CN120187298A - Pesticide composition comprising a compound containing a 1,2,4-triazolyl group and a 4-oxothiazolyl group and another pesticide - Google Patents

Pesticide composition comprising a compound containing a 1,2,4-triazolyl group and a 4-oxothiazolyl group and another pesticide Download PDF

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CN120187298A
CN120187298A CN202380077731.3A CN202380077731A CN120187298A CN 120187298 A CN120187298 A CN 120187298A CN 202380077731 A CN202380077731 A CN 202380077731A CN 120187298 A CN120187298 A CN 120187298A
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mixed
composition according
compatibilising
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N·C·詹皮特罗
S·奥尼尔
G·沃森
A·加斯帕
D·科克
D·鲁莱
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Kedihua Agricultural Technology Co ltd
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01C—PLANTING; SOWING; FERTILISING
    • A01C1/00—Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
    • A01C1/06—Coating or dressing seed
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G7/00—Botany in general
    • A01G7/06—Treatment of growing trees or plants, e.g. for preventing decay of wood, for tingeing flowers or wood, for prolonging the life of plants
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P13/00—Herbicides; Algicides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P5/00—Nematocides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P7/00—Arthropodicides
    • A01P7/02—Acaricides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P7/00—Arthropodicides
    • A01P7/04—Insecticides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P9/00—Molluscicides

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  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Insects & Arthropods (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Forests & Forestry (AREA)
  • Ecology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Botany (AREA)
  • Soil Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pretreatment Of Seeds And Plants (AREA)
  • Catching Or Destruction (AREA)

Abstract

本公开涉及以下的领域：对节肢动物门、软体动物门和线虫动物门中的有害生物具有杀有害生物效用的分子，生产此类分子的方法，在此类方法中使用的中间体，以及使用此类杀有害生物组合物对抗此类有害生物的方法。这些杀有害生物组合物可以例如用作杀螨剂、杀昆虫剂、杀螨药、杀软体动物剂、和杀线虫剂。The present disclosure relates to the field of molecules having pesticidal effects on harmful organisms in the phyla Arthropoda, Mollusca and Nematoda, methods of producing such molecules, intermediates used in such methods, and methods of using such pesticidal compositions to combat such harmful organisms. These pesticidal compositions can be used, for example, as acaricides, insecticides, acaricides, molluscicides, and nematicides.

Description

Pesticidal composition comprising a compound containing 1,2, 4-triazolyl and 4-oxothiazolyl and another pesticide
Background
The present disclosure relates to the field of molecules having pesticidal utility against pests in arthropoda, mollusca and nematoda, methods of producing such molecules, intermediates used in such methods, and methods of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, acaricides, molluscicides, and nematicides.
Each year, insects, plant pathogens and weeds destroy more than 40% of all food produced. This loss still occurs despite the application of pesticides and the use of a wide variety of non-chemical control measures (such as rotation) and biological control measures. If only a portion of this food can be saved, it can be used to keep up with more than 30 million malnourished people in the world (Pimental, d., pest Control in World Agriculture [ pest control in world agriculture ], agricultural Sciences [ agricultural science ] -volume II, 2009).
Plant parasitic nematodes are one of the most common pests and are generally one of the most cryptic and expensive pests. It is estimated that losses attributable to nematodes range from about 9% in developed countries to about 15% in undeveloped countries. However, investigation of various crops in 35 states in the united states has shown up to 25% loss from nematodes (Nicol et al, current Nematode Threats to World Agriculture [ current threat to nematodes in world agriculture ], pages 21-43, 2011 of Genomic and Molecular Genetics of Plant-Nematode Interactions [ genomics and molecular genetics of plant-nematode interactions ].
Notably, gastropods (slugs and snails) are pests of lower economic importance than other arthropods or nematodes, but in some places they can drastically reduce yield, severely impact the quality of the harvested product, and transmit human, animal, and plant diseases. Although only a few tens of gastropod species are serious regional pests, a few species are important pests on a global scale. In particular, gastropods affect a wide variety of agricultural and horticultural crops such as arable land, pastures (pastoral), and fiber crops, vegetables, shrubs and tree fruits, herbs, and ornamental plants (Speiser, b., molluscicides [ molluscicide ], encyclopedia of PEST MANAGEMENT [ Encyclopedia of pest management ], chapter 219, pages 506-508, 2002).
Termites cause damage to all types of private and public structures and agricultural and forestry resources. Termites were estimated to cause losses of over 500 billion dollars annually in the world (Korb, j., termites [ termites ], current Biology [ contemporary Biology ], volume 17, 23, 2007).
Thus, for many reasons, including those described above, the need for high (estimated to be about 2.86 million dollars per pesticide in 2014), time consuming (about 11.3 years on average per pesticide), and difficult to develop new pesticides persists for (Phillips McDougall,The Cost of New Agrochemical Product Discovery,Development and Registration in 1995,2000,2005-8and 2010-2014.R&D expenditure in 2014and expectations for2019[1995, 2000, 2005-8, and 2010-2014, the discovery, development, and registration costs of new agrochemical products. Development expenditure in 2014 and expectations in 2019), 2016).
Definition of the definition
The examples provided herein are not exhaustive and should not be construed as limiting. It will be appreciated that substituents should comply with chemical bonding rules and steric compatibility constraints with respect to the particular molecule to which they are attached. These definitions are for the purposes of this disclosure only.
The term "active substance" or "active ingredient" means a group of pesticides each of which is considered to be an "active substance" or "active ingredient" -selected from the group AIGA-1, AIGA-2, or AI-1 or AI-2. These generic names can be found in a number of locations, for example, "Compendium of Pesticide Common Names" by the uk crop production committee (universal pesticide outline), the web site being https:// pesticidecompensatum. Bcpc/. These active ingredients may be used in admixture with the molecules disclosed below for a variety of reasons.
The term "AIGA-1" means a preferred set of mixed formulations selected from the group consisting of abamectin (abamectin), acephate (acephate), methoquinone (acequinocyl), acetamiprid (acetamiprid), flumethrin (acrinathrin), acynonapyr, pyriproxyfen (afidopyropen), carbofuran (alanycarb), aldicarb (aldicarb), and combinations thereof to form a mixture having multiple agricultural functions, Allyl pyrethrin (allethrin), alpha-cypermethrin (alpha-CYPERMETHRIN), aminopyralid (aminopyralid), amitraz (amitraz), azadirachtin (azadirachtin), picoline (azamethiphos), phoxim-ethyl (azinphos-methyl), phoxim-methyl (azinphos-methyl), azocyclotin (azocyclotin), azoxystrobin (azoxystrobin), bendiocarb (bendiocarb), Carbosulfan (benfuracarb), bensultap (bensultap), bensultap (benzoximate), bensultap (benzpyrimoxan), beta-cyhalothrin (beta-cyfluthrin), beta-cyhalothrin (beta-CYPERMETHRIN), bifenazate (bifenazate), bifenthrin (bifenthrin), bioallethrin (bioallethrin), biobifenthrin (bioresmethrin), bistrifluron (bistrifluron), Brofenoxaprop (Brooflanilide), fenazate (bromopropylate), buprofezin (buprofezin), carbofuran (butocarboxim), carbofuran (butoxycarboxim), thiotepa (cadusafos), carbaryl (carbaryl), carbofuran (carbofuran), carbosulfan (carbosulfan), carbosulfan (carboxin), cartap hydrochloride (cartap hydrochloride), Mite killing mew (chinomethionat), chlorantraniliprole (chlorantraniliprole), chlordane (chlordane), chlorpyrifos (chlortetroxyfos), chlorfenapyr (chlorfenapyr), chlorpyrifos (chlorfenvinphos), chlorfluazuron (chlorfluazuron), chlorpyrifos (chlormephos), chlorpyrifos (chlorpyrifos), chlorpyrifos methyl (chlorpyrifos-methyl), Cyclopyralid (chromafenozide), clofentezine (clofentezine), clopyralid (clopyralid), cloquintocet-mexyl (cloquintocet), clothianidin (clothianidin), copper hydroxide, coumaphos (coumaphos), cartap (cyanophos), cyantraniliprole (cyantraniliprole), cycloxapride (cyclaniliprole), cyclo Ding Fulun (cyclobutrifluram), fenpropathrin (cycloprothrin), Cycloxaprid (cycloxaprid), cyhalothrin (cyenopyrafen), cyflumetofen (cyflumetofen), cyhalothrin (cyfluthrin), cyhalothrin (cyhalothrin), tricyclotin (cyhexatin), cymoxanil (cymoxanil), cypermethrin (CYPERMETHRIN), fenpropathrin (cyphenothrin), cyflufenamid (cyproflanilide), cyromazine (cyromazine), d-cis-trans-allyl pyrethrin (d-cis-TRANS ALLETHRIN), DDVP, deltamethrin (deltaametrin), endo-S-methyl (demeton-S-methyl), diafenthiuron (diafenthiuron), diazinon (diazinon), dichlorvos (dichlorvos), chlorfenapyr (dicofos), parafos (dicrotophos), difenoconazole (difenoconazole), flufenzine (diflovidazin), difluniuron (difengzuron), dimethoate (dimethoate), Methylvinphos (dimethyinphos), oxazamate (dimpropyridaz), dinotefuran (dinotefuran), ethiprole (disulfoton), DNOC, d-trans-allyl pyrethrin (d-TRANS ALLETHRIN), emamectin benzoate (emamectin benzoate), methoprene (empenthrin), endosulfan (endosulfan), EPN, fenvalerate (ESFENVALERATE), ethaboxam (ethaboxam), Ethionine (ethiofencarb), ethion (ethion), ethiprole (ethiprole), methophos (ethoprophos), ethofenprox (etofenprox), famoxadone (famoxadone), amisulfos (famphur), fenphos (fenamiphos), fenazaquin (fenazaquin), fenbuconazole (fenbuconazole), fenbucin (fenbutatin oxide), fenitrothion (fenitrothion), Fenbuconazole dity Ti is (fenmezoditiaz), fenobucarb (fenobucarb), fenoxycarb (fenoxycarb), fenpropathrin (fenpropathrin), fenpyroximate (fenpyroximate), fenthion (fenthion), fenvalerate (fenvalerate), fipronil (fipronil), flazasulfuron (flazasulfuron), flonicamid (flonicamid), florasulam (florasulam), pyriminostrobin (fluacrypyrim), Triflufenamid (fluazaindolizine), flubendiamide (flubendiamide), epothilone (flucycloxuron), flucythrinate (flucythrinate), fludioxonil (flucycloxail), fluthiamethoxam sulfone (fluensulfone), flufenoxuron (flufenoxuron), flumethrin (flumethrin), flumioxazin (flumioxazin), fluoxastrobin (fluopyram), fluoxastrobin (fluoxapiprolin), fluxapyroxad (fluoxapiprolin), Fluoxastrobin (fluoxastrobin), fluoxastrobin (flupyradifurone), flubendiamide (flupyrimin), fluoxastrobin (fluroxypyr), fluxastrobin (fluxametamide), fluxapyroxad (fluxapyroxad), valicarb (formetanate), fosthiazate (fosthiazate), furbenfuracarb (furazolidone), gamma-cyhalothrin (gamma-cyhalothrin), glyphosate (glyphosate), and, Flucopyridine ester (halauxifen), benzyl fenpyr (halfenprox), chlorfenozide (halofenozide), heptenophos (heptenophos), hexaflumuron (hexaflumuron), hexythiazox (hexythiazox), triadimefon (hydramethylnon), hydroprene (hydroprene), imazethapyr (imazamox), imazapyr (imazapyr), imidazophos (imaxyfos), imidacloprid (imidacloprid), imazethapyr (imazapyr), Imazalil (imiprothrin), indazapyroxamet, indoxacarb (indoxacarb), indenopyrazine (inpyrfluxam), ipconazole (ipconazole), isoxazolidinamide (isocycloseram), iso Liu Lin (isofenophos), iproflumidin (isoflucypram), isoprocarb (isoprocarb), isoxazolephosphine (isoxathion), kadethrin (kadethrin), nitenpyram (kinoprene), Lambda-cyhalothrin (lambda-cyhalothrin), lepimectin (lepimectin), lufenuron (lufenuron), malathion (malathion), mancozeb (mannozeb), MCPA, cyaphphos (mecarbam), mefenoxam (mefenoxam), metaflumizone (metaflumizone), metalaxyl (metaxaxyl), metconazole (metaconazole), methamidophos (methamidophos), urotropin (methenamine), Methidathion (methidathion), methiocarb (methiocarb), methomyl (methomyl), methoprene (methoprene), methoprene (methoxychlor), methoxyfenozide (methoxyfenozide), methiocarb (metolcarb), metsulfuron (metsulfuron), methidathion (mevinphos), milbemycins (milbecin), monocrotophos (monocrotophos), myclobutanil (myclobutanil), Dibromophosphorus (naled), nicosulfuron (nicosulfuron), chloropyridine (nitrapyrin), novaluron (novaluron), polyfluoro urea (noviflumuron), omethoate (omethoate), oxamyl (oxamyl), oxathiapiprolin (oxathiapiprolin), oxazolesulfonyl (oxazosulfyl), phoxim (oxydemeton-methyl), parathion (parathion), methyl parathion (parathion-methyl), Penflufen, penthiopyrad penthiopyrad permethrin (permethrin) phenothrin, phenthrin, phenthoate (phenthoate), fenitrothion (phorate) phosphorus (phosalone), phosphorus iminothiolate (phosmet), phosphorus amine (phosphamidon), phoxim (phoxim), piprazole (picarbutrazox), picloram, picoxystrobin (picoxystrobin), Pinoxaden, triazamate (pirimicarb), pirimiphos (pirimiphos-methyl), prallethrin (prallethrin), profenofos (profenofos), propargite (propargite), amisulpride (propetamphos), propiconazole (propiconazole), propoxur (propoxur), penoxsulam (propyzamide), prothioconazole (prothioconazole), profenofos (prothiofos), spiflumetofen, diflunisal (pyflubumide), penoxsulam (pyrromezine), pyraclonil (pyraclofos), pyraclostrobin (pyraclostrobin), pyrethrum (pyrethrum), pyridaben (pyridaben), pyridalyl (pyridalyl), pyridaphethione (pyridaphenthion), praziquantel (pyrifluquinazon), pyriminofen (pyrimidifen), pyriproxyfen (pyriproxyfen), pyriproxyfen (Pyrethrin), Rochemical sulfone (pyroxasulfone), quetiapine (quinalphos), methoprene (resmethrin), rimsulfuron (rimsulfuron), rotenone (rotenone), cyproconazole (sedaxane), silafluofen (silafluofen), dispirospiram (spidoxamat), spinetoram (spinetoram), spinosad (spinosad), spirodiclofen (spirobudifen), spirodiclofen (spirodiclofen), Spiromesifen (spiromesifen), methoprene (spiropidion), spirotetramat (spirotetramat), sulfluramid (sulfluramid), fenitrothion (sulfotep), sulfoxaflor (sulfoxaflor), tau-fluvalinate (tau-fluvalinate), tebuconazole (tebuconazole), tebufenozide (tebufenozide), tebufenpyrad (tebufenpyrad), butyl pyrifos (tebupirimfos), Flurone (teflubenzuron), tefluthrin (tefluthrin), dithiophosphate (temefos), terbutafos (terbufos), dicamba (tetrachlorvinphos), chlorfenapyr (tetradifon), tetramethrin (TETRAMETHRIN), flucyantraniliprole (tetraniliprole), theta-cypermethrin (theta-CYPERMETHRIN), thiabendazole (thiabendazole), thiamethoxam (thiamethoxam), Thiocyclam, thiodicarb (thiodicarb) permanent effect Wei (thiofanox) methyl ethyl phosphate (thiometon), bisultap (thiosultap-sodium), thiram (thiram) sulfenamide (tiorantraniliprole), thiamethoxam sulfone (tioxazafen), tolfenpyrad (tolfenpyrad), trifloxystrobin (tralkoxydim), tetrabromothrin (tralomethrin), transfluthrin (transfluthrin), Triazophos (triazamate), triazophos (triazophos), trichlorfon (trichlorfon), triclopyr (triclopyr), trifloxystrobin (triflumizopyrim), trifluralin (triflumuron), triamcinolone (trimethacarb), triamcinolone (vamidothion), XMC, methoprene (xylylcarb), zeta-cypermethrin (zeta-CYPERMETHRIN), And 2,4-D. for the avoidance of doubt, each of these pesticides is an active ingredient.
The term "AIGA-2" means a preferred set of mixed compatibilities to form a mixture that expands the use of the pesticidal composition and has multiple agricultural functions including abamectin, acetamiprid, benomyl, bifenthrin, chlorantraniliprole, chlorfenapyr, cyantraniliprole, cycloparaffin Ding Fulun, oxazachlor, fipronil, flonicamid, trifloxysulfuron, fluxapyroxad, imidacloprid, indoxacarb, isoxazolamide, lambda-cyhalothrin, methoxyfenozide, parvom, pyriproxyfen, dispirox, spinetoram, spinosad, methylpiperidine ethyl, spirotetramat, sulfoxaflor, thiamethoxam, and trifluopyrim.
A molecule designated N- (4-chloro-2- (pyridin-3-yl) thiazol-5-yl) -N-ethyl-3- (methylsulfonyl) propanamide is the active ingredient and, for the purposes of this disclosure, is defined as "AI-1"
A molecule designated as N- (3-chloro- (pyridin-3-yl) -1H-pyrazol-4-yl) -2- (methylsulfonyl) propanamide is the active ingredient and, for the purposes of this disclosure, is defined as "AI-2".
The term "locus" means a habitat, breeding ground, plant, seed, soil, material, or environment where pests are growing, may grow, or may pass through. For example, the locus may be where crops, trees, fruits, cereals, feed species, vines, turf, and/or ornamentals are growing, where livestock live, interior or exterior surfaces of a building (such as where cereal is stored), building materials used in a building (such as impregnated wood), and soil surrounding the building.
The term "pest" means an organism that is harmful to humans or human interest (such as crops, foods, livestock, etc.), wherein the organism is from the phylum arthropoda, mollusca, or nematoda. Specific examples are ants, aphids, bed bugs (bed bugs), beetles, moths, caterpillars, cockroaches, cricket, earwigs, fleas, flies, grasshoppers, maggots, wasps, leafhoppers (jassids), she Tiaochong (leafhoppers), lice, locust, maggots, white beetles (mealybug), mites, moths, nematodes, lygus (plantbug), planthoppers (planthopper), psyllids, leaf bees, scale, silverfish, slug, snails, spiders, springtails, stink bugs, synthetic class, termites, thrips, ticks, wasps, whiteflies and iron nematodes.
Further examples are the following pests
(1) There are the chela subgenos (CHELICERATA), the polypodia subgenos (Myriapoda), and the hexapod subgenos (Hexapoda).
(2) Arachnids (ARACHNIDA), complex classes (Symphyla), and entomoids (Insecta).
(3) Nit (Order Anoplura). A non-exhaustive list of specific genera includes, but is not limited to, a xueqip species (Haematopinus spp.), a hypochondriac species (Hoplopleura spp.), a long jaw species (Linognathus spp.), a Pediculus species (Pediculus spp.), a Pediculus species (Polyplax spp.), a Pediculus species (Solenopotes spp.), and a new pig species (Neohaematopinis spp.). A non-exhaustive list of specific species include, but are not limited to, donkey blood lice (Haematopinus asini), pig blood lice (Haematopinus suis), hair lice (Linognathus setosus), sheep jaw lice (Linognathus ovillus), human head lice (Pediculus humanus capitis), human body lice (Pediculus humanus humanus), and pubic lice (Pthirus pubis).
(4) Coleoptera (Order Coleoptera). A non-exhaustive list of specific genera include, but are not limited to, a tridentate species (Acanthoscelides spp.), a click beetle species (Agriotes spp.), a flower species (antthonomus spp.), a micropill species (Apion spp.), a sugar cane beetle species (Apogonia spp.), a pinus elongatus species (Araecerus spp.), a melon species (Aulacophora spp.), a bean species (Bruchus spp.), a Bruchus spp, Longicorn species (Cerosterna spp.), longicorn species (Cerotoma spp.), tortoise species (Ceutorhynchus spp.), tibiofemolum species (Chaetocnema spp.), phyllostachys species (coloaspis spp.), CTENICERA spp., elephantopus species (Curculio spp.), square-head species (Cyclocephala spp.), phyllostachys species (Diabrotica spp.), albopomofo spp, The species of the genus codling (Dinoderus spp.), the species of the genus Cornus (Gnathocerus spp.), hemicoelus spp, heterobostruchus spp, the species of the species phyllosphere (Hypera spp.), the species of the species bark beetle (Ips spp.), the species of the species Pinus (Lyctus spp.), the species of the genus America (MEGASCELIS spp), the species of the species Caerula sativa (MELIGETHES spp), the species of the genus Umbelliferae (Mezium spp), Brown spider genus species (Niptus spp.), ear beak genus species (Otiorhynchus spp.), short beak genus species (Pantomorus spp.), gill angle genus species (Phyllophaga spp.), fleshy genus species (Phyllotreta spp.), spider genus species (Ptinus spp.), root gill genus species (Rhizotrogus spp), RHYNCHITES spp, cryptochin genus species (Rhynchophorus spp), gill angle genus species (35 spp), Bark beetle species (Scolytus spp.), cryptoryptosis species (Sphenophorus spp.), midge species (Sitophilus spp.), amycolatopsis species (Tenebrio spp.), and botrytis species (Tribolium spp.). A non-exhaustive list of specific species include, but are not limited to, phaseolus vulgaris (Acanthoscelides obtectus), white wax jiding (Agrilus planipennis), milpa armyworm (Ahasverus advena), black fungus (Alphitobius diaperinus), alaska spinosa (Anoplophora glabripennis), weevil (Anthonomus grandis), codling (Anthrenus verbasci), bark beetle (Anthrenus verbasci), Huang Yuanpi beetle (Anthrenus falvipes), beetle (Ataenius spretulus), beet cryptophaga (Atomaria linearis), beetle (Attagenus unicolor), beet image (Bothynoderes punctiventris), pea image (Bruchus pisorum), tetrapod image (Callosobruchus maculatus), yellow croaker (Carpophilus hemipterus), Beet carapax et Plastrum Testudinis (CASSIDA VITTATA), paracorn beetle (Cathartus quadricollis), bean leaf beetle (Cerotoma trifurcata), chinese cabbage seed tortoise (Ceutorhynchus assimilis), chinese cabbage tortoise (Ceutorhynchus napi), yellow meal worm (Conoderus scalaris), yellow meal worm (Conoderus stigmosus), li Xiang (Conotrachelus nenuphar), Mossback (Cotinis nitida), asparagus negative mud worm (Crioceris asparagi), red brown gracile (Cryptolestes ferrugineus), long-angle gracile (Cryptolestes pusillus), turkish gracile (Cryptolestes turcicus), fine branch elephant (Cylindrocopturus adspersus), scissors She Xiangjia (Deporaus marginatus), bark beetle (DERMESTES LARDARIUS), and other components, Bark beetle (DERMESTES MACULATUS), ladybug (EPILACHNA VARIVESTIS), tsuga pelargonium (Euvrilletta peltata), elephant trunk borer (Faustinus cubae), white bark elephant (Hylobius pales), longhornworm (Hylotrupes bajulus), alfalfa leaf elephant (Hypera postica), coffee fruit bark beetle (Hypothenemus hampei), tobacco beetle (Lasioderma serricorne), and cotton boll bark beetle, Potato beetle (Leptinotarsa decemlineata), gray-head beetle (Limonius canus), fuke tortoise (Liogenys fuscus), su tortoise (Liogenys suturalis), rice water beetle (Lissorhoptrus oryzophilus), siamese beetle (Lophocateres pusillus), southern silverfish (Lyctus planicollis), markla Pi Qiaoli (Maecolaspis joliveti), Corn click beetle (Melanotus communis), rape flower tail beetle (MELIGETHES AENEUS), chinese chestnut gill beetle (Melolontha melolontha), red foot coconut beetle (Necrobia rufipes), longhorn beetle (Oberea brevis), linear longhorn beetle (Oberea linearis), coconut Rhinocerotis tortoise (Oryctes rhinoceros), large-eye saw and larch (Oryzaephilus mercator), Sulin larch (Oryzaephilus surinamensis), black horn beetle (Oulema melanopus), rice beetle (Oulema oryzae), june gill horn beetle (Phyllophaga cuyabana), scaphium japonicum (Polycaon stoutti), japanese arc beetle (Popillia japonica), bark beetle (Prostephanus truncatus), bark beetle (Rhyzopertha dominica), and other plant species, Rhizobium striped rhizomes (Sitona lineatus), oryza sativa (Sitophilus granarius), oryza sativa (Sitophilus oryzae), zea mays (Sitophilus zeamais), jatropha curcas (Stegobium paniceum), largehead atractylodes rhizome (Tenebroides mauritanicus), red larch (Tribolium castaneum), hybrid larch (Tribolium confusum), coryza glutinosa (Trogoderma granarium), and other plant species, bark beetle (Trogoderma variabile), red Mao Qie beetle (Xestobium rufovillosum), and corn beetle (Zabrus tenebrioides).
(5) Leather ptera (Order Dermaptera). A non-exhaustive list of specific species includes, but is not limited to, earwig (Forficula auricularia).
(6) Blatta (Order Blattaria). A non-exhaustive list of specific species include, but are not limited to, german cockroach (Blattella germanica), asian cockroach (Blattella asahinai), oriental cockroach (Blatta orientalis), cherry red cockroach (Blatta latealis), pennsylvania cockroach (Parcoblatta pennsylvanica), american cockroach (PERIPLANETA AMERICANA), australian cockroach (PERIPLANETA AUSTRALASIAE), brown cockroach (PERIPLANETA BRUNNEA), periplaneta nigra (PERIPLANETA FULIGINOSA), cane cockroach (Pycnoscelus surinamensis), and Blatta longifolia (Supella longipalpa).
(7) Diptera (Order Diptera). A non-exhaustive list of specific genera include, but are not limited to, aedes species (Aedes spp.), liriomyza species (Agromyza spp.), bactrocera species (ANASTREPHA spp.), anopheles spp, fruit fly species (Bactrocera spp.), cermets spp, hermetia species (Chrysops spp.), trypanosoma species (Cochliomyia spp.), kang Ying mosquito species (Contarinia spp.), Culex species (Culex spp.), custard species (Culicoides spp.), she Ying mosquito species (Dasineura spp.), geotrichum species (Delia spp.), drosophila species (Drosophila spp.), dorsalis species (Fannia spp.), species of genus Musca (Hylemya spp.), liriomyza spp), house fly species (Musca spp.), tsumada spp, drosophila species (triosophila spp), and the like, The species drosophila (Pollenia spp.), the species midge (Psychoda spp.), the species gnat (Simulium spp.), the species Tabanus (Tabanus spp.), and the species anopheles (Tipula spp). A non-exhaustive list of specific species include, but are not limited to, liriomyza sativae (Agromyza frontella), bactrian fly (ANASTREPHA SUSPENSA), bactrian fly (ANASTREPHA LUDENS), bactrian fly (ANASTREPHA OBLIQUA), bactrian fly (Bactrocera cucurbitae), bactrian fly (Bactrocera dorsalis), bactrian fly (Bactrocera invadens), Bactrocera dorsalis (Bactrocera zonata), bactrocera Mediterranean (CERATITIS CAPITATA), aleurites brassicae (Dasineura brassicae), aphidia cinerea (Delia platura), fusarium oxysporum (Fannia canicularis), fusarium oxysporum (FANNIA SCALARIS), fusarium oxysporum (Gasterophilus intestinalis), GRACILLIA PERSEAE, amomum orientalis (Haematobia irritans), Schlieren (Hypoderma lineatum), cailiriomyza sativae (Liriomyza brassicae), liriomyza sativae (Liriomyza sativa), ovine nity fly (Melophagus ovinus), autumn fly (Musca autumnalis), common fly (Musca domastica), ovine mania fly (Oestrus ovis), rye stalk fly (Oscinella frit), beet armyworm (Pegomya betae), tyrosophila (Piophila casei), cotton fly (Saccharomyia sinensis Roxb), Carrot fly (Psila rosae), cherry fruit fly (Rhagoletis cerasi), apple fruit fly (Rhagoletis pomonella), blue orange fruit fly (Rhagoletis mendax), wheat red plasmagogue (Sitodiplosis mosellana), and stable fly (Stomoxys calcitrans).
(8) Hemiptera (Order Hemiptera). A non-exhaustive list of specific genera include, but are not limited to, myzus species (Adelges spp.), white-spotted Lepidium species (Aulacaspis spp.), cicada species (Aphrophora spp.), aphis spp.), bemisia species (Bemisia spp.), ericerus species (Ceroplastes spp.), lepidium species (Chionaspis spp.), lepidium species (Chrysomphalus spp.), ericerus species (Coccus spp.), The plant species may be selected from the group consisting of a leafhopper species (Empoasca spp.), a plant bug species (euschistmus spp.), a oyster species (Lepidosaphes spp.), a plant bug species (Lagynotomus spp.), a Lygus spp.), a long tube aphid species (Macrosiphum spp.), a black tail leafhopper species (Nephotettix spp.), a green plant bug species (Nezara spp.), a brown plant bug species (NILAPARVATA spp.), a brown plant bug species (Lygus spp.), The species of Lepidium (Philaenus spp.), apostigma species (Phytocoris spp.), lepidium species (Piezodorus spp.), lepidium species (Planococcus spp.), lepidium species (Pseudococcus spp.), sinomenium species (Rhopalesiphum spp.), lepidium species (SAISSETIA spp.), lepidium species (Therioaphis spp.), lepidium species (Toumeyella spp.), orange aphid species (Toxoptera spp.), whitefly species (Trialeurodes spp.), trytis species (Triatoma spp), and cercoides species (Unaspis spp.). A non-exhaustive list of specific species include, but are not limited to, lygus lucorum (Acrosternum hilare), pisum sativum (Acyrthosiphon pisum), bemisia European (Aleyrodes proletella), bemisia spiralis (Aleurodicus dispersus), bemisia nilotica (Aleurothrixus floccosus), empoasca delphinidia (Amrasca biguttula biguttula), lecanier (Aonidiella aurantii), leptoradix Rhododendri mollis (Amersham), Beet aphid (Aphis fabae), cotton aphid (Aphis gossypii), soybean aphid (APHIS GLYCINES), apple aphid (Aphis pomi), potato aphid (Aulacorthum solani), potato psyllium (Bactericera cockerelli), huang Xingsong stink bug (Bagrada hilaris), silverfish (Bemisia argentifolii), bemisia tabaci (Bemisia tabaci), duo Mao Changchun (Blissus leucopterus), and, Maple stink bug (Boisea trivittata), asparagus cochinchinensis (Brachycorynella asparagi), lecanitis cinerea (Brevennia rehi), brassica oleracea (Brevicoryne brassicae), and pear psyllium
(Cacopsylla pyri), pear psyllium (Cacopsylla pyricola), lygus potato (Calocoris norvegicus), cercus red (Ceroplastes rubens), tropical bed bugs (Cimex hemipterus), temperate zone bed bugs (Cimex lectularius), cercus citri (Coccus pseudomagnoliarum), lygus fasciatus (Dagbertus fasciatus), stink bugs (Dichelops furcatus), myzus persicae (Diuraphis noxia), diaphorina citri (Diaphorina citri), myzus plantaginis (DYSAPHIS PLANTAGINEA), cerus ruber (Dysdercus suturellus), idesa merda (Edessa meditabunda), edsa pseudobulb (Empoasca vitis), cercus citri (Eriosoma lanigerum), grape She Xingban leaf cicada (Erythroneura elegantula), mo Labian shield stink bug
(Eurygaster maura), apolygus lucorum (Euschistus conspersus), apolygus lucorum (Luo Meizhou)
(Euschistmus heros), brown stink bug (Euschistus servus), tea wing bug (Halyomorpha halys), cashew lygus (Helopeltis antonii), peach powder tail aphid (Hyalopterus pruni), cashew lygus (Helopeltis antonii), tea horn lygus (Helopeltis theivora), mealy bugs (Icerya purchasi), lemon fruit brown leafhoppers (Idioscopus nitidulus), Leafhopper (Jacobiasca formosana), laodelphax striatellus (Laodelphax striatellus), gecko (Lecanium corni), orthosiphon aristatus (Leptocorisa oratorius), orthosiphon aristatus (Leptocorisa varicornis), lygus lucorum (Lygus hesperus), gecko (Maconellicoccus hirsutus), euphorbia pekinensis, aphis (Macrosiphum euphorbiae), orthosiphon aristatus (Amersham) and Orthosiphon aristatus, Myzus persicae (Macrosiphum granarium), rosa longifolia (Macrosiphum rosae), leafhoppers (Macrosteles quadrilineatus), raspberry hopper (MAHANARVA FIMBRIOLATA), lemongrass bug (Megacopta cribraria), mylabris longifolia (Metopolophium dirhodum), lemongrass bug (Mictis longicornis), myzus persicae (Myzus persicae), myzus persicae, and, Lettuce aphid (Nasonovia ribisnigri), black tail leafhopper (Nephotettix cincticeps), lygus lucorum (Neurocolpus longirostris), lygus lucorum (Nezara viridula), brown rice lice (NILAPARVATA LUGENS), papaya mealybugs (Paracoccus marginatus), potato psyllids (Paratrioza cockerelli), furuncle scale (Parlatoria pergandii), Lecanier nigricans (Parlatoria ziziphi), leptospira maydis (Peregrinus maidis), aphis rhizomatosa (Phylloxera vitifoliae), leptospira sequoyis (Physokermes piceae) lygus californicus (Phytocoris californicus), lygus relatives (Phytocoris relativus), ji Erde jade stink bug (Piezodorus guildinii), mealy bugs (Planococcus citri), Fig gecko (Planococcus ficus), lygus quadricarinus (Poecilocapsus lineatus), lygus cowberry (Psallus vaccinicola), avocado net bug (Pseudacysta perseae), pineapple gecko (Pseudococcus brevipes), lepidoptera pyriformis (Quadraspidiotus perniciosus), corn aphid (Rhopalosiphum maidis), he Gu Yiguan aphid (Rhopalosiphum padi), and plant bug, The preparation method comprises the following steps of (1) olive black mealybugs (SAISSETIA OLEAE), chestnut bugs (Scaptocoris castanea), wheat binary aphids (Schizaphis graminum), wheat long pipe aphids (Sitobion avena), white-back planthoppers (Sogatella furcifera), greenhouse white-powder lice (Trialeurodes vaporariorum), green-hemp white-powder lice (Trialeurodes abutiloneus), sagittaria acutifolia (Unaspis yanonensis), And Entenna leafhoppers (Zulia entrerriana).
(9) Hymenoptera (Order Hymenoptera). A non-exhaustive list of specific genera include, but are not limited to, top cut leaf ant species (Acromyrmex spp.), cut leaf ant species (Atta spp.), dorsalina species (Camponotus spp.), pine leaf ant species (Diprion spp.), yellow wasp species (Dolichovespula spp.), ant species (Formica spp.), microcephala species (Monomorium spp.), neous species (Neodiprion spp.), hairy ant species (PARATRECHINA spp.), large head ant species (Pheidole spp.), harvested spp species (Pogonomyrmex p.), wasp species (Polistes spp.), fire ant species (Solenopsis spp), fleshy ant species (Technomyrmex spp), pavement ant species (Tetramorium spp), wasp species (Vespula spp), vespa spp, and wasp (Xylocopa spp.). A non-exhaustive list of specific species include, but are not limited to, sinkiang wasps (Athalia rosae), texas cut ants (Atta texana), cherokee rose wasps (Caliroa cerasi), elm wasps (Cimbex americana), argentina iridescent ants (Iridomyrmex humilis), argentina ants (LINEPITHEMA HUMILE), eastern africa bees (MELLIFERA SCUTELLATA), black-headed ants (Monomorium minimum), yellow-headed ants (Monomorium pharaonis), european new pine wasps (Neodiprion sertifer), red fire ants (Solenopsis invicta), tropical fire ants (Solenopsis geminata), thiets (Solenopsis molesta), black fire ants (Solenopsis richtery), southern fire ants (Solenopsis xyloni), sour ants (Tapinoma sessile), and red fire ants (WASMANNIA AUROPUNCTATA).
(10) Isoptera (Order Isoptera). A non-exhaustive list of specific genera includes, but is not limited to: the species of the genus coptottermes (coptottermes spp.), the species of the genus Coptotermes (Cornitermes spp.), the species of the genus termes (Cryptotermes spp.), the species of the genus heterotermes (Heterotermes spp.), the species of the genus wood termes (Kalotermes spp.), the species of the genus termes (incoisitermes spp.), the species of the genus megatermes (Macrotermes spp.), the species of the genus termes (MARGINITERMES spp.), the species of the genus saw termes (Microcerotermes spp.), the species of the genus prototheca (Procornitermes spp.), the species of the genus rottermes (reticulter spp.), the species of the genus long nose termes (Schedorhinotermes spp.) and the species of the genus ancient termes (Zootermopsis spp.). A non-exhaustive list of specific species include, but are not limited to, short-cutter emulsion termites (Coptotermes acinaciformis), large-lip emulsion termites (Coptotermes curvignathus), large-lip emulsion termites (Coptotermes frenchi), taiwan emulsion termites (Coptotermes formosanus), gerstros emulsion termites (Coptotermes gestroi), beginner sand termites
(Cryptotermes brevis), golden yellow termite (Heterotermes aureus), sugarcane termite
(Heterotermes tenuis), albizia falcarina termite (INCISITERMES MINOR)
(INCISITERMES SNYDERI), au Bei Sixiao termite (Microtermes obesi), termite with an angular character
(Nasutitermes corniger), black-winged termites (Odontotermes formosanus), rhizomes (Odontotermes obesus), ban Nusi termites (Reticulitermes banyulensis), glazier termites (Reticulitermes grassei), north american termites (Reticulitermes flavipes), harbour termites (Reticulitermes hageni), western termites (Reticulitermes hesperus), sang Tesan termites (Reticulitermes santonensis), north termites (Reticulitermes speratus), black shank termites (Reticulitermes tibialis), and south termites (Reticulitermes virginicus).
(11) Lepidoptera (Order Lepidoptera). A non-exhaustive list of specific genera include, but are not limited to, brown stripe moth species (Adoxophyes spp.), cutworm species (Agrotis spp.), brown stripe moth species (Argyrotaenia spp.), leaf roller species (ccocia spp.), fall webworm species (Caloptilia spp.), graminea species (chiro spp.), leaf roller species (noctuid spp.)
(Chrysodeixis spp.), a bean flour butterfly species (Colias spp.), a grass borer species (Crambus spp.), a silk borer species (DIAPHANIA spp.), a stem borer species (Diatraea spp.), a diamond back moth species (Earias spp.), a Pink borer species (Ephestia spp.), an inchworm species (Epimecis spp.), a Spodoptera species (Feltia spp.), a hornworm species (Gortyna spp.), a black fungus species (P.sp.) and a black fungus species (P.E. P.C.), The species of the genus Spodoptera (Helicoverpa spp.), the species of the genus Spodoptera (Heliothis spp.), the species of the genus Rhizopus (Indarbela spp.), the species of the genus Potentilla (Lithocarpi spp.), the species of the genus Rhizopus (Loxagrotis spp.), the species of the genus Torulopsis (Malacosoma spp.), the species of the genus Valley (Nemapogon spp.), the species of the genus Fagopterus (Peridroma spp.), the species of the genus Potentilla (Phyllonorycter spp.), The species Spodoptera (Pseudaletia spp.), plutella xylostella (Plutella spp.), spodoptera (Sesamia spp.), spodoptera (Spodoptera spp.), speranskia (Synanthedon spp.), and fall webworm (Yponomeuta spp.). A non-exhaustive list of specific species include, but are not limited to, spodoptera littoralis (Achaea janata), philippine flea-a-moth (Adoxophyes orana), gekko Swinhonis (Agrotis ipsilon), philippine flea-moth (Alabama argillacea), philippine flea-moth (Amorbia cuneana), leriomyza borer moth (Amyelois transitella), plutella xylostella (Anacamptodes defectaria), leriomyza sativa moth (ANARSIA LINEATELLA), cyperus rotundus, spodoptera littoralis (Anomis sabulifera), spodoptera littoralis (ANTICARSIA GEMMATALIS), fruit tree loopers (Archips argyrospila), rose loopers (Archips rosana), orange loopers (Argyrotaenia citrana), spodoptera obtusifolia (Autographa gamma), apple loopers (Bonagota cranaodes), indica butterfly (Borbo cinnara), cotton moths (Bucculatrix thurberiella), cotton moths (Amersham) and Amersham's cotton moths (Amersham's cotton), Tobacco leaf rollers (Capua reticulana), peach fruit borers (Carposina niponensis), spodoptera exigua (Chlumetia transversa), rose leaf rollers (Choristoneura rosaceana), cnaphalocrocis medinalis (Cnaphalocrocis medinalis), cocoa moth (Conopomorpha cramerella), rice moth (Corcyra cephalonica), amoeba moth (Cossus cossus), and, Walnut plutella xylostella (CYDIA CARYANA), plum plutella xylostella (Cydia funebrana), pear plutella xylostella (Cydia molesta), pea plutella xylostella (CYDIA NIGRICANA), codling moth (Cydia pomonella), nettle caterpillar (Darna diducta), cucumber silk wild borer (DIAPHANIA NITIDALIS), small cane stem borer (DIATRAEA SACCHARALIS), southwest corn stem borer (Diatraea grandiosella), and cotton bollworm, noctuid (Earias insulana), noctuid (EARIAS VITTELLA), orange plutella xylostella (Ecdytolopha aurantianum), corn borer (Elasmopalpus lignosellus), pink bollworm (Ephestia cautella), tobacco pink bollworm (Ephestia elutella), mediterranean borer (Ephestia kuehniella), bean plutella xylostella (Epinotia apoma), cotton bollworm (P.praecox), Apple light brown moth (Epiphyas postvittana), banana butterfly (Erionota thrax), salt lamp moth (ESTIGMENE ACREA), ring needle single leaf roller (Eupoecilia ambiguella), prototheca (Euxoa auxiliaris), wax moth (Galleria mellonella), oriental fruit moth (Grapholita molesta), three-leaf moth (HEDYLEPTA INDICATA), cotton bollworm (Helicoverpa armigera), cotton bollworm (, Noctuid (Heliothis virescens), tobacco leaf moth (Heliothis virescens), cabbage moth (Hellula undalis), tomato moth (Keiferia lycopersicella), eggplant moth (Leucinodes orbonalis), coffee leaf miner (Leucoptera coffeella), leaf roller (Leucoptera malifoliella), grape diamond-back moth (lobisia botrana), Bean Bai Longqie root worm (Loxagrotis albicosta), gypsymoth (LYMANTRIA DISPAR), peach leaf miner (Lyonetia clerkella), oil palm euphorbia worm (Mahasena corbetti), cabbage looper (Mamestra brassicae), tobacco astromoth (Manduca sexta), pod borer (Maruca testulalis), bag moth (METISA PLANA), armyworm (Mythimna unipuncta), cotton bollworm (yellow cotton bollworm), Tomato moth (Neoleucinodes elegantalis), rice moth (Nymphula depunctalis), winter moth (Operophtera brumata), european corn moth (Ostrinia nubilalis), vitamin Su Che moth (Oxydia vesulia), grape moth (PANDEMIS CERASANA), apple moth (PANDEMIS HEPARANA), african butterfly (Papilio demodocus), a red moth (W), Pink bollworm (Pectinophora gossypiella), spodoptera exigua (Peridroma saucia), coffee leaf miner (Perileucoptera coffeella), potato tuber moth (Phthorimaea operculella), leaf miner (Phyllocnistis citrella), plutella xylostella (Phyllonorycter blancardella), cabbage butterfly (PIERIS RAPAE), alfalfa looper (PLATHYPENA SCABRA), a plant growth regulator, apple bud plutella xylostella (Platynota idaeusalis), plutella xylostella (Plodia interpunctella), plutella xylostella (Plutella xylostella), plutella xylostella (Polychrosis viteana), cellola citrina (Prays endocarpa), olea europaea (Prays oleae), phaliota armyworm (Pseudaletia unipuncta), spodoptera frugiperda (Pseudoplusia includens), The plant material comprises herba Menthae Trichoplusia ni (Rachiplus nu), tristem borer (Scirpophaga incertulas), borer (SESAMIA INFERENS), pink stem borer (Sesamia nonagrioides), phaerocinia cupana (Setora nitens), maifanitum (Sitotroga cerealella), plutella xylostella (Sparganothis pilleriana), beet armyworm (Spodoptera exigua), spodoptera frugiperda (Spodoptera frugiperda), chaetomium praecox (Spodoptera frugiperda), The plant species include, for example, armyworm (Spodoptera eridania) in the south, pineapple line, gray butterfly (Thecla basilides), bag moth (Tinea pellionella), curtain moth (Tineola bisselliella), armyworm (Trichoplusia ni), tomato spotted fly (Tuta absoluta), coffee leopard moth (Zeuzera coffeae), and pear leopard moth (Zeuzea pyrina).
(12) Order of food wool (Order Mallophaga). A non-exhaustive list of specific genera include, but are not limited to, gossypium species (Anaticola spp.), nivalgus species (Bovicola spp.), turkey species (Chelopistes spp.), canthus spinosus species (Goniodes spp.), gallinaceous species (Menacanthus spp.), and canine hair species (Trichodectes spp.). A non-exhaustive list of specific species include, but are not limited to, cattle feather lice (Bovicola bovis), goat hair ox louse (Bovicola caprae), sheep lice (Bovicola ovis), big turkey lice (Chelopistes meleagridis), chicken horn feather lice (Goniodes dissimilis), big horn feather lice (Goniodes gigas), chicken feather lice (Menacanthus stramineus), chicken feather lice (Menopon gallinea), and canine hair lice (Trichodectes canis).
(13) Orthoptera (Order Orthoptera). A non-exhaustive list of specific genera includes, but is not limited to, black locust species (Melanoplus spp.) and tree general name for grass hoppers and crickets species (Pterophylla spp.). A non-exhaustive list of specific species includes, but is not limited to, cricket (Acheta domesticus), molones (Anabrus simplex), mole cricket africana (Gryllotalpa africana), mole cricket southern (Gryllotalpa australis), mole cricket black (Gryllotalpa brachyptera), mole cricket european (Gryllotalpa hexadactyla), migratory locust east asia (Locusta migratoria), cantaloupe (Microcentrum retinerve), desert locust (Schistocerca gregaria), and bush with forktail (Scudderia furcata).
(14) Rodent (Order Psocoptera). A non-exhaustive list of specific species include, but are not limited to, colorless booklices (Liposcelis decolor), insecticidal booklices (Liposcelis entomophila), queen basidiomycetes (LACHESILLA QUERCUS), and dust lice (Trogium pulsatorium).
(15) Siphonaptera (Order Siphonaptera). A non-exhaustive list of specific species include, but are not limited to, flea gallica (Ceratophyllus gallinae), flea nigra (Ceratophyllus niger), flea canis (Ctenocephalides canis), flea felis (Ctenocephalides felis), and flea mandshurica (Pulex irritans).
(16) Thysanoptera (Order Thysanoptera). A non-exhaustive list of specific genera includes, but is not limited to, thrips species (Caliothrips spp.), thrips species (Frankliniella spp.), thrips species (Scirtothrips spp.), and Thrips species (threps spp.). A non-exhaustive list of specific species include, but are not limited to, pinto piscilla phaseoloides (Caliothrips phaseoli), pinto spinosa (FRANKLINIELLA BISPINOSA), tabaci (FRANKLINIELLA FUSCA), medicago sativa (FRANKLINIELLA OCCIDENTALIS), frankliniella gracilis (FRANKLINIELLA SCHULTZEI), frankliniella orientalis (FRANKLINIELLA TRITICI), corn Thrips (FRANKLINIELLA WILLIAMSI), tabaci Thrips (Heliothrips haemorrhoidalis), gracilis ventricosa (Rhipiphorothrips cruentatus), citrus Thrips (Scirtothrips citri), tabaci Thrips (Scirtothrips dorsalis), tabaci (Taeniothrips rhopalantennalis), thrips flavescens (THRIPS HAWAIIENSIS), bean Huang Jima (Thrips nigropilosus), oriental Thrips (Thrips orientalis), southern Huang Jima (THRIPS PALMI), and Thrips tabaci.
(17) The order of the Thysanoptera (Order Thysanura). A non-exhaustive list of specific genera includes, but is not limited to, tuna species (Lepisma spp.) and calibrant species (Thermobia spp.).
(18) Acarina (Order Acarina). A non-exhaustive list of specific genera include, but are not limited to, the flour mite species (Acarus spp.), the spinosa species (Aculops spp.), the oculopsis species (Argus spp.), the calyx taurus species (Boophilus spp.), the demodex species (Demodex spp.), the dorsum species (Dermacentor spp.), the gomphus species (Epitrimerus spp.), the festival species (Eriophyes spp.), the hard tick species (Ixodes spp.), the, Tetranychus species (Oligonychus spp.), panonychus species (Pannychus spp.), rhipicephalus species (Rhizoglyphus spp.), and Tetranychus species (Tetranychus spp.). a non-exhaustive list of specific species include, but are not limited to, tracheae mites (Acarapis woodi), white mites (Acarus siro), mango gall mites (ACERIA MANGIFERAE), tomato gall mites (Aculops lycopersici), citrus gall mites (Aculus pelekassi), apple gall mites (Aculus schlechtendali), american ticks (Amblyomma americanum), oval shorthair mites (Brevipalpus obovatus), and, The composition comprises white mite (Brevipalpus phoenicis), rhagophthalmus ohba (Dermacentor variabilis), rhagophthalmus ohba (Dermatophagoides pteronyssinus), carpinus hornbeam Panonychus (Eotetranychus carpini), acarina (Liponyssoides sanguineus), acarina cat anus mite (Notoedres cati), rhagophthalmus ohba (Oligonychus coffeae), Winter green little spider mite (Oligonychus ilicis), platycladus fowl spider mite (Ornithonyssus bacoti), panonychus citri (Panoneichus citri), apple red spider (Panonechus ulmi), panicum citri (Phyllocoptruta oleivora), tarsonemus polycephalus (Polyphagotarsonemus latus), rhapontici hemsleyanum (Rhipicephalus sanguineus), scabies mite (Sarcoptes scabiei), tarsonemus praecox, Rhapontici avocado (Tegolophus perseaflorae), tetranychus urticae (Tetranychus urticae), tyrophagus longus (Tyrophagus longior), and Dermatophagoides pteronyssinus (Varroa destructor).
(19) Spider order (Order Araneae). A non-exhaustive list of specific genera includes, but is not limited to, the flat nail spider species (Loxosceles spp.), the Kou Zhu species (latodectus spp.), and the australian spider species (Atrax spp.). A non-exhaustive list of specific species includes, but is not limited to xi, spider-skin (Loxosceles reclusa), erythema Kou Zhu (Latrodectus mactans), and sydney funnel spider (Atrax robustus).
(20) Comprehensive class (CLASS SYMPHYLA). A non-exhaustive list of specific species includes, but is not limited to, white pine worms (Scutigerella immaculata).
(21) The subclass Marsdenia (Subclass Collembola). A non-exhaustive list of specific species include, but are not limited to, garden round springtails (Bourletiella hortensis), army springtails (Onychiurus armatus), echinophaga (Onychiurus fimetarius), and green springtails (Sminthurus viridis).
(22) Nematophaga phylum (Phylum Nematoda). A non-exhaustive list of specific genera include, but are not limited to, nematoda species (Aphelenchoides spp.), spinosa species (Belonolaimus spp.), microcystis species (Criconemella spp.), stem nematode species (Ditylenchus spp.), heterodera species (Globodera spp.), cyst nematode species (heteodora spp.), peristalsis species (HIRSCHMANNIELLA spp.), ligament species (Hoplolaimus spp.), root nodule species (Meloidogyne spp.), root rot species (Pratylenchus spp.), and introgression species (Radopholus spp.). A non-exhaustive list of specific species include, but are not limited to, heartworm (Dirofilaria immitis), potato cyst nematode (Globodera pallida), soybean cyst nematode (Heterodera glycines), corn cyst nematode (Heterodera zeae), meloidogyne incognita (Meloidogyne incognita), meloidogyne javanica (Meloidogyne javanica), filarial (Onchocerca volvulus), praecox (Pratylenchus penetrans), radopholus similis (Radopholus similis), and reniform nematode (Rotylenchulus reniformis).
(23) A mollusc door (Phylum Mollusca). A non-exhaustive list of specific species include, but are not limited to, spreading snails (Cornu aspersum), reticulate wild slugs (Deroceras reticulatum), huangyu (Limax flavus), greenhouse slugs (Milax gagates), and ampullaria gigas (Pomacea canaliculata).
In one aspect, the pest group to be controlled is a pest feeding on juice. Pests that feed on juice often have piercing and/or sucking mouthparts and feed on juice of the plant and internal plant tissue. Examples of particularly agriculturally interesting sap-feeding pests include, but are not limited to, aphids, she Tiaochong, moths, scale insects, thrips, psyllids, white flies, stink bugs and white flies. Specific examples of the purpose of the pest having agricultural interest to feed on juice include, but are not limited to, the order of lice and hemiptera. Specific examples of agriculturally interesting hemipterans include, but are not limited to, leuconostoc species, pachyrhizus species, aphis species, bemisia species, ericerus species, aphis species, algus species, aleurites species, orthosiphon species and Sinonotus species.
In another aspect, the pest group to be controlled is chewing pest. Chewing pests typically have a mouth piece that allows them to chew on plant tissue including roots, stems, leaves, buds, and reproductive tissue (including but not limited to flowers, fruits, and seeds). Examples of chewing pests of particular agricultural interest include, but are not limited to, trichina, beetles, grasshoppers, and grasshoppers. Specific examples of purposes having agriculturally interesting chewing pests include, but are not limited to, coleoptera and lepidoptera. Specific examples of coleopterans of agricultural interest include, but are not limited to, anthoxylum species, phyllostachys species, cephalopodium species, phyllostachys species, gill angle metal species, phyllostachys species, cryptococus species, midimage species.
The phrase "pesticidally effective amount" means the amount of pesticidally agent required to achieve an observable effect on the pest, such as necrosis, death, retardation, prevention, elimination, destruction, or otherwise reducing the appearance and/or activity of the pest in the locus. This effect may occur when a pest population is expelled from the locus, pests are disabled in or around the locus, and/or pests are eradicated in or around the locus. Of course, combinations of these effects may occur. Typically, pest populations, activities, or both desirably decrease by more than fifty percent, preferably more than 90 percent, and most preferably more than 99 percent. Typically, a pesticidally effective amount for agricultural purposes is from about 0.0001 g/ha to about 5000 g/ha, preferably from about 0.0001 g/ha to about 500 g/ha, and even more preferably from about 0.0001 g/ha to about 50 g/ha.
All references, including publications, patent applications, and patents, cited herein are hereby incorporated by reference to the same extent as if each reference were individually and specifically indicated to be incorporated by reference and were set forth in its entirety herein.
The use of the terms "a" and "an" and "the" and "at least one" and similar referents in the context of this disclosure (especially in the context of the following claims) are to be construed to cover both the singular and the plural, unless otherwise indicated herein or clearly contradicted by context. Unless indicated otherwise or clearly contradicted by context, the use of the term "at least one" followed by a list of one or more entries (e.g., "at least one of a and B)") should be interpreted to mean one entry selected from the listed entries (a or B) or any combination of two or more of the listed entries (a and B). Unless otherwise indicated, the terms "comprising," "having," "including," and "containing" are to be construed as open-ended terms (i.e., meaning "including, but not limited to"). Recitation of ranges of values herein are merely intended to serve as a shorthand method of referring individually to each separate value falling within the range, unless otherwise indicated herein, and each separate value is incorporated into the specification as if it were individually recited herein. All methods described herein can be performed in any suitable order unless otherwise indicated herein or otherwise clearly contradicted by context. The use of any and all examples, or exemplary language (e.g., "such as") provided herein, is intended merely to better illuminate the disclosure and does not pose a limitation on the scope of the disclosure unless otherwise claimed. No language in the specification should be construed as indicating any non-claimed element as essential to the practice of any embodiment herein. In the present disclosure, the terms "molecule" and "compound" are used interchangeably.
Detailed Description
This document discloses pesticidal compositions, the pesticidal composition comprises:
(A) Molecules having a structure according to formula one
Wherein:
r 1 is CF 3、CHF2、CF2CF3、OCF3、OCF2CF3、SF5, or SO 2CF3;
R 2 is H, F, or CH 3;
R 3 is CH 3 or OCH 3, and
R 4 is CH 2OCH2CH3、CH2OCH2CF3, or CH 2OCH2CH2 F;
and (B) a mixed compatibility which is
(1) A member of AIGA-1;
(2) A member of AIGA-2;
(3) AI-1 or
(4)AI-2。
Examples of molecules having formula one are shown in table one.
The molecules in part (a) having formula one, and in particular, the molecules F1, F2, F3, F4, F5, F6, F7, F8, F9, F10, F11, F12, F13, F14, F15, and F16, can be prepared by one of skill in the art. See, for example, WO 2021/01722 A1, WO 2014/160031, and WO 2013/009791.
The pesticidal composition may be mixed with active ingredients and other mixed compatibilities to enhance the usefulness of the composition. Such active ingredients may have, for example, acaricidal, insecticidal, fungicidal, nematicidal activity, which widens the spectrum of pest control and other materials, compounds, and compositions. Procedures for preparing such compositional mixtures are known in the art.
In accordance with the above, the following details are provided in addition.
1D. A pesticidal composition, it comprises:
(A) Molecules having a structure according to formula one
Wherein:
r 1 is CF 3、CHF2、CF2CF3、OCF3、OCF2CF3、SF5, or SO 2CF3;
R 2 is H, F, or CH 3;
R 3 is CH 3 or OCH 3, and
R 4 is CH 2OCH2CH3、CH2OCH2CF3, or CH 2OCH2CH2 F;
And
(B) A mixed formulation of
(1) Members of AIGA;
(2) A member of AIGA-1;
(3) A member of AIGA-2;
(3) AI-1 or
(4)AI-2。
The pesticidal composition according to detail 1d, wherein the molecule having the structure according to formula one is F1, F2, F3, F4, F5, F6, F7, F8, F9, F10, F11, F12, F13, F14, F15, or F16.
3D. the composition according to detail 2d, wherein the molecule is F1
4D. the composition according to detail 2d, wherein the molecule is F2.
The composition according to detail 2d, wherein the molecule is F3.
6D. the composition according to detail 2d, wherein the molecule is F4.
The composition according to detail 2d, wherein the molecule is F5.
The composition according to detail 2d, wherein the molecule is F6.
The composition according to detail 2d, wherein the molecule is F7.
The composition according to detail 2d, wherein the molecule is F8.
The composition according to detail 2d, wherein the molecule is F9.
The composition according to detail 2d, wherein the molecule is F10.
The composition according to detail 2d, wherein the molecule is F11.
14D. the composition according to detail 2d, wherein said molecule is F12.
The composition according to detail 2d, wherein the molecule is F13.
The composition according to detail 2d, wherein the molecule is F14.
The composition according to detail 2d, wherein the molecule is F15.
The composition according to detail 2d, wherein the molecule is F16.
The composition according to detail 2d, wherein the molecule is a stereoisomer of F1, F2, F3, F4, F5, F6, F7, F8, F9, F10, F11, F12, F13, F14, F15, or F16.
The composition according to details 1d to 19d, wherein the mixed compatibilising substance is one selected from AIGA.
The composition according to details 1d to 19d, wherein the mixed compatibilising substance is one selected from AIGA-1.
The composition according to details 1d to 21d, wherein the mixed compatibilising is abamectin.
The composition according to details 1d to 21d, wherein the mixed compatibilising is acephate.
The composition according to details 1d to 21d, wherein the mixed compatibilising is chloranil.
The composition according to details 1d to 21d, wherein the mixed compatibilising is acetamiprid.
The composition according to details 1d to 21d, wherein the mixed compatibilising is bifenthrin.
The composition according to details 1d to 21d, wherein the mixed compatibilisation is acynonapyr.
The composition according to details 1d to 21d, wherein the mixed compatibilis is pyripyropene.
The composition according to details 1d to 21d, wherein the mixed compatibility is carbofuran.
The composition according to details 1d to 21d, wherein the mixed compatibility is aldicarb.
The composition according to details 1d to 21d, wherein the mixed compatibilising is allethrin.
The composition according to details 1d to 21d, wherein the mixed compatibilising is alpha-cypermethrin.
The composition according to details 1d to 21d, wherein the mixed compatibilising is aminopyralid.
The composition according to details 1d to 21d, wherein the mixed compatibilising is amitraz.
The composition according to details 1d through 21d, wherein the mixed compatibilising agent is azadirachtin.
The composition according to details 1d to 21d, wherein the mixed compatibilising is picoline phosphorus.
The composition according to details 1d to 21d, wherein the mixed compatibilising is valphos-ethyl.
The composition according to details 1d to 21d, wherein the mixed compatibilising is valphos-methyl.
39D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is azocyclotin.
The composition according to details 1d to 21d, wherein the mixed compatibilising is azoxystrobin.
41D. the composition according to details 1d to 21d, wherein the mixed compatibilis is bendiocarb.
42D. the composition according to details 1d to 21d, wherein the mixed compatibilising is benfuracarb.
43D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is monosulfan.
44D. the composition according to details 1d to 21d, wherein the mixed compatibilis is benflumetofen.
45D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is benazepine.
46D. the composition according to details 1d to 21d, wherein the mixed compatibilising is beta-cyhalothrin.
47D. the composition according to details 1d to 21d, wherein said mixed compatibilising is beta-cypermethrin.
48D. the composition according to details 1d to 21d, wherein the mixed compatibilising is bifenazate.
49D. the composition according to details 1d to 21d, wherein the mixed compatibilin.
The composition according to details 1d to 21d, wherein the mixed compatibilising is bioallethrin.
51D. the composition according to details 1d to 21d, wherein the mixed compatibilin is a biobifenthrin.
52D. the composition according to details 1d to 21d, wherein the mixed compatibilis is bistrifluron.
53D. the composition according to details 1d to 21d, wherein said mixed compatibilising substance is bromoxynil.
54D. the composition according to details 1d to 21d, wherein the mixed compatibilis is fenpyroximate.
55D. the composition according to details 1d to 21d, wherein the mixed compatibilising is buprofezin.
56D. the composition according to details 1d to 21d, wherein the mixed compatibilising is carbofuran.
57D. the composition according to details 1d to 21d, wherein the mixed compatibilising is bupropion sulfone.
58D. the composition according to details 1d to 21d, wherein the mixed compatibilising is thiowire phosphorus.
59D. the composition according to details 1d to 21d, wherein the mixed compatibilis is carbaryl.
The composition according to details 1d to 21d, wherein the mixed compatibilising is carbofuran.
The composition according to details 1d to 21d, wherein the mixed compatibilising is carbosulfan.
The composition according to details 1d to 21d, wherein the mixed compatibility is carboxin.
63D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is cartap hydrochloride.
64D. the composition according to details 1d to 21d, wherein the mixed compatibility is miticidal.
65D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is chlorantraniliprole.
66D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is chlordane.
67D. the composition according to details 1d to 21d, wherein the mixed compatibilising is phosphorus oxychloride.
The composition according to details 1d to 21d, wherein the mixed compatibilis is chlorfenapyr.
69D. the composition according to details 1d to 21d, wherein the mixed compatibilis is chlorantraniliprole.
70D. the composition according to details 1d to 21d, wherein the mixed compatibilis is chlorazuron.
71D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is clozaphosphorine.
72D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is chlorpyrifos.
The composition according to details 1d to 21d, wherein the mixed compatibilising substance is chlorpyrifos methyl.
74D. the composition according to details 1d to 21d, wherein the mixed compatibilising is chromafenozide.
75D. the composition according to details 1d to 21d, wherein the mixed compatibilin is clofentezine.
76D. the composition according to details 1d to 21d, wherein the mixed compatibilising is clopyralid.
77D. the composition according to details 1d to 21d, wherein the mixed compatibilis is cloquintocet-mexyl.
78D. the composition according to details 1d to 21d, wherein the mixed compatibilis clothianidin.
79D. the composition according to details 1d to 21d, wherein the mixed compatibilising is copper hydroxide.
80D. the composition according to details 1d to 21d, wherein the mixed compatibilis is coumaphos.
81D. the composition according to details 1d to 21d wherein the mixed compatibilising is fenitrothion.
82D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is cyantraniliprole.
83D. the composition according to details 1d to 21d, wherein the mixed compatibilis is cycloxaprid.
84D. the composition according to details 1d to 21d, wherein the mixed compatibilising is a ring Ding Fulun.
85D. the composition according to details 1d to 21d, wherein the mixed compatibilising is fenpropathrin.
86D. the composition according to details 1d to 21d, wherein the mixed compatibilis is cycloxaprid.
87D. the composition according to details 1d to 21d, wherein the mixed compatibilis is cyenopyrafen.
88D. the composition according to details 1d to 21d, wherein the mixed compatibilis is cyflumetofen.
89D the composition according to details 1d to 21d, wherein said mixed compatibilising is cyhalothrin.
The composition according to details 1d to 21d, wherein the mixed compatibilising is cyhalothrin.
91D. the composition according to details 1d to 21d, wherein the mixed compatibilising is tricyclotin.
92D. the composition according to details 1d to 21d, wherein the mixed compatibility is cymoxanil.
93D. the composition according to details 1d to 21d, wherein the mixed compatibilising is cypermethrin.
94D. the composition according to details 1d to 21d, wherein the mixed compatibilising is cyphenothrin.
95D. the composition according to details 1d to 21d, wherein the mixed compatibilis is cyflufenapyr.
96D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is cyromazine.
97D. the composition according to details 1d to 21d, wherein the mixed compatibilising is d-cis-trans allethrin.
The composition according to details 1d to 21d, wherein the mixed compatibilising is DDVP.
99D. the composition according to details 1d to 21d, wherein the mixed compatibilis deltamethrin.
100D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is a Neoprene-S-methyl.
101D. the composition according to details 1d to 21d, wherein the mixed compatibilising is diafenthiuron.
102D. the composition according to details 1d to 21d, wherein the mixed compatibiliser is diazinon.
103D. the composition according to details 1d to 21d, wherein the mixed compatibilising is dichlorvos.
104D. the composition according to details 1d to 21d, wherein the mixed compatibilis is chlorfenapyr.
105D. the composition according to details 1d to 21d, wherein the mixed compatibilis is baizhifu.
The composition according to details 1d to 21d, wherein the mixed compatibilising is difenoconazole.
107D. the composition according to details 1d to 21d, wherein the mixed compatibilin is flufenzine.
108D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is a difluoride.
109D. the composition according to details 1d to 21d, wherein the mixed compatibility is Dimethoate.
110D. the composition according to details 1d to 21d, wherein the mixed compatibilis is methylparaben.
111D. the composition according to details 1d to 21d, wherein the mixed compatibilin is zinxazod.
112D. the composition according to details 1d to 21d, wherein the mixed compatibilis dinotefuran.
113D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is etoposide.
114D. the composition according to details 1d to 21d, wherein the mixed compatibilisation is DNOC.
The composition according to details 1d to 21d, wherein the mixed compatibilising is d-trans allethrin.
116D. the composition according to details 1d to 21d, wherein the mixed compatibilising is emamectin benzoate.
117D. the composition according to details 1d to 21d, wherein the mixed compatibilising is emamectin benzoate.
118D. the composition according to details 1d to 21d, wherein the mixed compatibilin is an enetetramethrin.
119D. the composition according to details 1d to 21d, wherein said mixed compatibilis is endosulfan.
120D. the composition according to details 1d to 21d, wherein the mixed compatibilising is EPN.
121D. the composition according to details 1d to 21d, wherein the mixed compatibilis is fenvalerate.
122D. the composition according to details 1d to 21d, wherein the mixed compatibilis is ethaboxam.
123D. the composition according to details 1d to 21d, wherein the mixed compatibilis is ethionamide.
124D. the composition according to details 1d to 21d, wherein the mixed compatibilising is ethionamide.
125D. the composition according to details 1d to 21d, wherein the mixed compatibilis ethiprole.
126D. the composition according to details 1d to 21d, wherein the mixed compatibilis is acephate.
127D. the composition according to details 1d to 21d, wherein the mixed compatibilin is ethofenprox.
128D. the composition according to details 1d to 21d, wherein the mixed compatibilis is famoxadone.
129D. the composition according to details 1d to 21d, wherein the mixed compatibilising is amifos.
130D. the composition according to details 1d to 21d, wherein the mixed compatibilis is bendrophos.
131D. the composition according to details 1d to 21d, wherein the mixed compatibilis is fenazaquin.
The composition according to details 1d to 21d, wherein the mixed compatibilising is fenbuconazole.
133D. the composition according to details 1d to 21d, wherein the mixed compatibilising is phenyltin.
134D. the composition according to details 1d to 21d, wherein the mixed compatibilis fenitrothion.
The composition according to details 1d to 21d, wherein the mixed compatibilis is fengzuodi.
136D. the composition according to details 1d to 21d, wherein the mixed compatibilising is fenobucarb.
137D. the composition according to details 1d to 21d, wherein the mixed compatibilis is fenoxycarb.
138D. the composition according to details 1d to 21d, wherein the mixed compatibilising is fenpropathrin.
139D. the composition according to details 1d to 21d, wherein the mixed compatibilis is fenpyroximate.
The composition according to details 1d to 21d, wherein the mixed compatibilising is fenthion.
141D. the composition according to details 1d to 21d, wherein the mixed compatibilising is fenvalerate.
142D. the composition according to details 1d to 21d, wherein the mixed compatibilis fipronil.
143D. the composition according to details 1d to 21d, wherein the mixed compatibilising is flazasulfuron.
144D. the composition according to details 1d to 21d, wherein the mixed compatibilis is flonicamid.
145D. the composition according to details 1d to 21d, wherein the mixed compatibilis is florasulam.
146D. the composition according to details 1d to 21d, wherein the mixed compatibilis is pyriminostrobin.
147D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is trifluramide.
148D. the composition according to details 1d to 21d, wherein the mixed compatibilin is flubendiamide.
149D. the composition according to details 1d to 21d, wherein the mixed compatibilising is epothilone.
150D. the composition according to details 1d to 21d, wherein the mixed compatibilising is flucythrinate.
151D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is fludioxonil.
152D. the composition according to details 1d to 21d, wherein the mixed compatibilis is fluensulfone.
153D. the composition according to details 1d to 21d, wherein the mixed compatibilis flufenoxuron.
154D. the composition according to details 1d to 21d, wherein the mixed compatibilising is flumethrin.
155D. the composition according to details 1d to 21d, wherein the mixed compatibilis is flumioxazin.
156D. the composition according to details 1d to 21d, wherein the mixed compatibilis fluopyram.
157D. the composition according to details 1d to 21d, wherein the mixed compatibilis is trifloxysulfo.
158D. the composition according to details 1d to 21d, wherein the mixed compatibilising is fluoxastrobin.
159D. the composition according to details 1d to 21d, wherein said mixed compatibilising is flupirfuranone.
160D. the composition according to details 1d to 21d, wherein the mixed compatibilin is fluazinam.
161D. the composition according to details 1d to 21d, wherein the mixed compatibilis is fluxapyroxad.
162D. the composition according to details 1d to 21d, wherein the mixed compatibilising is fluxazolamide.
163D. the composition according to details 1d to 21d, wherein the mixed compatibilin is fluxapyroxad.
164D. the composition according to details 1d to 21d, wherein the mixed compatibilin is valdiamide.
165D. the composition according to details 1d to 21d, wherein the mixed compatibilising is fosthiazate.
166D. the composition according to details 1d to 21d, wherein the mixed compatibilis is furofacicarb.
167D. the composition according to details 1d to 21d, wherein the mixed compatibilising is gamma-cyhalothrin.
168D. the composition according to details 1d to 21d wherein the mixed compatibilising is glyphosate.
169D. the composition according to details 1d to 21d, wherein said mixed compatibilising is a fluroxypyr-meptyl ester.
170D. the composition according to details 1d to 21d, wherein the mixed compatibilis is benacarb.
171D. the composition according to details 1d to 21d, wherein the mixed compatibilising is chlorantraniliprole.
172D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is heptylphosphine.
173D. the composition according to details 1d to 21d, wherein said mixed compatibilis is hexaflumuron.
174D. the composition according to details 1d to 21d, wherein the mixed compatibilis is hexythiazox.
175D. the composition according to details 1d to 21d, wherein the mixed compatibilising is hydramethylnon.
176D. the composition according to details 1d to 21d, wherein the mixed compatibilis is nitenpyram.
177D. the composition according to details 1d to 21d, wherein the mixed compatibilis is imazethapyr.
178D. the composition according to details 1d to 21d, wherein the mixed formulation is imazapyr.
179D. the composition according to details 1d to 21d, wherein the mixed compatibilising is imidazocyclophospha.
180D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is imidacloprid.
181D. the composition according to details 1d to 21d, wherein said mixed compatibilin is cimicifuga foetida.
182D. the composition according to details 1d to 21d, wherein said mixed compatibilisation is indazapyroxamet.
183D. the composition according to details 1d to 21d, wherein the mixed compatibilis indoxacarb.
184D. the composition according to details 1d to 21d, wherein the mixed compatibilis is picolide.
185D. the composition according to details 1d to 21d, wherein the mixed compatibilis is penconazole.
186D. the composition according to details 1d to 21d, wherein the mixed compatibilin is isoxazolamide.
187D. the composition according to details 1d to 21d wherein said mixed compatibilis is isoxaprid.
188D the composition according to details 1d to 21d wherein the mixed compatibilis is iprovalicarb.
189D the composition according to details 1d to 21d, wherein the mixed compatibilising is isoprocarb.
190D. the composition according to details 1d to 21d, wherein the mixed compatibilite is isoxazole phosphorus.
191D. the composition according to details 1d to 21d, wherein said mixed compatibilising is a kadethrin.
192D. the composition according to details 1d to 21d, wherein the mixed compatibilis is methoprene.
193D. the composition according to details 1d to 21d, wherein said mixed compatibilising is lambda cyhalothrin.
194D. the composition according to details 1d to 21d, wherein the mixed compatibilis is lepidocrocin.
195D. the composition according to details 1d to 21d, wherein the mixed compatibilis is lufenuron.
196D. the composition according to details 1d to 21d, wherein the mixed compatibilising is malathion.
197D. the composition according to details 1d to 21d, wherein the mixed compatibilis is mancozeb.
198D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is MCPA.
199D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is cyphos.
200D. the composition according to details 1d to 21d, wherein the mixed compatibilis is metalaxyl-m.
201D. the composition according to details 1d to 21d, wherein the mixed compatibilis metaflumizone.
202D. the composition according to details 1d to 21d, wherein the mixed compatibilis is metalaxyl.
203D. the composition according to details 1d to 21d, wherein the mixed compatibilis is metconazole.
204D. the composition according to details 1d to 21d, wherein the mixed compatibilising is methamidophos.
205D. the composition according to details 1d to 21d, wherein the mixed compatibilising is urotropin.
206D. the composition according to details 1d to 21d, wherein the mixed compatibilis is methidathion.
207D. the composition according to details 1d to 21d, wherein the mixed compatibilis is methiocarb.
208D. the composition according to details 1d to 21d, wherein the mixed compatibilis is methomyl.
209D. the composition according to details 1d to 21d, wherein the mixed compatibilis is methoprene.
210D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is methox.
211D. the composition according to details 1d to 21d, wherein the mixed compatibilising is methoxyfenozide.
212D. the composition according to details 1d to 21d, wherein the mixed compatibilising is methomyl.
213D. the composition according to details 1d to 21d, wherein the mixed compatibilising is mesosulfuron.
214D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is acephate.
215D. the composition according to details 1d to 21d, wherein the mixed compatibilis is milbemycin.
The composition according to details 1d to 21d, wherein the mixed compatibilising substance is monocrotophos.
217D. the composition according to details 1d to 21d, wherein the mixed compatibilis is myclobutanil.
218D. the composition according to details 1d to 21d, wherein the mixed compatibilising is dibromophosphorus.
219D. the composition according to details 1d to 21d, wherein the mixed compatibilising is nicosulfuron.
220D. the composition according to details 1d to 21d, wherein the mixed compatibilising is chloropyridine.
221D. the composition according to details 1d to 21d, wherein the mixed compatibilising is a fluoroureide.
222D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is a polyfluorourea.
223D. the composition according to details 1d to 21d, wherein the mixed compatibilis is omethoate.
224D. the composition according to details 1d to 21d, wherein the mixed compatibility is methomyl.
225D. the composition according to details 1d to 21d, wherein the mixed compatibilite is fluzopyr-idone.
226D. the composition according to details 1d to 21d, wherein the mixed compatibilising is oxazolesulfonyl.
227D. the composition according to details 1d to 21d, wherein the mixed compatibilising is phophoxim.
228D. the composition according to details 1d to 21d, wherein the mixed compatibilising is parathion.
229D. the composition according to details 1d to 21d wherein said mixed compatibilising is methyl parathion.
230D. the composition according to details 1d to 21d, wherein the mixed compatibilis penflufen.
231D. the composition according to details 1d to 21d, wherein the mixed compatibilis penthiopyrad.
232D. the composition according to details 1d to 21d, wherein the mixed compatibilising is permethrin.
233D. the composition according to details 1d to 21d, wherein the mixed compatibilising is phenothrin.
234D. the composition according to details 1d to 21d, wherein the mixed compatibilising is phenthoate.
235D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is phorate.
236D. the composition according to details 1d to 21d, wherein the mixed compatibility is phosphorus oxychloride.
237D the composition according to details 1d to 21d, wherein the mixed compatibilis is phosmet.
238D. the composition according to details 1d to 21d, wherein the mixed compatibilising is a phosphazene.
239D. the composition according to details 1d to 21d, wherein the mixed compatibilis is phoxim.
240D. the composition according to details 1d to 21d, wherein the mixed compatibilis is piprazole.
241D. the composition according to details 1d to 21d, wherein the mixed compatibilis is picloram.
242D. the composition according to details 1d to 21d, wherein the mixed compatibilis is picoxystrobin.
243D. the composition according to details 1d to 21d, wherein the mixed compatibilis is pinoxaden.
244D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is pirimicarb.
245D. the composition according to details 1d to 21d, wherein the mixed compatibilite is pirimiphos-methyl.
246D. the composition according to details 1d to 21d, wherein the mixed compatibilising is dexpropathrin.
247D, the composition according to details 1d to 21d, wherein the mixed compatibilising is profenofos.
248D. the composition according to details 1d to 21d, wherein the mixed compatibilis is cyromazine.
249D. the composition according to details 1d to 21d wherein the mixed compatibilising is aminopropylvom.
250D. the composition according to details 1d to 21d, wherein the mixed compatibilising is propiconazole.
251D. a composition according to details 1d to 21d, wherein the mixed compatibility is propoxur.
252D. the composition according to details 1d to 21d, wherein the mixed compatibilis is penoxsulam.
253D. the composition according to details 1d to 21d, wherein the mixed compatibilis prothioconazole.
254D. the composition according to details 1d to 21d, wherein the mixed compatibilis propylsulfos.
255D. the composition according to details 1d to 21d, wherein said mixed compatibilis is fluxapyroxad hydroxylamine.
256D. the composition according to details 1d to 21d, wherein the mixed compatibilising is diflunisal.
257D. the composition according to details 1d to 21d, wherein the mixed compatibilin is parvalproin.
258D. the composition according to details 1d to 21d, wherein said mixed compatibilis pyrazole thiophosphorus.
259D. the composition according to details 1d to 21d, wherein the mixed compatibilin is pyraclostrobin.
260D. the composition according to details 1d to 21d, wherein the mixed compatibilis pyrethrum.
261D. the composition according to details 1d to 21d, wherein the mixed compatibilis is pyridaben.
262D. the composition according to details 1d to 21d, wherein the mixed compatibilis is pyridalyl.
263D. the composition according to details 1d to 21d, wherein the mixed compatibilite is pyridaphethione.
264D. the composition according to details 1d to 21d, wherein the mixed compatibilis is prafluquinconazole.
265D. the composition according to details 1d to 21d, wherein the mixed compatibilis is pyriminostrobin.
266D. the composition according to details 1d to 21d, wherein the mixed compatibilising is pyriproxyfen.
267D the composition according to details 1d to 21d wherein the mixed compatibility is rochloraz.
268D. the composition according to details 1d to 21d, wherein the mixed compatibilis is quetiapine.
269D the composition according to details 1d to 21d, wherein the mixed compatibilis is a pyrethrum.
270D. the composition according to details 1d to 21d, wherein the mixed compatibilising is rimsulfuron.
271D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is rotenone.
272D. the composition according to details 1d to 21d, wherein the mixed compatibilis is cyproconazole.
273D. composition according to details 1d to 21d, wherein the mixed compatibilising is silafluofen.
274D. the composition according to details 1d to 21d, wherein the mixed compatibilis is a dispiro.
275D. the composition according to details 1d to 21d, wherein the mixed compatibilising is spinetoram.
276D. the composition according to details 1d to 21d, wherein said mixed compatibilising is spinosad.
277D. the composition according to details 1d to 21d, wherein the mixed compatibilin is spirodiclofen.
278D. the composition according to details 1d to 21d, wherein the mixed compatibilis is spirodiclofen.
279D. the composition according to details 1d to 21d, wherein the mixed compatibilis is spiromesifen.
280D. the composition according to details 1d to 21d, wherein the mixed compatibilising is methoxypiperidine ethyl ester.
281D the composition according to details 1d to 21d, wherein said mixed compatibilis is spirotetramat.
282D. the composition according to details 1d to 21d, wherein the mixed compatibilis is flubendiamide.
283D. the composition according to details 1d to 21d, wherein the mixed compatibilis is fenitrothion.
284D. the composition according to details 1d to 21d, wherein the mixed compatibilin is sulfoxaflor.
285D. the composition according to details 1d to 21d, wherein the mixed compatibilising is tau-fluvalinate.
286D. the composition according to details 1d to 21d, wherein the mixed compatibilis tebuconazole.
287D. the composition of details 1d to 21d, wherein the mixed compatibilising is tebufenozide.
288D. the composition according to details 1d to 21d, wherein the mixed compatibilis tebufenpyrad.
289D. the composition according to details 1d to 21d, wherein said mixed compatibilis butyl pyrimidine phosphorus.
290D the composition according to details 1d to 21d, wherein the mixed compatibilising is flufenoxuron.
291D. the composition according to details 1d to 21d, wherein the mixed compatibilising is tefluthrin.
292D. the composition according to details 1d to 21d, wherein the mixed compatibilising is dithiophosphate.
293D. the composition according to details 1d to 21d wherein the mixed compatibilis terbutafos.
294D. the composition according to details 1d to 21d, wherein the mixed compatibilis is dicamba.
295D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is chlorfenapyr.
296D. the composition according to details 1d to 21d, wherein the mixed compatibilising is tetramethrin.
297D. the composition according to details 1d to 21d wherein the mixed compatibilising is flucyantraniliprole.
298D. the composition according to details 1d to 21d, wherein said mixed compatibilising is theta-cypermethrin.
299D. the composition according to details 1d to 21d, wherein the mixed compatibilising is thiabendazole.
300D. the composition according to details 1d to 21d, wherein the mixed compatibilite is thiamethoxam.
301D. the composition according to details 1d to 21d, wherein the mixed compatibilis is thiocyclam.
302D. the composition according to details 1d to 21d, wherein the mixed compatibilis is thiodichlox.
303D. the composition according to details 1d to 21d, wherein the mixed compatibility is monocarb.
304D. the composition according to details 1d to 21d, wherein the mixed compatibilising is methamphetamine.
305D. the composition according to details 1d to 21d, wherein the mixed compatibilis is dimehypo.
306D. the composition according to details 1d to 21d, wherein the mixed compatibili is thiram.
307D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is sulfenamide.
308D. the composition according to details 1d to 21d, wherein the mixed compatibilising is a thioxazole sulfone.
309D. the composition according to details 1d to 21d, wherein the mixed compatibilin is tolfenpyrad.
310D. the composition according to details 1d to 21d, wherein the mixed compatibilis is a trifloxystrobin.
311D. the composition according to details 1d to 21d, wherein the mixed compatibilising is tetrabromothrin.
312D. the composition according to details 1d to 21d, wherein the mixed compatibilising is transfluthrin.
313D. the composition according to details 1d to 21d, wherein the mixed compatibilis triazamate.
314D. the composition according to details 1d to 21d, wherein the mixed compatibilite is triazophos.
315D. the composition according to details 1d to 21d, wherein the mixed compatibilising is trichlorfon.
316D. the composition according to details 1d to 21d, wherein the mixed compatibilis is triclopyr.
317D. the composition according to details 1d to 21d, wherein the mixed compatibilis is trifloxystrobin.
318D. the composition according to details 1d to 21d, wherein the mixed compatibilite is trifluoracene.
319D. a composition according to details 1d to 21d, wherein the mixed compatibilising substance is triflumuron.
320D. the composition according to details 1d to 21d, wherein the mixed compatibility is trazocarb.
321D. the composition according to details 1d to 21d, wherein the mixed compatibilis is triamcinolone.
322D. the composition according to details 1d to 21d, wherein the mixed compatibilising is XMC.
323D. the composition according to details 1d to 21d, wherein the mixed compatibilising substance is methomyl.
324D. a composition according to details 1d to 21d, wherein the mixed compatibilising is zeta-cypermethrin.
325D. the composition according to details 1D to 21D, wherein said mixed compatibilisation is 2,4-D.
326D. the composition of any one of the preceding details 1d to 21d, wherein the mixed compatibilis is metazachlor.
327D the composition according to any one of the preceding details 1d to 21d, wherein the mixed compatibilising substance is N- (4-chloro-2- (pyridin-3-yl) thiazol-5-yl) -N-ethyl-3- (methylsulfonyl) propanamide (AI-1)
328D the composition according to any one of the preceding details 1d to 21d, wherein the mixed compatibilising substance is N- (3-chloro-1- (pyridin-3-yl) -1H-pyrazol-4-yl) -2- (methylsulfonyl) propanamide (AI-2)
329D the composition of any of the preceding details 1d to 328d, wherein the weight ratio of the molecule to the mixed compatibiliser is from about 50000:1 to about 1:50000.
The composition of any one of the preceding details 1d to 328d, wherein the weight ratio of the molecule to the mixed compatibiliser is about 40000:1 to about 1:40000.
331D the composition of any of the preceding details 1d to 328d, wherein the weight ratio of the molecule to the mixed compatibiliser is about 10256:1 to about 1:10256.
The composition of any one of the preceding details 1d to 328d, wherein the weight ratio of the molecule to the mixed compatibiliser is about 10000:1 to about 1:10000.
333D the composition of any of the preceding details 1 d-328 d, wherein the weight ratio of the molecule to the mixed compatibiliser is about 2564:1 to about 1:2564.
334D, the composition of any one of the preceding details 1d to 328d, wherein the weight ratio of the molecule to the mixed compatibiliser is 1000:1 to about 1:1000.
335D the composition of any of the preceding details 1d to 328d, wherein the weight ratio of the molecule to the mixed compatibiliser is from about 640:1 to about 1:640.
336D the composition of any one of the preceding details 1d to 238d, wherein the weight ratio of the molecule to the mixed compatibiliser is 500:1 to about 1:500.
337D the composition of any of the preceding details 1 d-238 d, wherein the weight ratio of the molecule to the mixed compatibiliser is from 100:1 to about 1:100.
338D the composition of any one of the preceding details 1d to 238d, wherein the weight ratio of the molecule to the mixed compatibiliser is from 50:1 to about 1:50.
339D, the composition of any one of the preceding details 1d to 238d, wherein the weight ratio of the molecule to the mixed compatibiliser is 20:1 to about 1:20.
The composition of any one of the preceding details 1d to 328d, wherein the weight ratio of the molecule to the mixed compatibiliser is about 16:1 to about 1:16.
341D the composition of any one of the preceding details 1d to 238d, wherein the weight ratio of the molecule to the mixed compatibiliser is from 10:1 to about 1:10.
342D the composition of any one of the preceding details 1d to 238d, wherein the weight ratio of the molecule to the mixed compatibiliser is from 5:1 to about 1:5.
343D the composition of any of the preceding details 1d to 238d, wherein the weight ratio of the molecule to the mixed compatibiliser is from 3:1 to about 1:3.
344D the composition of any one of the preceding details 1d to 238d, wherein the weight ratio of the molecule to the mixed compatibiliser is from 2:1 to about 1:2.
345D the composition of any preceding detail 1 d-238 d, wherein the weight ratio of the molecule to the mixed compatibility is 1:1.
346D. a method of controlling pests in a locus by using a pesticidally effective amount of a pesticidally composition according to any of the preceding details 1d to 345 d.
347D, the method of detail 346d, wherein the pest is from the phylum arthropoda, mollusca, and/or nematoda.
348D. the method of detail 346d, wherein the pest is an ant, aphid, bed bug, beetle, borer, caterpillar, cockroach, cricket, earwig, flea, fly, grasshopper, maggot, hornet, leafhopper, she Tiaochong, lice, locust, maggot, white-shell, mite, moths, nematode, lygus, planthopper, psyllid, leaf bees, scale, silverfish, slug, snail, spider, springtail, stink bug, complex class, termite, thrips, ticks, wasp, whitefly, and/or iron wire.
349D. The method of detail 346d, wherein the pest is an aphid, she Tiaochong, a moth, a scale insect, a thrips, a psyllid, a white fly, a stink bug, and/or a white fly.
350D. the method of detail 346d, wherein the pest is a caterpillar, a beetle, a grasshopper, and/or a locust.
351D. the composition according to detail 3d, wherein the mixed compatibilising agent is one selected from AIGA.
352D the composition according to detail 3d, wherein the mixed compatibilising agent is one selected from AIGA-1.
353D. the composition according to detail 3d, wherein said mixed compatibilising is abamectin.
354D. the composition according to detail 3d, wherein said mixed compatibilising agent is acephate.
355D the composition according to detail 3d, wherein said mixed compatibilising agent is chloranil.
356D. the composition according to detail 3d, wherein the mixed compatibilising is acetamiprid.
357D. the composition according to detail 3d, wherein said mixed compatibilising is bifenthrin.
358D, according to detail 3d, wherein said mixed compatibilisation is acynonapyr.
359D. the composition according to detail 3d wherein said mixed compatibilis is pyripyropene-ciprofloxacin.
360D. the composition according to detail 3d, wherein the mixed compatibilising is carbofuran.
361D. the composition according to detail 3d, wherein the mixed compatibilising is aldicarb.
362D, a composition according to detail 3d, wherein the mixed compatibilising is allethrin.
363D the composition according to detail 3d wherein the mixed compatibilising is alpha-cypermethrin.
364D. the composition according to detail 3d, wherein the mixed compatibilising is aminopyralid.
365D. the composition according to detail 3d, wherein the mixed compatibilising is amitraz.
366D. the composition according to detail 3d, wherein the mixed compatibilising agent is azadirachtin.
367D. the composition according to detail 3d, wherein the mixed compatibilising is picoline phosphorus.
368D. the composition according to detail 3d, wherein said mixed compatibilising is valphos-ethyl.
369D. the composition according to detail 3d, wherein the mixed compatibilising is valphos-methyl.
370D. the composition according to detail 3d, wherein the mixed compatibilising agent is azocyclotin.
371D. the composition according to detail 3d wherein said mixed compatibilising is azoxystrobin.
372D. the composition according to detail 3d, wherein the mixed compatibilising is bendiocarb.
373D, according to detail 3d, wherein said mixed compatibilising is benfuracarb.
374D. the composition according to detail 3d, wherein the mixed compatibilising is insecticidal sulphonic acid.
375D the composition according to detail 3d wherein said mixed compatibilising is saflufenacil.
376D. the composition according to detail 3d, wherein the mixed compatibilising is beta-cyhalothrin.
377D. the composition of detail 3d, wherein the mixed compatibilising is beta-cypermethrin.
378D. the composition according to detail 3d, wherein the mixed compatibilising is bifenazate.
379D the composition according to detail 3d, wherein the mixed compatibilising agent is bifenthrin.
380D. the composition according to detail 3d, wherein the mixed compatibilising is bioallethrin.
381D. the composition according to detail 3d, wherein said mixed compatibilis is biobifenthrin.
382D, the composition according to detail 3d, wherein said mixed compatibilising is bistrifluron.
383D. the composition according to detail 3d, wherein the mixed compatibilising agent is bromoxynil.
384D. the composition according to detail 3d, wherein the mixed compatibilis is fenpyroximate.
385D. the composition according to detail 3d, wherein said mixed compatibilising is buprofezin.
386D. the composition according to detail 3d, wherein said mixed compatibilising is carbofuran.
387D the composition according to detail 3d, wherein the mixed compatibilising is butanone sulfone wive.
388D the composition according to detail 3d, wherein the mixed compatibilising agent is phoxim.
389D. the composition according to detail 3d, wherein the mixed compatibilising is carbaryl.
390D, a composition according to detail 3d, wherein the mixed compatibilising is carbofuran.
391D. the composition according to details 1d to 21d wherein the mixed compatibilising is carbosulfan.
392D. the composition according to detail 3d, wherein the mixed compatibilis is carboxin.
393D the composition according to detail 3d, wherein the mixed formulation is cartap hydrochloride.
394D. the composition according to detail 3d, wherein the mixed compatibilising agent is miticidal.
395D the composition according to detail 3d wherein the mixed compatibilising substance is chlorantraniliprole.
396D the composition according to detail 3d wherein said mixed compatible is chlordane.
398. The composition of detail 3d, wherein the mixed compatibilis is chlorfenapyr.
399D the composition according to detail 3d, wherein said mixed compatibilis is chlorantraniliprole.
400D. the composition according to detail 3d, wherein the mixed compatibilising agent is chlorfluazuron.
401D. the composition according to detail 3d, wherein the mixed compatibilising agent is clodronate.
402D. the composition according to detail 3d, wherein the mixed compatibilising agent is chlorpyrifos.
403D. the composition according to detail 3d, wherein said mixed compatibilising agent is chlorpyrifos methyl.
404D. the composition according to detail 3d, wherein the mixed compatibilising is chromafenozide.
405D the composition according to detail 3d, wherein the mixed compatibilising is clopyralid.
406D. the composition according to detail 3d, wherein the mixed compatibilising is cloquintocet-mexyl.
407D, the composition according to detail 3d, wherein the mixed compatibilising agent is clothianidin.
408D. The composition according to detail 3d, wherein the mixed compatibilising is copper hydroxide.
409D. the composition according to detail 3d, wherein the mixed compatibilising is coumaphos.
410D. the composition according to detail 3d, wherein the mixed compatible compound is fenitrothion.
411D. the composition according to detail 3d, wherein the mixed compatibilising agent is cyantraniliprole.
412D. the composition according to detail 3d, wherein the mixed compatibilising is cycloxaprid.
413D according to detail 3d, wherein the mixed formulation is a ring Ding Fulun.
414D. the composition according to detail 3d, wherein the mixed compatibilising is etofenprox.
415D. the composition according to detail 3d, wherein the mixed compatibilising is cycloxaprid.
416D. the composition according to detail 3d, wherein the mixed compatibilis is cyenopyrafen.
417D. the composition according to detail 3d, wherein the mixed compatibilis is cyflumetofen.
418D. the composition according to detail 3d, wherein the mixed compatibilising is cyhalothrin.
419D. the composition according to detail 3d, wherein the mixed compatibilising is cyhalothrin.
420D. the composition according to detail 3d, wherein the mixed compatibilising agent is tricyclotin.
421D the composition according to detail 3d, wherein said mixed compatibilising is cymoxanil.
422D the composition according to detail 3d, wherein the mixed compatibilising is cypermethrin.
423D. the composition according to detail 3d, wherein the mixed compatibilising is fenpropathrin.
424D. the composition according to detail 3d, wherein the mixed compatibilis is cyflufenapyr.
425D. the composition according to detail 3d, wherein said mixed compatibilising is cyromazine.
426D. the composition according to detail 3d, wherein the mixed compatibilising is d-cis-trans allethrin.
427D. the composition according to detail 3d, wherein said mixed compatibilising agent is DDVP.
428D. the composition according to detail 3d, wherein the mixed compatibilising is deltamethrin.
429D. the composition according to detail 3d, wherein said mixed compatibilising is Neoprene-S-methyl.
430D. the composition according to detail 3d, wherein the mixed compatibilising agent is diafenthiuron.
431D the composition according to detail 3d, wherein the mixed compatibiliser is diazinon.
432D. the composition according to detail 3d, wherein the mixed compatibilising agent is dichlorvos.
433D, the composition according to detail 3d, wherein the mixed compatibilising agent is chlorfenapyr.
434D. the composition according to detail 3d, wherein the mixed compatibilising is baizhifu.
435D, the composition according to detail 3d, wherein the mixed compatibilising is difenoconazole.
436D the composition according to detail 3d, wherein said mixed compatibilin is flufenzine.
437D. the composition according to detail 3d, wherein the mixed compatibilising agent is a difluoride.
438D. the composition according to detail 3d, wherein the mixed compatibilising is Dimethoate.
439D. the composition according to detail 3d, wherein the mixed compatibilis is methylparaben.
440D. the composition according to detail 3d, wherein the mixed compatibilising is zinxazole amide.
441D the composition according to detail 3d, wherein the mixed compatibilising is dinotefuran.
442D. the composition according to detail 3d, wherein the mixed compatibilising is etoposide.
443D. the composition according to detail 3d, wherein said mixed compatibilising agent is DNOC.
444D. the composition according to detail 3d, wherein the mixed compatibilising is d-trans allethrin.
445D. the composition according to detail 3d, wherein the mixed compatibilising is emamectin benzoate.
446D. the composition according to detail 3d, wherein the mixed compatibilising is emamectin benzoate.
447D. the composition of detail 3d wherein said mixed compatibilising is eneyne pyrethrin.
448D. the composition according to detail 3d, wherein the mixed compatibilising agent is endosulfan.
449D the composition according to detail 3d wherein the mixed compatibilisation is EPN.
450D the composition according to detail 3d, wherein the mixed compatibilising is fenvalerate.
451D. the composition according to detail 3d, wherein the mixed compatible agent is ethaboxam.
452D. the composition according to detail 3d, wherein the mixed compatibilis is ethionamide.
453D, wherein the mixed compatibilising is ethionamide, according to detail 3d.
454D. the composition according to detail 3d, wherein the mixed compatibilising is ethiprole.
455D. the composition according to detail 3d, wherein said mixed compatibilising is acephate.
456D. the composition according to detail 3d, wherein said mixed compatibilising is ethofenprox.
457D. the composition according to detail 3d, wherein the mixed compatibilis is famoxadone.
458D. the composition according to detail 3d, wherein the mixed compatibilising is amifos.
459D the composition according to detail 3d wherein the mixed compatibilising agent is bendrophos.
460D. the composition according to detail 3d, wherein the mixed compatibilis is fenazaquin.
461D. the composition according to detail 3d, wherein the mixed compatibilising is fenbuconazole.
462D. the composition according to detail 3d, wherein the mixed compatibilising agent is bestin.
463D. the composition according to detail 3d, wherein the mixed compatibilising is fenitrothion.
464D, wherein the mixed compatibilis is fengzuodi, according to the composition of detail 3d.
465D. the composition according to detail 3d, wherein said mixed compatibilising is fenobucarb.
466D the composition according to detail 3d, wherein the mixed compatibilising is fenoxycarb.
467D. the composition of detail 3d, wherein the mixed compatibilising is fenpropathrin.
468D. the composition according to detail 3d, wherein the mixed compatibilis is fenpyroximate.
469D. the composition of detail 3d, wherein the mixed compatibilising is fenthion.
470D. the composition according to detail 3d, wherein the mixed compatibilising is fenvalerate.
471D. the composition according to detail 3d, wherein the mixed compatible compound is fipronil.
472D. the composition according to detail 3d, wherein the mixed compatibilising is flazasulfuron.
473D the composition of detail 3d, wherein said mixed compatibilis is flonicamid.
474D. the composition according to detail 3d, wherein the mixed compatibilis is florasulam.
475D the composition according to detail 3d wherein said mixed compatibilis is pyriminostrobin.
476D. a composition according to detail 3d wherein the mixed compatibilising is trifluralin.
477D the composition according to detail 3d wherein the mixed compatibilising agent is flubendiamide.
478D. the composition according to detail 3d, wherein said mixed compatibilising is a epoxiconamide.
479D the composition according to detail 3d wherein the mixed compatibilising agent is flucythrinate.
480D. the composition according to detail 3d, wherein the mixed compatibilising is fludioxonil.
481D. the composition according to detail 3d, wherein the mixed compatibilis is fluensulfone.
482D the composition according to detail 3d wherein the mixed compatibilising agent is flufenoxuron.
483D the composition according to detail 3d, wherein the mixed compatibilising is flumethrin.
484D. the composition according to detail 3d, wherein the mixed compatibilising is flumioxazin.
485D the composition according to detail 3d, wherein said mixed compatibilising substance is fluopyram.
486D. the composition according to detail 3d, wherein the mixed compatibilising is fluoxastrobin.
487D the composition according to detail 3d, wherein the mixed compatibilising is fluoxastrobin.
488D. the composition according to detail 3d, wherein the mixed compatibilising is flupirfuranone.
489D the composition according to detail 3d, wherein the mixed compatibilin is fluazinam.
490D. the composition according to detail 3d, wherein the mixed compatibilising is fluoxastrobin.
491D. the composition according to detail 3d, wherein said mixed compatibilising is fluxapyroxad.
492D. the composition according to detail 3d, wherein the mixed compatibilis is fluxapyroxad.
493D the composition according to detail 3d wherein said mixed compatibilis is varroa amidine.
494D, the composition according to detail 3d, wherein the mixed compatible compound is fosthiazate.
495D the composition according to detail 3d, wherein said mixed compatible compound is furben.
496D the composition according to detail 3d wherein the mixed compatibilising is gamma-cyhalothrin.
497D the composition according to detail 3d wherein said mixed compatibilising is glyphosate.
498D the composition according to detail 3d wherein said mixed compatibilising is a fluroxypyr meptyl ester.
499D the composition according to detail 3d, wherein said mixed compatibilis is benzyl fenpyrad.
500D. the composition according to detail 3d, wherein the mixed compatibilising is chlorantraniliprole.
501D. the composition according to detail 3d, wherein the mixed compatibilising is heptylphosphine.
502D. the composition according to detail 3d, wherein the mixed compatibilising agent is hexaflumuron.
503D. the composition according to detail 3d, wherein the mixed compatibilising agent is hexythiazox.
504D. the composition according to detail 3d, wherein the mixed compatible compound is flumizone.
505D. the composition according to detail 3d, wherein the mixed compatibilising is nitenpyram.
506D. the composition according to detail 3d, wherein the mixed compatibilis is imazethapyr.
507D. the composition according to detail 3d, wherein the mixed formulation is imazapyr.
508D. the composition according to detail 3d, wherein the mixed compatibilising agent is ifosfate.
509D. the composition according to detail 3d, wherein the mixed compatibilising is imidacloprid.
510D. the composition according to detail 3d, wherein the mixed compatibilising is cimetidine.
511D. According to the composition described in detail 3d, wherein the mixed formulation is indazapyroxamet.
512D. the composition according to detail 3d, wherein the mixed compatibilis indoxacarb.
513D the composition according to detail 3d, wherein the mixed compatibilis is picolide.
514D. the composition according to detail 3d, wherein the mixed compatibilis is ipconazole.
515D. the composition according to detail 3d, wherein the mixed compatibilis is isoxazole tebufenozide.
516D. the composition according to detail 3d, wherein the mixed compatibilis is isosalsalazine.
517D the composition according to detail 3d, wherein the mixed compatibilis is iprovalicarb.
518D. the composition according to detail 3d, wherein the mixed compatibilising agent is isoprocarb.
519D the composition according to detail 3d, wherein the mixed compatibilising agent is isoxazole phosphorus.
520D the composition according to detail 3d, wherein said mixed compatibilising is a kadethrine.
521D. the composition according to detail 3d, wherein said mixed compatibilising is methoprene.
522D. the composition according to detail 3d, wherein said mixed compatibilising is lambda cyhalothrin.
523D. the composition according to detail 3d, wherein said mixed compatibilising is lepidocrocin.
524D the composition according to detail 3d, wherein the mixed compatibilis is lufenuron.
525D. the composition according to detail 3d, wherein said mixed compatibilising is malathion.
526D. the composition according to detail 3d, wherein the mixed compatibilising is mancozeb.
527D the composition according to detail 3d, wherein the mixed compatibilising agent is MCPA.
528D. the composition according to detail 3d, wherein the mixed compatibilising agent is cyphos.
529D the composition according to detail 3d, wherein said mixed compatibilising is metalaxyl-m.
530D. the composition according to detail 3d, wherein the mixed compatibilising is metaflumizone.
531D. the composition according to detail 3d, wherein said mixed compatibilising is metalaxyl.
532D. the composition according to detail 3d, wherein the mixed compatibilis is metconazole.
533D. the composition according to detail 3d, wherein said mixed compatibilising agent is methamidophos.
534D. the composition according to detail 3d, wherein the mixed compatibilising is urotropin.
535D. the composition according to detail 3d, wherein the mixed compatibilising agent is methidathion.
536D. the composition according to detail 3d, wherein said mixed compatibilising is methiocarb.
537D. the composition according to detail 3d, wherein the mixed compatibilising is methomyl.
538D the composition according to detail 3d, wherein the mixed compatible agent is methoprene.
539D the composition according to detail 3d, wherein the mixed compatibilising agent is methox.
540D. the composition according to detail 3d, wherein the mixed compatibilising is methoxyfenozide.
541D the composition according to detail 3d wherein said mixed compatibilis is methomyl.
542D. the composition according to detail 3d, wherein the mixed compatibilising is metsulfuron-methyl.
543D. the composition according to detail 3d, wherein the mixed compatibilising agent is acephate.
544D the composition according to detail 3d, wherein the mixed compatibilising agent is milbemycin.
545D the composition according to detail 3d wherein the mixed compatibilising agent is monocrotophos.
546D the composition according to detail 3d, wherein the mixed compatibilis is myclobutanil.
547D the composition according to detail 3d, wherein the mixed compatibilising is dibromophosphorus.
548D. the composition according to detail 3d wherein said mixed compatibilising is nicosulfuron.
549D the composition of detail 3d, wherein the mixed compatibilising agent is chlorodine.
550D. the composition according to detail 3d, wherein the mixed compatibilising agent is a fluoroureide.
551D the composition according to detail 3d wherein said mixed compatibilising agent is a polyfluorourea.
552D the composition according to detail 3d, wherein the mixed compatibilising is omethoate.
553D the composition according to detail 3d, wherein said mixed compatibilis is carbofuran.
554D, the composition according to detail 3d, wherein said mixed compatible compound is fluzopyr-diethyl ketone.
555D the composition according to detail 3d, wherein the mixed compatibilising agent is oxazolesulfonyl.
556D. the composition according to detail 3d, wherein the mixed compatibilising is phophoxim.
557D the composition according to detail 3d wherein said mixed compatibilising is parathion.
558D. the composition according to detail 3d, wherein said mixed compatibilising is methyl parathion.
559 A composition according to detail 3d wherein said mixed compatibilis is penflufen.
560D. the composition according to detail 3d, wherein the mixed compatibilis is penthiopyrad.
561D. a composition according to detail 3d, wherein said mixed compatibilising is permethrin.
562D. the composition according to detail 3d, wherein the mixed compatibilising is phenothrin.
563D. the composition according to detail 3d, wherein the mixed compatibilising is phenthoate.
564D, a composition according to detail 3d, wherein said mixed compatibilising is phorate.
565D the composition according to detail 3d, wherein the mixed compatibility is phosphorus oxychloride.
566D. a composition according to detail 3d, wherein said mixed compatibilising is phosmet.
567D. the composition according to detail 3d, wherein said mixed compatibilising is a phosphazene.
568D. the composition according to detail 3d, wherein the mixed compatibilising is phoxim.
569D. the composition according to detail 3d, wherein the mixed compatibilising is piprazole.
570D. the composition according to detail 3d, wherein the mixed compatibilising is picloram.
571D. the composition according to detail 3d, wherein the mixed compatibilis is picoxystrobin.
572D. the composition according to detail 3d, wherein the mixed compatibilis is pinoxaden.
573D. the composition according to detail 3d, wherein the mixed compatibilising is pirimicarb.
574D. the composition according to detail 3d, wherein the mixed compatibilising is pirimiphos-methyl.
575D. the composition according to detail 3d, wherein the mixed compatibilising is dexprallethrin.
576D. the composition according to detail 3d wherein said mixed compatibilising is profenofos.
577D. the composition according to detail 3d, wherein the mixed compatibilis is cyromazine.
578D. the composition according to detail 3d, wherein the mixed compatibilising is aminopropylvom.
579D. the composition according to detail 3d, wherein the mixed compatibilising is propiconazole.
580D. the composition according to detail 3d, wherein said mixed compatibilising is propoxur.
581D. the composition according to detail 3d, wherein the mixed compatibilis is penoxsulam.
582D. the composition according to detail 3d, wherein the mixed compatibilis prothioconazole.
584D. the composition according to detail 3d, wherein said mixed compatibilising is fluxapyroxad hydroxylamine.
585D. the composition according to detail 3d, wherein the mixed compatibilising is diflunisal.
586D. the composition according to detail 3d, wherein the mixed compatibilising agent is parvalproin.
587D. the composition according to detail 3d, wherein the mixed compatibilising is pyraclostrobin.
588D. the composition according to detail 3d, wherein the mixed compatibilis is pyraclostrobin.
589D. the composition according to detail 3d, wherein the mixed compatibilis pyrethrum.
590D. the composition according to detail 3d, wherein the mixed compatibilin is pyridaben.
591D. the composition according to detail 3d, wherein the mixed compatibilising is pyridalyl.
592D. the composition according to detail 3d, wherein the mixed compatibilising is pyridaphethione.
593D. the composition according to detail 3d, wherein the mixed compatibilis praziquantel is praziquantel.
594D. the composition according to detail 3d, wherein the mixed compatibilis is pyriminostrobin.
595D. the composition according to detail 3d, wherein said mixed compatibilising is pyriproxyfen.
596D. the composition according to detail 3d, wherein the mixed compatibilis rochlox.
597D. the composition according to detail 3d, wherein said mixed compatibilis is quetiapine.
598D. the composition according to detail 3d, wherein the mixed compatibilis is a pyrethrum.
599D. the composition according to detail 3d, wherein the mixed compatibilising is rimsulfuron.
600D. the composition according to detail 3d, wherein the mixed compatibilising agent is rotenone.
601D. the composition according to detail 3d, wherein the mixed compatibilis is cyproconazole.
602D. the composition according to detail 3d, wherein the mixed compatibilising is silafluofen.
603D. the composition according to detail 3d, wherein the mixed compatibilis is a dispiro.
604D, the composition according to detail 3d, wherein said mixed compatibilising is spinetoram.
605D. The composition according to detail 3d, wherein the mixed compatibilising is spinosad.
606D. the composition according to detail 3d, wherein the mixed compatibilis is spirodiclofen.
607D. the composition according to detail 3d, wherein said mixed compatibilis is spirodiclofen.
608D. the composition according to detail 3d, wherein the mixed compatibilis is spiromesifen.
609D the composition according to detail 3d wherein the mixed compatible compound is methoxypiperidine ethyl ester.
610D. the composition according to detail 3d, wherein the mixed compatibilising agent is spirotetramat.
611D. the composition according to detail 3d, wherein the mixed compatibilising is flubendiamide.
612D. the composition according to detail 3d, wherein the mixed compatibilising agent is phoaphalocrocis medinalis.
613D. the composition according to detail 3d, wherein the mixed compatibilising is sulfoxaflor.
614D. the composition according to detail 3d, wherein the mixed compatibilising is tau-fluvalinate.
615D. the composition according to detail 3d, wherein the mixed compatibilising is tebuconazole.
618D. the composition according to detail 3d, wherein the mixed compatibilising is butyl pyrimidine phosphorus.
619D the composition according to detail 3d wherein said mixed compatibilising agent is flubenurea.
620D. the composition according to detail 3d, wherein the mixed compatibilising is tefluthrin.
621D. the composition according to detail 3d, wherein the mixed compatibilising is phosphorus disulfide.
622D. the composition according to detail 3d, wherein said mixed compatibilising is terbutafos.
623D the composition according to detail 3d, wherein the mixed compatibilising agent is dicamba.
624D. the composition according to detail 3d, wherein the mixed compatibilising is chlorpyrifos.
625D. the composition according to detail 3d, wherein the mixed compatibilising is tetramethrin.
626D. the composition according to detail 3d, wherein the mixed compatibilising is flucyantraniliprole.
627D. the composition according to detail 3d, wherein the mixed compatibilising agent is theta-cypermethrin.
628D. the composition according to detail 3d, wherein the mixed compatible agent is thiabendazole.
629D the composition according to detail 3d wherein the mixed compatibilising agent is thiamethoxam.
630D the composition according to detail 3d, wherein the mixed compatibilising agent is thiocyclam.
631D. the composition according to detail 3d, wherein the mixed compatibilising is thiodix.
632D. the composition according to detail 3d, wherein the mixed compatibilising agent is monocarb.
633D. the composition according to detail 3d, wherein the mixed compatibilising is methamphetamine.
634D. the composition according to detail 3d, wherein the mixed compatibilising agent is bisultap.
635D, the composition according to detail 3d, wherein the mixed compatibili-mate is thiram.
636D. The composition according to detail 3d, wherein the mixed compatibilis sulfenamide.
637D composition according to detail 3d, wherein the mixed compatibilising is a thiaxazole sulfone.
638D. the composition according to detail 3d, wherein the mixed compatibilis tolfenpyrad.
639D composition according to detail 3d, wherein the mixed compatibilis is trifloxystrobin.
640D. According to the composition described in detail 3d, wherein the mixed compatibilin is tetrabromothrin.
641D. the composition according to detail 3d, wherein said mixed compatibilising is transfluthrin.
642D. the composition according to detail 3d, wherein the mixed compatibilising is triazamate.
643D the composition of detail 3d, wherein said mixed compatibilis triazophos.
644D. the composition according to detail 3d wherein the mixed compatibilising agent is trichlorfon.
645D. the composition according to detail 3d, wherein the mixed compatibilis is triclopyr.
646D. the composition according to detail 3d, wherein the mixed compatibilising is trifloxystrobin.
647D. the composition of detail 3d, wherein said mixed compatibilising is trifluoracene.
648D. the composition according to detail 3d, wherein said mixed formulation is hexaflumuron.
649D the composition of detail 3d, wherein said mixed compatibility is methomyl.
650D. the composition according to detail 3d, wherein the mixed compatibilising is triticonazole.
651D the composition according to detail 3d, wherein said mixed compatibilising substance is triamcinolone.
652D. the composition according to detail 3d, wherein the mixed compatibilising agent is XMC.
653D the composition according to detail 3d, wherein said mixed compatibilising is methomyl.
654D. the composition according to detail 3d, wherein the mixed compatibilising is zeta-cypermethrin.
655D. the composition according to detail 3D, wherein the mixed compatibilisation is 2,4-D.
656D. the composition according to detail 3d, wherein the mixed compatibilising is metazachlor.
657D the composition according to detail 3d, wherein said mixed compatibilising is N- (4-chloro-2- (pyridin-3-yl) thiazol-5-yl) -N-ethyl-3- (methylsulfonyl) propanamide (AI-1)
658D. the composition according to detail 3d, wherein the mixed compatibilising agent is N- (3-chloro-1- (pyridin-3-yl) -1H-pyrazol-4-yl) -2- (methylsulfonyl) propanamide (AI-2)
659D. the composition according to detail 3d, wherein said mixed compatibilising is a heat inactivated Burkholderia species (Burkholderia spp).
660D the composition of any of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibiliser is from about 40000:1 to about 1:40000.
661D. the composition of any of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibiliser is about 10256:1 to about 1:10256.
662D the composition according to any of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibiliser is from about 10000:1 to about 1:10000.
663D the composition of any of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibiliser is about 2564:1 to about 1:2564.
664D the composition according to any of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibility is from 1000:1 to about 1:1000.
665D the composition according to any of the preceding details 351 d-659 d, wherein the weight ratio of F1 to the mixed compatibiliser is from about 640:1 to about 1:640.
666D the composition according to any one of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibiliser is from 500:1 to about 1:500.
667D the composition of any of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibiliser is from 100:1 to about 1:100.
668D the composition of any of the foregoing details 351d through 659d, wherein the weight ratio of F1 to the mixed compatibiliser is 50:1 to about 1:50.
669D the composition of any of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibiliser is 20:1 to about 1:20.
670D the composition of any of the preceding details 351 d-659 d, wherein the weight ratio of F1 to the mixed compatibiliser is about 16:1 to about 1:16.
671D the composition of any of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibiliser is 10:1 to about 1:10.
672D the composition of any of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibiliser is from 5:1 to about 1:5.
673D the composition of any of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibiliser is 3:1 to about 1:3.
674D, the composition of any one of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibiliser is from 2:1 to about 1:2.
675D the composition of any of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibiliser is 1:1.
676D the composition of any of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibiliser is 1:20,000 to 20,000:1.
677D the composition of any of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibiliser is 1:2,000 to 2,000:1.
678D the composition of any of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibiliser is 1:160,000 to 160,000:1.
679D the composition of any of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibiliser is 1:80,000 to 80,000:1.
680D, the composition according to any of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibiliser is 1:16,000 to 16,000:1.
681D the composition of any of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibiliser is 1:8,000 to 8,000:1.
682D the composition of any of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibiliser is 1:250 to 250:1.
683D the composition according to any of the preceding details 351d to 659d, wherein the weight ratio of F1 to the mixed compatibiliser is from 1:25 to 25:1.
684D. a method of controlling pests in a locus by using a pesticidally effective amount of a pesticidally composition according to any of the preceding details 351d to 683 d.
685D the method of detail 684d, wherein said pest is from the phylum arthropoda, mollusca, and/or nematoda.
686D the method according to detail 684d wherein the pest is ants, aphids, bed bugs, beetles, moths, caterpillars, cockroaches, crickets, earwigs, fleas, flies, grasshoppers, maggots, wasps, leafhoppers, she Tiaochong, lice, locust, maggots, white-scale insects, mites, moths, nematodes, plant bugs, planthoppers, psyllids, leaf bees, scale insects, silverfish, slugs, snails, spiders, jumpers, stink bugs, complex class, termites, thrips, ticks, wasps, whiteflies, and iron nematodes.
687D the method according to detail 684d wherein said pest is aphid, she Tiaochong, moth, scale, thrips, psyllid, white fly, stink bug, and/or white fly.
688D the method according to detail 684d, wherein said pest is a caterpillar, beetle, grasshopper, and/or locust.
In some aspects of the pesticidal compositions disclosed herein, the molecule having the structure of formula one is F1. In some aspects, the pesticidal compositions disclosed herein comprise F1 and at least one active ingredient selected from AIGA-1. In some other aspects, the pesticidal compositions disclosed herein comprise F1 and at least two active ingredients selected from AIGA-1. In some other aspects, the pesticidal compositions disclosed herein comprise F1 and at least three active ingredients selected from AIGA-1. In certain other aspects, the pesticidal compositions disclosed herein comprise F1 and at least four active ingredients selected from AIGA-1. In some aspects, the pesticidal compositions disclosed herein comprise F1 and AI-2. In some other aspects, the pesticidal compositions disclosed herein comprise F1 and AI-1.
In some aspects, the pesticidal compositions disclosed herein comprise F1 and another active ingredient selected from the group consisting of cyclo Ding Fulun, isoxazolamide, dispiro, methylpiperidine ethyl, oxazamate, and fenbuzonad. The ratio of F1 to any of these ingredients is a ratio of 1:100 to 100:1.
In some aspects, the pesticidal compositions disclosed herein comprise F1 and a loop Ding Fulun. The ratio of F1 to ring Ding Fulun is 1:200 to 200:1. When F1 is mixed with the ring Ding Fulun in a ratio within this range, enhanced efficacy can be expected. By "enhanced efficacy" in this context is meant efficacy that is greater than the expected efficacy as calculated by the Colby equation.
In some aspects, the pesticidal compositions disclosed herein comprise F1 and isoxazole tebufenozide. The ratio of F1 to isoxazole tebufenozide is 1:200 to 200:1. When F1 is mixed with isoxaflutole in a ratio within this range, enhanced efficacy can be expected. By "enhanced efficacy" in this context is meant efficacy that is greater than the expected efficacy as calculated by the colpitis equation.
In some aspects, the pesticidal compositions disclosed herein comprise F1 and dispiro. The ratio of F1 to dispiro is 1:200 to 200:1. When F1 is mixed with dispiro at a ratio within this range, enhanced efficacy can be expected. By "enhanced efficacy" in this context is meant efficacy that is greater than the expected efficacy as calculated by the colpitis equation.
In some aspects, the pesticidal compositions disclosed herein comprise F1 and methylpiperidine ethyl. The ratio of F1 to methoxypiperidine ethyl ester is from 1:200 to 200:1. When F1 is mixed with methoxypiperidine ethyl ester in a proportion within this range, enhanced efficacy can be expected. By "enhanced efficacy" in this context is meant efficacy that is greater than the expected efficacy as calculated by the colpitis equation.
In some aspects, the pesticidal compositions disclosed herein comprise F1 and metaxazole amide. The ratio of F1 to oxazamate is 1:200 to 200:1. When F1 is mixed with metaxazole amide in a certain ratio within this range, enhanced efficacy can be expected. By "enhanced efficacy" in this context is meant efficacy that is greater than the expected efficacy as calculated by the colpitis equation.
In some aspects, the pesticidal compositions disclosed herein comprise F1 and fendazoldi tzt. The ratio of F1 to fendazodi Ti sub-z is 1:200 to 200:1. Enhanced efficacy is expected when F1 is mixed with the fendazodi Ti sub-z in a proportion within this range. By "enhanced efficacy" in this context is meant efficacy that is greater than the expected efficacy as calculated by the colpitis equation.
In some aspects, the pesticidal compositions disclosed herein comprise F1 and at least one active ingredient selected from AIGA-2. In some other aspects, the pesticidal compositions disclosed herein comprise F1 and at least two active ingredients selected from AIGA-2. In some other aspects, the pesticidal compositions disclosed herein comprise F1 and at least three active ingredients selected from AIGA-2. In certain other aspects, the pesticidal compositions disclosed herein comprise F1 and at least four active ingredients selected from AIGA-2.
In certain aspects, the combination of F1 with at least one other active may be used in any of foliar, seed, soil, or furrow treatment. In some preferred aspects, a combination of F1 and at least one other active may be used for seed treatment. In some aspects, such seed treatment mixtures may comprise F1 and at least two active substances. In some other aspects, such seed treatment mixtures may comprise F1 and at least three active substances. In certain other aspects, such seed treatment mixtures may comprise F1 and at least four active substances.
In some aspects, the combination of F1 with other active substances may be any of the following:
f1, imidacloprid, metalaxyl, picoxystrobin, ethaboxam, ipconazole, fluothiazopyr-diethyl ketone
F1, metalaxyl, picoxystrobin, ethaboxam, ipconazole, and Fluozolpidem
F1, metalaxyl-M, picoxystrobin, ethaboxam, ipconazole, and fluzopyr-ethyl
F1 fluxapyroxad hydroxylamine Fluothiazole piretane
F1, imidacloprid, isoxazole tebufenozide, picoxystrobin, ethaboxam, ipconazole, and fluzopyrad
F1, isoxazole tebufenozide, picoxystrobin, ethaboxam, ipconazole, and fluzopyrad
F1, ring Ding Fulun, picoxystrobin, ethaboxam, ipconazole, fluozolpidem
F1, fludioxonil, metalaxyl-M, thiabendazole, azoxystrobin
F1, indonesia, thiazolidine, metalaxyl
F1, prothioconazole, fluoxastrobin, metalaxyl
F1, fludioxonil, thiabendazole, azoxystrobin, mefenoxam, cyproconazole and fluxapyroxad
F1, penflufen Prothiabendazole and metalaxyl
F1, difenoconazole, indene picolide, ipconazole and metalaxyl-M
Aspect a:
one aspect of the pesticidal composition disclosed herein is a pesticidal composition comprising:
(A)F1;
B) A mixed compatibility selected from the group consisting of: abamectin, acephate, chlorfenapyr, acetamiprid, flumethrin, acynonapyr, pyripyropene, carbofuran, aldicarb, allethrin, alpha-cypermethrin, aminopyralid, amitraz, azadirachtin, picoline, valphos-ethyl, valphos-methyl, azocyclotin azoxystrobin, bendiocarb, benfuracarb, trifloxysulfuron, benflumetofen, beta-cyhalothrin bifenazate, bifenthrin, bioallethrin, biotofluthrin, bistrifluron, flubendiamide, fenisobromolate, Buprofezin, methiphos, carbaryl, carbofuran, carbosulfan carboxin, cartap hydrochloride, chlorfenapyr, chlorantraniliprole, chlordane carboxin, cartap hydrochloride, chlorpyrifos, mite killing fierce chlorantraniliprole, chlordane clothianidin, copper hydroxide, coumaphos, cartap, cyantraniliprole, cycloxaprid, cyclo Ding Fulun, fenpropathrin, cycloxaprid, cyenopyrafen, cyflumetofen cyhalothrin, tricyclotin, cymoxanil, cypermethrin cyhalothrin, cyflufenapyr, cyromazine, d-cis-trans-allethrin, cyromazine, cy, DDVP, deltamethrin, neoprene-S-methyl, diafenthiuron, diazinon, dichlorvos, chlorfenapyr, triamcinolone, flufenbuxine, diflufuron, dimethoate Methylfipronil, oxazamate, dinotefuran, etoposide, DNOC, and d-trans-allethrin, emamectin benzoate eneyne pyrethrin, endosulfan, EPN, fenvalerate, ethaboxam, ethionamide, fenbucarb ethionamide, ethiprole, methoprene, ethofenprox, famoxadone amifos, bendrophos, fenazaquin, fenbuconazole, fenbutatin oxide, fenitrothion, fenbuconazole DiTi, fenobucarb, fenoxycarb, Fenpropathrin, fenpyroximate, phoxim, fenvalerate, fipronil, flazasulfuron, and flonicamid, florasulam, pyriminostrobin, triflumamid, triazamate, and the like flonicamid, florasulam, sulfenamide and the like azoxystrobin, triflumidamide, and fluoxastrobin, fluopyram, flubendiamide, fluxapyroxad, fluxad-c-methyl, fluxad-ethyl, flud-ethyl, fluxad-ethyl, flud Fluoxapyroxad, valicamidine, fosthiazate, furbenfuracarb, gamma-cyhalothrin Fluoxapyroxad, valicamidine, fosthiazate furacarb, gamma-cyhalothrin, Imidazole ring phosphorus, imidacloprid, cimetidine, indazapyroxamet, indoxacarb, indene picoline, pyrimethanil ipconazole, isoxazole and chlorfenapyr, iprovalicarb, iproflumilast ipconazole, isoxazole and tolfenpyrad Isosaponin, ipflupyraclostrobin, iprovalicarb MCPA, acephate, metalaxyl-M, metaflumizone, metalaxyl, metconazole, methamidophos, urotropine, methidathion, methiocarb, methomyl methoprene, methoxydroping, methoxyfenozide, methomyl, metsulfuron, and rapid phosphorus, milbemycin, monocrotophos, myclobutanil, dibromophosphorus, Nicosulfuron, chloropyridine, novaluron, omethoate, trifloxysulfuron, chlorpyrifos, chlor, chlorpyrifos Fluothiazole piretanone, oxazolesulfonyl, phoxim, parathion, methyl parathion Fluothiazole piretanone, oxazolesulfonyl sulfoximine, parathion, methyl parathion penconazole, picloram, picoxystrobin, pinoxaden, pirimicarb methyl pyrifos, dextro propathrin, profenofos, cyromazine, fenpropargite propiconazole, propoxur, penoxsulam, prothioconazole, profenofos, spiflumetofen, diflufenican, parvalinate, pyraclostrobin, pyrethrum, prothioconazole, trifloxystrobin, fenpyrad, Pyridaben, pyridalyl, pyridaphethione, praziquantel, pyriminobac-methyl, pyriminobac-rochemical sulfone, quetiapine, pyrethrum, rimsulfuron, rotenone rochemical sulfone, quetiapine, disinfestation chrysanthemum rimsulfuron, rotenone fipronil, tolfenpyrad, sulfoxaflor, tau-fluvalinate, tebuconazole tebufenozide, tebufenpyrad, butyl pyrifos, flufenoxuron, tefluthrin tebufenozide, tebufenpyrad, butyl pyrifos Fluorophenylurea, tefluthrin, thiodicarb, mevalonate, tolfenpyr, dimehypo, thiram, sulfenamide, thioxazole sulfone, tolfenpyr-mid, trifloxystrobin, tebufenpyrad, triazophos, trichlorfon, triclopyr, trifloxystrobin, triadimefon, triamcinolone, XMC, methoprene, zeta-cypermethrin, AI-1, AI-2, and 2,4-D.
Aspect B
Another aspect is a pesticidal composition comprising F1 and a mixed compatibility, wherein the mixed compatibility is selected from the group consisting of: abamectin, acetamiprid, benomyl, bifenthrin, chlorantraniliprole, chlorfenapyr, cyantraniliprole, cyclo Ding Fulun oxaziclomefone, fipronil, flonicamid, fluoxastrobin, flupyrafulone, flubendiamide, imidacloprid oxazine amide, fipronil, flonicamid, fluoxastrobin, trifloxysulfuron ester flupirfenidone, flubendiamide, fluxapyroxad, imidacloprid.
Aspect C
Another aspect is a pesticidal composition comprising F1 and a mixed compatibiliser, wherein the mixed compatibiliser is selected from the group consisting of: azoxystrobin, copper hydroxide, difenoconazole, ethaboxam, fludioxonil, fluopyram, fluoxastrobin, fluxastrobin, fluoxastrobin, ipconazole, ipflupyralimine, metalaxyl-M, pencycuron, myclobutanil, fluzopyr-ethyl, picoxystrobin, propiconazole, prothioconazole (prothiaconazole), fluxapyroxad, buconamine (pyroclostrobin), fluzoxamide, tebuconazole, thiabendazole, thiram, triticonazole (titriconazole), trifloxystrobin, abamectin, acetamiprid, pyripyropene, AI-1, AI-2, benomyl-methyl (benpyrimoxan) bifenthrin, chlorfenapyr flubendiamide, chlorfenapyr, clothianidin, cyantraniliprole, deltamethrin, dinotefuran, fipronil, flonicamid, trifloxystrobin, fluazifop-butyl, fluoxazamide, fluazifop-butyl, flubendiamide, fluxapyroxad-ethyl, flubendiamide, fluxapyroxad-ethyl, fluxad-ethyl, flubendiamide, flucycloxad-sodium, flubendiamide, fluxad-sodium, flubendiamide, fluxad, fluxa heat inactivated burkholderia species strain a 396, imidacloprid, indoxacarb, lambda cyhalothrin, methoxyfenozide, carbofuran, pyriproxyfen, spinosad, spinetoram, spiromesifen, spirotetramat, sulfoxaflor, flufenamid, thiamethoxam, and trifluopyrim.
Aspect D
Another aspect is a pesticidal composition comprising F1 and a mixed compatibility, wherein the mixed compatibility is selected from the group consisting of azoxystrobin, copper hydroxide, difenoconazole, ethaboxam, fludioxonil, fluopyram, fluoxastrobin, fluxastrobin, indene picolide, ipconazole, ipflupyrad, metalaxyl, pencycuron, cymoxanil, oxazamate, propiconazole, prothioconazole, fluxapyroxad, buconazole hydroxylamine, buconazole, cyproconazole, tebuconazole, thiram, sterilizing azole and trifloxystrobin.
Aspect E
Another aspect is a pesticidal composition comprising F1 and a mixed compatibiliser, wherein the mixed compatibiliser is selected from the group consisting of: abamectin, acetamiprid, pyripyropene, AI-1, AI-2, benomyl, bifenthrin, chlorantraniliprole, chlorfenapyr clothianidin, cyantraniliprole, deltamethrin, dinotefuran, fipronil, flonicamid, triflummid, flufenacet, flupyrifos, flubendiamide, fluxapyroxad, fluxad, flux, fluxad, fluxa clothianidin, cyantraniliprole, deltamethrin, dinotefuran, fipronil, flonicamid, chlorfenapyr trifluramide, fluthiamethoxam sulfone, flupirfenidone, flubendiamide.
In any of the pesticidal compositions according to aspects a-E, the ratio of F1 to the mixed compatibiliser B) is selected from 1:160,000 to 160,000:1, 1:80,000 to 80,000:1, 1:40,000 to 40,000:1, 1:20,000 to 20,000:1, 1:10,000 to 10,000:1, 1:8000 to 8000:1, 1:5000 to 5000:1, 1:2000 to 2000:1, 1:1000 to 1000:1, 1:500 to 500:1, 1:250 to 250:1, 1:100 to 100:1, 1:50 to 50:1, 1:25 to 25:1, 1:10 to 10:1, 1:5 to 5:1, and 1:1).
Also disclosed herein is a method of controlling pests that attack plants, plant propagation parts, plant habitat comprising the step of contacting the plants, plant propagation parts, plant habitat with a composition of aspects a-E.
Also disclosed herein is a method of controlling pests that attack plants, plant propagation parts, plant habitat, comprising the step of contacting the pests, or their habitat, food supply, breeding grounds, their locus with a composition of aspects a-E.
Disclosed herein is a method of treating a seed comprising the step of contacting the seed with a composition of aspects a-E.
Also disclosed herein is a seed treated with the composition of aspects a-E.
These combinations containing more than two active substances may be mixed in a suitable ratio such that all active substances together with F1 may exhibit an enhanced active effect than when they are used alone. For example, a particular mixture containing more than two active substances F1, picolide, ethaboxam and metalaxyl F1 may exhibit enhanced activity relative to the combination of these active substances when calculated using the Colbi equation or any other means, as compared to the activity of any of the active substances alone (i.e., the expected efficacy is calculated using the Colbi equation and compared to the observed efficacy; if the observed efficacy is greater than the expected efficacy calculated using the Colbi equation, the composition exhibits enhanced efficacy). In addition to providing enhanced activity, these combinations may provide additional unexpectedly advantageous properties. For example, desirable degradability characteristics, improved toxicological and/or ecotoxicological characteristics, improved useful plant characteristics including emergence, crop yield, more developed root system, increased tillering, increased plant height, increased greenness, larger leaves, fewer dead basal leaves, stronger tillers, earlier flowering, earlier grain maturation, increased shoot growth, improved essential nutrient content, improved plant vigor and early germination.
Although the enhanced activity of the compositions disclosed herein is unexpected and surprising, this activity also extends the range of action of F1 alone or any other active alone in two ways, with F1 and any other active being reduced in application rate while the activity remains good or better, wherein the mixture achieves a high degree of pest control even when both individual components have themselves become ineffective in such low application rate ranges. In addition, the use of such mixtures can considerably broaden the pest spectrum that can be controlled.
Bioassays
Bioassays were performed on green peach aphid (GREEN PEACH APHID) (myzus persicae), sweet potato whitefly (sweet potato whitefly) (bemisia tabaci), frankliniella occidentalis (western flower thrip) (alfalfa thrips), brown planthopper (brown planthopper) (brown planthopper (NILAPARVATA LUGENS)), neotropical brown stink bug (neotropical brown stink bug) (shi Luo Meizhou stink bug), cotton bollworm (corn earworm) (spodoptera frugiperda), spodoptera frugiperda (fall armyworm) (spodoptera frugiperda (Spodoptera frugiperda)), and soybean looper (soybean looper) (soybean inchworm (Chrysodeixis includens)), which are good indicator species for a wide range of agricultural pests. The results of these indicator species show the wide usefulness of various pesticides (also referred to as active ingredients) mixed with a molecule of formula one in controlling insect pests.
Biological assay 1. Green peach aphid (peach aphid MYZUPE, "GPA").
Green peach aphids are the most important aphid pests of peach trees, leading to slow growth, leaf blight, and death of various tissues. Green peach aphid is also dangerous because it acts as a vehicle for the transmission of plant viruses such as potato virus Y and potato leaf curl to members of the solanaceae/potato family (nightshade/potato family Solanaceae) and for the transmission of various flower leaf viruses to many other food crops. GPA attacks plants such as broccoli, burdock, cabbage, carrot, cauliflower, white radish, eggplant, green bean, lettuce, hawaii fruit, papaya, capsicum, sweet potato, tomato, watercress, and zucchini. GPA also attacks many ornamental crops such as carnation, chrysanthemum, white cabbage, poinsettia, and rose. GPA has developed resistance to many pesticides. Currently, it is the third largest pest in the number of insect resistance cases reported (Sparks et al). Therefore, prevention of such harmful organisms is important due to the above factors. In addition, molecules that control GPA (a pest feeding on juice) can be used to control other pests feeding on plant juice.
Stock solutions of F1 and the various active ingredients were initially prepared at concentrations of 4 milligrams per milliliter (mg/mL) (for F1) and 0.1mg/mL (for the active ingredient), respectively, using a 1:1 mixture of acetone and methanol as diluents. Stock solutions were prepared with F1 and each active ingredient alone. Test solutions were prepared from the stock solutions. Test solutions containing F1, the individual active ingredients and mixtures of F1 with each active ingredient were prepared. F1 and test solutions of individual active ingredients by adding 750 microliters (μl) of stock solution to a 25mL glass vial, then adding 750 μl of 1:1 acetone in methanol solvent, followed by 13.5mL of a solution containing 0.025%20 Was prepared to give a 0.0005% (w/v) solution. Test solution containing a mixture of F1 and individual active ingredients by adding 750. Mu.L of active ingredient stock solution to a 25mL glass vial, followed by 750. Mu.L of F1 stock solution, followed by 13.5mL of a solution containing 0.025%20 Were prepared with water to produce a test solution containing 0.0005% (w/v) F1 and 0.0005% (w/v) active ingredient. Each test solution was serially diluted to produce the desired doses of test solution (0.0005% (w/v), 0.000125% (w/v), 0.00003125% (w/v), 0.0000078% (w/v), 0.00000195% (w/v), and 0.0000005% (w/v)). In the test solution containing a mixture of F1 and active ingredient, the active ingredient was diluted as described above, but the concentration of F1 was kept constant (0.04% (w/v)).
The test solutions were tested for GPA using the procedure that cabbage seedlings with 2-3 small (3-5 centimeters (cm)) true leaves grown in 3 inch pots were used as the test substrate. Seedlings were infested with 20-50 GPA (wingless adult and nymph stage) one day before chemical application. Four pots with individual seedlings were used for each treatment. The solution was sprayed on both sides of the cabbage leaves using a hand aspirator type sprayer until runoff was produced. With only diluent (0.025% in water)20 And 10% acetone: methanol (1:1)) were sprayed with reference plants (solvent check). The treated plants were kept in the holding chamber for three days at about 25 ℃ and ambient relative humidity (RH about 20% to about 45%) prior to fractionation. The evaluation was carried out by counting the number of live aphids per plant under a microscope three days after the treatment. Percent control was measured using the following Arabic correction formula (W.S.Abbott, J.Econ.Entomol. [ journal of economic entomology ]18 (1925), pages 265-267):
corrected% control= (1- (Y/X)) = (100)
Where X = number of live aphids on solvent check plants and Y = number of live aphids on treated plants. In Table B1, "expected% control" is calculated using the method described in Colby S.R., weeds, 1967,15,20-22. The results are shown in table 1 of the table section.
Biological assay 2 sweet potato whiteflies (bemisia tabaci, BEMITA, "SPW").
Sweet potato whiteflies are the main destructive pest of cotton. It is also a serious pest for many vegetable crops such as melons, brassica crops, tomatoes, and head lettuce, and ornamental plants. SPW causes lesions by both direct feeding lesions and viral transmission. SPW is an insect that feeds on juice, and its feeding on takes away the nutrition of the plant. This can lead to retarded cotton growth, defoliation, reduced yield, and boll shedding. SPW produces a large amount of honeydew that supports the growth of nicotiana species on plant leaves. SPW is also a viral vector such as cotton leaf wrinkling virus and tomato yellow leaf curl virus.
Stock solutions of F1 and one or more active ingredients were prepared at a concentration of 0.2mg/mL using acetone as a diluent. Stock solutions were prepared with F1 and each active ingredient alone. Test solutions were prepared from the stock solutions. Test solutions containing F1, the individual active ingredients and mixtures of F1 with each active ingredient were prepared. F1 and test solutions of individual active ingredients by adding 500 μl of stock solution to a 25mL glass vial, then adding 500 μl of acetone, then adding 9mL of a solution containing 0.025%20 Was prepared to give a 0.001% (w/v) solution. Test solution containing mixtures of F1 and individual active ingredients by adding 500. Mu.L of active ingredient stock solution to a 25mL glass vial followed by 500. Mu.L of F1 stock solution followed by 9mL of solution containing 0.025%20 Was prepared with water to produce a test solution containing 0.001% (w/v) F1 and 0.001% (w/v) active ingredient. Each test solution was serially diluted to produce the desired doses of test solution (0.001% (w/v), 0.0001% (w/v), 0.00001% (w/v), 0.000001% (w/v), 0.0000001% (w/v), and 0.00000001% (w/v)).
The test solution was tested for SPW using the procedure that cotton seedlings grown in 3 inch pots remained after pruning with only one true leaf used as the test substrate. Bemisia tabaci (B.tabaci) adults were allowed to colonize on cotton plants and spawn for 24 hours, after which all adults were removed from the plants using compressed air. The plants were monitored for egg development and, while the reptile (crawler) eclosion was in progress (> 25% eclosion based on visual inspection using a microscope), the plants were sprayed using the test solutions and methods described above for Green Peach Aphid (GPA). The treated plants were kept in a holding chamber at about 25 ℃ and ambient Relative Humidity (RH) prior to fractionation. The evaluation was carried out by counting the number of 2-3 years old nymphs per plant development under a microscope 7-9 days after the treatment. Percent control was measured using the following Arabic correction formula (W.S.Abbott, J.Econ.Entomol. [ journal of economic entomology ]18 (1925), pages 265-267):
corrected% control= (1- (Y/X)) = (100)
Where X = number of live nymphs on solvent check plants and Y = number of live nymphs on treated plants. In Table B2, "expected% control" is calculated using the method described in Colby S.R., weeds [ Weeds ],1967,15,20-22. The results are shown in table 2 of the table section.
Biological assay 3 Frankliniella occidentalis (Medicago sativa thrips FRANOC, "WFT").
Frankliniella occidentalis is the major destructive pest of a number of commercially relevant plant species (more than 500 recorded host plants), including many fruits, vegetables and ornamental plants. WFT is a sap-feeding insect that feeds on various plant parts, destroying plant cells as they feed on. It is also known that WFT acts as a mediator of plant disease and is one of the main mediators of tomato spotted wilt virus.
Stock solutions of F1 and various active ingredients were initially prepared at a concentration of 0.1mg/mL using acetone as a diluent. Stock solutions were prepared with F1 and each active ingredient alone. Test solutions were prepared from the stock solutions. Test solutions containing F1, the individual active ingredients and mixtures of F1 with each active ingredient were prepared. F1 and test solutions of individual active ingredients by adding 500 μl of stock solution to a 25mL glass vial, then adding 500 μl of acetone, then adding 9mL of a solution containing 0.025%20 Was prepared to give a 0.0005% (w/v) solution. Test solution containing mixtures of F1 and individual active ingredients by adding 500. Mu.L of active ingredient stock solution to a 25mL glass vial followed by 500. Mu.L of F1 stock solution followed by 9mL of solution containing 0.025%20 Were prepared with water to produce a test solution containing 0.0005% (w/v) F1 and 0.0005% (w/v) active ingredient. Each test solution was serially diluted to produce the desired doses of test solution (0.0005% (w/v), 0.000125% (w/v), 0.00003125% (w/v), 0.0000078% (w/v), and 0.00000195% (w/v)).
The test solutions were tested for WFT using the procedure of cutting leaf discs (2.7 cm diameter) from the true leaves of cotton plants. The leaf discs were immersed in the test solution and shaken to ensure complete coverage of the leaf discs, and then placed in a tray containing the filter paperPETRISLIDES. The treated leaf discs were allowed to air dry for approximately 1 hour. Each leaf disk was infested by placing 5 WFTs (9-10 day old nymphs) on each leaf disk and PETRISLIDES were capped to prevent escape. Each treatment was repeated three times and the test treatment was maintained at approximately 26 ℃ and ambient Relative Humidity (RH) prior to fractionation. The reference leaf disk was treated with diluent only (solvent check). The evaluation was performed by counting the number of live WFTs under magnification 3 days after treatment. Percent control was measured using the following Arabic correction formula (W.S.Abbott, J.Econ.Entomol. [ journal of economic entomology ]18 (1925), pages 265-267):
corrected% control= (1- (Y/X)) = (100)
Where X = number of live nymphs on solvent check leaf discs and Y = number of live nymphs on treated leaf discs. In Table B3, "expected% control" is calculated using the method described in Colby S.R., weeds [ Weeds ],1967,15,20-22. The results are shown in table 3 of the table section.
Bioassays 4 cotton bollworms (noctuid, HELIZE, "CEW"), armyworms (Fall Armyworm) (spodoptera frugiperda, LAPHFR, "FAW"), and soybean loopers (soybean loopers, PSEPIN, "SBL").
Cotton bollworms are one of the most costly crop pests in north america, which typically attack the harvested portions of many valuable crops. In addition to corn and tomato, CEW larvae attack artichokes, asparagus, cabbage, cantaloupe, kale, cowpea, cucumber, eggplant, lettuce, lima bean, melon, okra, pea, pepper, potato, pumpkin, kidney bean, spinach, pumpkin, sweet potato, and watermelon. Other crops that are damaged by cotton bollworms include alfalfa, clover, cotton, flax, oat, millet, rice, sorghum, soybean, sugarcane, sunflower, tobacco, vetch, and wheat. Armyworm is a global pest of many agriculturally important plant species including alfalfa, barley, buckwheat, cotton, clover, corn, oat, millet, peanut, rice, ryegrass, sorghum, beet, soybean, sugarcane, timothy, tobacco, wheat, and the like. Larvae of FAW damage plants by feeding on leaves and fruits, resulting in reduced yield and even death of the host plant. Similarly, spodoptera frugiperda is a common and damaging pest of soybean, but it also feeds on other crops (such as peanut, cotton, and corn) as well as vegetable crops (including peas, crucifers, sweet potatoes, tomatoes, sweet peppers, dwarf beans, cucumbers, watermelons, and the like). CEW, FAW, and SBL are good representatives of destructive larval lepidopteran pests.
Stock solutions of F1 and one or more active ingredients were prepared at concentrations of 0.4mg/mL (for F1) and 4mg/mL (for active ingredient) using a 9:1 mixture of acetone and water as diluent. Stock solutions were prepared with F1 and each active ingredient alone. Test solutions were prepared from the stock solutions. Test solutions containing F1, the individual active ingredients and mixtures of F1 with each active ingredient were prepared. The test solution of F1 was prepared by adding 500. Mu.L of the stock solution to a 25mL glass vial, followed by 500. Mu.L of a 9:1 mixture of acetone and water. The individual active ingredients were prepared by adding 500 μl of the stock solution to a 25mL glass vial, followed by 500 μl of a 9:1 mixture of acetone and water. Test solutions containing a mixture of F1 and the individual active ingredients were prepared by adding 500. Mu.L of the active ingredient stock solution to a 25mL glass vial, followed by 500. Mu.L of the F1 stock solution, resulting in a test solution containing 0.04% (w/v) F1 and 0.4% (w/v) active ingredient. Each test solution was serially diluted to produce the desired dose of test solution (F1 was 0.04% (w/v), 0.004% (w/v), 0.0004% (w/v), 0.00004% (w/v), 0.000004% (w/v), and 0.0000004% (w/v), and the active ingredient was 0.4% (w/v), 0.04% (w/v), 0.004% (w/v), 0.0004% (w/v), 0.00004% (w/v), and 0.000004% (w/v)).
Test solutions were tested for CEW, FAW, and SBL using the procedure of distributing artificial lepidopteran feed (multi-species lepidopteran feed, south China products Co. (Southland Products)) in a 128-well bioassay tray (Frontier Agricultural Sciences TM). 50 μl of the test solution was pipetted into a well of a bioassay tray. (test solution doses of 0.04% (w/v), 0.004% (w/v), 0.0004% (w/v), 0.00004% (w/v), 0.000004% (w/v), and 0.0000004% (w/v) in the feed were converted to concentrations of 5, 0.5, 0.05, 0.005, 0.0005, and 0.00005 μg/cm 2, respectively) with diluent alone treatment reference treatment (solvent check). Each treatment for each species was repeated 8 times. 2-year old CEW, FAW, or SBL larvae were placed on top of the feed in each well and covered with a clear perforated adhesive cover. The test trays were maintained at approximately 26 ℃ and ambient Relative Humidity (RH) prior to fractionation. After 5 days, the number of live larvae per pool was recorded and the percent control was measured using the following Arabic correction formula (W.S.Abbott, J.Econ.Entomol [ journal of economic entomology ]18 (1925), pages 265-267):
corrected% control= (1- (Y/X)) = (100)
Where X = number of live larvae on solvent examination and Y = number of live larvae on treated feed. In Table B4, "expected% control" is calculated using the method described in Colby S.R., weeds [ Weeds ],1967,15,20-22. The results are shown in table 4 of the table section.
Bioassay 5 novel tropical brown stinkbugs (Luo Meizhou stinkbugs, EUSCHE, "BSB").
The new brown stinkbug is the main pest for soybean, cotton, sunflower, and other economically important crops. BSB is a sap-feeding insect that destroys plant cells and seeds during feeding. Feeding on plant seeds may reduce the vigor of the seeds and reduce yield.
Stock solutions of F1 and one or more active ingredients were prepared at a concentration of 0.2mg/mL using Dimethylsulfoxide (DMSO) as a solvent. Stock solutions were prepared with F1 and each active ingredient alone. Test solutions were prepared from the stock solutions. Test solutions containing F1, the individual active ingredients and mixtures of F1 with each active ingredient were prepared. The test solutions of F1 and individual active ingredients were prepared by adding 30. Mu.L of stock solution to a single well of a 96-well plate, then adding 30. Mu.L of DMSO, followed by 140. Mu.L of a 2:1 mixture of acetone and water as diluents to give a 0.03% (w/v) solution. Test solutions containing mixtures of F1 and individual active ingredients were prepared by adding 30. Mu.L of F1 stock solution to a single well of a 96-well plate, followed by adding 30. Mu.L of individual active ingredient stock solution to the same well, followed by adding 140. Mu.L of a 2:1 mixture of acetone and water as diluents to produce test solutions containing 0.03% (w/v) F1 and 0.03% (w/v) active ingredient. Each test solution was serially diluted to produce the desired doses of test solution (0.03% (w/v), 0.0075% (w/v), 0.001875% (w/v), 0.000469% (w/v), 0.000117% (w/v), and 0.000029% (w/v).
The test solutions were tested for BSB using the procedure of distributing artificial agar feed (2% agar, 12% sucrose) in 48-well plastic plates (FISHER SCIENTIFIC TM). 25 μl of the test solution was pipetted into a well of a bioassay tray. (test solution doses of 0.03% (w/v), 0.0075% (w/v), 0.001875% (w/v), 0.000469% (w/v), 0.000117% (w/v), and 0.000029% (w/v) in the feed were converted to concentrations of 36, 9, 2.25, 0.5625, 0.140625, and 0.035156 μg/cm 2, respectively.) reference treatment (solvent check) was treated with diluent alone. Each treatment was repeated three times and the test treatment was maintained at approximately 26 ℃ and ambient Relative Humidity (RH) prior to fractionation. Three to five BSB nymphs were added to each well and covered with a clear perforated adhesive cover. The total number of live BSB nymphs was recorded four days after administration. The score is based on the total number of live nymphs in all three replicates. Percent control was measured using the following Arabic correction formula (W.S.Abbott, J.Econ.Entomol. [ journal of economic entomology ]18 (1925), pages 265-267):
corrected% control= (1- (Y/X)) = (100)
Where X = number of live nymphs on solvent inspection and Y = number of live nymphs on treated bean segments. In Table B5, "expected% control" is calculated using the method described in Colby S.R., weeds [ Weeds ],1967,15,20-22. The results are shown in table 5 of the table section.
Bioassay 6 brown planthopper (Brown Planthopper) (brown planthopper (NILAPARVATA LUGENS), NILALU, "BPH").
Brown planthoppers are highly destructive rice pests found in asia-pacific areas. BPH is a sap-feeding insect that can mechanically damage rice, is sufficient to kill plants, and acts as a vehicle for viral pathogens that reduce rice yield. In addition, BPH has developed resistance to a variety of insecticides that have been used to control outbreaks. Because of these factors, it is important to manage BPH, as is the development of new technologies to control this major pest species.
F1 and one or more active ingredients were tested at 50, 12.5, 3.125, and 0.78 grams of active ingredient per hectare (g/ha). At these ratios, F1 and the individual active ingredients were tested at a 1:1 ratio. Since trifluorophenylpyrimidine has high potency for BPH, this chemical was tested at lower rates of 0.78, 0.19, 0.049, and 0.012 g/ha. F1 and trifluoracene were tested at a ratio of 16:1. Test solutions containing F1, the individual active ingredients and mixtures of F1 with each active ingredient were prepared. Test solutions were prepared by weighing 5mg of each test chemical (alone or in combination depending on the treatment) into 25mL glass vials. Next, 1mL of acetone was added to each vial to dissolve the test chemicals, followed by 19mL of water containing 0.125% Tween 20 adjuvant. This test solution represents a 50g/ha treatment, which was then serially diluted four times to produce three lower ratios, 12.5, 3.125, and 0.78g/ha. Trifluoro-phenylpyrimidine was prepared in a similar manner, but with two additional serial dilutions to yield 6 ratio solutions representing 12.5, 3.125, 0.78, 0.19, 0.049, and 0.012 g/ha. Two higher doses were discarded and four lower doses were used for testing. Four replicates of each ratio were performed and solvent blank was used as a control treatment.
Five (5) seedlings of rice (10-12 days old) planted in 3 inch pots were used as test plants. Seedlings of rice were grown in soil and covered with 2% agar solution. Test solutions were applied to test plants using Devries laboratory study sprayers set to spray at 200 liters per hectare (L/ha) using a TeeJet hollow cone nozzle. After application, the rice seedlings were dried for 1 hour, and then a single clear plastic tube (diameter 2 inches x height 12 inches) was placed over the seedlings in each pot. The tube was pushed down into the agar to create a sealed test chamber. Agar prevents insects from becoming hidden in the soil and makes collection and grading of adults easier. Ten to fifteen (10-15) 5-year-old BPH nymphs were transferred to each test chamber using a vacuum aspirator. Immediately after BPH infestation, the test chamber was covered with a piece of 90-grade cheesecloth and secured with a rubber band, and the test chamber was sealed. The test chambers were maintained at 25 ℃ for 6 days, and then the total number of live insects in each test chamber was counted. Percent control was measured using the following Arabic correction formula (W.S.Abbott, J.Econ.Entomol. [ journal of economic entomology ]18 (1925), pages 265-267):
corrected% control= (1- (Y/X)) = (100)
Where X = number of living insects on solvent examination and Y = number of living insects in the treated chamber. In Table B6, "expected% control" was calculated using the method described in Colby S.R., weeds [ Weeds ],1967,15,20-22. The results are shown in table 6 of the table section.
Bioassays 7 cotton bollworms (spodoptera frugiperda, HELIZE, "CEW"), armyworms (spodoptera frugiperda, LAPHFR, "FAW"), spodoptera exigua (Beet Armyworm) (spodoptera exigua (Spodoptera exigua), LAPHEG, "BAW"), and spodoptera exigua (soybean looper, PSEPIN, "SBL").
Test solutions were tested for CEW, FAW, BAW, and SBL using the following procedure, with artificial lepidopteran feed (multi-species lepidopteran feed, south country products) distributed in 96-well plates. mu.L of the test solution was pipetted into a well of a bioassay plate. The dosages of the test solutions in the feed were 5, 0.5, 0.05, 0.005, 0.0005, and 0.00005mg/cm2. (test solution doses of 0.04% (w/v), 0.004% (w/v), 0.0004% (w/v), 0.00004% (w/v), 0.000004% (w/v), and 0.0000004% (w/v) in the feed were converted to concentrations of 5, 0.5, 0.05, 0.005, 0.0005, and 0.00005mg/cm2, respectively.) with diluent alone treatment reference treatments (solvent check). Each treatment for each species was repeated 5 times. Approximately five one-instar CEW, FAW, BAW, or SBL larvae, were placed on top of the feed in each pond and covered with a clear perforated adhesive cover. The test trays were maintained at approximately 25 ℃ and ambient relative humidity prior to fractionation. Five days later, the number of pools in which all larvae died was recorded as 100% and all replicates were averaged, and the percent control was then measured using the following Arabic correction formula (W.S.Abbott, J.Econ.Entomol [ journal of economic entomology ]18 (1925), pages 265-267):
corrected% control= (1- (Y/X)) = (100)
Where X = number of live larvae on solvent examination and Y = number of live larvae on treated feed.
In Table 7, "expected% control" is calculated using the method described in Colby S.R., weeds, 1967,15,20-22. The results are shown in Table 7.
Biological assay 8 Western corn rootworm (Western Corn Rootworm) (corn rootworm (Diabrotica virgifera), DIABVI, "WCR")
Western corn rootworm is one of the most damaging beetle (coleopteran) pests that attack corn plant roots annually in north america and europe. The larval stage feeds on corn roots early in the season, which prevents the plant from growing properly and damages the structural integrity of the plant. This reduces yield and leads to lodging of the plant. WCR is a good representation of soil pests feeding on plant roots and seeds.
Corn seeds were planted in steam pasteurized soil filled greenhouse pots. Western corn rootworm eggs supplied from kedi water agriculture technologies company (Corteva Agriscience) of Johnston, IA, il were suspended in a 0.08% agar solution added to the soil. Stock solutions of F1 and active ingredient were prepared at a concentration of 250 or 500ugai/10mL for F1 and active ingredient using a 1:1 solution of acetone in water as diluent at a ratio of (F1: AI) of 1:0.004, 1:0.01, 1:0.02, 1:0.04, 1:0.08, 1:0.1, 1:0.15, 1:0.2, 1:0.4, 1:2, or 1:4. The soil application solution was applied to the soil as a 10mL dip. Plants were grown in the greenhouse at 25C for 13 days, then roots were removed from the soil, washed, and measured to determine the length of the intermediate node roots. The measured lengths were compared to the infested and non-infested untreated checks to determine the average percent control that provided protection to the corn roots. The results are shown in Table 8.
Agriculturally acceptable acid addition salts, salt derivatives, solvates, ester derivatives, polymorphs, isotopologues and radionuclides
The molecules of formula one may be formulated as agriculturally acceptable acid addition salts. As non-limiting examples, the amine functional groups can form salts with hydrochloric acid, hydrobromic acid, sulfuric acid, phosphoric acid, acetic acid, benzoic acid, citric acid, malonic acid, salicylic acid, malic acid, fumaric acid, oxalic acid, succinic acid, tartaric acid, lactic acid, gluconic acid, ascorbic acid, maleic acid, aspartic acid, benzenesulfonic acid, methanesulfonic acid, ethanesulfonic acid, hydroxymethanesulfonic acid, and hydroxyethanesulfonic acid. Further, as non-limiting examples, the acid functionality may form salts including salts derived from alkali metals or alkaline earth metals and salts derived from ammonia and amines. Examples of preferred cations include sodium, potassium, and magnesium.
The molecules of formula one may be formulated as salt derivatives. As a non-limiting example, salt derivatives can be prepared by contacting the free base with an amount of the desired acid sufficient to produce a salt. The free base may be regenerated by treating the salt with a suitable dilute aqueous base, such as dilute sodium hydroxide, potassium carbonate, ammonia, and aqueous sodium bicarbonate. For example, in many cases, pesticides (such as 2, 4-D) are more soluble in water by converting them to their dimethylamine salt.
The molecules of formula one may be formulated with a solvent to stabilize the complex such that the complex remains intact after removal of the non-complexing solvent. These complexes are often referred to as "solvates". However, it is particularly desirable to use water as a solvent to form stable hydrates.
The molecule of formula one containing an acid functionality may be made into an ester derivative. These ester derivatives can then be applied in the same way as the molecules disclosed in this document are applied.
The molecules of formula one can be made into a variety of polymorphs. Polymorphism is important in agrochemical development because different crystal polymorphs or structures of the same molecule can have greatly different physical and biological properties.
The molecules of formula one may be manufactured with different isotopes. Of particular importance are molecules having 2 H (also known as deuterium) or 3 H (also known as tritium) in place of 1 H. The molecules of formula one can be made with different radionuclides. Of particular importance are molecules having 14 C (also known as radioactive carbon). The molecules of formula one having deuterium, tritium, or 14 C can be used to allow biological studies, and half-life studies, as well as mode of action studies, to be followed during chemical and physiological processes.
Formulation preparation
The pesticide may not be suitable for application in its pure form. It is often necessary to add other materials so that the pesticide can be used at the desired concentration and in an appropriate form, allowing for ease of application, handling, transportation, storage and maximum pesticide activity. Thus, pesticides are formulated as, for example, baits, concentrated emulsions, powders, emulsifiable concentrates, fumigants, gels, granules, microcapsules, seed treatments, suspension concentrates, suspoemulsions, tablets, water-soluble liquids, water-dispersible granules, dry flowable agents, wettable powders, or ultra-low volume solutions.
The pesticides are most often applied in the form of aqueous suspensions or emulsions prepared from concentrated formulations of such pesticides. Such water-soluble, water-suspendable or emulsifiable formulations are liquids commonly referred to as solids (wettable powders, water-dispersible granules), commonly referred to as emulsifiable concentrates or aqueous suspensions. Wettable powders that can be compacted to form water dispersible granules comprise an intimate mixture of a pesticide, a carrier and a surfactant. The concentration of the pesticide is typically from about 10% to about 90% by weight. The carrier is typically selected from the group consisting of attapulgite (attapulgite) clay, montmorillonite (montmorillonite) clay, diatomaceous earth, or purified silicate. Effective surfactants comprising from about 0.5% to about 10% of the wettable powder are found in sulfonated lignin, condensed naphthalene sulfonates, alkylbenzene sulfonates, alkyl sulfates, and nonionic surfactants such as ethylene oxide adducts of alkylphenols.
Emulsifiable concentrates of the pesticide comprise a suitable concentration of the pesticide dissolved in a carrier, such as from about 50 to about 500 grams per liter of liquid, which is a water-miscible solvent or a mixture of a water-immiscible organic solvent and an emulsifier. Useful organic solvents include aromatic compounds (especially xylenes) and petroleum fractions (especially the high boiling naphthalene and alkene portions of petroleum, such as heavy aromatic naphthas). Other organic solvents may also be used, such as terpene solvents including rosin derivatives, aliphatic ketones such as cyclohexanone, and complex alcohols such as 2-ethoxyethanol. Suitable emulsifiers for emulsifiable concentrates are selected from the group consisting of conventional anionic and nonionic surfactants.
Aqueous suspensions include suspensions of water-insoluble pesticides dispersed in an aqueous carrier at a concentration ranging from about 5% to about 50% by weight. The suspension is prepared by finely grinding the pesticide and vigorously mixing it into a carrier consisting of water and surfactant. Ingredients such as inorganic salts and synthetic or natural gums may also be added to increase the density and viscosity of the aqueous carrier. It is generally most effective to simultaneously grind and mix the pesticide by preparing and homogenizing an aqueous mixture in an apparatus such as a sand mill, ball mill, or piston homogenizer. The pesticide may be microencapsulated in a plastic polymer in suspension.
Oil Dispersions (OD) include suspensions of an organic solvent insoluble pesticide finely dispersed in a mixture of organic solvent and emulsifier at a concentration in the range of from about 2% to about 50% by weight. One or more pesticides may be dissolved in the organic solvent. Useful organic solvents include aromatic compounds (especially xylenes) and petroleum fractions (especially the high boiling naphthalene and alkene portions of petroleum, such as heavy aromatic naphthas). Other solvents may include vegetable oils, seed oils, and esters of vegetable and seed oils. Suitable emulsifiers for the oil dispersion are selected from the group consisting of conventional anionic and nonionic surfactants. Thickeners or gelling agents are added in the formulation of oil dispersions to alter the rheology or flow characteristics of the liquid and prevent separation and settling of the dispersed particles or droplets.
The pesticides may also be applied in the form of particulate compositions which are particularly useful for application to soil. The particulate composition typically contains from about 0.5% to about 10% by weight of a pesticide dispersed in a carrier comprising clay or similar material. Such compositions are typically prepared by dissolving the pesticide in a suitable solvent and applying it to a particulate carrier that has been preformed to a suitable particle size of about 0.5mm to about 3 mm. Such compositions may also be formulated by making a coherent mass or paste of carrier and molecules and then extruding and drying to obtain the desired particle size. Another form of particle is a water Emulsifiable Granule (EG). It is a formulation consisting of granules to be applied in the form of a conventional oil-in-water emulsion in which one or more active ingredients are dissolved or diluted in an organic solvent after disintegration and dissolution in water. The water emulsifiable granules comprise one or several active ingredients dissolved or diluted in a suitable organic solvent, which are absorbed in a water soluble polymer shell or some other type of soluble or insoluble matrix.
The pesticide-containing dust is prepared by intimately mixing the pesticide in powder form with a suitable dust-like agricultural carrier, such as kaolin, ground volcanic rock, or the like. The dust may suitably contain from about 1% to about 10% of the pesticide. The dust can be applied in the form of seed dressing or in the form of foliar application using a powder blower.
It is also practical to apply the pesticides in the form of solutions in suitable organic solvents (typically petroleum), such as spray oils widely used in agricultural chemistry.
The pesticides may also be applied in the form of aerosol compositions. In such compositions, the pesticide is dissolved or dispersed in a carrier that is a propellant mixture that generates pressure. The aerosol composition is packaged in a container that dispenses the mixture through an atomizing valve.
When the pesticide is mixed with food or an attractant or both, a pesticide bait is formed. When the pests eat the bait, they also eat the pesticide. The bait may be in the form of granules, gels, flowable powders, liquids, or solids. The bait may be used in pest shelter.
Fumigants are pesticides that have a relatively high vapor pressure and thus can be present in the form of a gas of sufficient concentration to kill pests in soil or enclosed spaces. The toxicity of a fumigant is proportional to its concentration and exposure time. They are characterized by good diffusibility and function by penetrating the respiratory system of the pest or by epidermal absorption by the pest. Fumigants are applied to control grain-accumulating pests (stored product pest) under airtight sheets, in air-tight enclosures or buildings, or in specific chambers.
The pesticide may be microencapsulated by suspending the pesticide particles or droplets in various types of plastic polymers. Microcapsules of various sizes, solubilities, wall thicknesses and degrees of penetration can be formed by varying the polymer chemistry or by varying factors in the process. These factors govern the rate of release of the active ingredient inside, which in turn affects the residual performance, rate of action, and odor of the product. Microcapsules may be formulated as suspension concentrates or as water-dispersible granules.
The oil solution concentrate is made by dissolving the pesticide in a solvent that will keep the pesticide in solution. The oil solution of the pesticide typically breaks up and kills the pesticide faster than other formulations because the solvent itself has a pesticide effect and the dissolution of the wax covering the skin increases the rate of pesticide uptake. Other advantages of oil solutions include better storage stability, better crack penetration and better adhesion to greasy surfaces.
Another embodiment is an oil-in-water emulsion, wherein the emulsion comprises oily beads each having a lamellar liquid crystal coating and dispersed in an aqueous phase, wherein each oily bead comprises at least one agriculturally active molecule and is individually coated with a monolayer layer or a multilamellar layer comprising (1) at least one nonionic lipophilic surfactant, (2) at least one nonionic hydrophilic surfactant, and (3) at least one ionic surfactant, wherein the beads have an average particle size of less than 800 nanometers.
Other formulation Components
In general, when the molecules disclosed in formula one are used in a formulation, such a formulation may also contain other components. These components include, but are not limited to (this is a non-exhaustive and non-mutually exclusive list) wetting agents, spreading agents, adhesion agents, penetration agents, buffering agents, chelating agents, bleach inhibitors, compatibilizing agents, antifoaming agents, cleaning agents, and emulsifying agents. Several components are described next.
Wetting agents are substances that when added to a liquid increase the spreading or penetration ability of the liquid by reducing the surface tension between the liquid and the surface over which it spreads. Wetting agents are used in agrochemical formulations for two primary functions, increasing the rate of wetting of the powder in water during processing and manufacture to produce soluble liquid or suspension concentrates, and reducing the wetting time of the wettable powder and improving the penetration of water into the water dispersible granules during mixing of the product with water in the spray tank. Examples of wetting agents for wettable powder, suspension concentrates and water dispersible granule formulations are sodium lauryl sulfate, sodium dioctyl sulfosuccinate, alkylphenol ethoxylates, and aliphatic alcohol ethoxylates.
A dispersant is a substance that adsorbs onto the surface of particles, helping to maintain the dispersed state of the particles and prevent them from reagglomerating. Dispersants are added to agrochemical formulations to promote dispersion and suspension during manufacture and to ensure that the particles redisperse in water in the spray tank. They are widely used in wettable powders, suspension concentrates, and water dispersible granules. Surfactants used as dispersants have the ability to strongly adsorb onto particle surfaces and provide a charged or steric barrier to particle reagglomeration. The most commonly used surfactants are anionic surfactants, nonionic surfactants, or mixtures of both types. For wettable powder formulations, the most common dispersant is sodium lignin sulfonate. For suspension concentrates, very good adsorptivity and stability are obtained using polyelectrolytes such as sodium naphthalene sulfonate formaldehyde condensate. Tristyrylphenol ethoxylate phosphate esters are also used. Nonionic surfactants such as alkylaryl ethylene oxide condensates and EO-PO block copolymers are sometimes used in suspension concentrates in combination with anionic surfactants as dispersants. In recent years, novel very high molecular weight polymeric surfactants have been developed as dispersants. It has a very long hydrophobic "backbone" and a large number of ethylene oxide chains, forming the "teeth" of a "comb" surfactant. These high molecular weight polymers can give the suspension concentrate very good long term stability because the hydrophobic backbone has many anchor points on the particle surface. Examples of dispersants for agrochemical formulations are sodium lignin sulfonate, sodium naphthalene sulfonate formaldehyde condensate, tristyrylphenol ethoxylate phosphate esters, aliphatic alcohol ethoxylates, alkyl ethoxylates, EO-PO block copolymers, and graft copolymers.
An emulsifier is a substance that stabilizes a suspension of droplets of one liquid phase in another liquid phase. In the absence of an emulsifier, the two liquids may be separated into two immiscible liquid phases. The most commonly used emulsifier blends contain alkylphenols or aliphatic alcohols having twelve or more ethylene oxide units and an oil-soluble calcium salt of dodecylbenzenesulfonic acid. A range of hydrophilic-lipophilic balance ("HLB") values from about 8 to about 18 will normally provide a good stable emulsion. Emulsion stability can sometimes be improved by adding small amounts of EO-PO block copolymer surfactant.
The solubilizing agent is a surfactant that will form micelles in water at a concentration above the critical micelle concentration. These micelles are then able to dissolve or solubilize the water-insoluble material within the hydrophobic portion of the micelle. The types of surfactants commonly used for solubilization are nonionic surfactants, sorbitan monooleate ethoxylates, and methyl oleate.
Surfactants are sometimes used alone or in combination with other additives (such as mineral or vegetable oils) as adjuvants for spray tank mixing to improve the biological performance of the pesticide on the target. The type of surfactant used for bio-enhancement generally depends on the nature and mode of action of the pesticide. However, they are generally nonionic surfactants such as alkyl ethoxylates, linear aliphatic alcohol ethoxylates, and aliphatic amine ethoxylates.
Carriers or diluents in agricultural formulations are materials that are added to pesticides to give a product of the desired strength. The carrier is typically a material with high absorption capacity and the diluent is typically a material with low absorption capacity. Carriers and diluents are used in the formulation of powders, wettable powders, granules, and water dispersible granules.
Organic solvents are used primarily for formulating emulsifiable concentrates, oil-in-water emulsions, suspoemulsions, oil dispersions and ultra low volume formulations and to a lesser extent for formulating particulate formulations. Mixtures of solvents are sometimes used. The solvent of the first main group is an aliphatic paraffinic oil, such as kerosene or refined paraffin. The second main group (and most commonly used) of solvents includes aromatic solvents such as xylenes and higher molecular weight C9 and C10 aromatic solvent fractions. Chlorinated hydrocarbons may be used as co-solvents to prevent crystallization of the pesticide when the formulation is emulsified in water. Alcohols are sometimes used as co-solvents to increase the solvency. Other solvents may include vegetable oils, seed oils, and esters of vegetable and seed oils.
Thickeners or gelling agents are mainly used to formulate suspension concentrates, oil dispersions, emulsions and suspoemulsions to alter the rheological or flow characteristics of liquids and prevent separation and settling of dispersed particles or droplets. Thickeners, gelling agents, and anti-settling agents generally fall into two categories, namely water insoluble particles and water soluble polymers. Clays and silica can be used to produce suspension concentrates and oil dispersion formulations. Examples of these types of materials include, but are not limited to, montmorillonite, bentonite, magnesium aluminum silicate, and attapulgite. Water-soluble polysaccharides in water-based suspension concentrates have been used for many years as thickening-gelling agents. The most common polysaccharide types are natural extracts of seeds and seaweed or synthetic derivatives of cellulose. Examples of these types of materials include, but are not limited to, guar gum, locust bean gum, carrageenan, alginate, methylcellulose, sodium carboxymethylcellulose (SCMC), and Hydroxyethylcellulose (HEC). Other types of anti-settling agents are based on modified starches, polyacrylates, polyvinyl alcohols, and polyethylene oxides. Another good anti-settling agent is xanthan gum.
Microorganisms can cause spoilage of formulated products. Thus, the use of preservatives eliminates or reduces their effect. Examples of such agents include, but are not limited to, propionic acid and its sodium salt, sorbic acid and its sodium or potassium salt, benzoic acid and its sodium salt, sodium p-hydroxybenzoate, methyl p-hydroxybenzoate, and 1, 2-benzisothiazolin-3-one (BIT).
The presence of surfactants generally results in foaming of the water-based formulation during the mixing operation in production and application by spray cans. To reduce the tendency to foam, defoamers are typically added during the production stage or prior to filling into the bottles. Generally, there are two types of defoamers, silicone and non-silicone. Silicones are typically aqueous emulsions of dimethylpolysiloxane, while non-silicone defoamers are water insoluble oils (such as octanol and nonanol) or silica. In both cases, the function of the defoamer is to displace the surfactant from the air-water interface.
"Green" agents (e.g., adjuvants, surfactants, solvents) can reduce the overall environmental footprint of the crop protection formulation. The green agent is biodegradable and is typically derived from natural and/or sustainable sources, such as plant sources and animal sources. Specific examples are vegetable oils, seed oils, and esters thereof, and alkoxylated alkyl polyglucosides.
Application of
The molecules of formula one and combinations thereof disclosed herein may be applied to any locus. Specific sites for application of such molecules include alfalfa, almond, apple, barley, beans, canola, corn, cotton, crucifers, flowers, feed species (ryegrass, sudan Grass (Sudan Grass), festuca (Tall Fescue), kentucky bluegrass (Kentucky Blue Grass) and clover), fruit, lettuce, oat, oilseed crops, citrus, peanut, pear, pepper, potato, rice, sorghum, soybean, strawberry, sugarcane, sugar beet, sunflower, tobacco, tomato, wheat (e.g., hard red winter wheat (HARD RED WINTER WHEAT), soft red winter wheat (Soft RED WINTER WHEAT), bai Dongxiao wheat (WHITE WINTER WHEAT), hard red spring wheat (HARD RED SPRING WHEAT) and Du Lunchun wheat (Durum SPRING WHEAT)), and other valuable crop growing or planting sites.
The molecules of formula one and combinations thereof disclosed herein may also be applied where plants (such as crops) are growing and where there are small amounts (even virtually no) of pests that can commercially damage such plants. Application of such molecules at such sites would be beneficial for plant growth at such sites. Such benefits may include, but are not limited to, helping plants grow better root systems, helping plants better withstand stress growth conditions, improving plant health, improving plant yield (e.g., increased biomass and/or increased content of valuable components), improving plant vigor (e.g., improved plant growth and/or greener leaves), improving plant quality (e.g., improved content or composition of certain components), and improving tolerance of plants to abiotic and/or biotic stress.
When growing a variety of plants, the molecules of formula one and combinations thereof disclosed herein may be applied with ammonium sulfate, as this may provide additional benefits.
The molecules of formula one and combinations thereof disclosed herein can be applied to, in, or around plants genetically modified to express specific traits such as bacillus thuringiensis (e.g., cry1Ab, cry1Ac, cry1Fa, cry1a.105, cry2Ab, vip3A, mCry3A, cry Ab, cry3Bb, cry34Ab1/Cry35Ab 1), other insecticidal toxins, or plants that express herbicide tolerance, or plants that have "stacked" exogenous genes that express insecticidal toxins, herbicide tolerance, nutritional enhancement, or any other beneficial trait.
The molecules of formula one and combinations thereof disclosed herein may be applied to foliar and/or fruiting parts of plants to control pests. Such molecules will be in direct contact with the pest, or the pest will consume such molecules when eating the plant or when drawing juice or other nutrients from the plant.
The molecules of formula one and combinations thereof disclosed herein may also be applied to soil and when applied in this manner, may control pests that feed on roots and stems. The roots can absorb such molecules, thereby transporting them up to the leaf parts of the plants to control chewing pests on the ground and juice feeding pests.
Systemic movement of pesticides in plants can be utilized to control pests on one part of a plant by applying molecules of formula one (e.g., by spraying the locus) to a different part of the plant. For example, control of foliar feeding insects can be achieved by drip irrigation or furrow application, by treating the soil with, for example, a pre-or post-planting soil drench, or by treating plant seeds prior to planting.
The molecules of formula one and combinations thereof disclosed herein may be used with baits. Generally, for baits, the baits are placed on a ground surface where termites, for example, may come into contact with and/or be attracted to the bait. Baits may also be applied to surfaces (horizontal, vertical or inclined surfaces) of buildings where ants, termites, cockroaches and flies, for example, may come into contact with the lure and/or be attracted to the lure.
The molecules of formula one and combinations thereof disclosed herein may be encapsulated within a capsule or disposed on a surface of a capsule. The size of the capsules may range from nano-sized (about 100-900 nanometers in diameter) to micro-sized (about 10-900 microns in diameter).
The molecules of formula one and combinations thereof disclosed herein may be applied to eggs of pests. Because of the unique ability of eggs of some pests to resist certain pesticides, it may be desirable to repeatedly apply such molecules to control emerging larvae.
The molecules of formula one and combinations thereof disclosed herein may be applied as seed treatments. The seed treatment may be applied to all types of seeds, including seeds from which plants genetically modified to express a particular trait will germinate. Representative examples include those expressing proteins or other insecticidal toxins toxic to invertebrate pests (such as bacillus thuringiensis), those expressing herbicide tolerance (such as "round dup Ready" seeds), or those having "stacked" exogenous genes expressing insecticidal toxins, herbicide tolerance, nutrient enhancement, drought resistance, or any other beneficial trait. In addition, such seed treatments having the molecule of formula one may further enhance the ability of plants to better withstand stress growth conditions. This results in healthier, more viable plants, which can lead to higher yields at harvest time. In general, about 1 gram to about 500 grams of such molecules per 100,000 seeds are expected to provide good benefits, an amount of about 10 grams to about 100 grams per 100,000 seeds is expected to provide better benefits, and an amount of about 25 grams to about 75 grams per 100,000 seeds is expected to provide even better benefits.
Component a (a molecule having formula one) is present in the formulation for seed treatment in a pesticidally effective amount, for example in an amount of from 1% to about 60% by weight, based on the total weight of the seed treatment mixture. Each compound of component B is present in a pesticidally effective amount of from about 1% to about 60% by weight based on the total weight of the seed treatment mixture. Components a and B may be applied to the seed sequentially or simultaneously.
The seed treatment may comprise more than one active compound as component B, such as a compound having further fungicidal, insecticidal, acaricidal and/or nematicidal properties. As used herein, the term "seed" means any dormant stage of a plant that physically breaks away from the plant's plant state, and/or that can be stored for a long period of time and/or can be used to regenerate another plant of the same species. The term "dormancy" refers to a state in which a plant remains viable within reasonable limits despite the lack of light, water, and/or nutrients necessary for the plant (i.e., non-seed) state. In particular embodiments, the term refers to a true seed.
The molecules of formula one and combinations thereof disclosed herein may be administered with one or more active ingredients in a soil improvement agent.
The molecules of formula one and combinations thereof disclosed herein may be used to control endoparasites and ectoparasites in the veterinary field or in the field of non-human animal farming. Such molecules may be administered orally, for example in the form of tablets, capsules, beverages, granules, transdermally in the form of, for example, dips, sprays, dumps, spotting and dusting powders, and parenterally in the form of, for example, injections.
The molecules of formula one and combinations thereof disclosed herein may also be advantageously used in livestock farming, such as cattle, chickens, geese, goats, pigs, sheep, and turkeys. They may also be advantageously used with pets such as horses, dogs, and cats. The specific pests to be controlled may be flies, fleas, and ticks that make such animals anaerobically. Suitable formulations are administered orally to animals with drinking water or food. The appropriate dosage and formulation depends on the species.
The molecules of formula one and combinations thereof disclosed herein may also be used to control parasites in the animals listed above (especially the intestines).
The molecules of formula one and combinations thereof disclosed herein may also be used in methods of treatment for human health care. Such methods include, but are not limited to, oral administration in the form of, for example, tablets, capsules, beverages, granules, and transdermal applications.
The molecules of formula one and combinations thereof disclosed herein may also be applied to invasive pests. The pests worldwide have migrated to new environments (for such pests) and thereafter become new invasive species of such new environments. Such molecules may also be used in such new invasive species to control them in such new environments.
The table part is as follows
The% increase beyond expected in the following table is calculated according to the following equation:
((observed% control of mixture-expected% control)/expected% control) x 100
Thus, in some cases, x represents that the% increase beyond expected is too large to calculate using the above equation (e.g., when% control = 0 is expected).

Claims (13)

1.一种杀有害生物组合物，其包含：1. A pesticidal composition comprising: (A)具有根据式一的结构的分子(A) A molecule having a structure according to formula 1 其中：in: R1是CF3、CHF2、CF2CF3、OCF3、OCF2CF3、SF5、或SO2CF3；R 1 is CF 3 , CHF 2 , CF 2 CF 3 , OCF 3 , OCF 2 CF 3 , SF 5 , or SO 2 CF 3 ; R2是H、F、或CH3；R 2 is H, F, or CH 3 ; R3是CH3或OCH3；并且R 3 is CH 3 or OCH 3 ; and R4是-CH2OCH2CH3、-CH2OCH2CF3、或-CH2OCH2CH2F；R 4 is -CH 2 OCH 2 CH 3 , -CH 2 OCH 2 CF 3 , or -CH 2 OCH 2 CH 2 F; 以及as well as B)混合配伍物，其是B) a mixed compound, which is (1)AIGA的成员；(1)Members of AIGA; (2)AIGA-1的成员；(2) Members of AIGA-1; (3)AIGA-2的成员；(3) Members of AIGA-2; (3)AI-1；或(3) AI-1; or (4)AI-2。(4) AI-2. 2.根据权利要求1所述的杀有害生物组合物，其中，具有根据式一的结构的分子是F1、F2、F3、F4、F5、F6、F7、F8、F9、F10、F11、F12、F13、F14、F15、或F16。2. The pesticidal composition of claim 1, wherein the molecule having a structure according to Formula 1 is F1, F2, F3, F4, F5, F6, F7, F8, F9, F10, F11, F12, F13, F14, F15, or F16. 3.根据权利要求2所述的组合物，其中，所述分子是F1。3. The composition of claim 2, wherein the molecule is F1. 4.根据权利要求3所述的组合物，其包含：4. The composition according to claim 3, comprising: (A)F1；(A) F1; B)混合配伍物，其选自由以下组成的组：阿巴美丁、高灭磷、灭螨醌、啶虫脒、氟丙菊酯、acynonapyr、啶喃环丙虫酯、棉铃威、涕灭威、烯丙菊酯、α-氯氰菊酯、氯氨吡啶酸、双甲脒、印楝素、甲基吡啶磷、谷硫磷-乙基、谷硫磷-甲基、三唑锡、嘧菌酯、恶虫威、丙硫克百威、杀虫磺、苯螨特、苯嘧虫噁烷、β-氟氯氰菊酯、β-氯氰菊酯、联苯肼酯、联苯菊酯、生物烯丙菊酯、生物苄呋菊酯、双三氟虫脲、溴虫氟苯双酰胺、溴螨酯、噻嗪酮、丁酮威、丁酮砜威、硫线磷、甲萘威、克百威、丁硫克百威、萎锈灵、盐酸杀螟丹、灭螨猛、氯虫苯甲酰胺、氯丹、氯氧磷、虫螨腈、毒虫畏、定虫隆、氯甲磷、毒死蜱、甲基毒死蜱、环虫酰肼、四螨嗪、二氯吡啶酸、解草酯、噻虫胺、氢氧化铜、蝇毒磷、杀螟腈、氰虫酰胺、环溴虫酰胺、环丁氟仑、乙氰菊酯、环氧虫啶、腈吡螨酯、丁氟螨酯、氟氯氰菊酯、氯氟氰菊酯、三环锡、霜脲氰、氯氰菊酯、苯醚氰菊酯、环丙氟虫胺、灭蝇胺、d-顺式-反式烯丙菊酯、DDVP、溴氰菊酯、内吸磷-S-甲基、丁醚脲、二嗪农、敌敌畏、三氯杀螨醇、百治磷、苯醚甲环唑、氟螨嗪、二氟脲、乐果、甲基毒虫畏、嗪虫唑酰胺、呋虫胺、乙拌磷、DNOC、d-反式烯丙菊酯、甲氨基阿维菌素、苯甲酸甲氨基阿维菌素、烯炔菊酯、硫丹、EPN、高氰戊菊酯、噻唑菌胺、乙硫苯威、乙硫磷、乙虫腈、灭线磷、醚菊酯、噁唑菌酮、氨磺磷、苯线磷、喹螨醚、腈苯唑、苯丁锡、杀螟硫磷、丰迷唑迪缇亚兹、仲丁威、苯氧威、甲氰菊酯、唑螨酯、倍硫磷、氰戊菊酯、氟虫腈、啶嘧磺隆、氟啶虫酰胺、双氟磺草胺、嘧螨酯、三氟咪啶酰胺、氟虫双酰胺、氟环脲、氟氰菊酯、咯菌腈、氟噻虫砜、氟虫脲、氟氯苯菊酯、丙炔氟草胺、氟吡菌酰胺、氟噁菌磺酯、氟嘧菌酯、氟吡呋喃酮、氟虫啶胺、氟草定、氟噁唑酰胺、氟唑菌酰胺、伐虫脒、噻唑磷、呋线威、γ-氯氟氰菊酯、草甘膦、氟氯吡啶酯、苄螨醚、氯虫酰肼、庚烯磷、氟铃脲、噻螨酮、氟蚁腙、烯虫乙酯、甲氧咪草烟、灭草烟、咪唑环磷、吡虫啉、炔咪菊酯、indazapyroxamet、茚虫威、茚吡菌胺、种菌唑、异噁唑虫酰胺、异柳磷、异丙氟吡菌胺、异丙威、异噁唑磷、噻嗯菊酯、烯虫炔酯、λ-氯氟氰菊酯、雷皮菌素、虱螨脲、马拉硫磷、代森锰锌、MCPA、灭蚜磷、精甲霜灵、氰氟虫腙、甲霜灵、叶菌唑、甲胺磷、乌洛托品、杀扑磷、甲硫威、灭多威、甲氧普林、甲氧滴滴涕、甲氧虫酰肼、速灭威、甲磺隆、速灭磷、弥拜菌素、久效磷、腈菌唑、二溴磷、烟嘧磺隆、氯啶、氟酰脲、多氟脲、氧乐果、杀线威、氟噻唑吡乙酮、噁唑磺基、亚砜磷、对硫磷、甲基对硫磷、戊苯吡菌胺、吡噻菌胺、苄氯菊酯、苯醚菊酯、稻丰散、甲拌磷、伏杀磷、亚胺硫磷、磷胺、辛硫磷、哌碳唑、毒莠定、啶氧菌酯、唑啉草酯、抗蚜威、甲基嘧啶磷、右旋炔丙菊酯、丙溴磷、克螨特、胺丙畏、丙环唑、残杀威、戊炔草胺、丙硫菌唑、丙硫磷、spiflumetofen、吡氟丁酰胺、派灭净、吡唑硫磷、唑菌胺酯、除虫菊、哒螨灵、啶虫丙醚、哒嗪硫磷、吡氟喹虫唑、嘧螨醚、吡丙醚、罗克杀草砜、喹硫磷、灭虫菊、砜嘧磺隆、鱼藤酮、氟唑环菌胺、氟硅菊酯、二螺虫、乙基多杀菌素、多杀菌素、螺螨双酯、螺螨酯、螺甲螨酯、甲氧哌啶乙酯、螺虫乙酯、氟虫胺、治螟磷、氟啶虫胺腈、τ-氟胺氰菊酯、戊唑醇、虫酰肼、吡螨胺、丁基嘧啶磷、氟苯脲、七氟菊酯、双硫磷、特丁硫磷、杀虫畏、三氯杀螨砜、胺菊酯、氟氰虫酰胺、θ-氯氰菊酯、噻苯咪唑、噻虫嗪、杀虫环、硫敌克、久效威、甲基乙拌磷、杀虫双、福美双、硫虫酰胺、噻噁唑砜、唑虫酰胺、肟草酮、四溴菊酯、四氟苯菊酯、唑蚜威、三唑磷、敌百虫、绿草定、肟菌酯、三氟苯嘧啶、杀玲脲、混杀威、蚜灭多、XMC、灭杀威、ξ-氯氰菊酯、AI-1、AI-2、和2,4-D。B) a mixed compatibility selected from the group consisting of abamectin, acephate, acetamiprid, acralid, acynonapyr, pyraclostrobin, aldicarb, allethrin, α-cypermethrin, aminopyralid, amitraz, azadirachtin, methyl pyrifos, azinphos-methyl-ethyl, azinphos-methyl-methyl, triazotin, azoxystrobin, benfenac, benfuracarb, cypermethrin, benzathine, benzimidazole, benzylpyridin ... Benzene diamide, bromofenamide, buprofezin, butanone carbendazim, butanone sulfone carbendazim, cadusin, carbaryl, carbofuran, butanone carbendazim, carboxin, carbofuran hydrochloride, mite-killing, chlorantraniliprole, chlordane, chloroxyphos, chlorfenapyr ... Cypermethrin, cyprodinil, cyromazine, d-cis-trans allethrin, DDVP, deltamethrin, endothion-S-methyl, diafenthiuron, diazinon, dichlorvos, dicofol, dicrotophos, fenpropimorph, fluazifop, diflubenzuron, dimethoate, methyl chlorpyrifos, methimazole, dimethoate, dimethoate, d-trans allethrin, avermectin, avermectin benzoate, fenthrin, endosulfan, EPN, cypermethrin, ethaboxam, ethiofencarb, ethion, ethiprole, ethoprophos, oxathiapiprolin, sulfamethoxam, fenamiphos , fenazaquin, cypermethrin, fenbutazone, fenthiophos, fenamid, fenthiocarb, cypermethrin, fenthiocarb, fenthiophos, cypermethrin, flubendiamide, fluazifop, flutolanil, flutolanil, fluthiazolamide, flutolanil ... Chloropyridine ester, benzyl acarb, chlorfenapyr, heptyl phos, hexaflumuron, hexathiazolin, hydrazone, methoprene, imidacloprid, imidacloprid, indazapyroxamet, indoxacarb, indopyraclostrobin, cyproconazole, isoxazole, isofenphos, isoprofen, isoprocarb, isoxazole, thiamethoxam, methoprene, λ-cyhalothrin, lepidomycin, lufenuron, malathion, mancozeb, MCPA, cyproconazole, metalaxyl, cyanamide, metalaxyl, methoprene, metalaxyl, metconazole, methamidophos, methoprene, methidathion, methidathion, methidathion, methidathion Sulfurcarb, methomyl, methoprene, methoxychlor, methoxyfenozide, metoclopramide, metsulfuron, metoclopramide, metoclopramide, monocrotophos, myclobutanil, dibromophos, nicosulfuron, chlorpyrifos, fluazifop, polyfluanilide, omethoate, oxamyl, fluthiazolin, oxathiapiprolin, oxazolidinone, oxazolidinone, sulfoxide, parathion, methyl parathion, pentothiopyrad, penthiopyrad, permethrin, phenothrin, pyraclostrobin, phosphamidon, phosphamidon, phoxim, piperidine, pyraclostrobin, picoxystrobin, pinoxadone, pirimicarb, methyl pirimiphos, d-propylthrin, profenofos, propargite, amine Fear, propiconazole, propoxur, propargyl sulfamethoxam, prothioconazole, prothioconazole, spiflumetofen, pyraclostrobin, pyraclostrobin, pyraclostrobin, pyraclostrobin, pyraclostrobin, pyraclostrobin, pyraclostrobin, pyraclostrobin, pyraclostrobin, pyraclostrobin, pyraclostrobin, quinalphos, pyrethrum, sulfonesulfuron, rotenone, fluazifop, flutolanil, dispirothrin, ethyl spinosad, spinosad, spiroclofen, spirodiclofen, spiromesifen, ethyl methoxypiperidin, spirotetramat, sulfluramid, sulfoxaflor, τ-fluvalinate, tebuconazole, insecticide Hydrazide, tebufenpyrad, butyl pyrimidinphos, flubenzuron, tefluthrin, tebufos, terbufos, chlorpyrifos, trichlorfon, tetramethrin, flucythrinate, θ-cypermethrin, thiabendazole, thiamethoxam, cypermethrin, thiamethoxam, thiocarb, thiophanate-methyl, dimethoate, thiram, thiophanate-methyl, thiophanate-sulfuron, thiophanate-sulfuron, tolfenpyrad, oxathiapiprolin, tralomethrin, transfluthrin, triazophos, trichlorfon, trifloxystrobin, triflumuron, trifloxystrobin, trifloxystrobin, trifloxystrobin, thiophanate-methyl, cypermethrin, thiophanate-sulfuron, XMC, cypermethrin, ξ-cypermethrin, AI-1, AI-2, and 2,4-D. 5.根据权利要求1所述的杀有害生物组合物，其中，所述混合配伍物选自由以下组成的组：阿巴美丁、啶虫脒、苯嘧虫噁烷、联苯菊酯、氯虫苯甲酰胺、虫螨腈、氰虫酰胺、环丁氟仑、嗪虫唑酰胺、氟虫腈、氟啶虫酰胺、氟噁菌磺酯、氟吡呋喃酮、氟虫啶胺、氟噁唑酰胺、吡虫啉、茚虫威、异噁唑虫酰胺、λ-氯氟氰菊酯、甲氧虫酰肼、派灭净、吡丙醚、二螺虫、乙基多杀菌素、多杀菌素、甲氧哌啶乙酯、螺虫乙酯、氟啶虫胺腈、噻虫嗪、和三氟苯嘧啶。5. The pesticidal composition according to claim 1, wherein the mixed compatibility is selected from the group consisting of abamectin, acetamiprid, benzylpyridin, bifenthrin, chlorantraniliprole, cypermethrin, cyantraniliprole, cypermethrin, cypermethrin, thiamethoxam, flubendiamide, flufenac, flupyrad, flufenac, fluoxathiapiprolin, fluoxathiapiprolin, imidacloprid, indoxacarb, isoxathiapiprolin, lambda-cyhalothrin, methoxyfenozide, pentamidine, pyriproxyfen, dispirothrin, ethyl spinetoram, spinosad, methoxyfenopyr, spirotetramat, sulfoxaflor, thiamethoxam, and triflumuron. 6.根据权利要求4所述的杀有害生物组合物，其中，所述混合配伍物选自由以下组成的组：嘧菌酯、氢氧化铜、苯醚甲环唑、噻唑菌胺、咯菌腈、氟吡菌酰胺、氟嘧菌酯、氟唑菌酰胺、茚吡菌胺、种菌唑、异丙氟吡菌胺、精甲霜灵、氯氟醚菌唑、甲霜灵、腈菌唑、氟噻唑吡乙酮、啶氧菌酯、丙环唑、丙硫菌唑、氟唑菌酰羟胺、百克敏、氟唑环菌胺、戊唑醇、噻苯咪唑、福美双、灭菌唑、肟菌酯、阿巴美丁、啶虫脒、啶喃环丙虫酯、AI-1、AI-2、苯嘧虫噁烷、联苯菊酯、溴虫氟苯双酰胺、氯虫苯甲酰胺、虫螨腈、噻虫胺、氰虫酰胺、溴氰菊酯、呋虫胺、氟虫腈、氟啶虫酰胺、三氟咪啶酰胺、氟噻虫砜、氟吡呋喃酮、氟虫啶胺、氟噁唑酰胺、热灭活的伯克霍尔德菌属物种菌株A 396、吡虫啉、茚虫威、λ氯氟氰菊酯、甲氧虫酰肼、杀线威、吡丙醚、多杀菌素、乙基多杀菌素、螺甲螨酯、螺虫乙酯、氟啶虫胺腈、氟氰虫酰胺、噻虫嗪、和三氟苯嘧啶。6. The pesticidal composition according to claim 4, wherein the mixed compatibility is selected from the group consisting of: azoxystrobin, copper hydroxide, difenoconazole, ethaboxam, fludioxonil, fluopyram, fluoxastrobin, fluopyram, indopyram, cyproconazole, isopropyram, metalaxyl-M, clofoconazole, metalaxyl, myclobutanil, fluthiazolinone, picoxystrobin, propiconazole, prothioconazole, fluopyram, benomyl, fluopyram, metalaxyl-M, clofoconazole, metalaxyl, myclobutanil, fluthiazolinone, picoxystrobin, propiconazole, prothioconazole, fluopyram, benomyl, fluopyram, metalaxyl-M, clofoconazole, metalaxyl, myclobutanil, fluopyram, picoxystrobin, propiconazole, prothioconazole, fluopyram, benomyl, fluopyram oxazolidinone, thiabendazole, thiram, trichlorfon, trifloxystrobin, abamectin, acetamiprid, pyraclostrobin, AI-1, AI-2, benzathine, bifenthrin, bromofenac, chlorantraniliprole, chlorantraniliprole, cypermethrin, clothianidin, cyantraniliprole, deltamethrin, dinotefuran, fipronil, flonicamid, trifluanidamide, fluthiazolin, flupyrone, flufenamid, fluoxazolidinone, heat-killed Burkholderia sp. strain A 396, imidacloprid, indoxacarb, lambda-cyhalothrin, methoxyfenozide, oxamyl, pyriproxyfen, spinosad, spinetoram, spiromesifen, spirotetramat, sulfoxaflor, cyantraniliprole, thiamethoxam, and trifluanid. 7.根据权利要求5所述的杀有害生物组合物，其中，所述混合配伍物选自由以下组成的组：嘧菌酯、氢氧化铜、苯醚甲环唑、噻唑菌胺、咯菌腈、氟吡菌酰胺、氟嘧菌酯、氟唑菌酰胺、茚吡菌胺、种菌唑、异丙氟吡菌胺、精甲霜灵、氯氟醚菌唑、甲霜灵、腈菌唑、氟噻唑吡乙酮、啶氧菌酯、丙环唑、丙硫菌唑、氟唑菌酰羟胺、百克敏、氟唑环菌胺、戊唑醇、噻苯咪唑、福美双、灭菌唑和肟菌酯。7. The pesticidal composition according to claim 5, wherein the mixed partner is selected from the group consisting of: azoxystrobin, copper hydroxide, difenoconazole, ethaboxam, fludioxonil, fluopyram, fluoxastrobin, fluopyram, indopyram, ipiconazole, isopropyram, metalaxyl-M, clofoconazole, metalaxyl, myclobutanil, fluthiazolinone, picoxystrobin, propiconazole, prothioconazole, fluopyram, oxazolidinone, benomyl, flutoxacillin, tebuconazole, thiabendazole, thiram, trichlorfonazole and trifloxystrobin. 8.根据权利要求5所述的杀有害生物组合物，其中，所述混合配伍物选自由以下组成的组：阿巴美丁、啶虫脒、啶喃环丙虫酯、AI-1、AI-2、苯嘧虫噁烷、联苯菊酯、溴虫氟苯双酰胺、氯虫苯甲酰胺、虫螨腈、噻虫胺、氰虫酰胺、溴氰菊酯、呋虫胺、氟虫腈、氟啶虫酰胺、三氟咪啶酰胺、氟噻虫砜、氟吡呋喃酮、氟虫啶胺、氟噁唑酰胺、热灭活的伯克霍尔德菌属物种菌株A 396、吡虫啉、茚虫威、λ氯氟氰菊酯、甲氧虫酰肼、杀线威、吡丙醚、多杀菌素、乙基多杀菌素、螺甲螨酯、螺虫乙酯、氟啶虫胺腈、氟氰虫酰胺、噻虫嗪、和三氟苯嘧啶。8. The pesticidal composition of claim 5, wherein the mixed partner is selected from the group consisting of abamectin, acetamiprid, pyraclostrobin, AI-1, AI-2, benzylpyridin, bifenthrin, bromofenac, chlorantraniliprole, chlorfenapyr, cypermethrin, clothianidin, cyantraniliprole, deltamethrin, dinotefuran, fipronil, flonicamid, trifluanid, fluthiazolin, flupyrone, flufenac, fluoxazolidinone, heat-killed Burkholderia species strain A 396, imidacloprid, indoxacarb, lambda cyhalothrin, methoxyfenozide, oxamyl, pyriproxyfen, spinosad, spinetoram, spiromesifen, spirotetramat, sulfoxaflor, cyantraniliprole, thiamethoxam, and trifluanid. 9.根据权利要求1-8所述的杀有害生物组合物，其中，F1与所述混合配伍物B)的比率选自1:160,000至160,000:1、1:80,000至80,000:1、1:40,000至40,000:1、1:20,000至20,000:1、1:10,000至10,000:1、1:8000至8000:1、1:5000至5000:1、1:2000至2000:1、1:1000至1000:1、1:500至500:1、1:250至250:1、1:100至100:1、1:50至50:1、1:25至25:1、1:10至10:1、1:5至5:1、和1:1。9. The pesticidal composition according to claims 1-8, wherein the ratio of F1 to the mixed partner B) is selected from 1:160,000 to 160,000:1, 1:80,000 to 80,000:1, 1:40,000 to 40,000:1, 1:20,000 to 20,000:1, 1:10,000 to 10,000:1, 1:8000 to 8000:1, 1:5000 to 5000:1, 1:2000 to 2000:1, 1:1000 to 1000:1, 1:500 to 500:1, 1:250 to 250:1, 1:100 to 100:1, 1:50 to 50:1, 1:25 to 25:1, 1:10 to 10:1, 1:5 to 5:1, and 1:1. 10.一种防治攻击植物、植物繁殖部分、植物栖息地的有害生物的方法，所述方法包括使植物、植物繁殖部分、植物栖息地与根据权利要求1-8所述的组合物接触的步骤。10. A method of controlling pests which attack plants, plant reproductive parts, plant habitats, said method comprising the step of contacting the plants, plant reproductive parts, plant habitats with a composition according to claims 1 to 8. 11.一种防治攻击植物、植物繁殖部分、植物栖息地的有害生物的方法，所述方法包括使所述有害生物或其栖息地、食物供应、繁殖地、其场所与根据权利要求1-8所述的组合物接触的步骤。11. A method of controlling pests that attack plants, plant reproductive parts, plant habitats, said method comprising the step of contacting said pests or their habitats, food supplies, breeding grounds, loci thereof with a composition according to claims 1 to 8. 12.一种处理种子的方法，所述方法包括使所述种子与根据权利要求1-5所述的组合物接触的步骤。12. A method for treating seeds, said method comprising the step of contacting said seeds with a composition according to claims 1-5. 13.一种用根据权利要求1-8所述的组合物处理的种子。13. Seed treated with a composition according to claims 1-8.
CN202380077731.3A 2022-11-07 2023-11-07 Pesticide composition comprising a compound containing a 1,2,4-triazolyl group and a 4-oxothiazolyl group and another pesticide Pending CN120187298A (en)

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