SU138029A1 - The method of producing polycarbonates - Google Patents
The method of producing polycarbonatesInfo
- Publication number
- SU138029A1 SU138029A1 SU668664A SU668664A SU138029A1 SU 138029 A1 SU138029 A1 SU 138029A1 SU 668664 A SU668664 A SU 668664A SU 668664 A SU668664 A SU 668664A SU 138029 A1 SU138029 A1 SU 138029A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- producing polycarbonates
- polymer
- molecular weight
- solution
- diphenylolpropane
- Prior art date
Links
- 238000000034 method Methods 0.000 title description 6
- 229920000515 polycarbonate Polymers 0.000 title description 4
- 239000004417 polycarbonate Substances 0.000 title description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
- 239000000243 solution Substances 0.000 description 6
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 5
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 108700025906 fos Genes Proteins 0.000 description 1
- 101150078861 fos gene Proteins 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
Landscapes
- Polyesters Or Polycarbonates (AREA)
Description
Способ получени поликарбонатов из дифенилолпропана и раствора фосгена в метиленхлориде На границе раздела двух фаз в присутствии четвертичных аммонийных солей известен. С целью осуществлени непрерывности и возможности регулировани молекул рного веса полимера, процесс предложено вести в двухшнековой машине.The method of obtaining polycarbonates from diphenylolpropane and a solution of phosgene in methylene chloride. At the interface of two phases in the presence of quaternary ammonium salts, is known. In order to achieve continuity and the ability to regulate the molecular weight of the polymer, the process is proposed to be carried out in a twin-screw machine.
Предлагаемый способ получени поликарбонатов в отличие от известных вл етс непрерывным.The proposed method for producing polycarbonates, unlike the known ones, is continuous.
Особенность метода состоит в том, что реакци поликонденсации протекает в две стадии в двух апп аратах.The peculiarity of the method is that the polycondensation reaction proceeds in two stages in two apparatah.
Перва стади - смешивание реагирующих растворов и получение Низкомолекул рного продукта, в обычном сосуде с мешалкой.The first step is to mix the reacting solutions and obtain the Low Molecular Product, in an ordinary stirred vessel.
В сосуд непрерывно поступает раствор фосгена в метиленхлориде и водный раствор едкого натра и дифенилолпропана.The vessel is continuously fed a solution of phosgene in methylene chloride and an aqueous solution of caustic soda and diphenylolpropane.
Втора стади - поликонденсаци и получение продукта нужного молекул рного веса. Она протекает в тонком слое на разделе двух фаз в двухшнековой машине, забирающей жидкость из первого сосуда. В качестве катализатора при этом используетс четвертична аммониева соль.The second stage is polycondensation and obtaining the product of the desired molecular weight. It flows in a thin layer on the section of the two phases in a twin-screw machine that takes liquid from the first vessel. A quaternary ammonium salt is used as a catalyst.
На чертеже схематически изображена установка непрерывной поликонденсадии фосгена с ДФЛ (дифенилолпропаном).The drawing shows schematically the installation of continuous polycondensadia of phosgene with DFL (diphenylolpropane).
Из сосудов / и 2 растворы фоСгена и дифенилолщелочной раствор дифенилолпролана с определенной скоростью поступает в аппарат 3, Где мгновенно образуетс низкомолекул рный полимер. Затем из а:;царата низкомолекул рный продукт непрерывно засасываетс двухщнековой машиной 4.From the vessels and / and 2 solutions of foSgene and the diphenylol-alkaline solution of diphenylol-prolane, with a certain speed enters the apparatus 3, where a low-molecular polymer is instantly formed. Then, from a: Carata, the low molecular weight product is continuously sucked in by a twin-screw machine 4.
Одновременно дозирующий насос по трубке 5 подает раствор катализатора в полость машины через штуцер 6. Образовавшийс высокомолекул рный полимер отводитс в непрерывнодействующие аппараты дл дальнейшей обработки полимера.At the same time, the metering pump through tube 5 feeds the catalyst solution into the cavity of the machine through fitting 6. The resulting high molecular weight polymer is discharged into continuous machines for further processing of the polymer.
Предмет изобретени Subject invention
Способ получени поликарбонатов из дифенилолпропана и- раствора фосгена в метиленхлориде на границе раздела двух фаз в присутствии четвертичных аммонийных солей, отличающийс тем, что, с целью осуществлени непрерывности и возможности регулировани молекул рного веса полимера,, процесс ведут в двухшнековой машине..A method of producing polycarbonates from diphenylolpropane and a solution of phosgene in methylene chloride at the interface of two phases in the presence of quaternary ammonium salts, characterized in that, in order to achieve continuity and control of the molecular weight of the polymer, the process is carried out in a twin-screw machine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU668664A SU138029A1 (en) | 1960-06-01 | 1960-06-01 | The method of producing polycarbonates |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU668664A SU138029A1 (en) | 1960-06-01 | 1960-06-01 | The method of producing polycarbonates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU138029A1 true SU138029A1 (en) | 1960-11-30 |
Family
ID=48294203
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU668664A SU138029A1 (en) | 1960-06-01 | 1960-06-01 | The method of producing polycarbonates |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU138029A1 (en) |
-
1960
- 1960-06-01 SU SU668664A patent/SU138029A1/en active
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