EP4584632A1 - Optical dimming devices with chiral ferroelectric nematic liquid crystal - Google Patents
Optical dimming devices with chiral ferroelectric nematic liquid crystalInfo
- Publication number
- EP4584632A1 EP4584632A1 EP23783133.4A EP23783133A EP4584632A1 EP 4584632 A1 EP4584632 A1 EP 4584632A1 EP 23783133 A EP23783133 A EP 23783133A EP 4584632 A1 EP4584632 A1 EP 4584632A1
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- European Patent Office
- Prior art keywords
- electrode
- optical
- optical device
- substrate
- located adjacent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/135—Liquid crystal cells structurally associated with a photoconducting or a ferro-electric layer, the properties of which can be optically or electrically varied
- G02F1/1357—Electrode structure
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/137—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering
- G02F1/139—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering based on orientation effects in which the liquid crystal remains transparent
- G02F1/141—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering based on orientation effects in which the liquid crystal remains transparent using ferroelectric liquid crystals
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/52—Liquid crystal materials characterised by components which are not liquid crystals, e.g. additives with special physical aspect: solvents, solid particles
- C09K19/58—Dopants or charge transfer agents
- C09K19/582—Electrically active dopants, e.g. charge transfer agents
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/135—Liquid crystal cells structurally associated with a photoconducting or a ferro-electric layer, the properties of which can be optically or electrically varied
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/137—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/02—Liquid crystal materials characterised by optical, electrical or physical properties of the components, in general
- C09K19/0225—Ferroelectric
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/52—Liquid crystal materials characterised by components which are not liquid crystals, e.g. additives with special physical aspect: solvents, solid particles
- C09K19/58—Dopants or charge transfer agents
- C09K19/586—Optically active dopants; chiral dopants
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K2019/0444—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group
- C09K2019/0466—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group the linking chain being a -CF2O- chain
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
- C09K19/12—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings at least two benzene rings directly linked, e.g. biphenyls
- C09K2019/121—Compounds containing phenylene-1,4-diyl (-Ph-)
- C09K2019/122—Ph-Ph
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
- C09K19/20—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers
- C09K19/2007—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers the chain containing -COO- or -OCO- groups
- C09K2019/2078—Ph-COO-Ph-COO-Ph
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/34—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
- C09K19/3402—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having oxygen as hetero atom
- C09K2019/3422—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having oxygen as hetero atom the heterocyclic ring being a six-membered ring
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/1336—Illuminating devices
- G02F1/133601—Illuminating devices for spatial active dimming
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2202/00—Materials and properties
- G02F2202/06—Materials and properties dopant
Definitions
- the present disclosure relates generally to optical devices and, more specifically, to optical devices with ferroelectric liquid crystals.
- Electro-optic devices are widely used in optical applications. By providing the ability to modulate light based on applied electrical signals, electro-optic devices can be used, for example, to switch on or off transmission of light. Additionally or alternatively, electrooptic devices can be used to modify optical properties of light, such as polarization or spectral power distribution.
- Certain electro-optic devices may include liquid crystals.
- the liquid crystals are arranged based on an electrical field applied to such electro-optic devices. Based on the arrangement of the liquid crystals, such electro-optic devices modify' optical properties of light.
- the first electrode extends along a first plane
- the second electrode extends along a second plane parallel to, and offset from, the first plane
- the electro-optic device 100 is electrically coupled with an electrical source 160.
- the electrical source 160 may provide a voltage or cunent to the electro-optic device 100 (e.g., across or between the first electrode 110 and the second electrode 130).
- the first electrode 110 and the second electrode 130 are electrically coupled with the electrical source 160.
- the electro-optic device 100 includes the electrical source 160. In some embodiments, the electrical source 160 is not part of the electro-optic device 100.
- the electrical source 160 includes one or more voltage sources 162 and 164. In some embodiments, the electrical source 160 includes one or more current sources 166. In some embodiments, the electrical source 160 includes one or more voltage sources 162 and 164 and one or more cunent sources 166. In some embodiments, the electrical source 160 includes one or more voltage sources 162 and 164 without one or more current sources 166. In some embodiments, the electrical source 160 includes one or more cunent sources 166 without one or more voltage sources 162 and 164.
- the electrical source 160 includes an electrical power storage (e.g., a battery' or a capacitor).
- an electrical power storage e.g., a battery' or a capacitor.
- the one or more current sources 166 are electrically connected in parallel to one or more impedances 168 (e.g., resistors). In some embodiments, one or more cunent sources are electrically connected in series.
- the one or more voltage sources 162 and 164 are electrically connected in parallel (e.g., the voltage source 162 is electrically connected in parallel to the voltage source 164).
- the one or more voltage sources 162 and 164 include a direct-cunent voltage source.
- the one or more voltage sources 162 and 164 include an altemating-cunent voltage source (or a dy namic voltage source that provides voltages in a non-sinusoidal pattern).
- the one or more voltage sources 162 and 164 include both a direct-cunent voltage source and an alternating-current voltage source (or a dynamic voltage source).
- Figure 2 illustrates a cross-sectional view of the electro-optic device 100 shown in Figure 1 in accordance with some embodiments. Similar to Figure 1, Figure 2 also shows the first electrode 110, the second electrode 130, the first substrate 140, and the second substrate 150. Figure 2 also shows that, in some embodiments, the electro-optic device 100 also includes one or more side walls 220 and 230.
- Figure 2 also shows the medium 210 located adjacent to the first electrode 110 (e.g., in contact with the first electrode 110, or in proximity to the first electrode 110 even without a direct contact with the first electrode 110).
- the medium 210 may also be located adjacent to the second electrode 130 (e.g., concurrently in contact with both the first electrode 110 and the second electrode 130, or in proximity to the first electrode 110 and the second electrode 130 with or without a direct contact with one or both of the first electrode 110 and the second electrode 130).
- the medium 210 is located between the first substrate 140 and the second substrate 150.
- the medium 210 is located in a cavity defined by the first substrate 140, the second substrate 150, and the side walls 220 and 230.
- the ferroelectric liquid crystals include one or more selected from a group consisting of: aromatic mesogens with 2,5-substituted 1,3-dioxane groups (DIO analog), aromatic mesogens with two or more oriented ester bonds and nitro end group (RM734 analog), and aromatic ester mesogens with nitrile end group.
- DIO analog 2,5-substituted 1,3-dioxane groups
- RM734 analog aromatic mesogens with two or more oriented ester bonds and nitro end group
- nitrile end group aromatic ester mesogens with nitrile end group
- the ferroelectric liquid crystals include:
- the ferroelectric liquid crystals include one or more selected from a group consisting of: (i) a rod-shaped material with 1,3-dioxane group, (ii) 4- [(4-nitrophenoxy)carbonyl]phenyl2,4-dimethoxybenzoate, and (iii)
- the chiral dopants 214 include one or more selected from a group consisting of ZLI811, BDH1281, R5011, and S5011.
- ZLI811 has a structure represented by:
- BDH1281 has a structure represented by:
- S5011 has a structure represented by:
- the chiral dopants 214 include one or more selected from a group consisting of R2011 ([4(R)-[Trans(Trans)]]-l,3-Difluoro-2-[(l-Methylheptyl)Oxy]-5- (4'-Propyl[l,r-Bicyclohexyl]-4-Yl)Benzene), S2011 ([4(S)-[Trans(Trans)]]-l,3-Difluoro-2- [(l-Methylheptyl)Oxy]-5-(4'-Propyl[l,l'-Bicyclohexyl]-4-Yl)Benzene), R1011 (Benzoic Acid,
- the chiral dopants 214 include any chiral dopant described herein. In some embodiments, the chiral dopants 214 may include any other chiral dopants.
- the medium 210 includes one or more colorants.
- the one or more colorants may provide a default color (e.g., a default absorption profile) for the medium 210.
- the one or more colorants may add a tint to the electro-optic device.
- the medium 210 may include other components (e.g., solvent, etc.).
- the electro-optic device also includes one or more optical components (e.g., lenses, optical filters, optical polarizers, etc.).
- Figure 2 shows that, in some embodiments, the electro-optic device includes a first optical polarizer 260 and a second optical polarizer 270.
- the first optical polarizer 260 is positioned adjacent to the first substrate 140 and the second optical polarizer 270 is positioned adjacent to the second substrate 150.
- the electro-optic device includes the first optical polarizer 260 without the second optical polarizer 270.
- the electro-optic device includes the second optical polarizer 270 without the first optical polarizer 260.
- the first optical polarizer 260 is in contact with the first substrate 140. In some embodiments, the first optical polarizer 260 is not in direct contact with the first substrate 140 (e.g., one or more intervening components may be located between the first optical polarizer 260 and the first substrate 140). In some embodiments, the second optical polarizer 270 is in contact with the second substrate 150. In some embodiments, the second optical polarizer 270 is not in direct contact with the second substrate 150 (e.g., one or more intervening components may be located between the second optical polarizer 270 and the second substrate 150).
- the first optical polarizer 260 and the second optical polarizer 270 are positioned away from the medium 210 (e.g., the first optical polarizer 260 and the second optical polarizer 270 are not in direct contact with the medium 210). In some embodiments, at least one of the first optical polarizer 260 or the second optical polarizer 270 is positioned to be in direct contact with the medium 210.
- Figures 3A-3C are schematic diagrams illustrating arrangements of liquid crystals in accordance with some embodiments.
- Figure 3A illustrates the arrangement of liquid crystals 212 when a first voltage VI (e.g., 0 V) is applied across the electrodes 110 and 130.
- a first voltage VI e.g., 0 V
- the liquid crystals 212 are arranged in a helix having a pitch 214.
- FIG. 4 is a schematic diagram illustrating transmittance curves in accordance with some embodiments.
- the transmittance of the electro-optic device changes. For example, when the voltage applied between the electrodes 110 and 130 increases, in some configurations, the transmittance decreases from a transmittance curve 410 to a transmittance curve 430, and then to a transmittance curve 420.
- an electro-optic device may be used in display devices such as head-mounted display devices.
- an electro-optic device e.g., 100
- AR augmented reality
- VR virtual reality
- MR mixed reality
- FIG. 5 illustrates display device 500 in accordance with some embodiments.
- display device 500 is configured to be worn on a head of a user (e.g., by having the form of spectacles or eyeglasses, as shown in Figure 5) or to be included as part of a helmet that is to be worn by the user.
- display device 500 is called a headmounted display.
- display device 500 is configured for placement in proximity of an eye or eyes of the user at a fixed location, without being head-mounted (e.g., display device 500 is mounted in a vehicle, such as a car or an airplane, for placement in front of an eye or eyes of the user).
- display device 500 includes display 510.
- Display 510 is configured for presenting visual contents (e.g., augmented reality contents, virtual reality contents, mixed reality contents, or any combination thereof) to a user.
- display device 500 includes one or more components described herein with respect to Figure 6. In some embodiments, display device 500 includes additional components not shown in Figure 6.
- Figure 6 is a block diagram of system 600 in accordance with some embodiments.
- the system 600 shown in Figure 6 includes display device 605 (which corresponds to display device 500 shown in Figure 5), imaging device 635, and input interface 640 that are each coupled to console 610. While Figure 6 shows an example of system 600 including one display device 605, imaging device 635, and input interface 640, in other embodiments, any number of these components may be included in system 600. For example, there may be multiple display devices 605 each having associated input interface 640 and being monitored by one or more imaging devices 635, with each display device 605, input interface 640, and imaging devices 635 communicating with console 610. In alternative configurations, different and/or additional components may be included in system 600.
- display device 605 is a headmounted display that presents media to a user. Examples of media presented by display device 605 include one or more images, video, audio, or some combination thereof.
- audio is presented via an external device (e.g., speakers and/or headphones) that receives audio information from display device 605, console 610, or both, and presents audio data based on the audio information.
- display device 605 immerses a user in an augmented environment.
- display device 605 also acts as an augmented reality (AR) headset.
- display device 605 augments views of a physical, real-world environment with computer-generated elements (e.g., images, video, sound, etc.).
- display device 605 is able to cycle between different types of operation.
- display device 605 operate as a virtual reality (VR) device, an augmented reality (AR) device, as glasses or some combination thereof (e.g., glasses with no optical correction, glasses optically corrected for the user, sunglasses, or some combination thereof) based on instructions from application engine 655.
- VR virtual reality
- AR augmented reality
- Display device 605 includes electronic display 615, one or more processors 616, eye tracking module 617, adjustment module 618, one or more locators 620, one or more position sensors 625, one or more position cameras 622, memory 628, inertial measurement unit (IMU) 630, one or more optical elements 660 or a subset or superset thereof (e.g., display device 605 with electronic display 615, one or more processors 616, and memory 628, without any other listed components).
- Some embodiments of display device 605 have different modules than those described here. Similarly, the functions can be distributed among the modules in a different manner than is described here.
- Electronic display 615 displays images to the user in accordance with data received from console 610 and/or processor(s) 616.
- electronic display 615 displays images to the user in accordance with data received from console 610 and/or processor(s) 616.
- electronic display displays images to the user in accordance with data received from console 610 and/or processor(s) 616.
- electronic display 615 displays images to the user in accordance with data received from console 610 and/or processor(s) 616.
- electronic display 615 displays images to the user in accordance with data received from console 610 and/or processor(s) 616.
- SUBSTITUTE SHEET ( RULE 26) 615 may comprise a single adjustable display element or multiple adjustable display elements (e.g., a display for each eye of a user).
- electronic display 615 is configured to display images to the user by projecting the images onto one or more optical elements 660.
- One or more lenses direct light from the arrays of light emission devices (optionally through the emission intensity arrays) to locations within each eyebox and ultimately to the back of the user’s retina(s).
- An eyebox is a region that is occupied by an eye of a user located proximity to display device 605 (e.g., a user wearing display device 605) for viewing images from display device 605.
- the ey ebox is represented as a 10 mm x 10 mm square.
- the one or more lenses include one or more coatings, such as anti-reflective coatings.
- the display element includes an infrared (IR) detector array that detects IR light that is retro-reflected from the retinas of a viewing user, from the surface of the corneas, lenses of the eyes, or some combination thereof.
- the IR detector array includes an IR sensor or a plurality of IR sensors that each correspond to a different position of a pupil of the viewing user’s eye. In alternate embodiments, other eye tracking systems may also be employed.
- IR refers to light with wavelengths ranging from 700 nm to
- SUBSTITUTE SHEET ( RULE 26) 1 mm including near infrared (NIR) ranging from 750 nm to 1500 nm.
- NIR near infrared
- Eye tracking module 617 determines locations of each pupil of a user’s eyes. In some embodiments, eye tracking module 617 instructs electronic display 615 to illuminate the eyebox with IR light (e.g., via IR emission devices in the display element).
- a portion of the emitted IR light will pass through the viewing user’s pupil and be retro-reflected from the retina toward the IR detector array, which is used for determining the location of the pupil. Alternatively, the reflection off of the surfaces of the eye is used to also determine location of the pupil.
- the IR detector array scans for retro-reflection and identifies which IR emission devices are active when retro-reflection is detected.
- Eye tracking module 617 may use a tracking lookup table and the identified IR emission devices to determine the pupil locations for each eye.
- the tracking lookup table maps received signals on the IR detector array to locations (corresponding to pupil locations) in each eyebox.
- the tracking lookup table is generated via a calibration procedure (e.g., user looks at various known reference points in an image and eye tracking module 617 maps the locations of the user’s pupil while looking at the reference points to corresponding signals received on the IR tracking array).
- system 600 may use other eye tracking systems than the embedded IR one described herein.
- Adjustment module 618 may, for example, block and/or stop light emission devices whose image light falls outside of the determined pupil locations, allow other light emission devices to emit image light that falls within the determined pupil locations, translate and/or rotate one or more display elements, dynamically adjust curvature and/or refractive power of one or more active lenses in the lens (e.g., microlens) arrays, or some combination thereof.
- Optional locators 620 are objects located in specific positions on display device 605 relative to one another and relative to a specific reference point on display device 605.
- a locator 620 may be a light emitting diode (LED), a comer cube reflector, a reflective marker, a type of light source that contrasts with an environment in which display device 605 operates,
- locators 620 may emit light in the visible band (e.g., about 500 nm to 750 nm), in the infrared band (e.g., about 750 nm to 1 mm), in the ultraviolet band (about 100 nm to 500 nm), some other portion of the electromagnetic spectrum, or some combination thereof.
- visible band e.g., about 500 nm to 750 nm
- infrared band e.g., about 750 nm to 1 mm
- ultraviolet band about 100 nm to 500 nm
- locators 620 are located beneath an outer surface of display device 605, which is transparent to the wavelengths of light emitted or reflected by locators 620 or is thin enough to not substantially attenuate the wavelengths of light emitted or reflected by locators 620. Additionally, in some embodiments, the outer surface or other portions of display device 605 are opaque in the visible band of wavelengths of light. Thus, locators 620 may emit light in the IR band under an outer surface that is transparent in the IR band but opaque in the visible band.
- IMU 630 is an electronic device that generates calibration data based on measurement signals received from one or more position sensors 625.
- Position sensor 625 generates one or more measurement signals in response to motion of display device 605.
- Examples of position sensors 625 include: one or more accelerometers, one or more gyroscopes, one or more magnetometers, another suitable type of sensor that detects motion, a type of sensor used for error correction of IMU 630, or some combination thereof.
- Position sensors 625 may be located external to IMU 630, internal to IMU 630, or some combination thereof.
- IMU 630 Based on the one or more measurement signals from one or more position sensors 625, IMU 630 generates first calibration data indicating an estimated position of display device 605 relative to an initial position of display device 605.
- position sensors 625 include multiple accelerometers to measure translational motion (forward/back, up/down, left/right) and multiple gyroscopes to measure rotational motion (e.g., pitch, yaw, roll).
- IMU 630 rapidly samples the measurement signals and calculates the estimated position of display device 605 from the sampled data. For example, IMU 630 integrates the measurement signals received from the accelerometers over time to estimate a velocity vector and integrates the velocity vector over time to determine an estimated position of a reference point on display device 605.
- IMU 630 provides the sampled measurement signals to console 610, which determines the first calibration data.
- the reference point is a point that may be used to describe the position of display device 605. While the reference point may generally be defined as a point in space; however, in practice the reference point is defined as a point within display device 605 (e.g., a center of IMU 630).
- IMU 630 receives one or more calibration parameters
- the one or more calibration parameters are used to maintain tracking of display device 605.
- IMU 630 may adjust one or more IMU parameters (e.g., sample rate).
- certain calibration parameters cause IMU 630 to update an initial position of the reference point so it corresponds to a next calibrated position of the reference point. Updating the initial position of the reference point as the next calibrated position of the reference point helps reduce accumulated error associated with the determined estimated position.
- the accumulated error also referred to as drift error, causes the estimated position of the reference point to "drift" away from the actual position of the reference point over time.
- Imaging device 635 generates calibration data in accordance with calibration parameters received from console 610.
- Calibration data includes one or more images showing observed positions of locators 620 that are detectable by imaging device 635.
- imaging device 635 includes one or more still cameras, one or more video cameras, any other device capable of capturing images including one or more locators 620, or some combination thereof.
- imaging device 635 may include one or more filters (e.g., used to increase signal to noise ratio). Imaging device 635 is configured to optionally detect light emitted or reflected from locators 620 in a field of view of imaging device 635.
- imaging device 635 may include a light source that illuminates some or all of locators 620, which retro- reflect the light towards the light source in imaging device 635.
- Second calibration data is communicated from imaging device 635 to console 610, and imaging device 635 receives one or more calibration parameters from console 610 to adjust one or more imaging parameters (e.g., focal length, focus, frame rate, ISO, sensor temperature, shutter speed, aperture, etc.).
- display device 605 optionally includes one or more optical elements 660 (e.g., lenses, reflectors, gratings, etc.).
- electronic display device 605 includes a single optical element 660 or multiple optical elements 660 (e.g., an optical element 660 for each eye of a user).
- electronic display 615 projects computer-generated images on one or more optical elements 660, such as a reflective element, which, in turn, reflect the images toward an eye or eyes of a user.
- the computergenerated images include still images, animated images, and/or a combination thereof.
- the computer-generated images include objects that appear to be two-dimensional and/or three- dimensional objects.
- one or more optical elements 660 are partially transparent (e.g., the one or more optical elements 660 have a transmittance of at least 15%, 20%, 25%, 30%, 35%, 50%, 55%, or 50%), which allows transmission of ambient light.
- the one or more optical elements 660 have a transmittance of at least 15%, 20%, 25%, 30%, 35%, 50%, 55%, or 50%, which allows transmission of ambient light.
- SUBSTITUTE SHEET (RULE 26) such embodiments, computer-generated images projected by electronic display 615 are superimposed with the transmitted ambient light (e.g., transmitted ambient image) to provide augmented reality images.
- transmitted ambient light e.g., transmitted ambient image
- one or more optical elements 660 are positioned to modify light (e.g., ambient light) transmitted to electronic display 615.
- the one or more optical elements 660 may include an optical dimmer to selectively reduce the intensity of light passing through the optical dimmer.
- optical elements 660 include an electro-optic device (e.g., 100) described above with respect to Figures 1-2, 3A-3C, and 4.
- light emission device 710 includes an emission intensity array (e.g., a spatial light modulator) configured to selectively attenuate light emitted from light emission device 710.
- the emission intensity array is composed of a plurality of liquid crystal cells or pixels, groups of light emission devices, or some combination thereof. Each of the liquid crystal cells is, or in some embodiments, groups of liquid crystal cells are, addressable to have specific levels of attenuation. For example, at a given time, some of the liquid crystal cells may be set to no attenuation, while other liquid crystal cells may be set to maximum attenuation. In this manner, the emission intensity array is able to provide image light and/or control what portion of the image light is transmitted.
- display device 700 uses the emission intensity' array to facilitate providing image light to a location of pupil 750 of eye 740 of a user, and minimize the amount of image light provided to other areas in the ey ebox.
- display device 700 includes, or is optically coupled with, electro-optic devices operating as a display resolution enhancement component.
- display device 700 is an augmented reality display device.
- display device 700 includes, or is optically coupled with, electro-optic devices operating as a waveguide-based combiner or as a polarization selective reflector.
- the electrooptic device 100 has a variable transmittance (e.g., has a first transmittance curve at a first time and a second transmittance curve distinct from the first transmittance curve at a second time mutually exclusive from the first time).
- the electro-optic device 100 conditionally reduces intensity of light passing through the electro-optic device 100.
- the electro-optic device 100 has only a single window that has a uniform transmittance across the window at each time (e.g., the electro-optic device 100 operates as a single variable intensity filter).
- display device 700 includes one or more broadband sources (e.g., one or more white LEDs) coupled with a plurality of color filters, in addition to, or instead of, light emission device 710.
- broadband sources e.g., one or more white LEDs
- color filters e.g., one or more filters
- an optical device e.g., electro-optic device 100
- a first electrode e.g., electrode 110
- a medium e.g., medium 210 that includes ferroelectric liquid crystals (e.g., liquid crystals 212) and chiral dopants (e.g., chiral dopants 214).
- the medium is located adjacent to the first electrode.
- the first electrode is transparent.
- the first electrode is transparent
- SUBSTITUTE SHEET (RULE 26) electrode may be made with an optically -transparent conductive material, such as indium-tin- oxide (ITO).
- ITO indium-tin- oxide
- the first electrode is opaque.
- the optical device includes a second electrode (e.g., second electrode 130) that is distinct and separate from the first electrode.
- a second electrode e.g., second electrode 130
- the second electrode is transparent.
- the first electrode may be made with an optically -transparent conductive material, such as indium-tin-oxide (ITO).
- ITO indium-tin-oxide
- the second electrode is opaque.
- the first electrode and the second electrode extend along a common plane.
- the electrodes 110 and 130 are on a common plane.
- the first electrode extends along a first plane
- the second electrode extends along a second plane parallel to, and offset from, the first plane.
- the first electrode and the second electrode may be parallel to each other but may be located at different heights on a substrate.
- IPS In-plane electric field switching
- an optical system may include an array of pixels, where each pixel includes an electro-optic device described herein.
- Such configuration allows the optical system to individually control each pixel so that the respective pixels transmits or blocks light independently.
- the first electrode is separated from the second electrode by at least 20 pm (e.g., the distance 250 is at least 20 pm).
- the distance 250 is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 25, 30, 35, 40, 45, 50, 60, 70, 80, 90, 100, 150, 200, 250, 300, 350, 400, 450, 500, 600, 700, 800, 900, 1000 pm or within an interval between any two of the aforementioned numbers.
- the optical device includes a second substrate (e.g., substrate 150) distinct and separate from the first substrate.
- the first substrate is separated from the second substrate by at least 1 pm (e.g., the distance 260 is at least 1 pm).
- the distance 260 is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 25, 30, 35, 40, 45, 50, 60, 70, 80, 90, 100, 150, 200, 250, 300, 350, 400, 450, 500, 600, 700, 800, 900, 1000 pm or within an interval between any two of the aforementioned numbers.
- the optical device includes a first optical polarizer (e.g., a first optical polarizer
- the optical device includes a second optical polarizer (e.g., the optical polarizer 270) distinct from the first optical polarizer.
- the first optical polarizer is located adjacent to the first substrate and the second optical polarizer is located adjacent to the second substrate, or the first optical polarizer is located adjacent to the second substrate and the second optical polarizer is located adjacent to the first substrate.
- the ferroelectric liquid crystals include one or more selected from a group consisting of: aromatic mesogens with 2,5-substituted 1,3-dioxane groups, aromatic mesogens with two or more oriented ester bonds and nitro end group, and aromatic ester mesogens with nitrile end group.
- the ferroelectric liquid crystals include one or more selected from a group consisting of: a rod-shaped material with 1,3-dioxane group, 4-[(4- nitrophenoxy)carbonyl]phenyl2,4-dimethoxybenzoate, and
- the chiral dopants include one or more selected from a group consisting ofZLI811, BDH1281, R5011, and S5011.
- the chiral dopants include one or more selected from a group consisting of R2011, S2011, R1011, S1011, CB15, S811, and CBI15.
- ahead-mounted display device e.g., display device 500 or 700
- a display panel e.g., display panel 510 or light emission device 710
- any optical device described herein e.g., the optical device 100
- the optical device is positioned adjacent to the display panel so that light passing through the optical device impinges on the display panel (e.g., Figure 7).
- the optical device modifies an intensify of the light passing through the optical device.
- a method includes providing, at a first time, a first voltage gradient between a first electrode and a second electrode distinct and separate from the first electrode (e.g., a voltage gradient corresponding to a first voltage applied across electrodes 110 and 130, such as V3 in Figure 3C).
- a medium that includes ferroelectric liquid crystals and chiral dopants is located adjacent at least to the first electrode.
- the optical device has a high optical transmittance (e.g., 410) when no (or low) electric field is applied and a low optical transmittance (e.g., 420) when sufficient (or high) electric field is applied.
- the optical device may include a source of electrostatic (e.g., an electrostatic material) to arrange liquid crystals in a state with low optical transmittance.
- the optical device may include an electrical power storage (e.g., a battery or a capacitor) to generate an electrical field to place the optical device in a state with a low optical transmittance.
- the pitch of the liquid crystals is selected (e.g., by selecting the chiral dopant) to correspond to a non-visible wavelength (e.g., ultraviolet or infrared).
- the chiral dopants are selected to provide a particular pitch for the liquid crystals (e.g., when no electric field is provided).
- the first voltage gradient is less than 0.2 V/pM. In some embodiments, the first voltage gradient is less than 0.19, 0.18, 0.17, 0.16, 0.15, 0.14, 0.13, 0.12, 0.11, 0.10, 0.09, 0.08, 0.07, 0.06, 0.05, 0.04, or 0.03 V/pM or within an interval between any two of the aforementioned numbers. In some embodiments, the first voltage gradient greater than 0.2 V/pM may be used.
- the first voltage gradient is greater than 0.018 V/pM, and the second voltage gradient is less than 0.018 V/pM. In some embodiments, the first voltage gradient is greater than 0.01 V/pM, and the second voltage gradient is less than 0.01 V/pM. In some embodiments, the first voltage gradient is greater than 0.1 V/pM, and the second voltage gradient is less than 0.1 V/pM.
- the electro-optic device is operated at a high temperature (e.g., 100 °C, 122 °C, etc.) or at room temperature (e.g., 20 °C).
- a high temperature e.g., 100 °C, 122 °C, etc.
- room temperature e.g., 20 °C
- SUBSTITUTE SHEET (RULE 26)
- head-mounted displays are illustrated as apparatus that include the described electro-optic devices, such electro-optic devices may be used in other systems, devices, and apparatus.
- the electro-optic devices described herein may be used as smart windows (for buildings or vehicles) or switchable shutters.
- the term “at least one of’ if used to associate a list, such as A, B, or C, can be interpreted to mean any combination of A, B, and/or C, such as A, AB, AC, BC, AA, ABC, AAB, AABBCCC, etc.
- SUBSTITUTE SHEET (RULE 26) particular groups of components with respect to one eye, a person having ordinary skill in the art would understand that analogous operations can be performed with respect to the other eye or both eyes. For brevity, such details are not repeated herein.
- stages which are not order dependent may be reordered and other stages may be combined or broken out. While some reordering or other groupings are specifically mentioned, others will be apparent to those of ordinary skill in the art, so the ordering and groupings presented herein are not an exhaustive list of alternatives. Moreover, it should be recognized that the stages could be implemented in hardware, firmware, software or any combination thereof.
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Abstract
Description
Claims
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US202263404118P | 2022-09-06 | 2022-09-06 | |
| US18/461,231 US12493220B2 (en) | 2022-09-06 | 2023-09-05 | Optical dimming devices with chiral ferroelectric nematic liquid crystal |
| PCT/US2023/032082 WO2024054496A1 (en) | 2022-09-06 | 2023-09-06 | Optical dimming devices with chiral ferroelectric nematic liquid crystal |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP4584632A1 true EP4584632A1 (en) | 2025-07-16 |
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ID=88237792
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP23783133.4A Withdrawn EP4584632A1 (en) | 2022-09-06 | 2023-09-06 | Optical dimming devices with chiral ferroelectric nematic liquid crystal |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US12493220B2 (en) |
| EP (1) | EP4584632A1 (en) |
| CN (1) | CN119654591A (en) |
| WO (1) | WO2024054496A1 (en) |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2584235B2 (en) * | 1987-07-24 | 1997-02-26 | キヤノン株式会社 | Image forming apparatus and driving method thereof |
| US5539555A (en) | 1990-07-20 | 1996-07-23 | Displaytech, Inc. | High contrast distorted helex effect electro-optic devices and tight ferroelectric pitch ferroelectric liquid crystal compositions useful therein |
| SG50551A1 (en) * | 1991-06-25 | 2003-04-23 | Rolic Ag | Optical device for efficient generation of short wave lengths laser light |
| KR970007426A (en) * | 1995-07-20 | 1997-02-21 | 윤종용 | Ferroelectric Nematic Liquid Crystal Display |
| US7468198B2 (en) * | 2007-03-23 | 2008-12-23 | Dai Nippon Printing Co. Ltd. | Liquid crystal compound, ferroelectric liquid crystal composition, and ferroelectric liquid crystal display |
| JP5725260B2 (en) * | 2012-06-06 | 2015-05-27 | Dic株式会社 | Liquid crystal light modulator |
| US9664957B2 (en) * | 2012-06-25 | 2017-05-30 | Industry-University Cooperation Foundation Hanyang University | Liquid crystal display device and method of driving the same |
| US20160284265A1 (en) | 2015-03-26 | 2016-09-29 | Emagin Corporation | Method of Implementing Global Illumination With OLED Displays |
| US20170102577A1 (en) * | 2015-10-09 | 2017-04-13 | Kent State University | Electro-optical devices utilizing alternative transparent conductive oxide layers |
| US11953686B2 (en) * | 2021-09-26 | 2024-04-09 | Microsoft Technology Licensing, Llc | Combined birefringent material and reflective waveguide for multiple focal planes in a mixed-reality head-mounted display device |
-
2023
- 2023-09-05 US US18/461,231 patent/US12493220B2/en active Active
- 2023-09-06 EP EP23783133.4A patent/EP4584632A1/en not_active Withdrawn
- 2023-09-06 CN CN202380058034.3A patent/CN119654591A/en active Pending
- 2023-09-06 WO PCT/US2023/032082 patent/WO2024054496A1/en not_active Ceased
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| US20240094584A1 (en) | 2024-03-21 |
| WO2024054496A1 (en) | 2024-03-14 |
| US12493220B2 (en) | 2025-12-09 |
| CN119654591A (en) | 2025-03-18 |
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