KR20140008850A - Inorganic binder composition for sculpture and a method for manufacturing sculpture using thereof - Google Patents
Inorganic binder composition for sculpture and a method for manufacturing sculpture using thereof Download PDFInfo
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- KR20140008850A KR20140008850A KR1020120076188A KR20120076188A KR20140008850A KR 20140008850 A KR20140008850 A KR 20140008850A KR 1020120076188 A KR1020120076188 A KR 1020120076188A KR 20120076188 A KR20120076188 A KR 20120076188A KR 20140008850 A KR20140008850 A KR 20140008850A
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- 239000000203 mixture Substances 0.000 title claims abstract description 39
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims abstract description 21
- 239000011230 binding agent Substances 0.000 title abstract description 18
- 239000004575 stone Substances 0.000 claims abstract description 56
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000000463 material Substances 0.000 claims abstract description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002969 artificial stone Substances 0.000 claims abstract description 9
- 238000000465 moulding Methods 0.000 claims abstract description 9
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims abstract description 8
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 claims abstract description 8
- 238000001035 drying Methods 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 7
- 239000002562 thickening agent Substances 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims abstract description 6
- 229910021487 silica fume Inorganic materials 0.000 claims abstract description 6
- 238000004381 surface treatment Methods 0.000 claims abstract description 6
- 238000005406 washing Methods 0.000 claims abstract description 6
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 5
- 239000000701 coagulant Substances 0.000 claims abstract description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 230000002940 repellent Effects 0.000 claims abstract description 5
- 239000005871 repellent Substances 0.000 claims abstract description 5
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 4
- 239000010975 amethyst Substances 0.000 claims abstract description 4
- 239000011324 bead Substances 0.000 claims abstract description 4
- 239000013078 crystal Substances 0.000 claims abstract description 4
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 4
- 239000011737 fluorine Substances 0.000 claims abstract description 4
- 239000010977 jade Substances 0.000 claims abstract description 4
- 229920005610 lignin Polymers 0.000 claims abstract description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000010451 perlite Substances 0.000 claims abstract description 4
- 235000019362 perlite Nutrition 0.000 claims abstract description 4
- 229920005646 polycarboxylate Polymers 0.000 claims abstract description 4
- 229910052594 sapphire Inorganic materials 0.000 claims abstract description 4
- 239000010980 sapphire Substances 0.000 claims abstract description 4
- 239000010455 vermiculite Substances 0.000 claims abstract description 4
- 229910052902 vermiculite Inorganic materials 0.000 claims abstract description 4
- 235000019354 vermiculite Nutrition 0.000 claims abstract description 4
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims abstract description 4
- 239000003415 peat Substances 0.000 claims abstract description 3
- 239000004568 cement Substances 0.000 claims description 8
- 239000003973 paint Substances 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 5
- 238000004040 coloring Methods 0.000 claims 1
- 239000004816 latex Substances 0.000 claims 1
- 229920000126 latex Polymers 0.000 claims 1
- 239000011049 pearl Substances 0.000 claims 1
- 239000002966 varnish Substances 0.000 claims 1
- 239000004927 clay Substances 0.000 abstract description 9
- 238000005345 coagulation Methods 0.000 abstract description 7
- 230000015271 coagulation Effects 0.000 abstract description 7
- 239000000919 ceramic Substances 0.000 abstract description 6
- 229910052900 illite Inorganic materials 0.000 abstract description 4
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 abstract description 4
- 239000004576 sand Substances 0.000 abstract description 2
- 239000004566 building material Substances 0.000 abstract 3
- -1 and if it is used Substances 0.000 abstract 2
- 241000196324 Embryophyta Species 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 238000010304 firing Methods 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000013538 functional additive Substances 0.000 description 3
- 239000010440 gypsum Substances 0.000 description 3
- 229910052602 gypsum Inorganic materials 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000004382 potting Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 244000280244 Luffa acutangula Species 0.000 description 1
- 235000009814 Luffa aegyptiaca Nutrition 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000011083 cement mortar Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/36—Inorganic materials not provided for in groups C04B14/022 and C04B14/04 - C04B14/34
- C04B14/365—Gypsum
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/0016—Granular materials, e.g. microballoons
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/22—Natural resins, e.g. rosin
- C04B26/24—Cellulosic waste liquor, e.g. sulfite lye
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Civil Engineering (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
본 발명은 화분, 조경용품, 실내인테리어 소품, 친환경건축재료, 공예용품 재료로 활용이 가능한 ‘조형물 제작이 가능한 무기질결합재 조성물 및 이를 이용한 조형물의 제조방법’에 관한 것으로 이를 활용할 경우 기존 공예재료인 클레이 및 도자기를 대용하여 화분, 인테리어소품, 건축재료, 공예재료등을 쉽고 빠르게 제작할 수 있다. 본 발명의 경우 자유자재로 형체 성형이 가능하고 혼합조성물에 물만 부어 믹싱하여 화분, 석부작용 인조석, 조경석, 조경용 조형물, 조경용 블록, 수족관용 장식돌, 수공예용품, 건축용 자재, 공예용품등을 제조할 수 있는 조성물을 제공하고자 하며, 또한 이러한 조성물을 이용하여 조형물을 제조하는 방법을 제공하고자 하는데 있다.
상기 목적을 달성하기 위한 본 발명의 조성물은 알파형반수석고, 무수석고, 메타카올린, 실리카 흄, 일라이트로부터 선택된 단독 또는 2종이상이 혼합된 알파형 반수석고:40~60중량%, 입도 선별된 화산석, 퍼라이트, 질석, 피트모스, 맥반석,규사, 석분, 옥돌,황토석, 비즈공예석, 천연 또는 인조진주, 사파이어석, 수정, 자수정, 경량골재로부터 선택된 단독 또는 2종이상이 혼합된 잔골재:30~50중량%, 폴리카르복실레이트계, 리그닌계, 나프탈렌계, 멜라민계로부터 선택된 단독 또는 2종이상이 혼합된 고성능감수제:0.01~1중량%, 메텔셀룰오스 계열증점제 :0.1∼2중량%, Zinc Stearate 또는 불소계 발수제:0.1∼1중량%, 응결연제:0.5∼2중량%, 응결촉진제:0.1∼2중량%를 포함하는 것을 특징으로 하며,
또한, 상기 목적을 달성하기 위한 본 발명의 조형물 제조방법은 상기 조성물을 비율에 맞게 혼합하는 단계; 상기 혼합된 혼합물에 물/결합재의 중량비가 0.20∼0.30가 되도록 물을 첨가하는 단계; 가수 후 충분히 믹싱하는 단계; 믹싱 후 미리 수작업으로 조형물을 성형하는 단계; 1∼2시간 양생 및 세척하는 단계; 세척후 건조 및 표면처리 처리하는 단계를 포함하는 것을 특징으로 한다.The present invention relates to an 'inorganic binder composition capable of producing a sculpture and a method of manufacturing a sculpture using the same', which can be used as a flower pot, a landscaping article, an interior interior accessory, an eco-friendly building material, a craft article material, and if it is used, clay of an existing craft material And can be used to quickly and easily produce flower pots, interior accessories, building materials, craft materials, etc. in place of ceramics. In the case of the present invention, it is possible to mold freely, and only by pouring water into the mixed composition to mix, to produce flower pots, stone artificial stone, landscaping stone, landscaping sculptures, landscaping blocks, aquarium decorative stones, handicrafts, building materials, craft supplies, etc. It is to provide a composition that can be, and also to provide a method for producing a sculpture using such a composition.
The composition of the present invention for achieving the above object is alpha-type hemihydrate gypsum, anhydrous gypsum, metakaolin, silica fume, illite selected from the alpha type hemihydrate gypsum alone or in combination of two or more: 40 to 60% by weight, particle size selection Volcanic stone, perlite, vermiculite, peat moss, ganban stone, silica sand, stone powder, jade stone, ocher stone, beads craft stone, natural or artificial pearl, sapphire stone, crystal, amethyst, light aggregate aggregated alone or in combination of two or more: 30 ~ 50% by weight, polycarboxylate-based, lignin-based, naphthalene-based, melamine-based high performance water reducing agent mixed with one or two or more: 0.01 to 1% by weight, metelcellulose-based thickener: 0.1 to 2% by weight, Zinc Stearate or fluorine-based water repellent: 0.1 to 1% by weight, coagulant: 0.5 to 2% by weight, coagulation accelerator: characterized in that it comprises 0.1 to 2% by weight,
In addition, the molding method of the present invention for achieving the above object comprises the steps of mixing the composition in proportion; Adding water to the mixed mixture such that a weight ratio of water / binder is 0.20 to 0.30; Mixing after mixing sufficiently; Manually molding the sculpture after mixing; Curing and washing for 1-2 hours; It characterized in that it comprises a step of drying and surface treatment after washing.
Description
본 발명은 친환경재료를 사용하여 지점토 및 도예토처럼 형체 성형이 가능한 무기질 결합재 조성물 및 그 제조방법에 관한 것으로서 이를 이용할 경우 기존 도예토의 소성 과정을 생략할 수 있고 지점토같이 강도가 약한 점을 보완하며 응결조절을 통해 1∼2시간 이내에 원하는 조형물과 성형체를 쉽고 경제적이며 빠른 방법으로 제조할 수 있는 조성물 및 그 제조방법에 관한 것이다. 또한 이러한 조성물을 활용하여 화분, 수반, 인조석, 조경석, 조경용 조형물, 조경용 블록, 수족관용 장식돌, 공예용품 같은 제품을 제조할 수 있는 조성물 및 그 조성물을 이용하여 조형물을 제조하는 방법에 관한 것이다.The present invention relates to an inorganic binder composition capable of forming a mold like clay and pottery using environmentally friendly materials, and a method for manufacturing the same. When using this, it is possible to omit the firing process of existing ceramics and to compensate for the weak strength such as clay. The present invention relates to a composition and a method for preparing the same, which can be manufactured easily and economically and quickly within 1 to 2 hours through adjustment. In addition, the present invention relates to a composition capable of producing a product such as a flower pot, head, artificial stone, landscape stone, landscape sculpture, landscape block, aquarium decorative stone, and crafts using the composition, and a method of manufacturing the sculpture using the composition.
본 발명의 배경기술은 친환경무기질 결합재와 잔골재 기능성 첨가재를 활용하여 빠르고 경제적인 방법으로 신개념의 공예용 재료를 개발하는 것이 목적이며 배경기술에는 무기질결합재 및 기능성 첨가제에 대한 이해와 지식이 필요하다.기존에 사용되는 무기질결합재를 활용한 조형물의 경우 시멘트, 백시멘트 또는 CSA, 알루미나시멘트를 주결합재로 하고 플라이애시, 실리카흄, 슬래그미분말 같은 포졸란 물질을 보조 결합재로 활용하여 잔골재 및 석분을 골재와 믹싱후 형틀에 부어 조형물을 제작하는 방법이 주를 이루고 있거나 제작하고자 하는 조형물의 골격을 제작후 외부에서 뿜칠 또는 도포에 의한 방법이 주를 이루고 있다. 그렇지만 이러한 방법에 의해 제작된 조형물의 경우 형틀을 제작하는데 시간과 비용이 많이 소요되고 시멘트 계열이 주성분임이므로 Ph가 높아 식물을 식재하는 화분의 경우 중화처리가 필요하고 재료를 직접 손으로 만질 경우 피부에 손상을 주는 단점이 있다. 또한 기존 클레이 점토의 경우 가격이 고가이고 내구성이 떨어지는 관계로 규모가 큰 조형물 제작이나 화분을 제작하는데 강도가 약하고 경제성이 떨어지는 단점이 있다. 한편 기존 도자기를 활용한 화분제품의 경우 모양 성형, 초벌, 유약바르기, 재벌등의 과정을 거치므로 시간이 많이 걸리고 또한 소성공정이 반드시 필요하므로 소성비용이 많이 소요되는 단점이 있다. 본 발명은 기존의 도자기화분, 클레이공예, 조경물조형물등의 재료를 대체할 수 있는 조성물을 제공하는데 목적이 있으며 상기 목적 달성을 위해 직접 피부에 닫더라도 피부손상이 없고 제작시간이 빠르며 손쉽고 경제적인 방법으로 상기 조형물 제작이 가능한 공예용 재료 및 제조방법에 관한 것이다.Background art of the present invention aims to develop a new concept of craft materials in a fast and economical manner using environmentally friendly inorganic binders and fine aggregate functional additives, the background art requires an understanding and knowledge of inorganic binders and functional additives. In the case of sculptures using inorganic binders used in cement, cement, back cement or CSA and alumina cement are used as main binders, and after mixing the fine aggregates and stone powders with aggregates using pozzolanic materials such as fly ash, silica fume and slag powder as auxiliary binders. The method of making a sculpture is mainly made or the method of spraying or applying the outside of the skeleton of the sculpture to be produced is the main method. However, in the case of sculptures manufactured by this method, it takes a lot of time and cost to manufacture the mold, and since the cement type is the main ingredient, potting plants that have a high Ph require neutralization treatment, and the skin is touched if the material is touched by hand. There is a disadvantage to damage. In addition, the existing clay clay has a weak strength and low economic feasibility to manufacture large sculptures or flower pots due to the high price and low durability. On the other hand, in the case of a potted product using the existing ceramics, it takes a lot of time because it undergoes a process of shape molding, priming, glazing, chaebol, etc., and also requires a firing process, which requires a lot of firing costs. The present invention has an object to provide a composition that can replace the existing ceramic pots, clay crafts, landscaping sculptures and other materials, even if closed directly to the skin to achieve the above object, no damage to the skin and the production time is fast and easy and economical method The present invention relates to a craft material and a manufacturing method capable of manufacturing the sculpture.
본 발명의 내용은 기존 도자기의 단점인 시간과 소성비용이 많이 드는 점을 보완하여 1∼2시간 내에 원하는 형상의 조형물을 제작할 수 있는 무기질결합재 조성물을 제공하고 이러한 조성물을 활용하여 화분, 수반, 인조석, 조경석, 조경용 조형물, 조경용 블록, 수족관용 장식돌과 같은 조형물을 제조하는 방법에 관한 것이다.이에 본 발명자는 상기 단점을 해결하기 위해 연구와 실험을 거듭한 결과로서 본 발명을 제안하게 된 것으로, 본 발명은 직접 손으로 접촉해도 피부에 손상이 없고 클레이, 지점토, 도예토처럼 형체성형이 자유로우며 제작된 조형물 또한 내구성이 강하고 비시멘트계열 친환경재료를 사용함으로서 화분제작후 식물 식재시 식물생장이 용이하고 재료에 물만 부어 반죽을 성형할 수 있는 방법으로 신속하고 경제적인 방법으로 원하는 조형물을 제작하는 방법을 제공하고자 한다. 또한 경화후 아크릴 물감 및 유성안료 도료를 이용하여 통해 표면처리를 함으로서 매우 자연스럽고 다양한 질감의 조형물 제작이 가능한 방법을 제공하고자 한다.이를 통해 화분, 석부작용 돌, 수반, 조경석, 조경용 조형물, 조경용 블록, 수족관용 장식돌, 공예용품 등을 제조할 수 있는 조성물을 제공하고자 하며, 또한 이러한 조성물을 이용하여 조형물을 제조하는 방법을 제공하고자 하는데, 그 목적이 있다.The contents of the present invention provide an inorganic binder composition which can produce a sculpture of a desired shape within 1 to 2 hours by supplementing the disadvantages of time and firing costs, which are disadvantages of existing ceramics, and using such a composition, potted plants, accompanying stones, artificial stones , And a method of manufacturing a sculpture, such as a landscape stone, a landscape sculpture, a landscape block, an ornamental stone for an aquarium. The present inventors have proposed the present invention as a result of repeated studies and experiments to solve the above disadvantages. The present invention has no damage to the skin even by direct contact, and freely molded body like clay, clay, pottery, etc. The manufactured product is also durable and easy to grow plants when planting plants after potting by using non-cement-based eco-friendly materials. Can be poured into the water and the dough can be molded quickly and economically It is to provide a method of making a sculpture. In addition, by curing the surface using acrylic paints and oil paints after curing, it is intended to provide a method that can produce sculptures of very natural and diverse textures.This enables pots, stone stones, heads, landscaping stones, landscaping sculptures, landscaping blocks. To provide a composition that can be prepared, such as an aquarium decorative stone, craft supplies, and also to provide a method for producing a sculpture using such a composition, the purpose is.
상기 목적을 달성하기 위한 본 발명의 조성물은 상기 목적을 달성하기 위한 본 발명의 조성물은 반수석고, 무수수석고, 메타카올린, 실리카 흄, 일라이트로부터 선택된 단독 또는 2종이상이 혼합된 반수석고:40~60중량%, 입도 선별된 화산석, 퍼라이트, 질석, 피트모스, 맥반석,규사, 석분, 옥돌,황토석, 비즈공예석, 천연 또는 인조진주, 사파이어석, 수정, 자수정, 경량골재로부터 선택된 단독 또는 2종이상이 혼합된 잔골재:30~50중량%, 폴리카르복실레이트계, 리그닌계, 나프탈렌계, 멜라민계로부터 선택된 단독 또는 2종이상이 혼합된 고성능감수제:0.01~1중량%, 메텔셀룰오스 계열증점제 :0.1∼2중량%, Zinc Stearate 또는 불소계 발수제:01∼1중량%, 응결연제:0.5∼2중량%, 응결촉진제:0.1∼2중량%를 포함하는 것을 특징으로 한다.The composition of the present invention for achieving the above object is a composition of the present invention for achieving the above object is hemihydrate gypsum, anhydrous gypsum, metakaolin, silica fume, illite selected from hemihydrate gypsum or two or more kinds: 40 ~ 60% by weight, particle size selected volcanic stone, perlite, vermiculite, pit moss, ganban stone, silica, stone powder, jade stone, ocher stone, beads craft stone, natural or artificial pearl, sapphire stone, crystal, amethyst, light aggregate Fine aggregate mixed with paper phase: 30-50% by weight, polycarboxylate-based, lignin-based, naphthalene-based, melamine-based single or two or more mixtures of high performance water reducing agent: 0.01-1% by weight, metelcellulose-based Thickener: 0.1 to 2% by weight, Zinc Stearate or fluorine-based water repellent: 01 to 1% by weight, coagulant: 0.5 to 2% by weight, coagulation accelerator: 0.1 to 2% by weight.
또한, 상기 목적을 달성하기 위한 본 발명의 조형물 제조방법은 상기 조성물을 비율에 맞게 혼합하는 단계; 상기 혼합된 혼합물에 물/결합재의 비가 0.20∼0.30가 되도록 물을 첨가하는 단계; 가수 후 충분히 믹싱하는 단계; 믹싱 후 조형물 제작단계 단계; 1∼2시간 양생 후 세척 및 건조하는 단계 ; 건조처리후 표면처리하는 단계를 포함하는 것을 특징으로 한다.In addition, the molding method of the present invention for achieving the above object comprises the steps of mixing the composition in proportion; Adding water to the mixed mixture such that the ratio of water / binder is 0.20 to 0.30; Mixing after mixing sufficiently; A step of manufacturing the sculpture after mixing; Washing and drying after curing for 1 to 2 hours; It characterized by including a surface treatment after the drying treatment.
상술한 바와 같은 본 발명에 따르면, 무기질결합재의 내구성과 도예토의 점성과 성형이 용이한 기능이 동시에 부여됨으로서 조형물제작이 매우 용이하고 일반 공예 재료에 비해 빠르고, 손쉬울 뿐만 아니라 경제성이 있는 방법으로 화분을 비롯한 다양한 조형물 제작이 가능하다. 또한 본 발명 조성물을 활용할 경우 수반, 인조석, 조경석, 조경용 조형물, 조경용 블록, 수족관용 장식돌, 클레이, 공예용품 등으로도 활용할 수 있는 효과가 있다.According to the present invention as described above, the durability of the inorganic binder and the viscosity of the ceramic and easy to mold is given at the same time to make the molding is very easy, compared to the general craft materials, quick and easy as well as economical pots Various sculptures can be produced. In addition, when using the composition of the present invention, there is an effect that can be utilized as accompaniment, artificial stone, landscape stone, landscape sculpture, landscape block, aquarium decorative stone, clay, craft supplies and the like.
도1은 본 발명에 의한 조형물 제작순서도이다. 도2는 본 발명에 의해 제작된 화분의 사진이다.1 is a flow chart of the production of the sculpture according to the present invention. Figure 2 is a photograph of the potted plant produced by the present invention.
이하, 본 발명을 보다 상세히 설명한다.Hereinafter, the present invention will be described in more detail.
본 발명은 화분, 수반, 인조석, 조경석, 조경용 조형물, 조경용 블록, 수족관용 장식돌, 공예용품 등을 제조하기 위한 조성물 및 이를 이용한 제조방법에 관한 것으The present invention relates to a composition for producing a flower pot, accompaniment, artificial stone, landscape stone, landscape sculpture, landscape block, aquarium decorative stone, craft supplies and the like and a manufacturing method using the same.
로, 이후 설명은 주로 자연스러운 돌질감을 주는 화분을 이용하여 설명한다. As will be described later using mainly a pot giving a natural stone texture.
본 발명은 화분에 자연스러운 돌 질감을 주면서도 식재된 식물이 식재후 잘 어울리며 친화경적인 재료를 사용함으로서 식물이건강하게 잘 자랄수 있게 하는 방법에 관한 것이다.The present invention relates to a method for giving plants a natural stone texture while planting plants well after planting and using a friendly environment-friendly material to make plants grow healthy well.
이같은 화분을 제조하기 위한 재료로는 알파형 반수석고, 잔골재, 기능성첨가재로 고성능감수제, 증점제, 발수제, 응결지연제, 응결촉진제등이 있다.Materials for producing such pots include alpha-type hemihydrate gypsum, fine aggregates, and functional additives such as high-performance sensitizers, thickeners, water repellents, coagulation retardants, and coagulation accelerators.
또한, 상기 목적을 달성하기 위한 본 발명의 조형물 제조방법은 상기 조성물을 비율에 맞게 혼합하는 단계; 상기 혼합된 혼합물에 물/결합재의 중량비가 0.20∼0.30이 되도록 물을 첨가하는 단계; 가수 후 충분히 믹싱하는 단계; 믹싱 후 미리 수작업으로 조형물을 성형하는 단계; 1∼2시간 양생 후 탈형하는 단계; 세척후 표면처리 처리하는 단계를 포함하는 것을 특징으로 한다In addition, the molding method of the present invention for achieving the above object comprises the steps of mixing the composition in proportion; Adding water to the mixed mixture such that a weight ratio of water / binder is 0.20 to 0.30; Mixing after mixing sufficiently; Manually molding the sculpture after mixing; Demolding after curing for 1-2 hours; It characterized in that it comprises a step of surface treatment after washing.
상기 반수석고는 무수석고, 메타카올린, 실리카 흄, 일라이트메타카올린, 일라이트 단독 또는 복합사용할 수 있다. 이러한 반수석고 골재를 접착시키는 접착재와 같은 역할을 하는 것으로, 그 함량이 40중량% 미만이면 제작된 화분 및 수반, 인조석, 조경석, 조경용 조형물, 조경용 블록, 수족관용 장식돌, 공예용품 등 투수성을 응용한 제품의 내구성에 문제가 있으며, 60중량%를 초과하면 경제성과 질감에 있어 문제가 있어 40~60중량%의 비율로 첨가한다.The hemihydrate gypsum can be used alone or in combination with anhydrous gypsum, metakaolin, silica fume, illite metakaolin, illite. It plays the same role as the adhesive material for adhering the semi-hydrated gypsum aggregate, and if the content thereof is less than 40% by weight, the permeability of the manufactured flowerpots and heads, artificial stone, landscaping stones, landscaping sculptures, landscaping blocks, aquarium decorative stones, and craft supplies There is a problem in the durability of the applied product, and if it exceeds 60% by weight, there is a problem in economy and texture, so it is added at a ratio of 40 to 60% by weight.
상기 잔골재는 5mm, 또는 10mmm 이하로 입도선별된 화산석, 퍼라이트, 질석, 피트모스, 맥반석,규사, 석분, 옥돌,황토석, 비즈공예석, 천연 또는 인조진주, 사파이어석, 수정, 자수정, 경량골재로부터 선택된 단독 또는 2종이상이 혼합된 잔골재:30~50중량%입도 선별된 화산석, 규사, 경량골재를 단독 또는 복합사용할 수 있다. The fine aggregate is selected from volcanic stone, perlite, vermiculite, peat moss, ganban stone, silica, stone powder, jade stone, ocher stone, beads craft, natural or artificial pearl, sapphire stone, crystal, amethyst, and light aggregate Single or mixed fine aggregates of two or more: 30 to 50% by weight particle size selected volcanic stone, silica sand, lightweight aggregates can be used alone or in combination.
상기 잔골재의 경우 제작된 조형물이 자연스러움을 주기위해서는 평균입도가 0∼10mm 사이가 보다 바람직하며, 제작하고자 하는 조형물의 목적 및 용도, 형태 및 기능에 따라 부분적으로 제거 또한 부가적으로 첨가할 수 있다. 이러한 잔골재는 반수석고접착재 사이에 존재하면서 제작된 조형물에 자연스러움을 주고아울러 질감 및 미감을 향상시키는 종시에 필러의 역할을 하는 것으로, 그 함량이 30중량% 미만이면 자연스러운 질감을 주는데 문제가 있고, 50중량%를 초과하면 골재의 과량으로 인해 제작된 제품의 내구성에 문제가 있어, 30~50중량%의 비율로 첨가한다.
In the case of the fine aggregate, in order to give the manufactured sculptures a natural look, the average particle size is more preferably between 0 and 10 mm, and may be partially removed and additionally added according to the purpose, use, form, and function of the shaped articles to be manufactured. . These fine aggregates are present between the semi-hydrated gypsum adhesive and act as a filler in the end to improve the texture and aesthetics as well as give naturalness to the manufactured sculptures. If the content is less than 30% by weight, there is a problem in giving a natural texture. If it exceeds 50% by weight, there is a problem in the durability of the manufactured product due to the excessive amount of aggregate, it is added in a ratio of 30 to 50% by weight.
상기 고성능감수제는 폴리카르복실레이트계, 리그닌계, 나프탈렌계, 멜라민계를 단독 또는 복합사용할 수 있다. 이러한 고성능감수제는 물/시멘트비를 줄여 투수성을 이용한 제품들의 내구성을 증진하고 재료믹싱시 작업성을 원활하게 하는 역할을 하는 것으로, 그 함량이 0.05중량% 미만이면 효과가 미미하고, 1중량%를 초과하면 원재료비가 상승하고 과다한 감수효과로 인해 재료분리 현상이 발생하는 문제가 있어, 0.05~1중량%의 비율로 첨가한다.The high performance reducing agent may be used alone or in combination of polycarboxylate-based, lignin-based, naphthalene-based, melamine-based. These high performance reducers reduce water / cement ratio to enhance the durability of products using water permeability and smooth workability when mixing materials. When the content is less than 0.05% by weight, the effect is insignificant, and 1% by weight is used. If it exceeds, there is a problem that the raw material cost rises and the material separation phenomenon occurs due to excessive water-reducing effect, and is added at a ratio of 0.05 to 1% by weight.
상기 메텔셀룰오스 계열증점제는 화분 및 조형물 제작시 형태 유지를 하는 역할을 하는 것으로 0.1중량% 미만이면 모양 제작시 형태 유지가 어렵고 2중량% 초과시 경제성 및 과다한 점성으로 인해 문제가 발생하므로 증점제는 0.1중량%∼2중량% 사이로 한다. 상기 Zinc Stearate 및 불소계 발수제는 화분 및 조형물 제작후 수분에 의한 화분의 부식을 막는 역할을 하는 것으로 01중량% 이하면 발수성 유지가 어렵고 1중량% 초과시 경제성 과량으로 인한 내구성에 문제가 있으므로 발수제는 0.1∼1중량%로 한다. 상기 구연산 및 Tartaric Acid와 같은 응결연제는 화분 또는 조형물 제작시 응결지연 효과를 주는 것으로서 0.5중량% 미만이면 응결지연 효과가 미미하고 2중량%초과시 응결지연이 과도하게 일으나고 경제성이 떨어지므로 응결지연제는 0.5∼2중량% 사이로 한다. 상기 리튬카보네이트 응결촉진제는 동절기 또는 온도하락시 경화를 촉진하는 역할을 하는 것으로 0.1중량%미만이며 경화촉진 효과가 떨어지고 2중량% 초과하면 경제성이 떨어지므로 응결촉진제는 0.1∼2중량%를 포함하는 것을 특징으로 하며,The metelcellulose-based thickeners play a role in maintaining the shape when manufacturing pots and sculptures. If the weight is less than 0.1% by weight, it is difficult to maintain the shape when the shape is produced. When the weight is greater than 2% by weight, the thickener is 0.1%. It shall be between% and 2 weight%. The zinc stearate and the fluorine-based water repellent act to prevent corrosion of the pollen by moisture after the production of flower pots and sculptures. If it is less than 01% by weight, it is difficult to maintain water repellency. Let it be 1 weight%. A coagulant such as citric acid and tartaric acid, which has a coagulation delay effect when manufacturing a flower pot or a sculpture, is less than 0.5% by weight, and a coagulation delay effect is insignificant when the weight is over 2% by weight. Shall be between 0.5 and 2% by weight. The lithium carbonate condensation accelerator is less than 0.1% by weight to serve to promote hardening during the winter or temperature drop, and the curing accelerator is inferior in economic efficiency when the curing accelerator is less than 2% by weight, so the condensation accelerator comprises 0.1 to 2% by weight. ,
또한, 상기 성분이외에도 흑색안료, 적색안료를 비롯하여 여러 가지 원하는 색상의 안료를 추가로 첨가할 수도 있다. 이때 첨가되는 안료는 1∼5중량%의 비율로 첨가하는 것이 보다 바람직하다. In addition to the above components, pigments of various desired colors may be further added, including black pigments and red pigments. It is more preferable to add the pigment added at the ratio of 1 to 5 weight% at this time.
상기한 바와 같은 조성비율의 재료를 이용하여 구조체를 제조하는 방법 중 바람직한 예는 도 1에 나타낸 것과 같은 순서로 행할 수 있다.Preferred examples of the method for producing a structure using the materials having the composition ratios described above can be performed in the same order as shown in FIG.
즉, 화분 및 조형물 제작시 상기 조성물을 비율에 맞게 혼합하는 단계를 거친다. 재료는 상기한 바와 같은 비율로 보다 균질하게 혼합하는 것이 바람직하다. That is, during the production of pots and sculptures, the composition is subjected to mixing in proportion. It is preferable to mix the material more homogeneously in the ratio as described above.
또한, 상기 혼합된 혼합물에 물을 첨가하는 단계를 거친다. 이때 물/결합재의 중량비가 0.20∼0.30가 되도록 하는 것이 바람직한데, 중량비가 0.20 미만일 경우 작업성이 현저히 저하되어 강도발현과 내구성에 문제가 있고 0.30을 초과할 경우 과도한 수분으로 인해 화분성형시 모양유지가 어렵고 내구성이 저하되는 문제가 발생하기 때문이다.In addition, water is added to the mixed mixture. At this time, it is preferable to make the weight ratio of water / binder to be 0.20 to 0.30. If the weight ratio is less than 0.20, workability is remarkably deteriorated, which causes problems in strength expression and durability. This is because a problem occurs that is difficult and durability is reduced.
가수 후에는 충분히 믹싱하는 단계를 거친다. 상기 믹싱은 믹서기를 이용하는 방법과 수작업을 통한 방법으로 행할 수 있다. After the singer, the mixing step is sufficiently performed. The mixing can be performed by a method using a blender or by a manual method.
또한, 믹싱완료된 재료를 이용하여 화분을 비롯하여 만들고자 하는 조형물을 제작하는 단계를 거친다. 제작하고자 하는 조형물은 화분, 수반, 인조석, 조경석, 조경용 조형물, 조경용 블록, 수족관용 장식돌, 공예용품 등과 같은 목적하는 조형물을 자유자재로 제작할 수 있다.In addition, by using the mixed material to go through the steps to produce the sculpture to be made, including the pot. Sculptures to be produced can be freely made of the desired sculptures, such as flower pots, heads, artificial stone, landscape stone, landscape sculptures, landscaping blocks, aquarium decorative stones, craft supplies.
또한, 화분을 비롯한 조형물 제작후에는 1∼2시간 정도의 양생기간을 거치고 물로 세척후 건조하는 단계를 거친다. In addition, after the production of sculptures, including potted plants undergo a curing period of about 1 to 2 hours, and then washed with water and dried.
또한, 건조후에는 아크릴물감, 유성 또는 수성물감을 이용하여 표면 처리하는 과정을 거친다. 표면처리 후 수세미등과 같은 거친 도구를 이용하여 표면을 연마하면 더욱 자연스러운 질감을 낼수가 있다.In addition, after drying, the surface treatment is performed using acrylic, oily or aqueous paints. After surface treatment, polishing the surface with a rough tool such as a loofah can give a more natural texture.
이하, 실시예를 통하여 본 발명을 보다 상세하게 설명한다. Hereinafter, the present invention will be described in more detail with reference to Examples.
본 발명에 따른 실시예는 여러 가지 다른 형태로 변형될 수 있으므로, 본 발명의 범위가 아래에서 설명되는 실시예에 한정되지는 않는다.
Embodiments according to the present invention can be modified in many different forms, the scope of the present invention is not limited to the embodiments described below.
<실시예><Examples>
하기 표 1과 같은 비율의 재료를 균질하게 혼합한 후, 하기 표 1과 같은 물/결합재 비가 되도록 물을 첨가한 후, 수작업으로 충분히 믹싱을 행하였다. 믹싱후 수작업으로 화분을 비롯한 조형물, 공예용품등을 제작하였다. 제작된 화분을 1∼2시간 양생후 세척과 건조과정을 거친후 아크릴물감과 물을 희석하여 붓으로 바르거나 희석된 아크릴물감에 침지하는 방법으로 표면처리를 하였다.
After mixing the materials in the ratio as shown in Table 1 below homogeneously, water was added to the water / binder ratio shown in Table 1, and then thoroughly mixed by hand. After mixing, we made flower pots, sculptures and crafts. After curing the prepared pots for 1-2 hours, after washing and drying, acrylic paints and water were diluted and applied with a brush or immersed in diluted acrylic paints.
(2시간)Compressive strength
(2 hours)
상기한 바와 같이 제조된 화분 중에서 본 발명의 조건을 만족하는 발명예 1 및 2는 내구성 확보를 위한 압축강도가 각 각 11.2N/mm2,, 10.5N/mm2.로 나타나 일반적인 화분 및 조형물 제작시 내구성에 문제가 없는 것으로 나타났지만 비교예.1의 경우 결합재비가 적기 때문에 압축강도가 3.2 N/mm2로 나타나 화분 및 조형물 제작시 내구성에 문제가 있는 것으로 나타났다. 비교예.2의 경우 물/결합재의 중량비가 0.35로 높게 했을 경우에도 역시 과다한 수분으로 인해 압축강도가 낮게 나타나 단기간에 화분 또는 조형물 제작이 어려운 것으로 나타났다. 발명예 1,2와 비교예 1,2의 실헙결과는 표.2와 같으며 물성시험방법은 압축강도의 경우 KSF 5105 시멘트 모르타르의 압축강도 시험방법에 의해 시험을 실시하였다.Inventive examples 1 and 2 satisfying the conditions of the present invention among the pots manufactured as described above are 11.2N / mm 2 , 10.5N / mm 2 . Although it was shown that there is no problem in the durability, Comparative Example 1 shows that the compressive strength is 3.2 N / mm 2 because the binder cost is small, and there is a problem in durability in the production of pots and sculptures. In the case of Comparative Example 2, even when the weight ratio of water / bonding material was increased to 0.35, the compressive strength was low due to excessive moisture, making it difficult to manufacture flowerpots or sculptures in a short time. The practical results of Inventive Examples 1 and 2 and Comparative Examples 1 and 2 are shown in Table 2, and the physical property test method was tested by the compressive strength test method of KSF 5105 cement mortar for compressive strength.
표.2의 물성시험 결과에서 보듯이 발명예1,2 의 경우 압축강도는 10N/mm2 이상 본발명에서 추구하고자 하는 화분으로서의 내구성을 확보할 수 있고 화분, 수반,인조석, 조경석, 조경용 조형물, 조경용 블록, 수족관용 장식돌, 공예용품 제작이 가능한 수준으로 판명되었다. 압축강도 10N/mm2 이상은 일반화분에 비해 매우 견고한 수준의 내구성을 확보했다고 볼 수 있으며 화분의 종류에 따라 내구성 차이가 있겠지만 본 발명예 수준의 압축강도라면 화분 및 조형물을 만드는데 충분한 수준의 내구성으로 평가된다. .As shown in the results of the physical property test of Table 2, in the case of Inventive Examples 1 and 2, the compressive strength of 10 N / mm 2 or more can ensure the durability of the pollen to be pursued in the present invention, and the pollen, head, artificial stone, landscape stone, landscape sculpture, It was found to be possible to produce landscaping blocks, aquarium decorative stones, and craft supplies. Compressive strength of 10N / mm 2 or more can be seen to secure a very solid level of durability compared to the general flowerpot and may vary depending on the type of flower pot, but if the compressive strength of the present invention level of sufficient strength to make pots and sculptures Is evaluated. .
발명예 1의 조성물을 이용하여 화분을 제작한 사진을 도2에 나타내었다. A photo of a flower pot manufactured using the composition of Inventive Example 1 is shown in FIG. 2.
해당사항 없슴Not applicable
Claims (5)
상기 조성물에 1∼5중량%의 색상용 안료가 추가되는 것을 특징으로 하는 조형 및 공예재료 조성물The method of claim 1,
Molding and craft material composition, characterized in that 1 to 5% by weight of the color pigment is added to the composition
상기 잔골재는 평균입경이 0~10mm인 것을 특징으로 하는 조형 및 공예재료 조성물The method of claim 1,
The fine aggregate is a molding and craft material composition, characterized in that the average particle diameter of 0 ~ 10mm
상기 표면처리후 바니시, 라텍스등을 표면에 도포하여 용도에 따라 표면 광택을 부여하는 화분, 수반, 인조석, 조경석, 조경용 조형물, 조경용 블록, 수족관용 장식돌, 공예용품 중에서 선택된 모양인 것임을 특징으로 하는 조형물의 제조방법5. The method of claim 4,
After the surface treatment by applying varnish, latex, etc. on the surface to give a surface gloss according to the use, characterized in that the shape selected from potted, accompanying, artificial stone, landscaping stone, landscaping sculptures, landscaping blocks, aquarium decorative stones, craft supplies Manufacturing Method
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101645501B1 (en) * | 2015-03-24 | 2016-08-04 | 충남대학교산학협력단 | Mortars Binder Composition Using Recycling Non-firing Binder |
| KR102072498B1 (en) * | 2018-08-23 | 2020-02-03 | 백혜나 | Gypsum Paste for Crafts, Method for Production Thereof |
| KR102437358B1 (en) * | 2022-05-04 | 2022-08-30 | 한란 | Functional gypsum composition for craft |
| KR20230119296A (en) * | 2022-02-07 | 2023-08-16 | 이상국 | Manufacturing method of artificial landscape stone using foamed glass |
-
2012
- 2012-07-12 KR KR1020120076188A patent/KR20140008850A/en not_active Ceased
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101645501B1 (en) * | 2015-03-24 | 2016-08-04 | 충남대학교산학협력단 | Mortars Binder Composition Using Recycling Non-firing Binder |
| KR102072498B1 (en) * | 2018-08-23 | 2020-02-03 | 백혜나 | Gypsum Paste for Crafts, Method for Production Thereof |
| KR20230119296A (en) * | 2022-02-07 | 2023-08-16 | 이상국 | Manufacturing method of artificial landscape stone using foamed glass |
| KR102437358B1 (en) * | 2022-05-04 | 2022-08-30 | 한란 | Functional gypsum composition for craft |
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