CN118908391A - Heavy metal wastewater treatment device - Google Patents
Heavy metal wastewater treatment device Download PDFInfo
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- CN118908391A CN118908391A CN202411260209.1A CN202411260209A CN118908391A CN 118908391 A CN118908391 A CN 118908391A CN 202411260209 A CN202411260209 A CN 202411260209A CN 118908391 A CN118908391 A CN 118908391A
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- 229910001385 heavy metal Inorganic materials 0.000 title claims abstract description 69
- 238000004065 wastewater treatment Methods 0.000 title claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 79
- 230000007246 mechanism Effects 0.000 claims abstract description 39
- 238000003825 pressing Methods 0.000 claims abstract description 37
- 238000007789 sealing Methods 0.000 claims abstract description 22
- 238000003756 stirring Methods 0.000 claims description 78
- 238000000034 method Methods 0.000 claims description 13
- 230000008569 process Effects 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- 238000005485 electric heating Methods 0.000 claims description 6
- 238000000429 assembly Methods 0.000 claims description 5
- 230000000712 assembly Effects 0.000 claims description 5
- 230000005540 biological transmission Effects 0.000 claims description 5
- 239000007921 spray Substances 0.000 claims 1
- 239000002351 wastewater Substances 0.000 abstract description 53
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 46
- 230000015556 catabolic process Effects 0.000 abstract description 7
- 238000006731 degradation reaction Methods 0.000 abstract description 7
- 238000002156 mixing Methods 0.000 abstract description 5
- 239000005416 organic matter Substances 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 9
- 238000012545 processing Methods 0.000 description 6
- 239000012535 impurity Substances 0.000 description 5
- 238000003723 Smelting Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000001914 filtration Methods 0.000 description 3
- 229910052761 rare earth metal Inorganic materials 0.000 description 3
- 150000002910 rare earth metals Chemical class 0.000 description 3
- 239000012028 Fenton's reagent Substances 0.000 description 2
- 101001121408 Homo sapiens L-amino-acid oxidase Proteins 0.000 description 2
- 102100026388 L-amino-acid oxidase Human genes 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 101100012902 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) FIG2 gene Proteins 0.000 description 1
- 101100233916 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) KAR5 gene Proteins 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000002306 biochemical method Methods 0.000 description 1
- 238000005842 biochemical reaction Methods 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000012840 feeding operation Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/58—Treatment of water, waste water, or sewage by removing specified dissolved compounds
- C02F1/62—Heavy metal compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0053—Details of the reactor
- B01J19/0066—Stirrers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J4/00—Feed or outlet devices; Feed or outlet control devices
- B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
- B01J4/002—Nozzle-type elements
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/002—Construction details of the apparatus
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Removal Of Specific Substances (AREA)
Abstract
Description
技术领域Technical Field
本发明涉及废水处理设备技术领域。更具体地说,本发明涉及一种重金属废水处理装置。The present invention relates to the technical field of wastewater treatment equipment, and more specifically, to a heavy metal wastewater treatment device.
背景技术Background Art
稀土加工行业包括才可、选矿、分离、冶炼、加工一系列加工生产链,其中冶炼过程中的会产生大量的重金属废水,如这些重金属废水直接排放至环境,难降解的有机物长期存在于环境中,势必会对人类的健康、生态案件带来极大的危害,因此需要对稀土冶炼过程中产生的废水进行处理净化,使得其达到排放标准后再排向环境。The rare earth processing industry includes a series of processing production chains, including mineral processing, separation, smelting and processing. The smelting process will produce a large amount of heavy metal wastewater. If these heavy metal wastewaters are directly discharged into the environment, the difficult-to-degrade organic matter will exist in the environment for a long time, which is bound to cause great harm to human health and ecological cases. Therefore, it is necessary to treat and purify the wastewater generated in the rare earth smelting process so that it can meet the emission standards before being discharged into the environment.
重金属废水处理过程中会向废水中加入处理试剂,其能够与废水中难降解的有机物发生反应,改变有机物的可生化性、溶解性和混凝沉淀性;现有的利用试剂对重金属废水进行处理过程中,向待处理的重金属废水中局部加料,易造成局部试剂浓度过高,进而导致局部高反应,而距离加料区较远的边缘反应较弱,为了提高废水中有机物反应完成率,通常会加入过量的试剂,造成试剂浪费,试剂利用率低,过于过量的药剂还会造成二次污染;此外,现有技术的处理过程中,搅拌维度单一,导致试剂与重金属废水混合不均匀,进一步降低试剂利用率。During the treatment of heavy metal wastewater, treatment reagents are added to the wastewater, which can react with the difficult-to-degrade organic matter in the wastewater to change the biodegradability, solubility and coagulation and sedimentation properties of the organic matter. In the existing process of treating heavy metal wastewater with reagents, local addition of reagents to the heavy metal wastewater to be treated can easily cause excessive concentration of local reagents, thereby leading to local high reaction, while the edge reaction far away from the addition area is weaker. In order to increase the completion rate of the reaction of organic matter in the wastewater, excessive reagents are usually added, resulting in reagent waste and low reagent utilization. Excessive reagents can also cause secondary pollution. In addition, in the treatment process of the prior art, the stirring dimension is single, resulting in uneven mixing of the reagents and heavy metal wastewater, further reducing the reagent utilization rate.
发明内容Summary of the invention
本发明的一个目的是解决至少上述问题,并提供至少后面将说明的优点。An object of the present invention is to solve at least the above problems and to provide at least the advantages which will be described hereinafter.
为了实现根据本发明的这些目的和其它优点,提供了一种重金属废水处理装置,其包括:In order to achieve these purposes and other advantages according to the present invention, a heavy metal wastewater treatment device is provided, comprising:
箱体,其底部设有排液口;The box body has a drain port at the bottom;
第一滤网,其水平内接于所述箱体内,所述第一滤网将所述箱体内部分隔为第一空间、第二空间;A first filter screen is horizontally inscribed in the box body, and the first filter screen divides the interior of the box body into a first space and a second space;
加水机构,其设于所述所述第一空间内,所述加水机构包括:A water adding mechanism is provided in the first space, and the water adding mechanism comprises:
加水竖管,其与所述箱体同轴设置,所述加水竖管包括通过轴承环转动连接的第一竖管和第二竖管,所述第一竖管顶部向上延伸至所述箱体的上方且连通有加水漏斗;所述第一竖管通过支撑件与所述箱体的顶部连接;所述第二竖管内设有水轮,其中心轴与所述第二竖管连接;A water supply vertical pipe is coaxially arranged with the box body, and comprises a first vertical pipe and a second vertical pipe rotatably connected through a bearing ring, the top of the first vertical pipe extends upward to the top of the box body and is connected to a water supply funnel; the first vertical pipe is connected to the top of the box body through a support member; a water wheel is arranged in the second vertical pipe, and the central axis of the water wheel is connected to the second vertical pipe;
加水横管,其水平设置且中点位于所述第二竖管的轴线上,所述加水横管与所述第二竖管底部连通;所述加水横管的底部沿其长度方向间隔设有多个加水喷头;所述加水横管的底部设有多个凸块;A water supply horizontal pipe, which is arranged horizontally and whose midpoint is located on the axis of the second vertical pipe, and the water supply horizontal pipe is connected to the bottom of the second vertical pipe; a plurality of water supply nozzles are arranged at intervals along the length direction of the bottom of the water supply horizontal pipe; a plurality of protrusions are arranged at the bottom of the water supply horizontal pipe;
加料管,其水平设于所述第一空间内且位于所述加水横管的下方,所述加料管的顶部设有多个与多个凸块一一对应的弹性压块,底部设有多个与多个弹性凸块一一对应的加料口,每个压块与所述箱体轴线的距离,和与该压块对应的凸块与所述箱体轴线的距离相等,每个弹性压块沿竖直方向密封滑动设于所述加料管的顶部,每个加料口对应设有封堵塞,每个封堵塞与对应的弹性压块连接;A feeding pipe, which is horizontally arranged in the first space and located below the water-adding horizontal pipe, a plurality of elastic pressing blocks corresponding to the plurality of protrusions are arranged on the top of the feeding pipe, and a plurality of feeding ports corresponding to the plurality of elastic protrusions are arranged on the bottom, the distance between each pressing block and the axis of the box body is equal to the distance between the protrusion corresponding to the pressing block and the axis of the box body, each elastic pressing block is sealed and slidably arranged on the top of the feeding pipe in the vertical direction, each feeding port is correspondingly provided with a sealing plug, and each sealing plug is connected to the corresponding elastic pressing block;
凸块、弹性压块和对应的封堵塞设置为:自然状态下,每个压块的顶部高于对应凸块的底部,封堵塞将对应的加料口封堵;在所述加水横管转动过程中,带动每个凸块转动,在转动行程中,凸块将对应弹性凸块向下按压,进而带动对应的封堵塞向下移动,打开对应的加料口。The protrusions, elastic pressure blocks and corresponding sealing plugs are configured as follows: in a natural state, the top of each pressure block is higher than the bottom of the corresponding protrusion, and the sealing plug blocks the corresponding feeding port; during the rotation of the water adding horizontal pipe, each protrusion is driven to rotate, and during the rotation stroke, the protrusion presses the corresponding elastic protrusion downward, thereby driving the corresponding sealing plug to move downward and open the corresponding feeding port.
优选的是,所述的重金属废水处理装置,还包括设于所述第二空间内的搅拌机构,其包括:Preferably, the heavy metal wastewater treatment device further comprises a stirring mechanism disposed in the second space, comprising:
套筒,其同轴设于第二空间内,所述套筒的两端分别与所述第一滤网的底部、所述箱体的底面转动连接;A sleeve is coaxially disposed in the second space, and two ends of the sleeve are rotatably connected to the bottom of the first filter screen and the bottom surface of the box body respectively;
多对搅拌组件,其沿竖直方向间隔设于所述套筒的圆周侧壁上,每对搅拌组件沿所述箱体的轴线对称设于所述套筒的两侧,每个搅拌组件包括沿所述套筒径向设置的搅拌杆以及多个设于搅拌杆上的搅拌叶片,每个搅拌杆的一端与所述套筒的圆周侧壁转动连接。A plurality of pairs of stirring components are arranged at intervals along the vertical direction on the circumferential side wall of the sleeve, and each pair of stirring components are symmetrically arranged on both sides of the sleeve along the axis of the box body. Each stirring component includes a stirring rod arranged radially along the sleeve and a plurality of stirring blades arranged on the stirring rod, and one end of each stirring rod is rotatably connected to the circumferential side wall of the sleeve.
优选的是,所述的重金属废水处理装置,所述搅拌机构还包括:Preferably, in the heavy metal wastewater treatment device, the stirring mechanism further comprises:
固定杆,其同轴设于所述套筒内,且底部与所述箱体的底面固接;位于最上部的一对搅拌组件对应的搅拌杆的一端穿过套筒的圆周侧壁,并延伸至所述套筒与所述固定杆形成的环形空间内;A fixed rod is coaxially arranged in the sleeve, and the bottom is fixedly connected to the bottom surface of the box body; one end of the stirring rod corresponding to the pair of stirring assemblies located at the uppermost part passes through the circumferential side wall of the sleeve and extends into the annular space formed by the sleeve and the fixed rod;
第一伞齿轮,其同轴固定套设于所述固定杆上;A first bevel gear, which is coaxially fixedly sleeved on the fixing rod;
两个第二伞齿轮,其分别同轴固定套设于最上部的一对搅拌杆的一端上,每个第二伞齿轮与所述第一伞齿轮啮合;Two second bevel gears are coaxially fixedly sleeved on one end of the pair of stirring rods at the top, and each second bevel gear is meshed with the first bevel gear;
多个齿轮盘,每个搅拌杆的另一端上同轴固定套设有一个齿轮盘,上下相邻的两个齿轮盘相互啮合。A plurality of gear plates are provided, and a coaxial fixed sleeve is provided with a gear plate on the other end of each stirring rod, and two gear plates adjacent to each other are meshed with each other.
优选的是,所述的重金属废水处理装置,所述固定杆的圆周侧面上设有螺纹段;Preferably, in the heavy metal wastewater treatment device, a threaded section is provided on the circumferential side surface of the fixing rod;
所述重金属废水处理装置还包括设于所述套筒与所述固定杆形成的环形空间内加热机构,其包括:The heavy metal wastewater treatment device further comprises a heating mechanism disposed in the annular space formed by the sleeve and the fixing rod, which comprises:
转动套,其转动套设于固定杆上,位于最上部的两个搅拌杆的一端与转动套转动连接;A rotating sleeve is arranged on the fixed rod, and one end of the two stirring rods at the uppermost part is rotatably connected to the rotating sleeve;
螺纹套,其螺纹转动设于所述固定杆的螺纹段上,螺纹套通过竖直设置的伸缩杆与转动套连接;A threaded sleeve, whose thread is rotatably arranged on the threaded section of the fixed rod, and the threaded sleeve is connected to the rotating sleeve via a vertically arranged telescopic rod;
电加热块,其固设于所述螺纹套上。The electric heating block is fixed on the threaded sleeve.
优选的是,所述的重金属废水处理装置,所述套筒的下端竖直向下延伸至所述箱体的下方,所述套筒与所述箱体的底面通过密封轴承转动连接;Preferably, in the heavy metal wastewater treatment device, the lower end of the sleeve extends vertically downward to the bottom of the box, and the sleeve is rotatably connected to the bottom surface of the box through a sealed bearing;
所述搅拌机构还包括电机,其设于所述箱体的侧壁上,所述电机的输出轴竖直向下延伸并通过传动皮带与所述套筒的下端传动连接。The stirring mechanism also includes a motor, which is arranged on the side wall of the box body. The output shaft of the motor extends vertically downward and is transmission-connected to the lower end of the sleeve through a transmission belt.
优选的是,所述的重金属废水处理装置,所述支撑件包括:Preferably, in the heavy metal wastewater treatment device, the support member comprises:
支撑板,其水平设于所述箱体的上方,所述支撑板的中部设于供所述第二竖管穿过的通孔,所述通孔内壁通过轴承环与所述第二竖管的侧壁转动连接;A support plate, which is horizontally arranged above the box body, wherein the middle portion of the support plate is arranged at a through hole for the second vertical pipe to pass through, and the inner wall of the through hole is rotatably connected to the side wall of the second vertical pipe through a bearing ring;
支撑杆,其一端与所述支撑板的顶部固接,另一端与所述第一竖管的侧壁固接。A support rod, one end of which is fixedly connected to the top of the support plate, and the other end of which is fixedly connected to the side wall of the first vertical pipe.
优选的是,所述的重金属废水处理装置,所述支撑件还包括竖向伸缩的升降机构,其设于所述支撑板与所述箱体顶面之间;Preferably, in the heavy metal wastewater treatment device, the support member further comprises a vertically telescopic lifting mechanism, which is arranged between the support plate and the top surface of the box body;
所述升降机构包括一对沿箱体的轴线对称设置的液压气缸,每个液压气缸的本体固设于所述箱体的顶面上,活塞杆竖直向上延伸并与所述支撑板的底面连接。The lifting mechanism comprises a pair of hydraulic cylinders symmetrically arranged along the axis of the box body, the body of each hydraulic cylinder is fixed on the top surface of the box body, and the piston rod extends vertically upward and is connected to the bottom surface of the support plate.
本发明至少包括以下有益效果:The present invention has at least the following beneficial effects:
1、本发明提供的重金属废水处理装置,可实现边加废水边加处理试剂,且废水和处理试剂均为均匀喷洒,提高了废水与处理试剂混合均匀性,提高废水中有机物的降解率,进而达到提高废水处理效率;1. The heavy metal wastewater treatment device provided by the present invention can realize adding wastewater and treatment reagents at the same time, and the wastewater and treatment reagents are evenly sprayed, which improves the mixing uniformity of the wastewater and the treatment reagents, improves the degradation rate of organic matter in the wastewater, and thus improves the wastewater treatment efficiency;
2、本发明进一步在第二空间设置搅拌机构,可对重金属废水与处理试剂的混合物进行多维度的大幅度搅拌,提高反应效率,进而提高重金属废水中有机物的降解率,从而达到提高处理效率的目的;2. The present invention further provides a stirring mechanism in the second space, which can stir the mixture of heavy metal wastewater and treatment reagent in multiple dimensions, thereby improving the reaction efficiency and further improving the degradation rate of organic matter in the heavy metal wastewater, thereby achieving the purpose of improving the treatment efficiency;
3、本发明通过设置齿轮组件将套筒的转动与多个搅拌杆的转动进行联动,使得套筒的转动可同步带动多个搅拌杆的转动,减少驱动源的设置,达到节省能源的效果。3. The present invention links the rotation of the sleeve with the rotation of the multiple stirring rods by setting a gear assembly, so that the rotation of the sleeve can synchronously drive the rotation of the multiple stirring rods, reducing the setting of the driving source and achieving the effect of saving energy.
本发明的其它优点、目标和特征将部分通过下面的说明体现,部分还将通过对本发明的研究和实践而为本领域的技术人员所理解。Other advantages, objectives and features of the present invention will be embodied in part through the following description, and in part will be understood by those skilled in the art through study and practice of the present invention.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1为本发明所述的重金属废水处理装置在加料口打开状态的结构示意图;FIG1 is a schematic structural diagram of the heavy metal wastewater treatment device of the present invention in a state where the feed port is open;
图2为本发明图1中A的局部放大图;FIG2 is a partial enlarged view of A in FIG1 of the present invention;
图3为本发明所述的重金属废水处理装置在加料口关闭状态的结构示意图;FIG3 is a schematic structural diagram of the heavy metal wastewater treatment device of the present invention in a state where the feed port is closed;
图4为本发明图3中B的局部放大图。FIG. 4 is a partial enlarged view of B in FIG. 3 of the present invention.
附图标记说明:1-箱体;2-第一滤网;31-第一竖管;32-第二竖管;33-加水漏斗;34-水轮;351-支撑板;352-支撑杆;353-升降机构;36-加水横管;361-喷头;362-凸块;4-加料管;41-弹性压块;42-加料口;43-封堵塞;51-套筒;52-搅拌杆;521-搅拌叶片;53-固定杆;54-第一伞齿轮;55-第二伞齿轮;56-齿轮盘;61-转动套;62-螺纹套;63-伸缩杆;64-电加热块;71-电机;72-皮带。Explanation of the reference numerals: 1-housing; 2-first filter screen; 31-first vertical pipe; 32-second vertical pipe; 33-water adding funnel; 34-water wheel; 351-support plate; 352-support rod; 353-lifting mechanism; 36-water adding horizontal pipe; 361-nozzle; 362-bump; 4-feeding pipe; 41-elastic pressure block; 42-feeding port; 43-sealing plug; 51-sleeve; 52-stirring rod; 521-stirring blade; 53-fixed rod; 54-first bevel gear; 55-second bevel gear; 56-gear plate; 61-rotating sleeve; 62-threaded sleeve; 63-telescopic rod; 64-electric heating block; 71-motor; 72-belt.
具体实施方式DETAILED DESCRIPTION
下面结合附图及实施例对本发明做进一步的详细说明,以令本领域技术人员参照说明书文字能够据以实施。The present invention is further described in detail below in conjunction with the accompanying drawings and embodiments so that those skilled in the art can implement the invention with reference to the description.
应当理解,本文所使用的诸如“具有”、“包含”以及“包括”术语并不排除一个或多个其它元件或其组合的存在或添加。It should be understood that the terms such as “having”, “including” and “comprising” used herein do not exclude the existence or addition of one or more other elements or combinations thereof.
需要说明的是,下述实施方案中所述实验方法,如无特殊说明,均为常规方法,所述试剂和材料,如无特殊说明,均可从商业途径获得。It should be noted that the experimental methods described in the following embodiments are conventional methods unless otherwise specified, and the reagents and materials can be obtained from commercial channels unless otherwise specified.
在本发明的描述中,术语“横向”、“纵向”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,并不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。In the description of the present invention, the terms "lateral", "longitudinal", "up", "down", "front", "back", "left", "right", "vertical", "horizontal", "top", "bottom", "inside" and "outside" etc. to indicate directions or positional relationships are based on the directions or positional relationships shown in the accompanying drawings and are only for the convenience of describing the present invention and simplifying the description. They do not indicate or imply that the device or element referred to must have a specific direction, be constructed and operated in a specific direction, and therefore should not be understood as a limitation on the present invention.
如图1~4所示,本发明提供一种重金属废水处理装置,其包括:As shown in Figures 1 to 4, the present invention provides a heavy metal wastewater treatment device, which includes:
箱体1,其底部设有排液口;The box body 1 has a drain port at the bottom;
第一滤网2,其水平内接于所述箱体1内,所述第一滤网2将所述箱体1内部分隔为第一空间、第二空间;A first filter screen 2, which is horizontally connected to the box body 1, and the first filter screen 2 divides the interior of the box body 1 into a first space and a second space;
加水机构,其设于所述所述第一空间内,所述加水机构包括:A water adding mechanism is provided in the first space, and the water adding mechanism comprises:
加水竖管,其与所述箱体1同轴设置,所述加水竖管包括通过轴承环转动连接的第一竖管31和第二竖管32,所述第一竖管31顶部向上延伸至所述箱体1的上方且连通有加水漏斗33;所述第一竖管31通过支撑件与所述箱体1的顶部连接;所述第二竖管32内设有水轮34,其中心轴与所述第二竖管32连接;A water supply vertical pipe is coaxially arranged with the box body 1, and comprises a first vertical pipe 31 and a second vertical pipe 32 rotatably connected through a bearing ring, the top of the first vertical pipe 31 extends upward to the top of the box body 1 and is connected to a water supply funnel 33; the first vertical pipe 31 is connected to the top of the box body 1 through a support; a water wheel 34 is arranged in the second vertical pipe 32, and the central axis thereof is connected to the second vertical pipe 32;
加水横管36,其水平设置且中点位于所述第二竖管32的轴线上,所述加水横管36与所述第二竖管32底部连通;所述加水横管36的底部沿其长度方向间隔设有多个加水喷头361;所述加水横管36的底部设有多个凸块362;A water supply transverse pipe 36 is horizontally arranged with its midpoint located on the axis of the second vertical pipe 32, and the water supply transverse pipe 36 is connected to the bottom of the second vertical pipe 32; a plurality of water supply nozzles 361 are arranged at intervals along the length direction of the bottom of the water supply transverse pipe 36; a plurality of protrusions 362 are arranged at the bottom of the water supply transverse pipe 36;
加料管4,其水平设于所述第一空间内且位于所述加水横管36的下方,所述加料管4的顶部设有多个与多个凸块362一一对应的弹性压块41,底部设有多个与多个弹性凸块362一一对应的加料口42,每个弹性压块41与所述箱体1轴线的距离,和与该弹性压块41对应的凸块362与所述箱体1轴线的距离相等,每个弹性压块41沿竖直方向密封滑动设于所述加料管4的顶部,每个加料口42对应设有封堵塞43,每个封堵塞43为尖部朝上的圆锥结构,每个封堵塞43与对应的弹性压块41连接;所述加料管4的一端与设于所述箱体1侧壁上的进料口连通;A feeding pipe 4 is horizontally arranged in the first space and below the water-adding horizontal pipe 36. A plurality of elastic pressing blocks 41 corresponding to the plurality of protrusions 362 are arranged on the top of the feeding pipe 4. A plurality of feeding ports 42 corresponding to the plurality of elastic protrusions 362 are arranged on the bottom. The distance between each elastic pressing block 41 and the axis of the box body 1 is equal to the distance between the protrusion 362 corresponding to the elastic pressing block 41 and the axis of the box body 1. Each elastic pressing block 41 is sealed and slidably arranged on the top of the feeding pipe 4 in the vertical direction. A sealing plug 43 is correspondingly arranged on each feeding port 42. Each sealing plug 43 is a conical structure with the tip facing upward. Each sealing plug 43 is connected to the corresponding elastic pressing block 41. One end of the feeding pipe 4 is connected to the feeding port arranged on the side wall of the box body 1.
凸块362、弹性压块41和对应的封堵塞43设置为:自然状态下,每个压块的顶部高于对应凸块362的底部,封堵塞43将对应的加料口42封堵;在所述加水横管36转动过程中,带动每个凸块362转动,在转动行程中,凸块362将对应弹性凸块362向下按压,进而带动对应的封堵塞43向下移动,打开对应的加料口42。The protrusion 362, the elastic pressure block 41 and the corresponding sealing plug 43 are configured as follows: in a natural state, the top of each pressure block is higher than the bottom of the corresponding protrusion 362, and the sealing plug 43 blocks the corresponding feeding port 42; during the rotation of the water adding horizontal pipe 36, each protrusion 362 is driven to rotate, and during the rotation stroke, the protrusion 362 presses the corresponding elastic protrusion 362 downward, thereby driving the corresponding sealing plug 43 to move downward, opening the corresponding feeding port 42.
在上述技术方案中,本发明提供一种重金属废水处理装置,其可用于处理稀土冶炼过程中产生的重金属废水,具体的,通过本装置可向重金属废水中加入处理试剂,如Fenton试剂,其可对重金属废水的难降解的有机物进行部分氧化、偶合或氧化,将有机物转化成分子量不太大的中间产物,从而改变难降解有机物的可生化性、溶解性和混凝土沉淀性,后续利用生化法、混凝沉淀法等工艺加以去除,最终实现对重金属废水的净化。In the above technical scheme, the present invention provides a heavy metal wastewater treatment device, which can be used to treat heavy metal wastewater generated in the rare earth smelting process. Specifically, through this device, a treatment reagent, such as Fenton reagent, can be added to the heavy metal wastewater, which can partially oxidize, couple or oxidize the difficult-to-degrade organic matter in the heavy metal wastewater, and convert the organic matter into an intermediate product with a relatively small molecular weight, thereby changing the biodegradability, solubility and concrete precipitation of the difficult-to-degrade organic matter, and subsequently using biochemical methods, coagulation precipitation methods and other processes to remove it, and finally achieve purification of the heavy metal wastewater.
本发明提供的一种重金属废水处理装置,其包括中空筒体结构的箱体1,其底部设有排液口,排液口处内接第二过滤网,可对试剂处理过程中产生的固体物进行分离,通过排液口可将经过试剂处理后的水排出,并输送至下一步工艺设备(如生化反应设备、沉淀池等)中,通过加水机构向箱体1内部注入待处理的重金属废水,通过加料管4向箱体1内部加入处理试剂(本发明所用处理试剂为液体试剂,如是固体处理剂也可以将其配置成液体混合,通过加料管4加入至箱体1内),在箱体1的内部设置第一滤网2,可对重金属废水进行初过滤,将重金属废水中固定杂质在废水与处理试剂混合之前去除,避免固体杂质影响试剂与重金属废水中有机物的反应;第一滤网2将箱体1内部分隔为第一空间和第二空间(作为优选的可将第一滤网2设置为向上凸起的曲面,除能够提高对重金属废水的冲击抵抗力外,还利用水流将杂质沿曲面冲刷,便于杂质自主落入周边,保证大面积滤网网孔的通透性,进而提高初步过滤效率),加水机构包括通过轴承环转动连接并连通的第一竖管31和第二竖管32,第一竖管31的上端竖直向上延伸穿出箱体1,并连通有加水漏斗33,第一竖管31通过支撑件与箱体1顶部连接,对第一竖管31的圆周转动进行限位,第二竖管32内设有水轮34,当有水流经过第二竖管32时,水轮34转动进而带动第二竖管32绕自身轴线的转动,在支撑件的限位作用下,第一竖管31不转动,在第二竖管32的底部连通有水平设置的加水横管36,其两端封闭、底部设有多个加水喷头361,加水横管36、加水喷头361在第二竖管32的转动作用下转动,实现向第一滤网2上均匀的喷洒重金属废水,提高初过滤效率;进一步,在第一滤网2和加水横管36之间水平设置加料管4,加料管4的两端封口且与箱体1内壁连接,加料管4的一端与设于箱体1侧壁上的进料口连通,通过进料口向加料管4内加入处理试剂,具体的还可以通过一个进料管将加料管4的一端与外部连通,进料管的一端与加料管4的一端连通,另一端穿过箱体1侧壁延伸至箱体1外,通过向进料管内注入处理试剂,进而向加料管4内加入处理试剂;加料管4的顶部延期长度方向设置多个弹性压块41,每个压块沿竖直方向密封滑动设于加料管4的顶部,即压块的上端位于加料管4的上方,下部穿过加料管4竖直延伸至加料管4的内部,压块与加料管4侧壁接触部位始终为密封,避免漏液;压块通过竖直伸缩的弹性件与加料管4的内壁连接,压块的个数与加水横管36底部的凸块362个数一致,对应的压块和凸块362与箱体1的轴线间距相等(使得当加水横管36绕箱体1轴线转动至加水横管36的轴线与加料管4轴线位于同一竖直面时,对应的凸块362位于压块正上方,进而使得凸块362可向下挤压推动压块,本发明作为优选的,可将凸块362的底部设置为圆滑的曲面,将压块的顶部设置为顶部朝上的圆锥结构,减少转动过程中凸块362经由压块对压块向下推动的阻力,保证凸块362随加水横管36转动可对压块产生向下的挤压推力,进而打开加料管4底部的加料口42,实现边加废水边加处理试剂),加料管4的底部延期长度方向设有一排加料口42,每个弹性压块41的正下方对应设置一个加料口42,加料口42内对应设置一个封堵塞43,其为尖部朝上的圆锥结构,每个封堵塞43与对应的弹性压块41连接,使得弹性压块41的上下移动可带动封堵塞43的上下移动,进而可打开加料口42,并可根据调节加料口42的打开大小,进而实现加入重金属废水的同时加入处理试剂,大大提高了重金属废水与处理试剂混合的均匀性,避免局部加入处理试剂导致局部试剂浓度过高,进而造成局部高反应,而其他部位又因试剂量不够反应率低下,导致有机物降解率较低;The present invention provides a heavy metal wastewater treatment device, which includes a box body 1 with a hollow cylindrical structure, a drain port is provided at the bottom, and a second filter screen is connected to the drain port to separate solids generated during the reagent treatment process. The water treated with the reagent can be discharged through the drain port and transported to the next process equipment (such as biochemical reaction equipment, sedimentation tank, etc.). The heavy metal wastewater to be treated is injected into the box body 1 through a water adding mechanism, and a treatment reagent is added into the box body 1 through a feeding pipe 4 (the treatment reagent used in the present invention is a liquid reagent, and if it is a solid treatment agent, it can also be added to the solid treatment agent). The first filter screen 2 is configured to mix the liquid and add it into the box body 1 through the feeding pipe 4), and a first filter screen 2 is arranged inside the box body 1 to perform preliminary filtration on the heavy metal wastewater, and remove the fixed impurities in the heavy metal wastewater before the wastewater is mixed with the treatment reagent, so as to avoid the solid impurities affecting the reaction between the reagent and the organic matter in the heavy metal wastewater; the first filter screen 2 divides the interior of the box body 1 into a first space and a second space (as a preferred embodiment, the first filter screen 2 can be arranged as an upwardly convex curved surface, which can not only improve the impact resistance of the heavy metal wastewater, but also use the water flow to flush the impurities along the curved surface, so that the impurities can fall into the box body 1 autonomously). The water adding mechanism includes a first vertical pipe 31 and a second vertical pipe 32 which are connected and communicated by a bearing ring. The upper end of the first vertical pipe 31 extends vertically upward through the box body 1 and is connected with a water adding funnel 33. The first vertical pipe 31 is connected to the top of the box body 1 through a support member to limit the circumferential rotation of the first vertical pipe 31. A water wheel 34 is provided in the second vertical pipe 32. When water flows through the second vertical pipe 32, the water wheel 34 rotates to drive the second vertical pipe 32 to rotate around its own axis. Under the limiting effect, the first vertical pipe 31 does not rotate, and a horizontally arranged water-adding transverse pipe 36 is connected at the bottom of the second vertical pipe 32, the two ends of which are closed and a plurality of water-adding nozzles 361 are arranged at the bottom. The water-adding transverse pipe 36 and the water-adding nozzles 361 rotate under the rotation of the second vertical pipe 32 to realize uniform spraying of heavy metal wastewater onto the first filter screen 2, thereby improving the primary filtration efficiency; further, a feeding pipe 4 is horizontally arranged between the first filter screen 2 and the water-adding transverse pipe 36, the two ends of the feeding pipe 4 are sealed and connected to the inner wall of the box body 1, and one end of the feeding pipe 4 is connected to the feeding port arranged on the side wall of the box body 1. The treatment reagent is added into the feeding pipe 4 through the feeding port. Specifically, one end of the feeding pipe 4 can be connected to the outside through a feeding pipe. One end of the feeding pipe is connected to one end of the feeding pipe 4, and the other end extends to the outside of the box body 1 through the side wall of the box body 1. The treatment reagent is injected into the feeding pipe, and then added to the feeding pipe 4; a plurality of elastic pressing blocks 41 are arranged on the top of the feeding pipe 4 in an extended length direction, and each pressing block is sealed and slidably arranged on the top of the feeding pipe 4 in a vertical direction, that is, the upper end of the pressing block is located above the feeding pipe 4, and the lower part passes through the feeding pipe 4 and extends vertically to the feeding pipe 4. The contact part between the pressing block and the side wall of the feeding tube 4 is always sealed to prevent leakage; the pressing block is connected to the inner wall of the feeding tube 4 through a vertically retractable elastic member, and the number of the pressing blocks is consistent with the number of the protrusions 362 at the bottom of the water-adding transverse tube 36, and the corresponding pressing blocks and protrusions 362 are at the same distance from the axis of the box body 1 (so that when the water-adding transverse tube 36 rotates around the axis of the box body 1 until the axis of the water-adding transverse tube 36 and the axis of the feeding tube 4 are in the same vertical plane, the corresponding protrusion 362 is located directly above the pressing block, so that the protrusion 362 can squeeze and push the pressing block downward. As a preferred embodiment of the present invention, the protrusion 362 can be The bottom of the block 362 is set as a smooth curved surface, and the top of the pressing block is set as a conical structure with the top facing upward, so as to reduce the resistance of the protrusion 362 to the pressing block pushing downward through the pressing block during the rotation process, and ensure that the protrusion 362 can produce a downward extrusion thrust on the pressing block as the water adding cross pipe 36 rotates, thereby opening the feeding port 42 at the bottom of the feeding pipe 4, and adding wastewater and treatment reagents at the same time). A row of feeding ports 42 are provided in the extended length direction of the bottom of the feeding pipe 4, and a feeding port 42 is correspondingly provided directly below each elastic pressing block 41, and a sealing plug 43 is correspondingly provided in the feeding port 42, which It is a conical structure with the tip facing upward. Each sealing plug 43 is connected to the corresponding elastic pressing block 41, so that the up and down movement of the elastic pressing block 41 can drive the up and down movement of the sealing plug 43, thereby opening the feeding port 42, and the opening size of the feeding port 42 can be adjusted to achieve the addition of treatment reagents while adding heavy metal wastewater, greatly improving the uniformity of mixing heavy metal wastewater and treatment reagents, avoiding local addition of treatment reagents resulting in excessive concentration of local reagents, thereby causing local high reaction, while other parts have low reaction rates due to insufficient reagents, resulting in low organic matter degradation rate;
具体的:本发明提供的重金属废水处理装置在向箱体1内加入重金属废水之前,加水横管36与加料管4位于不同竖直面,任意凸块362与对应的压块互不接触,弹性压块41处于自然状态下,封堵块将对应的加料口42封堵;Specifically: before adding heavy metal wastewater into the box 1, the water adding horizontal pipe 36 and the feeding pipe 4 are located on different vertical planes, any protrusion 362 and the corresponding pressing block do not contact each other, the elastic pressing block 41 is in a natural state, and the blocking block blocks the corresponding feeding port 42;
将待处理的重金属废水通过加水漏斗33进入第一竖管31,随后进入第二竖管32、加水横管36,进而通过多个加水口向下流动至第一滤网2上,在水流经过第二竖管32时,水流可带动水轮34转动,进而带动第二竖管32、加水横管36绕箱体1轴线的转动,可实现旋转加水,使得重金属废水可均匀地喷洒在第一滤网2上,提高初步过滤效率,也避免杂质堆积在同一个位置导致滤网网孔堵塞;进一步的在第一滤网2和加水横管36之间水平设置加料管4,重金属废水加入过程中,加水横管36相对加料管4绕箱体1轴线圆周转动,加水横管36转动至与加料管4位于同一平面时,凸块362会对对应的弹性压块41产生向下的挤压力,弹性压块41向下移动带动对应的封堵塞43向下移动,进而将加料口42打开,加料管4内的处理试剂通过打开的加料口42向下流出经与重金属废水混合;加水横管36继续转动,凸块362转动至与对应压块互不干涉的位置时,弹性压块41在弹力作用下向上移动复位,带动封堵塞43复位,加水横管36每转动一圈,多个加料口42被打开一次;一个处理周期中,重金属废水的加水量控制在,箱体1内重金属废水的液面不高于第一滤网2,停止加水后,反应一段时间,打开排液口将箱体1内的水排出,并输送至下一个处理工段。The heavy metal wastewater to be treated enters the first vertical pipe 31 through the water adding funnel 33, and then enters the second vertical pipe 32 and the water adding transverse pipe 36, and then flows downward to the first filter screen 2 through multiple water adding ports. When the water flows through the second vertical pipe 32, the water flow can drive the water wheel 34 to rotate, and then drive the second vertical pipe 32 and the water adding transverse pipe 36 to rotate around the axis of the box body 1, so as to realize rotary water adding, so that the heavy metal wastewater can be evenly sprayed on the first filter screen 2, thereby improving the initial filtration efficiency and avoiding the accumulation of impurities in the same position to cause the filter mesh to be blocked; further, a feeding pipe 4 is horizontally arranged between the first filter screen 2 and the water adding transverse pipe 36. During the addition of heavy metal wastewater, the water adding transverse pipe 36 rotates in a circle around the axis of the box body 1 relative to the feeding pipe 4. When the water adding transverse pipe 36 rotates to be on the same plane as the feeding pipe 4, the convex The block 362 will generate a downward squeezing force on the corresponding elastic pressure block 41. The downward movement of the elastic pressure block 41 drives the corresponding sealing plug 43 to move downward, thereby opening the feeding port 42, and the treatment reagent in the feeding pipe 4 flows downward through the opened feeding port 42 to mix with the heavy metal wastewater; the water adding transverse pipe 36 continues to rotate, and when the protrusion 362 rotates to a position where it does not interfere with the corresponding pressure block, the elastic pressure block 41 moves upward and resets under the action of the elastic force, driving the sealing plug 43 to reset. For each rotation of the water adding transverse pipe 36, multiple feeding ports 42 are opened once; in one treatment cycle, the amount of water added to the heavy metal wastewater is controlled so that the liquid level of the heavy metal wastewater in the box 1 is not higher than the first filter screen 2. After stopping the water addition, react for a period of time, open the drain port to discharge the water in the box 1, and transport it to the next treatment section.
本发明提供的重金属废水处理装置,可实现边加废水边加处理试剂,且废水和处理试剂均为均匀喷洒,提高了废水与处理试剂混合均匀性,提高废水中有机物的降解率,进而达到提高废水处理效率。The heavy metal wastewater treatment device provided by the present invention can realize adding wastewater and treatment reagent at the same time, and both the wastewater and the treatment reagent are sprayed evenly, thereby improving the mixing uniformity of the wastewater and the treatment reagent, improving the degradation rate of organic matter in the wastewater, and thus achieving improved wastewater treatment efficiency.
另一种技术方案中,所述的重金属废水处理装置,还包括设于所述第二空间内的搅拌机构,其包括:In another technical solution, the heavy metal wastewater treatment device further includes a stirring mechanism disposed in the second space, which includes:
套筒51,其同轴设于所述第二空间内,所述套筒51的两端分别与所述第一滤网2的底部、所述箱体1的底面转动连接;A sleeve 51 is coaxially disposed in the second space, and two ends of the sleeve 51 are rotatably connected to the bottom of the first filter screen 2 and the bottom surface of the box body 1 respectively;
多对搅拌组件,其沿竖直方向间隔设于所述套筒51的圆周侧壁上,每对搅拌组件沿所述箱体1的轴线对称设于所述套筒51的两侧,每个搅拌组件包括沿所述套筒51径向设置的搅拌杆52以及多个设于搅拌杆52上的搅拌叶片521,每个搅拌杆52的一端与所述套筒51的圆周侧壁转动连接。A plurality of pairs of stirring assemblies are arranged at intervals along the vertical direction on the circumferential side wall of the sleeve 51, and each pair of stirring assemblies are symmetrically arranged on both sides of the sleeve 51 along the axis of the housing 1. Each stirring assembly includes a stirring rod 52 arranged radially along the sleeve 51 and a plurality of stirring blades 521 arranged on the stirring rod 52. One end of each stirring rod 52 is rotatably connected to the circumferential side wall of the sleeve 51.
本发明进一步在第二空间设置搅拌机构,可对重金属废水与处理试剂的混合物进行多维度的大幅度搅拌,提高反应效率,进而提高重金属废水中有机物的降解率,从而达到提高处理效率的目的。The present invention further arranges a stirring mechanism in the second space, which can stir the mixture of heavy metal wastewater and treatment reagent in multiple dimensions and in large scale, thereby improving the reaction efficiency and further improving the degradation rate of organic matter in the heavy metal wastewater, thereby achieving the purpose of improving the treatment efficiency.
具体的搅拌机构包括同轴转动设于第二空间内的套筒51,其上端与第一滤网2的底部转动连接,下端与箱体1的底面转动连接,套筒51可绕自身轴线转动,套筒51的两端为封闭设置,在套筒51上沿竖直方向间隔设置多对搅拌组件,每对搅拌组件沿箱体1的轴线对称设于套筒51的两侧,每个搅拌组件包括一端与套筒51侧壁转动连接、另一端沿套筒51的径向水平延伸的搅拌杆52以及间隔设于搅拌杆52上的多个搅拌叶片521,任意竖向相邻的两个搅拌组件的搅拌叶片521互不干涉,每个搅拌杆52可相对套筒51绕自身轴线转动,即每个搅拌组件可随套筒51绕箱体1轴线转动,与此同时搅拌组件又可绕自身的搅拌杆52的轴线转动,实现了多维搅拌,使得处理试剂能够与重金属废水中的有机物充分接触,进一步提高处理效率。The specific stirring mechanism includes a sleeve 51 that is coaxially rotatably arranged in the second space, the upper end of which is rotatably connected to the bottom of the first filter 2, and the lower end is rotatably connected to the bottom surface of the box body 1. The sleeve 51 can rotate around its own axis. The two ends of the sleeve 51 are closed. A plurality of pairs of stirring components are arranged on the sleeve 51 at intervals along the vertical direction. Each pair of stirring components is symmetrically arranged on both sides of the sleeve 51 along the axis of the box body 1. Each stirring component includes a stirring rod 52, one end of which is rotatably connected to the side wall of the sleeve 51 and the other end of which extends horizontally along the radial direction of the sleeve 51, and a plurality of stirring blades 521 are arranged on the stirring rod 52 at intervals. The stirring blades 521 of any two vertically adjacent stirring components do not interfere with each other. Each stirring rod 52 can rotate around its own axis relative to the sleeve 51, that is, each stirring component can rotate around the axis of the box body 1 with the sleeve 51. At the same time, the stirring component can rotate around the axis of its own stirring rod 52, thereby realizing multi-dimensional stirring, so that the treatment reagent can fully contact with the organic matter in the heavy metal wastewater, thereby further improving the treatment efficiency.
另一种技术方案中,所述的重金属废水处理装置,所述搅拌机构还包括:In another technical solution, the heavy metal wastewater treatment device, the stirring mechanism further comprises:
固定杆53,其同轴设于所述套筒51内,且底部与所述箱体1的底面固接;位于最上部的一对搅拌组件对应的搅拌杆52的一端穿过套筒51的圆周侧壁,并延伸至所述套筒51与所述固定杆53形成的环形空间内;A fixed rod 53 is coaxially disposed in the sleeve 51, and the bottom is fixedly connected to the bottom surface of the box body 1; one end of the stirring rod 52 corresponding to the pair of stirring assemblies at the top passes through the circumferential side wall of the sleeve 51 and extends into the annular space formed by the sleeve 51 and the fixed rod 53;
第一伞齿轮54,其同轴固定套设于所述固定杆53上;A first bevel gear 54, which is coaxially fixedly sleeved on the fixing rod 53;
两个第二伞齿轮55,其分别同轴固定套设于最上部的一对搅拌杆52的一端上,每个第二伞齿轮55与所述第一伞齿轮54啮合;Two second bevel gears 55 are coaxially fixedly sleeved on one end of the pair of stirring rods 52 at the top, and each second bevel gear 55 is meshed with the first bevel gear 54;
多个齿轮盘56,每个搅拌杆52的另一端上同轴固定套设有一个齿轮盘56,上下相邻的两个齿轮盘56相互啮合。A plurality of gear plates 56 are provided. A gear plate 56 is coaxially fixedly sleeved on the other end of each stirring rod 52. Two gear plates 56 adjacent to each other are meshed with each other.
上述技术方案中,本发明通过设置齿轮组件将套筒51的转动与多个搅拌杆52的转动进行联动,使得套筒51的转动可同步带动多个搅拌杆52的转动,减少驱动源的设置,达到节省能源的效果;具体的在套筒51的内部同轴固定设置一个固定杆53,固定杆53的两端与第一滤网2和箱体1底面固定连接,固定杆53上同轴固定套设一个第一伞齿轮54,固定杆53与套筒51之间形成环形空间,将最上部的一对搅拌杆52的一端水平向内延伸至环形空间内,并在这一对搅拌杆52的一端上固定套设一个第二伞齿轮55,每个第二伞齿轮55与第一伞齿轮54啮合,每个搅拌杆52的另一端上均固定套设一个齿轮盘56,任意竖直方向相邻的两个齿轮盘56啮合,将所有的搅拌杆52通过齿轮盘56实现传动;套筒51绕自身轴线转动过程中,带动搅拌杆52绕箱体1轴线的转动,位于最上部的搅拌杆52,在第一伞齿轮54和第二伞齿轮55的啮合作用下,又可同步绕自身轴线转动,位于最上部的搅拌杆52绕自身轴线转动,通过齿轮盘56的传动,可带动位于其下方的多个搅拌杆52绕自身转动,且任意相邻的两个搅拌杆52的转动方向相反,可对箱体1内的液体进行大幅度、无死角的搅动,制造湍流,进一步提高处理效率。In the above technical scheme, the present invention links the rotation of the sleeve 51 with the rotation of the multiple stirring rods 52 by setting a gear assembly, so that the rotation of the sleeve 51 can synchronously drive the rotation of the multiple stirring rods 52, reduce the setting of the driving source, and achieve the effect of saving energy; specifically, a fixed rod 53 is coaxially fixedly arranged inside the sleeve 51, and the two ends of the fixed rod 53 are fixedly connected to the first filter screen 2 and the bottom surface of the box body 1, and a first bevel gear 54 is coaxially fixedly sleeved on the fixed rod 53, and an annular space is formed between the fixed rod 53 and the sleeve 51, and one end of the uppermost pair of stirring rods 52 is horizontally extended inward into the annular space, and a second bevel gear 55 is fixedly sleeved on one end of the pair of stirring rods 52, and each second bevel gear 55 is meshed with the first bevel gear 54. A gear plate 56 is fixedly mounted on the other end of each stirring rod 52. Any two adjacent gear plates 56 in the vertical direction are meshed, so that all the stirring rods 52 are transmitted through the gear plate 56. During the rotation of the sleeve 51 around its own axis, the stirring rod 52 is driven to rotate around the axis of the box body 1. The stirring rod 52 located at the top can synchronously rotate around its own axis under the meshing action of the first bevel gear 54 and the second bevel gear 55. The stirring rod 52 located at the top rotates around its own axis, and through the transmission of the gear plate 56, it can drive multiple stirring rods 52 located below it to rotate around themselves, and the rotation directions of any two adjacent stirring rods 52 are opposite, so that the liquid in the box body 1 can be stirred significantly and without dead angles, creating turbulence, thereby further improving the processing efficiency.
另一种技术方案中,所述的重金属废水处理装置,所述固定杆53的圆周侧面上设有螺纹段;In another technical solution, in the heavy metal wastewater treatment device, a threaded section is provided on the circumferential side surface of the fixing rod 53;
所述重金属废水处理装置还包括设于所述套筒51与所述固定杆53形成的环形空间内加热机构,其包括:The heavy metal wastewater treatment device further includes a heating mechanism disposed in the annular space formed by the sleeve 51 and the fixing rod 53, which includes:
转动套61,其转动套61设于固定杆53上,位于最上部的两个搅拌杆52的一端与转动套61转动连接;The rotating sleeve 61 is disposed on the fixed rod 53, and one end of the two stirring rods 52 at the top is rotatably connected to the rotating sleeve 61;
螺纹套62,其螺纹转动设于所述固定杆53的螺纹段上,螺纹套62通过竖直设置的伸缩杆63与转动套61连接;A threaded sleeve 62, whose thread is rotatably arranged on the threaded section of the fixed rod 53, and the threaded sleeve 62 is connected to the rotating sleeve 61 through a vertically arranged telescopic rod 63;
电加热块64,其固设于所述螺纹套62上。The electric heating block 64 is fixed on the threaded sleeve 62 .
处理试剂在处理重金属废水过程中,适当的加热可加快反应速率,例如Fenton试剂在处理废水过程中,优选的温度是60℃,不能太高也不能太低,现有的加热管多为固定式的,对局部位置进行加热,会导致局部温度过高,影响降解效率;为了解决上述技术问题,在上述技术方案中,本发明进一步设置了加热机构,其可对箱体1的液体进行适当加热,具体的在固定杆53从上到下分别设置有转动套61和螺纹段,转动套61通过轴承件与固定杆53转动连接,在螺纹段上螺纹转动套61设螺纹套62,螺纹套62通过伸缩杆63与转动套61连接,螺纹套62上设有电加热块64,多个搅拌杆52在绕箱体1轴线转动的过程中,会带动转动套61绕固定杆53轴线转动,进而带动螺纹套62绕固定杆53轴线转动,因螺纹套62与螺纹段螺纹转动连接,螺纹套62在绕固定杆53轴线转动的同时会沿竖直方向移动,从而带动电加热块64上下移动,进而可以对箱体1内的液体进行均匀加热。优选的是,套筒51选用导热材质制作而成。In the process of treating heavy metal wastewater, proper heating of the treatment reagent can accelerate the reaction rate. For example, in the process of treating wastewater, the preferred temperature of Fenton reagent is 60°C, which cannot be too high or too low. The existing heating tubes are mostly fixed, and heating at a local position will cause the local temperature to be too high, affecting the degradation efficiency. In order to solve the above technical problems, in the above technical scheme, the present invention further provides a heating mechanism, which can properly heat the liquid in the box 1. Specifically, a rotating sleeve 61 and a threaded section are respectively provided on the fixed rod 53 from top to bottom, and the rotating sleeve 61 is connected to the fixed rod through a bearing member. 53 is rotatably connected, a threaded rotating sleeve 61 is provided with a threaded sleeve 62 on the threaded section, the threaded sleeve 62 is connected to the rotating sleeve 61 through a telescopic rod 63, and an electric heating block 64 is provided on the threaded sleeve 62. When the multiple stirring rods 52 rotate around the axis of the box body 1, the rotating sleeve 61 will be driven to rotate around the axis of the fixed rod 53, thereby driving the threaded sleeve 62 to rotate around the axis of the fixed rod 53. Since the threaded sleeve 62 is rotatably connected with the threaded section, the threaded sleeve 62 will move in the vertical direction while rotating around the axis of the fixed rod 53, thereby driving the electric heating block 64 to move up and down, thereby evenly heating the liquid in the box body 1. Preferably, the sleeve 51 is made of a heat-conducting material.
另一种技术方案中,所述的重金属废水处理装置,所述套筒51的下端竖直向下延伸至所述箱体1的下方,所述套筒51与所述箱体1的底面通过密封轴承转动连接;In another technical solution, in the heavy metal wastewater treatment device, the lower end of the sleeve 51 extends vertically downward to the bottom of the box body 1, and the sleeve 51 is rotatably connected to the bottom surface of the box body 1 through a sealed bearing;
所述搅拌机构还包括电机71,其设于所述箱体1的侧壁上,所述电机71的输出轴竖直向下延伸并通过传动皮带72与所述套筒51的下端传动连接。电机71优选为可循环正反转的伺服电机71。The stirring mechanism further comprises a motor 71, which is arranged on the side wall of the box body 1, and the output shaft of the motor 71 extends vertically downward and is connected to the lower end of the sleeve 51 through a transmission belt 72. The motor 71 is preferably a servo motor 71 that can cycle forward and reverse.
在上述技术方案中,设置在箱体1侧壁上的电机71作为动力源,并通过皮带72将点击输出轴与套筒51的下端传动连接,带动套筒51在箱体1内的转动。In the above technical solution, the motor 71 arranged on the side wall of the box body 1 is used as a power source, and the click output shaft is connected to the lower end of the sleeve 51 through the belt 72, driving the sleeve 51 to rotate in the box body 1.
另一种技术方案中,所述的重金属废水处理装置,所述支撑件包括:In another technical solution, the heavy metal wastewater treatment device, the support member comprises:
支撑板351,其水平设于所述箱体1的上方,所述支撑板351的中部设于供所述第二竖管32穿过的通孔,所述通孔内壁通过轴承环与所述第二竖管32的侧壁转动连接;A support plate 351 is horizontally disposed above the box body 1, and a middle portion of the support plate 351 is disposed at a through hole for the second vertical pipe 32 to pass through, and an inner wall of the through hole is rotatably connected to a side wall of the second vertical pipe 32 via a bearing ring;
支撑杆352,其一端与所述支撑板351的顶部固接,另一端与所述第一竖管31的侧壁固接。The support rod 352 has one end fixedly connected to the top of the support plate 351 , and the other end fixedly connected to the side wall of the first vertical pipe 31 .
设置有支撑板351和支撑杆352组成的支撑件,将第一竖管31与箱体1顶部进行稳固支撑安装,作为优选的,支撑杆352可沿圆周方向设置多个,提高对第一竖管31、加水漏斗33支撑的稳固性。A support member consisting of a support plate 351 and a support rod 352 is provided to stably support and install the first vertical pipe 31 and the top of the box body 1. Preferably, a plurality of support rods 352 can be provided along the circumferential direction to improve the stability of the support for the first vertical pipe 31 and the water adding funnel 33.
另一种技术方案中,所述的重金属废水处理装置,所述支撑件还包括竖向伸缩的升降机构353,其设于所述支撑板351与所述箱体1顶面之间;所述升降机构353包括一对沿箱体1的轴线对称设置的液压气缸,每个液压气缸的本体固设于所述箱体1的顶面上,活塞杆竖直向上延伸并与所述支撑板351的底面连接。In another technical solution, in the heavy metal wastewater treatment device, the support member also includes a vertically telescopic lifting mechanism 353, which is arranged between the support plate 351 and the top surface of the box body 1; the lifting mechanism 353 includes a pair of hydraulic cylinders symmetrically arranged along the axis of the box body 1, and the body of each hydraulic cylinder is fixed on the top surface of the box body 1, and the piston rod extends vertically upward and is connected to the bottom surface of the support plate 351.
在支撑件的顶部设置升降机构353,可调节加水机构的高度,进而调节加水横管36与加料管4的间距,可在不需要向箱体1加入处理试剂(处理试剂加入量足够时、或在重金属废水加入完成后,恰好加水横管36临近与加料管4位于同一平面的位置时)通过升降机构353将加水机构向上顶升,带动加水横管36向上移动至与加料管4互不干涉,加水横管36继续转动,或加水完成后保持在与加料管4位于同一平面的状态,不会对弹性压块41产生向下挤压力,不会打开加料口42继续不需要的加料作业。A lifting mechanism 353 is set on the top of the support member, which can adjust the height of the water adding mechanism, and then adjust the distance between the water adding transverse pipe 36 and the feeding pipe 4. When there is no need to add treatment reagent to the box body 1 (when the amount of treatment reagent added is sufficient, or after the heavy metal wastewater is added, the water adding transverse pipe 36 is close to the position on the same plane as the feeding pipe 4), the water adding mechanism can be lifted up by the lifting mechanism 353, and the water adding transverse pipe 36 can be driven to move upward to a position where it does not interfere with the feeding pipe 4. The water adding transverse pipe 36 continues to rotate, or remains in the state of being on the same plane as the feeding pipe 4 after water adding is completed, and will not generate downward squeezing force on the elastic pressure block 41, and will not open the feeding port 42 to continue unnecessary feeding operations.
设置升降机构353还可调节变加水边加处理试剂的量,加水横管36与加料管4距离越近,凸块362对弹性压块41向下挤压的行程越大,加料口42打开的越大,加水横管36每转动一圈加入的处理试剂越多,例如重金属废水中有机物浓度较大时,就可以通过升降机构353将加水横管36向下移动至与加料管4较近的位置,反之,如果重金属废水中有机物浓度较小,可通过升降机构353将加水横管36向上顶升至,加水横管36与加料管4较远的位置,增大加水横管36与加料管4的间距,此时每转动一圈,凸块362作用于压块带动压块向下移动的行程较小,加料口42打开的较小,加入的处理试剂也就较少。The lifting mechanism 353 can also be set to adjust the amount of treatment reagent added while adding water. The closer the water-adding transverse pipe 36 is to the feeding pipe 4, the greater the stroke of the protrusion 362 pressing the elastic pressure block 41 downward, the larger the feeding port 42 is opened, and the more treatment reagent is added for each rotation of the water-adding transverse pipe 36. For example, when the concentration of organic matter in the heavy metal wastewater is relatively high, the water-adding transverse pipe 36 can be moved downward to a position closer to the feeding pipe 4 by the lifting mechanism 353. Conversely, if the concentration of organic matter in the heavy metal wastewater is relatively low, the water-adding transverse pipe 36 can be lifted upward to a position farther away from the feeding pipe 4 by the lifting mechanism 353, thereby increasing the distance between the water-adding transverse pipe 36 and the feeding pipe 4. At this time, for each rotation, the protrusion 362 acts on the pressure block to drive the pressure block to move downward. The feeding port 42 is opened less, and less treatment reagent is added.
这里说明的设备数量和处理规模是用来简化本发明的说明的。对本发明的应用、修改和变化对本领域的技术人员来说是显而易见的。The number of devices and processing scales described here are used to simplify the description of the present invention. Applications, modifications and variations of the present invention will be obvious to those skilled in the art.
尽管本发明的实施方案已公开如上,但其并不仅仅限于说明书和实施方式中所列运用,它完全可以被适用于各种适合本发明的领域,对于熟悉本领域的人员而言,可容易地实现另外的修改,因此在不背离权利要求及等同范围所限定的一般概念下,本发明并不限于特定的细节和这里示出与描述的图例。Although the embodiments of the present invention have been disclosed as above, they are not limited to the applications listed in the specification and the implementation modes, and they can be fully applied to various fields suitable for the present invention. For those familiar with the art, additional modifications can be easily implemented. Therefore, without departing from the general concept defined by the claims and the scope of equivalents, the present invention is not limited to the specific details and the illustrations shown and described herein.
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| CN212152024U (en) * | 2020-01-14 | 2020-12-15 | 陶青菁 | Urban sewer sludge purification device of environmental protection |
| CN216499351U (en) * | 2021-12-21 | 2022-05-13 | 宇山新环保科技(大连)有限公司 | Reaction kettle for preparing battery-grade nickel nitrate |
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Application publication date: 20241108 |