且具有該預定外型的該平面的塑膠基板進行曲面熱壓加工,使其成為一具曲面且具有該硬質層、該光學功能層與該印刷層且具有該預定外型的曲面塑膠基板41。該曲面熱壓裝置具有包括:一可變曲率的上模具42、一可變曲率的下模具43、複數個上加熱器421、複數個上感溫器422、複數個下加熱器431、以及複數個下感溫器432。請見圖五E是本發明所述曲面熱壓裝置的上模具(或下模具)的俯視示意圖。於本實施例中,複數個該上加熱器421和複數個該上感溫器422是以陣列方式均勻且交錯地分佈設於該上模具42的各個區域,複數個該下加熱器431和複數個該下感溫器432是以陣列方式均勻且交錯地分佈設於該下模具43的各個區域。該上模具42與該下模具43的外型結構是相對應配合且都至少可以局部調整其曲率。於本實施例中,該曲面熱壓裝置是以下列步驟來對該平面的塑膠基板41進行曲面熱壓加工:如圖五A所示,首先,將該上模具42與該下模具43的曲率調整為平面(曲率=0),並將該平面的塑膠基板41夾置於該上模具42與該下模具43之間,並且藉由複數個該上加熱器421和複數個該下加熱器431將該平面的塑膠基板41的溫度加熱至一預定溫度,且使用複數個該上感溫器422和複數個該下感溫器432來感測、確認或迴授控制該平面的塑膠基板41的該各個區域的溫度都是維持在該預定溫度。 Figures 5A, 5B, 5C, and 5D are schematic diagrams illustrating several processes of hot-pressing a planar plastic substrate into a curved plastic substrate according to the present invention. The processing method of the present invention uses a curved hot-pressing device to perform curved hot-pressing processing on the planar plastic substrate that has formed the hard layer, the optical functional layer, and the printed layer and has the predetermined shape, so as to make it into a curved plastic substrate 41 that has the hard layer, the optical functional layer, and the printed layer and has the predetermined shape. The curved surface hot pressing device includes: an upper mold 42 with variable curvature, a lower mold 43 with variable curvature, a plurality of upper heaters 421, a plurality of upper temperature sensors 422, a plurality of lower heaters 431, and a plurality of lower temperature sensors 432. Figure 5E is a top view of the upper mold (or lower mold) of the curved surface hot pressing device described in this invention. In this embodiment, the plurality of upper heaters 421 and the plurality of upper temperature sensors 422 are uniformly and alternately distributed in an array in various regions of the upper mold 42, and the plurality of lower heaters 431 and the plurality of lower temperature sensors 432 are uniformly and alternately distributed in an array in various regions of the lower mold 43. The upper mold 42 and the lower mold 43 have corresponding and matching external structures, and their curvatures can be adjusted at least locally. In this embodiment, the curved hot pressing apparatus performs curved hot pressing processing on the flat plastic substrate 41 using the following steps: As shown in Figure 5A, firstly, the curvature of the upper mold 42 and the lower mold 43 is adjusted to be flat (curvature = 0), and the flat plastic substrate 41 is sandwiched between the upper mold 42 and the lower mold 43. The temperature of the flat plastic substrate 41 is heated to a predetermined temperature using a plurality of upper heaters 421 and a plurality of lower heaters 431. A plurality of upper temperature sensors 422 and a plurality of lower temperature sensors 432 are used to sense, confirm, or feedback control to ensure that the temperature of each area of the flat plastic substrate 41 is maintained at the predetermined temperature.
如圖五B所示,接著,將該上模具42與該下模具43的曲率調整為一第一曲率(相對較小曲率),使得夾置於該上模具42與該下模具43之 間的該平面的塑膠基板41因為被該上模具42與該下模具43熱壓加工而成為具該第一曲率的曲面塑膠基板41;同時,複數個該上感溫器422和複數個該下感溫器432仍持續感測、確認並迴授控制具該第一曲率的該曲面塑膠基板41的該各個區域的溫度都是維持在該預定溫度。 As shown in Figure 5B, the curvature of the upper mold 42 and the lower mold 43 is then adjusted to a first curvature (a relatively small curvature), so that the flat plastic substrate 41 sandwiched between the upper mold 42 and the lower mold 43 is formed into a curved plastic substrate 41 with the first curvature by hot pressing with the upper mold 42 and the lower mold 43; simultaneously, the plurality of upper temperature sensors 422 and the plurality of lower temperature sensors 432 continue to sense, confirm, and feedback control to maintain the temperature of each region of the curved plastic substrate 41 with the first curvature at the predetermined temperature.
如圖五C所示,然後,將該上模具42與該下模具43的曲率調整為一第二曲率(相對較大一點的曲率),使得夾置於該上模具42與該下模具43之間的該曲面塑膠基板41被該上模具42與該下模具43熱壓加工成為具該第二曲率的該曲面塑膠基板41;同時,複數個該上感溫器422和複數個該下感溫器432仍持續感測並確認具該第二曲率的該曲面塑膠基板41的該各個區域的溫度都是維持在該預定溫度;其中,該第二曲率的曲率是大於該第一曲率。 As shown in Figure 5C, the curvature of the upper mold 42 and the lower mold 43 is then adjusted to a second curvature (a relatively larger curvature), so that the curved plastic substrate 41 sandwiched between the upper mold 42 and the lower mold 43 is hot-pressed by the upper mold 42 and the lower mold 43 to form the curved plastic substrate 41 with the second curvature; simultaneously, the plurality of upper temperature sensors 422 and the plurality of lower temperature sensors 432 continue to sense and confirm that the temperature of each region of the curved plastic substrate 41 with the second curvature is maintained at the predetermined temperature; wherein, the curvature of the second curvature is greater than the first curvature.
如圖五D所示,當曲面塑膠基板41的曲率(亦即,該上模具42與該下模具43的曲率)達到預定曲率後,即可將上、下模具42、43打開並取出具該預定曲率的曲面塑膠基板41。由於本發明的曲面熱壓裝置是在上、下模具42、43分別設置多個加熱器421、431與感溫器422、432來分別進行加熱與控溫,每一個加熱器421、431與感溫器422、432都能獨立運作進行控溫,所以在熱壓過程中塑膠基板41的各區域的溫度都很穩定、均勻。並且,曲面熱壓裝置可於加熱過程中同步進行熱壓成型,並且具有即時監控局部溫度及即時監控局部曲率成型狀態之功能、進而再回饋至加熱局部機構調整。溫度及曲率之監控可區分為多個階段,逐一階段監控並進行加溫或曲率成型調整,藉以避免在曲面塑膠基板41的彎折處49發生應力集中或硬質層龜裂的現象,並能提高生產良率。本發明更透過高分子材料配方、塗料配方設計與精密塗佈技術,可將高分子表面(尤其是硬質層)的可延展特性提升至可熱彎加工之水準,即使在經熱壓成型曲面塑膠面板並可通過各項耐候性測試後仍然維持原有光學及物理特性。 As shown in Figure 5D, once the curvature of the curved plastic substrate 41 (i.e., the curvature of the upper mold 42 and the lower mold 43) reaches the predetermined curvature, the upper and lower molds 42 and 43 can be opened and the curved plastic substrate 41 with the predetermined curvature can be removed. Since the curved hot pressing device of the present invention is equipped with multiple heaters 421 and 431 and temperature sensors 422 and 432 respectively in the upper and lower molds 42 and 43 for heating and temperature control, each heater 421 and 431 and temperature sensor 422 and 432 can operate independently to control the temperature. Therefore, the temperature of each area of the plastic substrate 41 is very stable and uniform during the hot pressing process. Furthermore, the curved hot pressing device can perform hot pressing molding simultaneously during the heating process, and has the function of real-time monitoring of local temperature and real-time monitoring of local curvature molding status, and then feeding back to the heating local mechanism for adjustment. Temperature and curvature monitoring can be divided into multiple stages, and each stage is monitored and heated or the curvature molding is adjusted to avoid stress concentration or hard layer cracking at the bend 49 of the curved plastic substrate 41, and to improve production yield. This invention further enhances the malleability of polymer surfaces (especially rigid layers) to a level suitable for hot bending through polymer material formulation, coating formulation design, and precision coating technology. Even after hot-pressing curved plastic panels and passing various weather resistance tests, the original optical and physical properties are maintained.
請參閱圖六,為本發明所述曲面熱壓裝置進行即時監控局部溫度及即時監控局部曲率成型狀態的流程示意圖。如圖六所示、並搭配圖五A至圖五D內容,於熱壓曲面成型過程中,首先,在第一階段(1st Step)361中,一如圖五A所示般上、下模具42、43仍呈低溫且平面(曲率為0)狀態;此時,藉由多個加熱器421、431分別對塑膠基板的各個部位進行局部 加熱(步驟3611)、並以多個感溫器422、432來分別感測塑膠基板的各個部位進行局部溫度感測(Sensor),倘若有某感溫器422、432感測到任一部位(區域)的溫度未達到預定溫度時,則迴授控制相對應的加熱器421、431進行加熱(步驟3612),直到塑膠基板的每個部位(區域)都達到預定溫度為止;同時,曲面熱壓裝置也藉由曲率感測器來即時監測上、下模具42、43的各個局部位置的曲率(步驟3613),倘若監測到任一部位(區域)的曲率未達到第一曲率時,則迴授控制上、下模具42、43進行該部位的局部彎曲(步驟3614),直到塑膠基板的每個部位(區域)都達到第一曲率為止。接著,才會進入第二階段(2nd Step)362,此時如圖五B所示般上、下模具42、43已維持在預定溫度且具有相對較小的第一曲率;此時,多個加熱器421、431仍持續對塑膠基板的各個部位進行局部加熱(步驟3621)、且多個感溫器422、432仍持續對塑膠基板的各個部位進行局部溫度感測,倘若有某感溫器422、432感測到任一部位(區域)的溫度未達到預定溫度時,則迴授控制相對應的加熱器421、431進行加熱(步驟3622),直到塑膠基板的每個部位(區域)都達到且維持在預定溫度為止;同時,曲面熱壓裝置也繼續以曲率感測器來即時監測上、下模具42、43的各個局部位置的曲率(步驟3623),倘若監測到任一部位(區域)的曲率未達到第二曲率時,則迴授控制上、下模具42、43進行該部位的局部彎曲(步驟3624),直到塑膠基板的每個部位(區域)都達到第二曲率為止;其中,第二曲率大於第一曲率。之後,才會進入第三階段(3rd Step)363,此時如圖五C所示般上、下模具42、43已維持在預定溫度且具有相對略大的第二曲率;此時,多個加熱器421、431仍持續對塑膠基板的各個部位進行局部加熱(步驟3631)、且多個感溫器422、432仍持續對塑膠基板的各個部位進行局部溫度感測,倘若有某感溫器422、432感測到任一部位(區域)的溫度未達到預定溫度時,則迴授控制相對應的加熱器421、431進行加熱(步驟3632),直到塑膠基板的每個部位(區域)都達到且維持在預定溫度為止;同時,曲面熱壓裝置也繼續以曲率感測器來即時監測上、下模具42、43的各個局部位置的曲率(步驟3633),倘若監測到任一部位(區域)的曲率未達到預定曲率時,則迴授控制上、下模具42、43進行該部位的局部彎曲(步驟3634),直到塑膠基板的每個部位(區域)都達到預定曲率為止;其中,預定曲率大於或等於第 二曲率。最後,便能獲得具預定曲率的曲面塑膠面板成品(第四階段364)。 Please refer to Figure 6, which is a flowchart illustrating the real-time monitoring of local temperature and curvature forming status of the curved surface hot pressing device described in this invention. As shown in Figure 6, and in conjunction with Figures 5A to 5D, in the hot pressing curved surface forming process, firstly, in the first stage (1st ... In Step 361, as shown in Figure 5A, the upper and lower molds 42 and 43 are still in a low-temperature and flat (curvature 0) state. At this time, multiple heaters 421 and 431 are used to locally heat different parts of the plastic substrate (Step 3611), and multiple temperature sensors 422 and 432 are used to locally detect the temperature of different parts of the plastic substrate. If any temperature sensor 422 or 432 detects that the temperature of any part (area) has not reached the preset temperature, it will send feedback to control the corresponding heating. Heaters 421 and 431 are used for heating (step 3612) until every part (area) of the plastic substrate reaches the predetermined temperature; simultaneously, the curved hot pressing device also uses a curvature sensor to monitor the curvature of various local positions of the upper and lower molds 42 and 43 in real time (step 3613). If the curvature of any part (area) is detected to be below the first curvature, feedback control is sent to the upper and lower molds 42 and 43 to perform local bending of that part (step 3614) until every part (area) of the plastic substrate reaches the first curvature. Then, the second stage (2nd ) begins. Step 362: At this point, as shown in Figure 5B, the upper and lower molds 42 and 43 are maintained at the predetermined temperature and have a relatively small initial curvature. Meanwhile, multiple heaters 421 and 431 continue to locally heat various parts of the plastic substrate (Step 3621), and multiple temperature sensors 422 and 432 continue to locally sense the temperature of various parts of the plastic substrate. If any temperature sensor 422 or 432 detects that the temperature of any part (area) has not reached the predetermined temperature, it sends feedback control to the corresponding heater 421 or 431 to perform heating. (Step 3622) This continues until every part (region) of the plastic substrate reaches and maintains a predetermined temperature. Simultaneously, the curved hot pressing device continues to monitor the curvature of various local positions of the upper and lower molds 42 and 43 in real time using a curvature sensor (Step 3623). If the curvature of any part (region) is detected as not reaching the second curvature, feedback control is sent to the upper and lower molds 42 and 43 to perform local bending of that part (Step 3624) until every part (region) of the plastic substrate reaches the second curvature; wherein the second curvature is greater than the first curvature. Only then will the third stage (3rd step) begin. Step 363: At this point, as shown in Figure 5C, the upper and lower molds 42 and 43 are maintained at the predetermined temperature and have a relatively large second curvature. Meanwhile, multiple heaters 421 and 431 continue to locally heat various parts of the plastic substrate (Step 3631), and multiple temperature sensors 422 and 432 continue to locally sense the temperature of various parts of the plastic substrate. If any temperature sensor 422 or 432 detects that the temperature of any part (area) has not reached the predetermined temperature, it sends feedback control to the corresponding heater 421 or 431 to heat it (Step 3631). Step 3632) continues until every part (region) of the plastic substrate reaches and maintains a predetermined temperature; simultaneously, the curved hot pressing device continues to monitor the curvature of each local position of the upper and lower molds 42 and 43 in real time using a curvature sensor (step 3633). If the curvature of any part (region) is detected to be below the predetermined curvature, the upper and lower molds 42 and 43 are fed back to perform local bending of that part (step 3634) until every part (region) of the plastic substrate reaches the predetermined curvature; wherein the predetermined curvature is greater than or equal to a second curvature. Finally, a finished curved plastic panel with a predetermined curvature is obtained (fourth stage 364).
請參閱圖七A及圖七B,分別為本發明之曲面塑膠面板的加工裝置的一實施例於門板開啟及門板關閉狀態下的示意圖。於本實施例中本發明之曲面塑膠面板的加工裝置包括該曲面熱壓裝置。該曲面熱壓裝置50除了包括前述的可變曲率的上模具42、可變曲率的下模具43、複數個上加熱器421、複數個上感溫器422、複數個下加熱器431、以及複數個下感溫器432之外,更包括以下元件:一機台本體51、一可啟閉的門板52、複數個油壓裝置53、54、複數個攝像器55、以及一控制單元60。其中,該控制單元60更包括:一加熱模組61、一偵測模組(包含一溫度感測模組62以及一影像擷取模組64)、一驅動裝置63、一資料庫65、一分析模組66、一控制模組67、一電源模組68以及一人機介面69。 Please refer to Figures 7A and 7B, which are schematic diagrams of an embodiment of the curved plastic panel processing apparatus of the present invention in the open and closed states of the door panel, respectively. In this embodiment, the curved plastic panel processing apparatus of the present invention includes the curved hot pressing device. In addition to the aforementioned variable curvature upper mold 42, variable curvature lower mold 43, a plurality of upper heaters 421, a plurality of upper temperature sensors 422, a plurality of lower heaters 431, and a plurality of lower temperature sensors 432, the curved hot pressing device 50 further includes the following components: a machine body 51, an openable and closable door panel 52, a plurality of hydraulic devices 53 and 54, a plurality of cameras 55, and a control unit 60. The control unit 60 further includes: a heating module 61, a detection module (including a temperature sensing module 62 and an image capture module 64), a driving device 63, a database 65, an analysis module 66, a control module 67, a power module 68, and a human-machine interface 69.
於本實施例中,門板52是裝設於機台本體51上。當門板52開啟時(如圖七A所示),可以將欲進行熱壓加工的平面的塑膠基板41放入機台本體51內的上、下模具42、43之間、或是把加工完成的曲面塑膠基板41從上、下模具42、43之間取出機台本體51外;而當門板52關閉時(如圖七B所示)則可以進行對於塑膠基板41的熱壓彎曲加工處理。上、下模具42、43分別藉由模具鎖附機構531、541結合於複數個油壓裝置53、54上,藉由驅動裝置63驅動油壓裝置53、54作動來對上、下模具42、43提供推拉力量,用於帶動該上模具及該下模具施加壓力或是局部彎曲(改變曲率)運動,進而對夾置於上、下模具42、43之間的塑膠基板41執行熱壓彎曲的加工處理。 In this embodiment, the door panel 52 is mounted on the machine body 51. When the door panel 52 is open (as shown in Figure 7A), the flat plastic substrate 41 to be hot-pressed can be placed between the upper and lower molds 42 and 43 inside the machine body 51, or the processed curved plastic substrate 41 can be removed from the machine body 51 from between the upper and lower molds 42 and 43; and when the door panel 52 is closed (as shown in Figure 7B), hot-pressing bending processing can be performed on the plastic substrate 41. The upper and lower molds 42 and 43 are respectively connected to a plurality of hydraulic devices 53 and 54 via mold locking mechanisms 531 and 541. A driving device 63 drives the hydraulic devices 53 and 54 to provide pushing and pulling forces to the upper and lower molds 42 and 43, thereby applying pressure or partially bending (changing curvature) to the upper and lower molds, and thus performing hot-press bending processing on the plastic substrate 41 sandwiched between the upper and lower molds 42 and 43.
複數個攝像器55構成了一曲率感測器,其可在進行熱壓彎曲加工處理的過程中即時地擷取(拍攝)該上、下模具42、43的曲率(外觀)影像,藉由分析上、下模具42、43的曲率(外觀)影像可以獲得被夾置於上、下模具42、43之間的塑膠基板41在當時的彎折狀態也就是曲率狀態,進而即時判斷出該曲面塑膠基板41的曲率是否已達到預定曲率。加熱模組61是電性連接於複數個該上加熱器421及複數個該下加熱器431,用於控制複數個該上加熱器421及複數個該下加熱器431的加熱操作。偵測模組更包含一溫度感測模組62以及一影像擷取模組64。該溫度感測模組62是電性連接於複數個該上感溫器422及複數個該下感溫器432,用於獲得複數個該上 感溫器422及複數個該下感溫器432所感測到的溫度資訊。該影像擷取模組64是電性連接於複數個該攝像器55,用於擷取複數個該攝像器55所拍攝該上模具42與該下模具43的曲率(外觀)影像。該資料庫65中儲存了控制曲面熱壓裝置50作動所需的電腦軟體及相關參數,其中也包括了該預定溫度與該預定曲率的資料。 A plurality of cameras 55 constitute a curvature sensor, which can capture (photograph) the curvature (appearance) images of the upper and lower molds 42 and 43 in real time during the hot pressing bending process. By analyzing the curvature (appearance) images of the upper and lower molds 42 and 43, the bending state, i.e., the curvature state, of the plastic substrate 41 sandwiched between the upper and lower molds 42 and 43 at that time can be obtained, and then it can be determined in real time whether the curvature of the curved plastic substrate 41 has reached the predetermined curvature. The heating module 61 is electrically connected to a plurality of the upper heaters 421 and a plurality of the lower heaters 431, and is used to control the heating operation of the plurality of upper heaters 421 and the plurality of lower heaters 431. The detection module further includes a temperature sensing module 62 and an image capture module 64. The temperature sensing module 62 is electrically connected to a plurality of upper temperature sensors 422 and a plurality of lower temperature sensors 432, used to obtain temperature information sensed by the plurality of upper temperature sensors 422 and the plurality of lower temperature sensors 432. The image capture module 64 is electrically connected to a plurality of cameras 55, used to capture curvature (appearance) images of the upper mold 42 and the lower mold 43 captured by the plurality of cameras 55. The database 65 stores the computer software and related parameters required to control the operation of the curved surface hot pressing device 50, including data on the predetermined temperature and the predetermined curvature.
該分析模組66可接收來自該偵測模組的該溫度資訊以及該曲率影像,並可自該資料庫65擷取該預定溫度與該預定曲率的資料。該分析模組66可將該溫度資訊和該預定溫度進行比對,當該溫度資訊的溫度低於該預定溫度時,該分析模組66產生一加熱訊號給該加熱模組61,促使該加熱模組61控制複數個該上加熱器421及複數個該下加熱器431對塑膠基板41進行加熱操作。這裡所述的加熱操作可以是全面性或是局部性的加熱,換言之,加熱模組61依據來自分析模組66的加熱訊號,除了可以控制所有的加熱器來對塑膠基板41進行全面性的加熱之外,另一方面,加熱模組61當然也能依據來自分析模組66的加熱訊號而僅控制其中數個加熱器對塑膠基板41進行局部性的加熱,而此功能是習知技術所無法達成的。除此之外,該分析模組66還可將該曲率影像和該預定曲率進行比對,當該曲率影像的曲率小於該預定曲率時,該分析模組66產生一提高曲率訊號給該驅動裝置63,促使該驅動裝置63驅動油壓裝置53、54來帶動該上模具42及該下模具43進行全面性或局部性提高彎折曲率的熱壓操作。該人機介面69可提供一使用者操作並至少可供該使用者將該預定溫度與該預定曲率等資訊輸入或設定於該資料庫65內。於本實施例中,該人機介面69包括一傳輸埠可供與外界的一電腦裝置連接,使用者可透過操作電腦裝置來把該預定溫度、該預定曲率及其他加工參數透過人機介面69傳輸並儲存於資料庫65內。於另一實施例中,該人機介面69也可包括一觸控螢幕及/或鍵盤,使用者可藉由操作觸控螢幕及/或鍵盤來將該預定溫度、該預定曲率及其他加工參數設定於資料庫65內。該控制模組67包括有微控制器(MCU)或是中央處理器(CPU),其電性連接於並可控制該驅動裝置63、該加熱模組61、該偵測模組、該資料庫65、該分析模組66以及該人機介面69的運作。電源模組68連結於控制模組67,用於提供控制單元60電源。 The analysis module 66 can receive the temperature information and curvature image from the detection module, and can retrieve the data of the predetermined temperature and the predetermined curvature from the database 65. The analysis module 66 can compare the temperature information with the predetermined temperature. When the temperature of the temperature information is lower than the predetermined temperature, the analysis module 66 generates a heating signal to the heating module 61, causing the heating module 61 to control a plurality of the upper heaters 421 and a plurality of the lower heaters 431 to heat the plastic substrate 41. The heating operation described here can be either comprehensive or localized. In other words, based on the heating signal from the analysis module 66, the heating module 61 can control all the heaters to comprehensively heat the plastic substrate 41. On the other hand, the heating module 61 can also control only a few heaters to locally heat the plastic substrate 41 based on the heating signal from the analysis module 66. This function is not achievable with prior art. In addition, the analysis module 66 can compare the curvature image with the predetermined curvature. When the curvature of the curvature image is less than the predetermined curvature, the analysis module 66 generates a curvature increase signal to the drive device 63, causing the drive device 63 to drive the hydraulic devices 53 and 54 to drive the upper mold 42 and the lower mold 43 to perform a hot pressing operation that increases the bending curvature comprehensively or locally. The human-machine interface 69 provides a user interface and allows the user to input or set information such as the predetermined temperature and the predetermined curvature into the database 65. In this embodiment, the human-machine interface 69 includes a port for connection to an external computer device. The user can use the computer device to transmit and store the predetermined temperature, predetermined curvature, and other processing parameters in the database 65 through the human-machine interface 69. In another embodiment, the human-machine interface 69 may also include a touch screen and/or keyboard. The user can use the touch screen and/or keyboard to set the predetermined temperature, predetermined curvature, and other processing parameters in the database 65. The control module 67 includes a microcontroller (MCU) or a central processing unit (CPU), which is electrically connected to and controls the operation of the drive device 63, the heating module 61, the detection module, the database 65, the analysis module 66, and the human-machine interface 69. A power module 68 is connected to the control module 67 to provide power to the control unit 60.
請參閱圖八A及圖八B,分別為本發明之曲面熱壓裝置的可 變曲率的上、下模具於平面狀態與彎曲狀態時的示意圖。於本發明中,曲面熱壓裝置50的上、下模具42、43都是可變曲率的;並且,上、下模具42、43需依照預定要製作之曲面塑膠面板的彎折圖面來進行上、下模具42、43內部的具體構造設計,並藉由線性滑軌帶動力矩方式進行相對運動來達到把上、下模具42、43彎折的目的。於一實施例中,該上模具42至少包括有位於左側的一第一上模板、位於中間的一第二上模板及位於右側的一第三上模板。該第一上模板與該第二上模板之間是以一第一上關節420a連結,使得該第一上模板可藉由該第一上關節420a進行相對於該第二上模板的曲率調整運動。該第二上模板與該第三上模板之間是以一第二上關節420b連結,使得該第三上模板可藉由該第二上關節420b進行相對於該第二上模板的曲率調整運動。同樣地,該下模具43至少包括有位於左側的一第一下模板、位於中間的一第二下模板及位於右側的一第三下模板。該第一下模板與該第二下模板之間是以一第一下關節430a連結,使得該第一下模板可藉由該第一下關節430a進行相對於該第二下模板的曲率調整運動。該第二下模板與該第三下模板之間是以一第二下關節430b連結,使得該第三下模板可藉由該第二下關節430b進行相對於該第二下模板的曲率調整運動。其中,該第一上模板的外型和位置是對應於該第一下模板,該第二上模板的外型和位置是對應於該第二下模板,該第三上模板的外型和位置是對應於該第三下模板。於該第一上模板、該第二上模板及該第三上模板中都分別設有該上加熱器421及該上感溫器422;於該第一下模板、該第二下模板及該第三下模板中都分別設有該下加熱器431及該下感溫器432。該第一上關節420a、該第二上關節420b、該第一下關節430a及該第二下關節430b都分別各包括一線性滑軌4201、4301,藉由該線性滑軌4201、4301帶動力矩的方式來調整相鄰兩模板之間的彎折曲率。 Please refer to Figures 8A and 8B, which are schematic diagrams of the variable curvature upper and lower molds of the curved hot pressing device of the present invention in a planar state and a bent state, respectively. In the present invention, the upper and lower molds 42 and 43 of the curved hot pressing device 50 are both variable curvature; and the upper and lower molds 42 and 43 need to be specifically designed internally according to the bending drawing of the curved plastic panel to be produced, and the relative motion of the upper and lower molds 42 and 43 is achieved by using linear slide rails to drive torque to achieve the purpose of bending the upper and lower molds 42 and 43. In one embodiment, the upper mold 42 includes at least a first upper template located on the left, a second upper template located in the middle, and a third upper template located on the right. The first upper template and the second upper template are connected by a first upper joint 420a, allowing the first upper template to adjust its curvature relative to the second upper template via the first upper joint 420a. The second upper template and the third upper template are connected by a second upper joint 420b, allowing the third upper template to adjust its curvature relative to the second upper template via the second upper joint 420b. Similarly, the lower mold 43 includes at least a first lower template located on the left, a second lower template located in the middle, and a third lower template located on the right. The first lower template and the second lower template are connected by a first lower joint 430a, allowing the first lower template to adjust its curvature relative to the second lower template via the first lower joint 430a. The second lower template and the third lower template are connected by a second lower joint 430b, allowing the third lower template to adjust its curvature relative to the second lower template via the second lower joint 430b. The shape and position of the first upper template correspond to the first lower template, the shape and position of the second upper template correspond to the second lower template, and the shape and position of the third upper template correspond to the third lower template. An upper heater 421 and an upper temperature sensor 422 are respectively provided in the first upper template, the second upper template, and the third upper template; a lower heater 431 and a lower temperature sensor 432 are respectively provided in the first lower template, the second lower template, and the third lower template. Each of the first upper joint 420a, the second upper joint 420b, the first lower joint 430a, and the second lower joint 430b includes a linear slide rail 4201, 4301, respectively. The bending curvature between two adjacent templates is adjusted by using the torque generated by the linear slide rails 4201, 4301.
本技術以PMMA/PC/PMMA或PMMA/PC複合材料為基材,結合可延伸型塗料配方濕式塗佈製程所製作的可延伸型複合材料前面板,可於所有表面處理完成後再進行熱壓曲面成型,所有表面處理在此製程階段不會產生任何外觀及功能性異常。此製程之突破性的關鍵在於可延伸型塗料配方之搭配,可延展塗料配方包含:可延展高硬度塗層、可延展高折射率塗層、可延展低折射率塗層。可延伸型塗料配方可改變原玻璃必 須先進行曲面熱壓再進行光學表面處理之工序,大幅降低曲面塗佈製程之不良率。經曲面熱壓後之可延伸型複合材料前面板表面硬度可提升至4H以上(4H~9H),耐化學性磨耗測試可通過車規水準,UV耐黃化測試(1000小時)可維持△E<3之規格。 This technology uses PMMA/PC/PMMA or PMMA/PC composite materials as the base material, combined with a stretchable coating formulation and wet coating process to produce stretchable composite material front panels. Hot pressing and curving can be performed after all surface treatments are completed, and no appearance or functional abnormalities occur during this process stage. The key to this breakthrough lies in the combination of stretchable coating formulations, which include: stretchable high-hardness coatings, stretchable high-refractive-index coatings, and stretchable low-refractive-index coatings. The stretchable coating formulations can change the original process where glass must first undergo curved hot pressing before optical surface treatment, significantly reducing the defect rate of curved surface coating processes. The surface hardness of the stretchable composite front panel, after hot pressing, can be increased to above 4H (4H~9H). Chemical abrasion resistance testing meets automotive-grade standards, and UV yellowing resistance testing (1000 hours) maintains a ΔE < 3.
本發明針對多種不同結構之塑膠基板搭配不同材料組成的硬質層與光學功能層來進行測試,如下表一所示為進行測試之各樣本的結構資訊。舉例來說,表一中的樣本6(Sample 6)的基板,於欄位A中是選用A3/A4結構也就是「PMMA/PC雙層板結構」或是「PMMA/PC/PMMA三層板結構」兩者其中之一均可;於欄位B中其硬質層中有無添加「Inorganic hybrid composition(有機無機混成寡聚物/單體)」是選B2也就是「有添加Inorganic hybrid composition(有機無機混成寡聚物/單體)」;於欄位C中其硬質層中有無添加「High Tg composition(高玻璃轉移溫度寡聚物/單體)」是選C2也就是「有添加High Tg composition(高玻璃轉移溫度寡聚物/單體)」;於欄位D中其硬質層中有無添加「High Elongation Composition(高延伸特性寡聚物/單體)」是選D2也就是「有添加High Elongation Composition(高延伸特性寡聚物/單體)」;於欄位E中其光學功能層有無添加「Optical Function Composition(光學功能成分)」是選E2也就是「有添加Optical Function Composition(光學功能成分)」;於欄位F中有無使用本發明所獨創的「新型模具及熱壓成型製程」是選F2也就是「有使用新型模具及熱壓成型製程」。其他的樣本(Samples 0~5,8 and 9)結構可同理得知,故不贅述。 This invention tests various plastic substrates with different structures and rigid and optical functional layers composed of different materials. Table 1 below shows the structural information of each sample tested. For example, for the substrate of Sample 6 in Table 1, either the A3/A4 structure (PMMA/PC double-layer structure) or the PMMA/PC/PMMA triple-layer structure can be selected in column A; in column B, whether or not "Inorganic hybrid composition" is added to its rigid layer is selected as B2, which means "Inorganic hybrid composition" is added; in column C, whether or not "High Tg composition" is added to its rigid layer is selected as C2, which means "High Tg composition" is added; and in column D, whether or not "High Elongation" is added to its rigid layer is selected as... For "Composition (high elongation oligomer/monomer)," select D2, which means "High Elongation Composition added." For field E, whether "Optical Function Composition" is added to the optical functional layer, select E2, which means "Optical Function Composition added." For field F, whether the invention's unique "novel mold and hot-pressing process" is used, select F2, which means "Novel mold and hot-pressing process used." The structures of the other samples (Samples 0-5, 8, and 9) can be deduced similarly and will not be elaborated upon.
由表一可知,樣本6(Sample 6)的曲面塑膠面板其硬度、耐熱、成型都OK,且具光學功能,為相對最佳的曲面塑膠面板樣本。相對地,其他樣本0~5、8、9則或多或少都有些缺失。 As shown in Table 1, Sample 6, with its curved plastic panel, exhibits good hardness, heat resistance, and moldability, and also possesses optical properties, making it the relatively best curved plastic panel sample. In contrast, other samples 0-5, 8, and 9 all have some degree of deficiency.
於本實施例中,各欄位A~E中所述的材料組成都能自目前市售的商品中選用。舉例來說,欄位B中所述的「Inorganic hybrid composition」可以選用Allenx EBECRYL 8311商品或其他型號或廠牌的同性質商品;欄位C中所述的「High Tg composition」可以選用Allenx EBECRYL 4859商品或其他型號或廠牌的同性質商品;欄位D中所述的「High Elongation Composition」可以選用Allenx EBECRYL 8804商品或其他型號或廠牌的同性質商品;欄位E中所述的「Optical Function Composition」可以選用Nippon Shokubai ZIRCOSTAR系列商品或其他型號或廠牌的同性質商品。 In this embodiment, the material compositions described in each of the columns A through E can be selected from currently commercially available products. For example, the "Inorganic hybrid composition" described in column B can be Allenx EBECRYL 8311 or other similar products of the same type or brand; the "High Tg composition" described in column C can be Allenx EBECRYL 4859 or other similar products of the same type or brand; the "High Elongation Composition" described in column D can be Allenx EBECRYL 8804 or other similar products of the same type or brand; and the "Optical Function Composition" described in column E can be Nippon Shokubai ZIRCOSTAR series or other similar products of the same type or brand.
由上表二所示之曲面塑膠面板各樣本的測試結果可知,樣本6因為是採用PC/PMMA或PMMA/PC/PMMA之複合板材作為塑膠基板,且都設置了包含有機無機混成、高Tg與高延伸特性的寡聚物/單體的硬質層以及光學功能層,並有使用本發明所獨創的「新型模具及熱壓成型製程」來進行曲面熱壓,也就是類似圖四、圖五A~五C以及圖六所示的實施例,所以在各項測試中都得到極佳或良好的表現。相對地,其他的樣本(Samples 0~5,7 and 8)則或多或少在部分測試項目中都有不佳表現。由此可證,藉 由本發明的加工方法所製成的具曲面的塑膠面板相較於習知技術確實能獲得更佳的測試結果。 As shown in Table 2 above, the test results of the curved plastic panel samples show that Sample 6, because it uses PC/PMMA or PMMA/PC/PMMA composite material as the plastic substrate, and has a rigid layer and an optical functional layer containing organic-inorganic hybrid oligomers/monomers with high Tg and high elongation characteristics, and uses the "novel mold and hot pressing process" unique to this invention for curved hot pressing, similar to the embodiments shown in Figures 4, 5A-5C and 6, achieved excellent or good performance in all tests. In contrast, the other samples (Samples 0-5, 7 and 8) showed poor performance in some test items to varying degrees. This demonstrates that the curved plastic panel manufactured using the processing method of this invention does indeed achieve better test results compared to prior art.
唯以上所述之實施例不應用於限制本發明之可應用範圍,本發明之保護範圍應以本發明之申請專利範圍內容所界定技術精神及其均等變化所含括之範圍為主者。即大凡依本發明申請專利範圍所做之均等變化及修飾,仍將不失本發明之要義所在,亦不脫離本發明之精神和範圍,故都應視為本發明的進一步實施狀況。 However, the embodiments described above should not be used to limit the scope of application of this invention. The scope of protection of this invention shall be primarily defined by the technical spirit and equivalent variations thereof as defined in the patent application. That is, all equivalent variations and modifications made within the scope of the patent application will not deviate from the essence of this invention, nor will they depart from its spirit and scope; therefore, they should all be considered further embodiments of this invention.
31~37:步驟基板 Steps 31-37: Substrate
Claims (11)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW110142418A TWI800097B (en) | 2021-11-15 | 2021-11-15 | A curved plastic panel and method and device for fabricating the same |
| CN202510736927.XA CN120461792A (en) | 2021-11-15 | 2021-11-18 | Curved plastic panel and processing method and processing device thereof |
| CN202111371349.2A CN116118163B (en) | 2021-11-15 | 2021-11-18 | Curved plastic panel and processing method and processing device thereof |
| JP2022003717A JP7197734B1 (en) | 2021-11-15 | 2022-01-13 | Curved plastic panel and its processing method and processing device |
| US17/874,090 US12296513B2 (en) | 2021-11-15 | 2022-07-26 | Curved plastic panel and method and device for processing the same |
| US18/920,942 US20250042068A1 (en) | 2021-11-15 | 2024-10-20 | Curved Plastic Panel And Method And Device For Processing The Same |
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| TW110142418A TWI800097B (en) | 2021-11-15 | 2021-11-15 | A curved plastic panel and method and device for fabricating the same |
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| TWI800097B true TWI800097B (en) | 2023-04-21 |
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| TWI910825B (en) * | 2024-09-13 | 2026-01-01 | 穎華科技股份有限公司 | Method for manufacturing plastic panels with anti-glare and anti-reflective functions |
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| TW202005781A (en) * | 2018-07-13 | 2020-02-01 | 穎華科技股份有限公司 | Light-transmissive plastic plate structure with curved surface and metod for fabricating the same |
Also Published As
| Publication number | Publication date |
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| CN116118163A (en) | 2023-05-16 |
| CN116118163B (en) | 2025-07-25 |
| JP7197734B1 (en) | 2022-12-27 |
| CN120461792A (en) | 2025-08-12 |
| US12296513B2 (en) | 2025-05-13 |
| US20250042068A1 (en) | 2025-02-06 |
| JP2023073180A (en) | 2023-05-25 |
| US20230150177A1 (en) | 2023-05-18 |
| TW202321011A (en) | 2023-06-01 |
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