EP2737497B1 - Method for producing an electrical component and electrical component - Google Patents
Method for producing an electrical component and electrical component Download PDFInfo
- Publication number
- EP2737497B1 EP2737497B1 EP12740158.6A EP12740158A EP2737497B1 EP 2737497 B1 EP2737497 B1 EP 2737497B1 EP 12740158 A EP12740158 A EP 12740158A EP 2737497 B1 EP2737497 B1 EP 2737497B1
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- European Patent Office
- Prior art keywords
- base body
- layer
- electrical component
- contacts
- metallic
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/008—Thermistors
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/04—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material having negative temperature coefficient
- H01C7/041—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material having negative temperature coefficient formed with two or more layers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C17/00—Apparatus or processes specially adapted for manufacturing resistors
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/10—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material voltage responsive, i.e. varistors
- H01C7/12—Overvoltage protection resistors; Arresters
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/18—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material comprising a plurality of layers stacked between terminals
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49082—Resistor making
- Y10T29/49085—Thermally variable
Definitions
- the invention relates to a method for producing an electrical component, which can be used, for example, for protection against electrostatic discharge or as a sensor, and an electrical component produced by the method.
- Electronic circuits which are generally operated at low supply and signal voltages, can be destroyed if a high voltage occurs, for example an electrostatic overvoltage, at the voltage-supplying contact connections.
- a high voltage for example an electrostatic overvoltage
- protective components for protection against electrostatic discharge can be connected to the voltage-supplying contact connections, through which high electrostatic voltages can be diverted to a reference potential, for example a ground potential.
- multilayer varistors in SMD Surface Mounted Device
- SMD Surface Mounted Device
- ESD Electro Static Discharge
- the pamphlet US 2008/0238604 A1 relates to a varistor component with a part-body determining the varistor properties and a heat-emitting part-body.
- An internal electrode is arranged in the part body which determines the varistor properties.
- Two further electrodes, which are separated from one another by an electrically insulating layer, are applied to the partial body at a distance from one another.
- a method according to the invention for producing an electrical component is specified in claim 1.
- the method for producing an electrical component comprises providing a ceramic semiconducting base body with a surface and a first side face opposite the surface, a metallic layer being contained within the base body. At least two further metallic layers are arranged separately from one another on the side surface of the base body. The arrangement made up of the base body and the further metallic layers is sintered. An electrically insulating layer is arranged on the first side surface of the base body between the at least two further metallic layers as a passivation layer. A contact layer is arranged on each of the at least two further metallic layers by means of a chemical process. Through the chemical process the material of the base body is removed starting from the surface of the base body up to at most the metallic layer arranged within the base body.
- the material of the base body which is arranged over the metallic layer contained within the base body, represents a sacrificial layer that is already etched down during the chemical process of applying the contact layers by the acids / bases involved in the chemical process.
- the metallic layer applied to the first side surface and the electrically insulating layer are uncovered, trenches are etched into the material of the base body.
- Electroless plating for example an ENIG (electroless nickel immersion gold), ENEPIG (electroless nickel, electroless palladium immersion gold) or electroplating, with the electrolyte being a corrosive acid or base, can be used as a chemical process for applying the contact layer can be used.
- the trench can be further etched and the sacrificial layer can be removed down to the metallic layer arranged within the base body.
- the metallic layer within the base body acts as an etch stop layer so that the underlying material of the base body is no longer etched. Since the metallic layer arranged within the material of the base body can be introduced into the material of the base body close to the first side surface of the base body, the method enables the production of a component with a low overall height.
- the electrically insulating layer between the contacts is a passivation layer which prevents the material of the base body arranged under the electrically insulating layer from being etched during the chemical process or during the etching process for separating the component.
- the passivation layer arranged between the contacts can, for example, have a material that contains glass, silicon nitride (Si 3 N 4 ), silicon carbide (SiC), aluminum oxide (Al 2 O 3 ) or a polymer.
- the contact layer can be designed as a single layer made of, for example, silver. As an alternative to this, the contact layer can also have several partial layers, for example different metal sequences, such as nickel, palladium, gold or tin.
- the specified embodiment of the method for producing an electrical component enables in particular the implementation of ESD protective components or ceramic sensors with component heights between a metallic layer acting as an electrode and the contact layers of less than 150 ⁇ m and typically of approximately 50 ⁇ m.
- the electrical component can be produced inexpensively and used for the production of ultra-thin individual chips as well as for arrays.
- an electrical component produced by the method comprises a ceramic semiconducting base body with a first side surface on which at least two spaced apart contacts are arranged, and a second side surface opposite the first side surface, on which a metallic layer is arranged.
- Each of the contacts has a further metallic layer, which is arranged on the first side surface of the base body, and a contact layer, which is arranged on the further metallic layer.
- the electrical component has a component height of at most 150 ⁇ m and preferably of 50 ⁇ m between including the metallic layer and including the respective contact layer of the contacts.
- FIG. 1 shows an embodiment 1 of an electrical component which can be used, for example, for protection against electrostatic discharge or as a sensor.
- the electrical component comprises a ceramic semiconducting base body 10.
- the base body 10 has a side surface S10a and a side surface S10b opposite the side surface S10a.
- a metallic layer 40 is arranged in the material of the base body between the side surfaces S10a and S10b.
- the metallic layer 40 can contain silver, for example.
- the contacts 21 and 22 each have a metallic layer 210 and a contact layer 220.
- the metallic layer 210 of the contact 21 and of the contact 22 are each arranged on the side surface S10a of the base body 10 at a distance from one another.
- the contact layers 220 of the contacts 21 and 22 are each arranged on the metallic layer 210.
- the metallic layer 210 of the contacts 21 and 22 can contain silver, for example.
- the contact layer 220 can have a material made of nickel and / or gold, for example.
- the respective contact layer 220 of the contacts 21 and 22 can have a sub-layer 221 and a sub-layer 222.
- the sub-layer 221 can be arranged on the metallic layer 210 and the sub-layer 222 can be arranged on the sub-layer 221.
- the partial layer 221 can, for example, have a material made of nickel and the partial layer 222 can, for example, have a material made of gold.
- An electrically insulating layer 30 is arranged between the contacts 21 and 22 on the side surface S10a of the base body 10.
- the electrically insulating layer 30 is embodied in such a way that it separates both the metallic layer 210 of the contact connections 21 and 22 and the contact layers 220 of the two contacts 21 and 22 from one another.
- the two contacts 21 and 22 are thus electrically isolated from one another by the layer 30.
- the electrically insulating layer 30 can contain a material made of glass, for example.
- Figure 1B shows a top view of the in Figure 1A Embodiment 1 shown of the electrical component.
- the contacts 21 and 22, in particular the respective contact layer, are shown 220 of the contacts 21 and 22, which are separated from one another by the electrically insulating layer 30 and thereby electrically isolated from one another.
- the electrical component between the metallic layer 40 and the contact surfaces 220 can have a component height H of 50 ⁇ m.
- the width B of the component can for example be 100 ⁇ m and the length L can be 250 ⁇ m.
- the contact layers 220 can each have a length L1 of 50 ⁇ m and the electrically insulating layer 30 can have a length L2 of 150 ⁇ m.
- the Figures 2A to 2F show an embodiment of a manufacturing method for manufacturing an electrical component that can be used, for example, to protect against electrostatic discharge or as a sensor.
- a ceramic semiconducting base body 10 is provided with a surface O10 and a side surface S10a opposite the surface O10, a metallic layer 40 being contained within the base body.
- the metallic layer 40 arranged within the base body 10 can be interrupted at at least two points U1, U2.
- the sections of the metallic layer 40 arranged on both sides of the locations U1 and U2 belong to other components.
- the metallic layer 40 is arranged approximately parallel to the surface O10 or the side surface S10a of the base body in the interior of the base body.
- the base body 10 with the metallic layer 40 contained therein can be designed as a wafer.
- the manufacturing step shown in the manufacturing process involves lamination, stacking and pressing of the base body 10.
- the wafer or base body 10 is structured on the side surface S10a with at least two metallic layers 210, which each form part of the contacts 21 and 22 of the electrical component.
- the metallic layers 210 are arranged separated from one another at a distance on the side surface S10a of the base body.
- a thin layer of a material made of silver can be applied to sections of the side surface S10a that are spaced apart from one another.
- the at least two metallic layers 210 are arranged on the side surface S10a of the base body 10 such that an area B1 and an area B2 of the side surface S10a of the base body 10 are uncovered by the at least two further metallic layers.
- the areas B1 and B2 are arranged in projection below the locations U1 and U2.
- metallic layers 210 are arranged, which belong to other components.
- the metallic layers 210 form a passivation layer for the underlying material of the base body.
- FIG. 11 shows a further production step which comprises the application of a passivation to a section of the side surface S10a between the metallic layers 210.
- An electrically insulating layer 30, for example made of a material made of glass, can be applied as a passivation layer between the metallic layers 210 of the contacts 21 and 22.
- the electrically insulating layer 30 can directly are arranged on a section of the side surface S10a of the base body 10 between the spaced-apart metallic layers 210.
- the passivation layer 30 can also be applied to partial sections of the metallic layer 210.
- the areas B1 and B2 remain uncovered by passivation.
- the contacts 21 and 22 are completed in that the contact layers 220 are applied to the metallic layers 210.
- a material which comprises nickel and / or gold, for example can be applied to the metallic layer 210.
- a partial layer 221 that contains nickel can first be applied, and then a partial layer 222 that contains gold can be applied to the partial layer 221.
- the application of the contact layers 220 to the metallic layers 210 can take place electrolessly by a chemical process.
- the material of the base body is etched at the non-passivated areas B1 and B2 while the contact layers 220 are being applied.
- a trench G is etched into the base body. The etching takes place, for example, anisotropically.
- the chemical process of applying the contact layers 210 removes the material of the base body down to a surface OG of the trench.
- the material of the base body 10 can be removed so far in the areas B1 and B2 that the surface of the trench between the metallic layer 210 and the metallic layer 40 lies. Etching of the material of the base body is prevented under a region B0 of the side surface S10a, which is covered by the metallic layers 210, which act as passivation layers, and the electrically insulating layer 30.
- the material of the base body is also etched on the non-passivated surface O10 in the direction of the metallic layer 40.
- the material of the base body present between the surface O10 and the metallic layer 40 represents a sacrificial layer which is removed during the chemical process of applying the contact layers starting from the surface O10 up to a surface O10 '. If the area between the original surface O10 and the metallic layer 40 represents the initial thickness of the sacrificial layer, the surface O10 ′ of the sacrificial layer can after exposure to the chemical process for applying the contact areas 220 between the original surface O10 of the sacrificial layer and the metallic layer 40 lie. The layer thickness of the base body above the metallic layer 40 thus decreases further during the chemical process for applying the contact layer 220.
- Figure 2F shows the separation of the electrical component 1 from the wafer 10 as a further production step.
- the trenches already formed in the chemical process of applying the contact surfaces 220 in the areas B1 and B2 can be further etched in a further etching process, which for example takes place anisotropically, until the material of the base body under the interruptions U1 and U2 of the metallic layer 40 has been completely removed.
- the material of the base body can now be at least to the metallic layer 40 can be removed.
- the material of the ceramic semiconducting base body which is still present above the metallic layer 40 and which forms the sacrificial layer can be etched away down to the metallic layer 40.
- the metallic layer 40 acts as an etch stop layer, so that the underlying material of the base body is no longer etched.
- the components can thus be separated from the wafer assembly. In addition to the etching, the separation can alternatively take place by breaking the individual components out of the wafer assembly.
- FIG. 3A shows a further embodiment 2 of the electrical component, which can be used, for example, for protection against electrostatic discharge or as a sensor, in a transverse view.
- the electrostatic component comprises a ceramic semiconducting base body 10, which has a surface O10 and a side surface S10a opposite the surface O10.
- a metallic layer 40 is provided in the interior of the material of the ceramic semiconducting base body 10.
- the metallic layer 40 can comprise a material made of silver, for example.
- At least two contacts 21 and 22 are arranged at a distance from one another on the side surface S10a of the ceramic semiconducting base body 10.
- Each of the contacts 21 and 22 comprises a metallic layer 210 and a contact layer 220.
- the metallic layer 210 of the respective contact is arranged directly on the side surface S10a of the base body and can contain a material made of silver, for example.
- the respective contact layer 220 of each of the contacts is arranged on the respective metallic layer 210.
- the contact layer 220 can have a material made of nickel and / or gold, for example.
- the contact layer 220 can for example have a partial layer 221 which is arranged on the metallic layer 210 of the respective contact.
- a further sub-layer 222 of the contact layer 220 can be arranged on the sub-layer 221.
- the sub-layer 221 can for example contain a material made of nickel and the sub-layer 222 can contain a material made of gold.
- An electrically insulating layer 30 is provided as passivation as shown in the variant of the electrical component shown.
- the electrically insulating layer 30 can be arranged on a section of the side surface S10a between the metallic layers 210.
- the passivation layer 30 is designed in such a way that both the metallic layer 210 and the contact layer 220 of the respective contacts 21 and 22 are electrically isolated from one another.
- Figure 3B shows a top view of the in Figure 3A The illustrated embodiment of the electrical component 2.
- the contacts 21 and 22, in particular the contact layers 220 of the respective contacts 21 and 22, are arranged on the underside of the electrical component and are electrically isolated from one another by the electrically insulating layer 30.
- the electrical component 2 shown can be implemented, for example, with a component height H of 50 ⁇ m measured between the surface O10 and the contact layers 220.
- the width B of the component can be 100 ⁇ m and the length L can be 250 ⁇ m.
- the contacts 21 and 22 can each have a length L1 of 50 ⁇ m and the electrically insulating layer 30 can have a length L2 of 150 ⁇ m.
- the component according to embodiment 2 can be produced, for example, by in the last production step the Figure 2E the sacrificial layer of the base body 10 arranged over the metallic layer 40 is not completely removed down to the metallic layer 40.
- Figure 4A shows a further embodiment 3 of the electrical component, which can be used, for example, for protection against electrostatic discharge or as a sensor, in a transverse view. Similar to the in Figure 1 In the embodiment shown, the electrical component has a ceramic semiconducting base body 10. At least two contacts are arranged at a distance from one another on a side surface S10a of the base body 10. The in Figure 4A The embodiment shown, the electrical component is designed as an array with more than two contacts. The component can have four contacts 21, 22, 23 and 24, for example. At the in Figure 4A Only the contacts 21 and 22 are visible in the transverse view shown.
- Each of the contacts 21 and 22 has a metallic layer 210, for example a layer of silver, which are arranged on the side surface S10a at a distance from one another. Furthermore, the contacts each have a contact layer 220 which is arranged on the respective metallic layer 210 of the contacts.
- the contact layer 220 can comprise a material made of nickel and / or gold.
- the contact layer 220 can have a partial layer 221 and a partial layer 222, for example.
- the partial layer 221 is arranged directly on the metallic layer 210 of the respective contact.
- the sub-layer 222 is arranged on the sub-layer 221 of the respective contact.
- the sub-layer 221 can for example contain a material made of nickel and the sub-layer 222 can contain a material made of gold.
- An electrically insulating layer 30 is arranged between the two contacts 21 and 22, by means of which the contacts 21 and 22 and thus the respective metallic layer 210 and the respective contact layer 220 of the contacts are electrically insulated from one another.
- the electrically insulating layer 30 can, for example, be arranged directly on a section of the side surface S10a of the base body 10 between the metallic layers 210.
- the electrically insulating layer represents a passivation layer and can for example comprise a material made of glass.
- Figure 4B shows the in Figure 4A Embodiment 3 of the electrical component shown in a plan view of the contacts 21, 22, 23 and 24 and the electrically insulating layer 30. As in FIG Figure 4B As shown, the contacts 21, 22, 23 and 24 are separated from one another with a high resistance or electrically insulated from one another by the electrically insulating layer 30 arranged therebetween.
- the electrical component 3 between the metallic layer 40 and the contact surfaces 220 have a component height H of 50 ⁇ m.
- embodiment 3 of the electrical component has a square base area.
- the electrical component can have a width B and a length L of 250 ⁇ m, for example.
- the contacts can each have a width B1 of 100 ⁇ m and the electrically insulating layer a width B2 of 50 ⁇ m.
- the contacts can each have a length L1 of 50 ⁇ m and the electrically insulating layer can have a length L2 of 150 ⁇ m.
- FIG. 1 shows embodiment 1 of the electrical component in the form of a passivated ceramic chip which has the base body 10, the contacts 21 and 22, the electrically insulating layer 30 arranged between them and the further metallic layer 40.
- an ESD component with a multilayer varistor or a component that can be used as a sensor with a multilayer NTC (Negative Temperature Coefficient) resistor can be implemented.
- Figure 5B shows a realization of the component as a varistor, so that the component can be used, for example, as an ESD protective component.
- the base body 10 of the component contains, for example, a material made of zinc oxide and praseodymium, for example ZnO (Pr).
- ZnO zinc oxide doped with praseodymium
- a material made of zinc oxide and bismuth, for example ZnO (Bi) can also be used.
- the contacts 21 and 22 each form a connection for applying a reference potential, for example the ground potential.
- the metallic layer 40 has the function of a current-carrying electrode during production during later operation of the component.
- the ceramic semiconducting base body forms a voltage-dependent resistor R1 between the current-carrying electrode 40 and the contact 21. Between the current-carrying electrode in the form of the metallic layer 40 and the contact 22, the ceramic semiconducting base body 10 forms a further voltage-dependent resistor R2.
- Figure 5C shows an equivalent circuit diagram of the component when the material of the base body is a material with a negative Temperature coefficient, for example an NTC material, is used.
- the component can be used as a ceramic sensor.
- the base body 10 forms a temperature-dependent resistor R3 and R4 between the contacts 21 and 22 and the metallic layer 40.
- the contacts 21 and 22 can be used as connections for applying a reference potential, for example the ground potential.
- the metallic layer 40 has the function of a current-carrying electrode when the component is in operation. Between the metallic layer 40 and the contact 21, the ceramic semiconducting base body 10 forms the temperature-dependent resistor R3. Between the metallic layer 40 and the contact 22, the ceramic semiconducting base body 10 forms the further temperature-dependent resistor R4.
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Description
Die Erfindung betrifft ein Verfahren zum Herstellen eines elektrischen Bauelements, das beispielsweise zu einem Schutz vor elektrostatischer Entladung oder als ein Sensor einsetzbar ist, und ein durch das Verfahren hergestelltes elektrisches Bauelement.The invention relates to a method for producing an electrical component, which can be used, for example, for protection against electrostatic discharge or as a sensor, and an electrical component produced by the method.
Elektronische Schaltungen, die im Allgemeinen bei niedrigen Versorgungs- und Signalspannungen betrieben werden, können beim Auftreten einer hohen Spannung, beispielsweise einer elektrostatischen Überspannung, an den spannungszuführenden Kontaktanschlüssen zerstört werden. Zum Schutz der empfindlichen Schaltungskomponenten vor einer derartigen elektrischen Überspannung können Schutzbauelemente zum Schutz vor elektrostatischer Entladung an die spannungszuführenden Kontaktanschlüsse angeschlossen werden, durch die hohe elektrostatische Spannungen zu einem Bezugspotential, beispielsweise einem Massepotential abgeleitet werden können.Electronic circuits, which are generally operated at low supply and signal voltages, can be destroyed if a high voltage occurs, for example an electrostatic overvoltage, at the voltage-supplying contact connections. To protect the sensitive circuit components from such an electrical overvoltage, protective components for protection against electrostatic discharge can be connected to the voltage-supplying contact connections, through which high electrostatic voltages can be diverted to a reference potential, for example a ground potential.
Als Schutzschaltungen vor elektrostatischer Entladung können beispielsweise Vielschichtvaristoren in SMD(Surface Mounted Device)-Technik verwendet werden. Für Integrationszwecke in eine Leiterplatte oder in ein LED(Light Emitting Diode)-Gehäuse werden ESD(Electro-Static-Discharge)-Schutzbauelemente benötigt, die möglichst dünn sind. In Bezug auf die Bauteilhöhe beziehungsweise Schichtdicke stößt die Herstellung von SMD-Vielschichtvaristoren bislang allerdings auf fertigungstechnische Grenzen.For example, multilayer varistors in SMD (Surface Mounted Device) technology can be used as protective circuits against electrostatic discharge. For integration purposes in a circuit board or in an LED (Light Emitting Diode) housing, ESD (Electro Static Discharge) protective components are required that are as thin as possible. With regard to the component height or layer thickness, however, the manufacture of SMD multilayer varistors has so far come up against manufacturing limits.
Die Druckschrift
Es ist wünschenswert, ein Verfahren zum Herstellen eines elektrischen Bauelements anzugeben, mit dem sich ein Bauelement herstellen lässt, das eine sehr geringe Bauteilhöhe aufweist. Des Weiteren soll ein mit dem Verfahren hergestelltes elektrisches Bauelement angegeben werden.It is desirable to specify a method for producing an electrical component with which a component can be produced which has a very low component height. Furthermore, an electrical component produced using the method is to be specified.
Ein erfindungsgemäßes Verfahren zum Herstellen eines elektrischen Bauelements ist im Patentanspruch 1 angegeben.A method according to the invention for producing an electrical component is specified in claim 1.
Gemäß einer möglichen Ausführungsform umfasst das Verfahren zum Herstellen eines elektrischen Bauelements das Bereitstellen eines keramisch halbleitenden Grundkörpers mit einer Oberfläche und einer der Oberfläche gegenüberliegenden ersten Seitenfläche, wobei innerhalb des Grundkörpers eine metallische Schicht enthalten ist. Auf der Seitenfläche des Grundkörpers werden mindestens zwei weitere metallische Schichten getrennt voneinander angeordnet. Die Anordnung aus dem Grundkörper und den weiteren metallischen Schichten wird gesintert. Eine elektrisch isolierende Schicht wird auf der ersten Seitenfläche des Grundkörpers zwischen den mindestens zwei weiteren metallischen Schichten als Passivierungsschicht angeordnet. Auf den mindestens zwei weiteren metallischen Schichten wird mittels eines chemischen Prozesses jeweils eine Kontaktschicht angeordnet. Durch den chemischen Prozess wird dabei das Material des Grundkörpers ausgehend von der Oberfläche des Grundkörpers bis höchstens zu der innerhalb des Grundkörpers angeordneten metallischen Schicht entfernt.According to one possible embodiment, the method for producing an electrical component comprises providing a ceramic semiconducting base body with a surface and a first side face opposite the surface, a metallic layer being contained within the base body. At least two further metallic layers are arranged separately from one another on the side surface of the base body. The arrangement made up of the base body and the further metallic layers is sintered. An electrically insulating layer is arranged on the first side surface of the base body between the at least two further metallic layers as a passivation layer. A contact layer is arranged on each of the at least two further metallic layers by means of a chemical process. Through the chemical process the material of the base body is removed starting from the surface of the base body up to at most the metallic layer arranged within the base body.
Somit stellt das Material des Grundkörpers, das über der innerhalb des Grundkörpers enthaltenen metallischen Schicht angeordnet ist, eine Opferschicht dar, die bereits während dem chemischen Vorgang des Aufbringens der Kontaktschichten durch die an dem chemischen Prozess beteiligten Säuren/Basen heruntergeätzt wird. Gleichzeitig werden an den unpassivierten Bereichen der ersten Seitenfläche, die von der auf der ersten Seitenfläche aufgebrachten metallischen Schicht und der elektrisch isolierenden Schicht unbedeckt sind, Gräben in das Material des Grundköpers geätzt. Als chemischer Prozess zum Aufbringen der Kontaktschicht kann beispielsweise stromloses Galvanisieren (electroless plating), beispielsweise ein ENIG(electroless Nickel immersion gold), ENEPIG(electroless Nickel, electroless Palladium immersion gold) oder Elektro-Galvanisieren, wobei der Elektrolyth eine ätzende Säure oder Base sein kann, verwendet werden.Thus, the material of the base body, which is arranged over the metallic layer contained within the base body, represents a sacrificial layer that is already etched down during the chemical process of applying the contact layers by the acids / bases involved in the chemical process. At the same time, on the unpassivated areas of the first side surface, the metallic layer applied to the first side surface and the electrically insulating layer are uncovered, trenches are etched into the material of the base body. Electroless plating, for example an ENIG (electroless nickel immersion gold), ENEPIG (electroless nickel, electroless palladium immersion gold) or electroplating, with the electrolyte being a corrosive acid or base, can be used as a chemical process for applying the contact layer can be used.
Während eines nachfolgenden Ätzprozesses kann zum Vereinzeln eines Bauelements aus dem Grundkörper der Graben weiter geätzt werden und die Opferschicht bis zu der innerhalb des Grundkörpers angeordneten metallischen Schicht abgetragen werden. Die metallische Schicht innerhalb des Grundkörpers wirkt als Ätzstoppschicht, so dass das darunter liegende Material des Grundkörpers nicht weiter geätzt wird. Da die innerhalb des Materials des Grundkörpers angeordnete metallische Schicht nahe an der ersten Seitenfläche des Grundkörpers in das Material des Grundkörpers eingebracht werden kann, ermöglicht das Verfahren die Herstellung eines Bauelements mit niedriger Bauhöhe.During a subsequent etching process, in order to isolate a component from the base body, the trench can be further etched and the sacrificial layer can be removed down to the metallic layer arranged within the base body. The metallic layer within the base body acts as an etch stop layer so that the underlying material of the base body is no longer etched. Since the metallic layer arranged within the material of the base body can be introduced into the material of the base body close to the first side surface of the base body, the method enables the production of a component with a low overall height.
Die elektrisch isolierende Schicht zwischen den Kontakten ist eine Passivierungsschicht, die verhindert, dass während dem chemischen Prozess beziehungsweise beim Ätzprozess zum Vereinzeln des Bauelements das unter der elektrisch isolierenden Schicht angeordnete Material des Grundkörpers geätzt wird. Die zwischen den Kontakten angeordnete Passivierungsschicht kann beispielsweise ein Material, das Glas, Siliziumnitrid (Si3N4), Siliziumkarbid (SiC), Aluminiumoxid (Al2O3) oder ein Polymer enthält, aufweisen. Die Kontaktschicht kann als einzelne Schicht aus beispielsweise Silber ausgebildet sein. Die Kontaktschicht kann auch alternativ dazu mehrere Teilschichten, beispielsweise verschiedene Metallabfolgen, wie zum Beispiel Nickel, Palladium, Gold oder Zinn enthalten.The electrically insulating layer between the contacts is a passivation layer which prevents the material of the base body arranged under the electrically insulating layer from being etched during the chemical process or during the etching process for separating the component. The passivation layer arranged between the contacts can, for example, have a material that contains glass, silicon nitride (Si 3 N 4 ), silicon carbide (SiC), aluminum oxide (Al 2 O 3 ) or a polymer. The contact layer can be designed as a single layer made of, for example, silver. As an alternative to this, the contact layer can also have several partial layers, for example different metal sequences, such as nickel, palladium, gold or tin.
Die angegebene Ausführungsform des Verfahrens zum Herstellen eines elektrischen Bauelements ermöglicht insbesondere die Realisierung von ESD-Schutzbauelementen oder keramischen Sensoren mit Bauteilhöhen zwischen einer als Elektrode wirkenden metallischen Schicht und den Kontaktschichten von weniger als 150 µm und typischerweise von ungefähr 50 µm. Dabei kann das elektrische Bauelement kostengünstig hergestellt werden und für die Fertigung von ultradünnen Einzelchips wie auch für Arrays verwendet werden.The specified embodiment of the method for producing an electrical component enables in particular the implementation of ESD protective components or ceramic sensors with component heights between a metallic layer acting as an electrode and the contact layers of less than 150 μm and typically of approximately 50 μm. The electrical component can be produced inexpensively and used for the production of ultra-thin individual chips as well as for arrays.
Erfindungsgemäße, mit dem Verfahren hergestellte elektrische Bauelemente sind in den Patentansprüchen 9 und 10 angegeben.Electrical components according to the invention produced using the method are specified in
Gemäß der Erfindung umfasst ein mit dem Verfahren hergestelltes elektrisches Bauelement einen keramisch halbleitenden Grundkörper mit einer ersten Seitenfläche, auf der mindestens zwei voneinander beabstandete Kontakte angeordnet sind, und einer der ersten Seitenfläche gegenüberliegende zweiten Seitenfläche, auf der eine metallische Schicht angeordnet ist. Jeder der Kontakte weist eine weitere metallische Schicht, die auf der ersten Seitenfläche des Grundkörpers angeordnet ist, und eine Kontaktschicht, die auf der weiteren metallischen Schicht angeordnet ist, auf. Zwischen den mindestens zwei Kontakten ist eine elektrisch isolierende Schicht, durch die die mindestens zwei Kontakte voneinander elektrisch isoliert sind, angeordnet. Das elektrische Bauelement weist zwischen einschließlich der metallischen Schicht und einschließlich der jeweiligen Kontaktschicht der Kontakte eine Bauteilhöhe von höchstens 150 µm und vorzugsweise von 50 µm auf.According to the invention, an electrical component produced by the method comprises a ceramic semiconducting base body with a first side surface on which at least two spaced apart contacts are arranged, and a second side surface opposite the first side surface, on which a metallic layer is arranged. Each of the contacts has a further metallic layer, which is arranged on the first side surface of the base body, and a contact layer, which is arranged on the further metallic layer. An electrically insulating layer, by means of which the at least two contacts are electrically isolated from one another, is arranged between the at least two contacts. The electrical component has a component height of at most 150 μm and preferably of 50 μm between including the metallic layer and including the respective contact layer of the contacts.
Ausführungsformen des Verfahrens zum Herstellen des elektrischen Bauelements sowie Ausführungsformen von mit dem Verfahren herstellbaren elektrischen Bauelementen werden anhand von Figuren nachfolgend beispielhaft erläutert. Es zeigen:
- Figur 1A
- eine Queransicht einer Ausführungsform eines elektrischen Bauelements,
- Figur 1B
- eine Draufsicht auf die Ausführungsform des elektrischen Bauelements,
- Figur 2A
- einen Fertigungsschritt einer Ausführungsform eines Herstellungsverfahrens für ein elektrisches Bauelement,
- Figur 2B
- einen weiteren Fertigungsschritt der Ausführungsform des Herstellungsverfahrens für das elektrische Bauelement,
- Figur 2C
- einen weiteren Fertigungsschritt der Ausführungsform des Herstellungsverfahrens für das elektrische Bauelement,
- Figur 2D
- einen weiteren Fertigungsschritt der Ausführungsform des Herstellungsverfahrens für das elektrische Bauelement,
- Figur 2E
- einen weiteren Fertigungsschritt der Ausführungsform des Herstellungsverfahrens für das elektrische Bauelement,
- Figur 2F
- einen weiteren Fertigungsschritt der Ausführungsform des Herstellungsverfahrens für das elektrische Bauelement,
- Figur 3A
- eine Queransicht einer weiteren Ausführungsform eines elektrischen Bauelements,
- Figur 3B
- eine Draufsicht auf die weitere Ausführungsform des elektrischen Bauelements,
- Figur 4A
- eine Queransicht einer weiteren Ausführungsform des elektrischen Bauelements,
- Figur 4B
- eine Draufsicht auf eine weitere Ausführungsform eines elektrischen Bauelements,
- Figur 5A
- eine Ausführungsform eines elektrischen Bauelements zum Schutz vor elektrostatischer Entladung oder als keramischer Sensor,
- Figur 5B
- eine Ersatzschaltung einer Ausführungsform eines elektrischen Bauelements zum Schutz vor elektrostatischer Entladung,
- Figur 5C
- eine Ersatzschaltung einer Ausführungsform eines elektrischen Bauelements als keramischer Sensor.
- Figure 1A
- a transverse view of an embodiment of an electrical component,
- Figure 1B
- a plan view of the embodiment of the electrical component,
- Figure 2A
- a manufacturing step of an embodiment of a manufacturing method for an electrical component,
- Figure 2B
- a further manufacturing step of the embodiment of the manufacturing method for the electrical component,
- Figure 2C
- a further manufacturing step of the embodiment of the manufacturing method for the electrical component,
- Figure 2D
- a further manufacturing step of the embodiment of the manufacturing method for the electrical component,
- Figure 2E
- a further manufacturing step of the embodiment of the manufacturing method for the electrical component,
- Figure 2F
- a further manufacturing step of the embodiment of the manufacturing method for the electrical component,
- Figure 3A
- a transverse view of a further embodiment of an electrical component,
- Figure 3B
- a plan view of the further embodiment of the electrical component,
- Figure 4A
- a transverse view of a further embodiment of the electrical component,
- Figure 4B
- a plan view of a further embodiment of an electrical component,
- Figure 5A
- an embodiment of an electrical component for protection against electrostatic discharge or as a ceramic sensor,
- Figure 5B
- an equivalent circuit of an embodiment of an electrical component for protection against electrostatic discharge,
- Figure 5C
- an equivalent circuit of an embodiment of an electrical component as a ceramic sensor.
Die metallische Schicht 210 der Kontakte 21 und 22 kann beispielsweise Silber enthalten. Die Kontaktschicht 220 kann beispielsweise ein Material aus Nickel und/oder Gold aufweisen. Beispielsweise kann die jeweilige Kontaktschicht 220 der Kontakte 21 und 22 eine Teilschicht 221 und eine Teilschicht 222 aufweisen. Die Teilschicht 221 kann auf der metallischen Schicht 210 angeordnet sein und die Teilschicht 222 kann auf der Teilschicht 221 angeordnet sein. Die Teilschicht 221 kann beispielsweise ein Material aus Nickel und die Teilschicht 222 kann beispielsweise ein Material aus Gold aufweisen.The
Zwischen den Kontakten 21 und 22 ist auf der Seitenfläche S10a des Grundkörpers 10 eine elektrisch isolierende Schicht 30 angeordnet. Die elektrisch isolierende Schicht 30 ist derart ausgebildet, dass sie sowohl die metallische Schicht 210 der Kontaktanschlüsse 21 und 22 als auch die Kontaktschichten 220 der beiden Kontakte 21 und 22 voneinander trennt. Durch die Schicht 30 sind somit die beiden Kontakte 21 und 22 elektrisch voneinander isoliert. Die elektrisch isolierende Schicht 30 kann beispielsweise ein Material aus Glas enthalten.An electrically insulating
Bei der in den
Die
In einem weiteren in
In einem weiteren Fertigungsschritt, der in
In dem in
Durch den chemischen Prozess zum Aufbringen der Kontaktschichten 220, an dem Säuren beziehungsweise Basen beteiligt sind, wird während des Aufbringens der Kontaktschichten 220 das Material des Grundkörpers an den nicht passivierten Bereichen B1 und B2 geätzt. Dabei wird ausgehend von den nicht passivierten Bereichen B1, B2 an der Seitenfläche S10a des Grundkörpers ein Graben G in den Grundkörper geätzt. Das Ätzen erfolgt beispielsweise anisotrop. Durch den chemischen Prozess des Aufbringens der Kontaktschichten 210 wird das Material des Grundkörpers bis zu einer Oberfläche OG des Grabens entfernt. Das Material des Grundkörpers 10 kann an den Bereichen B1 und B2 so weit entfernt werden, dass die Oberfläche des Grabens zwischen der metallischen Schicht 210 und der metallischen Schicht 40 liegt. Unter einem Bereich B0 der Seitenfläche S10a, der von den als Passivierungsschichten wirkenden metallischen Schichten 210 und der elektrische isolierenden Schicht 30 bedeckt ist, ist das Ätzen des Materials des Grundkörpers verhindert.As a result of the chemical process for applying the contact layers 220, in which acids or bases are involved, the material of the base body is etched at the non-passivated areas B1 and B2 while the contact layers 220 are being applied. Starting from the non-passivated areas B1, B2 on the side surface S10a of the base body, a trench G is etched into the base body. The etching takes place, for example, anisotropically. The chemical process of applying the contact layers 210 removes the material of the base body down to a surface OG of the trench. The material of the
Des Weiteren wird auch das Material des Grundkörpers an der nicht passivierten Oberfläche O10 in Richtung auf die metallische Schicht 40 geätzt. Das zwischen der Oberfläche O10 und der metallischen Schicht 40 vorhandene Material des Grundkörpers stellt eine Opferschicht dar, die während des chemischen Prozesses des Aufbringens der Kontaktschichten ausgehend von der Oberfläche O10 bis zu einer Oberfläche O10' entfernt wird. Wenn der Bereich zwischen der ursprünglichen Oberfläche O10 und der metallischen Schicht 40 die anfängliche Dicke der Opferschicht darstellt, kann die Oberfläche O10' der Opferschicht nach dem Einwirken des chemischen Prozesses zum Aufbringen der Kontaktflächen 220 zwischen der ursprünglichen Oberfläche O10 der Opferschicht und der metallischen Schicht 40 liegen. Somit nimmt die Schichtdicke des Grundkörpers oberhalb der metallischen Schicht 40 während des chemischen Prozesses zum Aufbringen der Kontaktschicht 220 weiter ab.Furthermore, the material of the base body is also etched on the non-passivated surface O10 in the direction of the
Die jeweilige Kontaktschicht 220 eines jeden der Kontakte ist auf der jeweiligen metallischen Schicht 210 angeordnet. Die Kontaktschicht 220 kann beispielsweise ein Material aus Nickel und/oder Gold aufweisen. Die Kontaktschicht 220 kann beispielsweise eine Teilschicht 221 aufweisen, die auf der metallischen Schicht 210 des jeweiligen Kontakts angeordnet ist. Eine weitere Teilschicht 222 der Kontaktschicht 220 kann auf der Teilschicht 221 angeordnet sein. Die Teilschicht 221 kann beispielsweise ein Material aus Nickel und die Teilschicht 222 kann ein Material aus Gold enthalten.The
Zwischen den Kontakten 21 und 22 ist wie bei der in
Das in den
Jeder der Kontakte 21 und 22 weist eine metallische Schicht 210, beispielsweise eine Schicht aus Silber, auf, die auf der Seitenfläche S10a beabstandet zueinander angeordnet sind. Des Weiteren weisen die Kontakte jeweils eine Kontaktschicht 220 auf, die auf der jeweiligen metallischen Schicht 210 der Kontakte angeordnet ist. Die Kontaktschicht 220 kann ein Material aus Nickel und/oder Gold aufweisen. Die Kontaktschicht 220 kann beispielsweise eine Teilschicht 221 und eine Teilschicht 222 aufweisen. Die Teilschicht 221 ist unmittelbar auf der metallischen Schicht 210 des jeweiligen Kontakts angeordnet. Die Teilschicht 222 ist auf der Teilschicht 221 des jeweiligen Kontakts angeordnet. Die Teilschicht 221 kann beispielsweise ein Material aus Nickel und die Teilschicht 222 kann ein Material aus Gold enthalten.Each of the
Zwischen den beiden Kontakten 21 und 22 ist eine elektrisch isolierende Schicht 30 angeordnet, durch die die Kontakte 21 und 22 und somit die jeweilige metallische Schicht 210 und die jeweilige Kontaktschicht 220 der Kontakte elektrisch voneinander isoliert sind. Die elektrisch isolierende Schicht 30 kann beispielsweise unmittelbar auf einem Abschnitt der Seitenfläche S10a des Grundkörpers 10 zwischen den metallischen Schichten 210 angeordnet sein. Die elektrisch isolierende Schicht stellt eine Passivierungsschicht dar und kann beispielsweise ein Material aus Glas aufweisen.An electrically insulating
Bei der in den
- 1, 2, 31, 2, 3
- Ausführungsformen des elektrischen BauelementsEmbodiments of the electrical component
- 1010
- keramisch halbleitender Grundkörperceramic semiconducting body
- 21, 2221, 22
- Kontaktecontacts
- 3030th
- elektrisch isolierende Schichtelectrically insulating layer
- 4040
- metallische Schichtmetallic layer
- 210210
- metallische Schichtmetallic layer
- 220220
- KontaktschichtContact layer
- 221, 222221, 222
- Teilschichten der KontaktschichtPartial layers of the contact layer
- R1, R2R1, R2
- spannungsabhängige Widerständevoltage-dependent resistances
- R3, R4R3, R4
- temperaturabhängige Widerständetemperature-dependent resistances
Claims (15)
- Method for producing an electrical component (1), comprising:- providing a ceramic semiconducting base body (10) having a surface (O10) and a first side area (S10a) lying opposite the surface (O10), wherein a metallic layer (40) is contained within the base body,- arranging at least two further metallic layers (210) separately from one another on the side area (S10a) of the base body,- sintering the arrangement composed of the base body (10) and the further metallic layers (210),- arranging an electrically insulating layer (30) on the first side area (S10a) between the at least two further metallic layers (210),- arranging a respective contact layer (220) on the at least two further metallic layers (210) by means of a chemical process, characterized in that, during the arrangement of the contact layers (220), the material of the base body (10) is removed by the chemical process proceeding from the surface (O10) of the base body (10), specifically at most as far as the metallic layer (40) arranged within the base body.
- Method according to Claim 1,- wherein the metallic layer (40) arranged within the base body (10) is interrupted at at least two locations (U1, U2),- wherein the at least two further metallic layers (210) are arranged on the first side area (S10a) of the base body (10) in such a way that a first and a second region (B1, B2) of the first side area (S10a) of the base body are not covered by the at least two further metallic layers (210),- wherein the material of the base body (10) is etched at the regions (B1, B2) of the first side area (S10a) of the base body (10) by the chemical process.
- Method according to Claim 2,
wherein the electrical component (1, 2, 3) is singulated from the material of the base body (10) by an etching process succeeding the chemical process. - Method according to any of Claims 1 to 3,
wherein the material of the base body is prevented from being etched at a region (B0) of the base body (10) which is covered by the at least two further metallic layers (210) and by the electrically insulating layer (30). - Method according to Claim 4.
wherein the metallic layer (40) is arranged within the base body in such a way that the electrical component (1, 2, 3) between the metallic layer (40) arranged within the base body (10) and the contact layers (220) has a thickness of at most 150 µm and preferably of 50 µm. - Method according to any of Claims 1 to 5,
wherein the ceramic semiconducting base body (10) contains a material composed of zinc oxide and praseodymium or a material having a negative temperature coefficient. - Method according to any of Claims 1 to 6,
wherein the electrically insulating layer (30) contains a material composed of glass or silicon nitride or silicon carbide or aluminium oxide or a polymer and the metallic layer (40) and the further metallic layers (210) contain a material composed of silver. - Method according to any of Claims 1 to 7,
wherein the contact layer (220) contains a material composed of nickel and/or gold and/or palladium and/or tin and/or silver. - Electrical component (1, 3) comprising:- a ceramic semiconducting base body (10) having a first side area (S10a), on which at least two contacts (21, 22) spaced apart from one another are arranged, and a second side area (S10b), which lies opposite the first side area (S10a) and on which a metallic layer (40) is arranged,- wherein each of the contacts (21, 22) has a further metallic layer (210), which is arranged on the first side area (S10a) of the base body, and a contact layer (220), which is arranged on the further metallic layer (210),- wherein an electrically insulating layer (30) is arranged between the at least two contacts (21, 22), the at least two contacts (21, 22) being electrically insulated from one another by said electrically insulating layer,- wherein the metallic layer (40) is thinner than the ceramic semiconducting base body (10),- characterized in that the electrical component between the metallic layer (40) and the respective contact layer (220) of the contacts (21, 22), inclusive, has a component height (H) of at most 150 µm and preferably of 50 µm.
- Electrical component (2) comprising:- a ceramic semiconducting base body (10) having a surface (O10) and a first side area (S10a), which lies opposite the surface (O10) and on which at least two contacts (21, 22) spaced apart from one another are arranged,- wherein a metallic layer (40) is arranged within the base body (10),- wherein each of the contacts (21, 22) has a further metallic layer (210), which is arranged on the first side area (S10a) of the base body, and a contact layer (220), which is arranged on the further metallic layer (210),- wherein an electrically insulating layer (30) is arranged between the at least two contacts (21, 22), the at least two contacts (21, 22) being electrically insulated from one another by said electrically insulating layer,- characterized in that the electrical component between the surface (O10) and the respective contact layer (220) of the contacts (21, 22), inclusive, has a component height (H) of at most 150 µm and preferably of 50 µm.
- Electrical component according to either of Claims 9 and 10,
wherein the ceramic semiconducting base body (10) contains a material composed of zinc oxide and praseodymium or a material having a negative temperature coefficient. - Electrical component according to any of Claims 9 to 11,
wherein the electrically insulating layer (30) is arranged on the first side area (S10a) of the base body (10) . - Electrical component according to any of Claims 9 to 12,
wherein the electrically insulating layer (30) contains a material composed of glass or silicon nitride or silicon carbide or aluminium oxide or a polymer. - Electrical component according to any of Claims 9 to 13,
wherein at least one of the metallic and of the further metallic layers (40, 210) contains a material composed of silver. - Electrical component according to any of Claims 9 to 14,
wherein the contact layer (220) contains a material composed of nickel and/or gold and/or palladium and/or tin and/or silver.
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| JP6930586B2 (en) * | 2017-05-23 | 2021-09-01 | 株式会社村田製作所 | Manufacturing method of electronic parts |
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| CN116741482A (en) * | 2022-03-01 | 2023-09-12 | 国巨电子(中国)有限公司 | Current sensing resistor and method of manufacturing same |
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| EP2737497A1 (en) | 2014-06-04 |
| TWI562294B (en) | 2016-12-11 |
| US20140225710A1 (en) | 2014-08-14 |
| WO2013017531A1 (en) | 2013-02-07 |
| DE102011109007A1 (en) | 2013-01-31 |
| TW201308528A (en) | 2013-02-16 |
| JP5813227B2 (en) | 2015-11-17 |
| US9230719B2 (en) | 2016-01-05 |
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