CN110403853A - A kind of novel polymeric silicone oil emulsion and preparation method - Google Patents
A kind of novel polymeric silicone oil emulsion and preparation method Download PDFInfo
- Publication number
- CN110403853A CN110403853A CN201910839624.5A CN201910839624A CN110403853A CN 110403853 A CN110403853 A CN 110403853A CN 201910839624 A CN201910839624 A CN 201910839624A CN 110403853 A CN110403853 A CN 110403853A
- Authority
- CN
- China
- Prior art keywords
- silicone oil
- oil emulsion
- novel polymeric
- polymeric silicone
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000839 emulsion Substances 0.000 title claims abstract description 54
- 229920002545 silicone oil Polymers 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 238000004945 emulsification Methods 0.000 title abstract description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000003054 catalyst Substances 0.000 claims abstract description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000003921 oil Substances 0.000 claims abstract description 18
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 17
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims abstract description 16
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 15
- XQSFXFQDJCDXDT-UHFFFAOYSA-N hydroxysilicon Chemical compound [Si]O XQSFXFQDJCDXDT-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003755 preservative agent Substances 0.000 claims abstract description 15
- 230000002335 preservative effect Effects 0.000 claims abstract description 15
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims description 57
- 239000000243 solution Substances 0.000 claims description 22
- 239000002245 particle Substances 0.000 claims description 16
- 238000010438 heat treatment Methods 0.000 claims description 15
- 230000005484 gravity Effects 0.000 claims description 14
- 239000011259 mixed solution Substances 0.000 claims description 14
- 238000005070 sampling Methods 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 8
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 claims description 7
- 238000001514 detection method Methods 0.000 claims description 7
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 claims description 7
- 238000012545 processing Methods 0.000 claims description 7
- 230000004044 response Effects 0.000 claims description 7
- 230000002459 sustained effect Effects 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- 210000004209 hair Anatomy 0.000 abstract description 21
- 239000002453 shampoo Substances 0.000 abstract description 15
- 238000005406 washing Methods 0.000 abstract description 4
- 230000007774 longterm Effects 0.000 abstract description 2
- 230000002209 hydrophobic effect Effects 0.000 abstract 1
- 239000012528 membrane Substances 0.000 abstract 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000003599 detergent Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 229920001296 polysiloxane Polymers 0.000 description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 210000004761 scalp Anatomy 0.000 description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 description 4
- 235000011152 sodium sulphate Nutrition 0.000 description 4
- -1 amido silicon Chemical compound 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 244000060011 Cocos nucifera Species 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 2
- 229920002907 Guar gum Polymers 0.000 description 2
- 229920000289 Polyquaternium Polymers 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005485 electric heating Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229940100608 glycol distearate Drugs 0.000 description 2
- 239000000665 guar gum Substances 0.000 description 2
- 229960002154 guar gum Drugs 0.000 description 2
- 235000010417 guar gum Nutrition 0.000 description 2
- 210000003780 hair follicle Anatomy 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 description 2
- 230000000474 nursing effect Effects 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 201000004384 Alopecia Diseases 0.000 description 1
- 241000406668 Loxodonta cyclotis Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 231100000360 alopecia Toxicity 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/892—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a hydroxy group, e.g. dimethiconol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q7/00—Preparations for affecting hair growth
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
- Silicon Polymers (AREA)
Abstract
The invention belongs to washing product field more particularly to a kind of novel polymeric silicone oil emulsion and preparation methods.Contain by weight percentage in the novel polymeric silicone oil emulsion and preparation method: hydroxy silicon oil: 50%-60%, the basic sulfonic acid of dodecane: 1%-5%, fatty alcohol ether: 1%-5%, catalyst: 0.1%-0.5%, triethanolamine: 1%-5%, preservative: 0.1%-0.3% and water: 30%-50%, the present invention is since silicone oil is more evenly distributed, in addition partial size is smaller, so after shampoo is added, the hydrophobic membrane formed on hair is thinner, softer, long-term to have one's hair wash, hair is not easy thicker, it is hardened, should be widely promoted use.
Description
Technical field
The invention belongs to washing product field more particularly to a kind of novel polymeric silicone oil emulsion and preparation methods.
Background technique
With the development of science and technology, social progress, the continuous improvement of people's quality of life, people more focus on itself instrument
With appearance image, the especially requirement to hair and hair style is more focused on, not only needs to clean up in hair, Er Qiexu
One long-term nursing is carried out to hair.
The most commonly used shampoo of people also known as shampoo, shampoo, shampoo or hair cream at present are to apply at present
Most commonly used hair shampoo article and most common wash protect one of cosmetics；For cleaning the people being attached on scalp and hair
The grease of body secretion, sweat mixed with dirt, the cell and external dust to fall off on scalp, microorganism, the residue of approved product and not
Good smell etc. makes hair keep scalp and hair cleaning and hair beautiful after cleaning.But the common shampoo one of the prior art
As be to be added to common silicone oil emulsion, after long-time service, user's hair be easy it is thicker, be hardened, and become extremely not soft
It is suitable, especially there is serious accumulation to feel.
After the present invention passes through a large number of experiments, using the Multiple components not used in the prior art, to overcome the prior art
Silicone oil emulsion there are the problem of, reach the purpose of the present invention.In the prior art application No. is 201811363578.8, denomination of invention
For a kind of compound silicone oil emulsion and preparation method thereof；Application No. is 201810281484.X, a kind of entitled amido silicon oil
Lotion and preparation method thereof, the patent of invention of the two above prior art and formula of the invention and manufacturing process difference are huge
Greatly, and the present invention compared with the existing technology in other silicone oil emulsions formula and manufacturing process difference it is huge.
Therefore, for many disadvantages existing for existing hair cream, research and develop it is a kind of, multi-functional, hair nursing is imitated
The problem of good silicone oil emulsion of fruit is those skilled in the art's urgent need to resolve.
Summary of the invention
(1) technical problems to be solved
The present invention is larger with energy consumption in order to overcome existing novel polymeric silicone oil emulsion longer for the production time, and silicon crude oil is same
Emulsifier ratio needs the amount of emulsifier relatively more, and general bulk emulsification silicone oil emulsion content is lower, can not accomplish high-content
Stable silicone oil emulsion, bulk emulsification silicone oil emulsion appearance stability is very poor, serious layering occurs now after placing a period of time
As the product of bulk emulsification is if it is intended to accomplish that partial size is that nanoscale degree just needs a large amount of emulsifiers, and content is accomplished
Lower disadvantage, and the common shampoo of the prior art is usually to be added to common silicone oil emulsion, after long-time service, is used
Person's hair be easy it is thicker, be hardened, and become extremely not submissive, especially there is serious accumulation to feel, the invention solves technology
Problem is to provide a kind of novel polymeric silicone oil emulsion and preparation method.
(2) technical solution
It is described novel poly- in order to solve the above-mentioned technical problems, the present invention provides such a novel polymeric silicone oil emulsion
Silicone oil emulsion is closed to contain by weight percentage:
Hydroxy silicon oil: 50%-60%；
The basic sulfonic acid of dodecane: 1%-5%；
Fatty alcohol ether: 1%-5%；
Catalyst: 0.1%-0.5%；
Triethanolamine: 1%-5%；
Preservative: 0.1%-0.3%；
Water: 30%-50%.
A kind of preparation method of novel polymeric silicone oil emulsion, the procedure of processing are as follows:
Step 1: the water of hydroxy silicon oil, fatty alcohol ether, dodecyl benzene sulfonic acid and formula ratio is put in proportion into reaction
Kettle；
Step 2: opening reaction kettle, heating stirring；
Step 3: water and catalyst being added in blender, are uniformly mixed；
Step 4: catalyst solution obtained in step 3 is drawn into gravity tank；
Step 5: the catalyst solution in step 4 in gravity tank is added drop-wise in the reaction kettle of step 2；
Step 6: mixed solution obtained in step 5 being transferred in homogenizer, homogenizer fast homogeneous is opened；
Step 7: after homogeneous index reaches requirement, the good mixed solution of homogeneous being transferred in the reaction kettle of step 2, is started
Continue to heat up, sustained response；
Step 8: after the reaction was completed, triethanolamine is added, adjusts pH value, stop reaction；
Step 9: finished product being detected, after reaching required value, preservative is added and is packed.
Preferably, the ratio 1:2 for the water that the water and step 3 that the step 1 is added are added.
Preferably, the temperature of heating stirring is 50-70 degree in step 2 reaction kettle.
Preferably, the catalyst solution of the step 5 be added dropwise into reaction kettle time be 1-2 hours.
Preferably, partial size is measured by sampling in midway when the step 7 homogenizer homogeneous, and warming temperature is arranged in 65-70 degree, holds
It is continuous that be stirred to react the time be 6 hours.
Preferably, particle size diameter size is measured by sampling by particle size analyzer in the step 7.
Preferably, the step 8 passes through thunder magnetic PH meter detection pH value.
(3) beneficial effect
Novel polymeric silicone oil emulsion of the invention plays the role of washing but also protecting not only in Two-in-one shampoo, due to grain
Diameter is smaller, applies to and washes inside shield product, reduces the poly- phenomenon of sinking resetted and managed and injures to scalp and hair follicle bring, inhibits and subtract
Few alopecia, the generation of disconnected discovery elephant, return the hair follicle environment of health, balance, and to hair bring it is soft, sliding, light, float it is new now
It for nature experience sense, is used for multiple times and is still consistent effect, achieved the effect that hair conditioning, and embodiment 4 can also be used
In shampoo, and embodiment 5 can also apply to liquid detergent, and laundry is submissive not to be hurt hands, while passing through Gong when preparing production
Adopted magnetic force constant temperature electric heating set is evenly heated reaction kettle, is examined by infrared moisture meter device to polymerization silicone oil emulsion
It surveys, precision is high, easy to use.
Detailed description of the invention
Fig. 1 is the thickness variation line chart that of the invention and conventional articles wash hair after shield number variation.
Specific embodiment
The present invention is further illustrated with reference to the accompanying drawings and examples.
Embodiment 1
A kind of novel polymeric silicone oil emulsion, the novel polymeric silicone oil emulsion contain by weight percentage:
Hydroxy silicon oil: 50%；
The basic sulfonic acid of dodecane: 1%；
Fatty alcohol ether: 1%；
Catalyst: 0.1%；
Triethanolamine: 1%；
Preservative: 0.1%；
Water: 46.8%.
A kind of preparation method of novel polymeric silicone oil emulsion, the procedure of processing are as follows:
Step 1: the water of hydroxy silicon oil, fatty alcohol ether, dodecyl benzene sulfonic acid and formula ratio is put in proportion into reaction
Kettle；
Step 2: opening reaction kettle, heating stirring；
Step 3: water and catalyst being added in blender, are uniformly mixed；
Step 4: catalyst solution obtained in step 3 is drawn into gravity tank；
Step 5: the catalyst solution in step 4 in gravity tank is added drop-wise in the reaction kettle of step 2；
Step 6: mixed solution obtained in step 5 being transferred in homogenizer, homogenizer fast homogeneous is opened；
Step 7: after homogeneous index reaches requirement, the good mixed solution of homogeneous being transferred in the reaction kettle of step 2, is started
Continue to heat up, sustained response；
Step 8: after the reaction was completed, triethanolamine is added, adjusts pH value, stop reaction；
Step 9: finished product being detected, after reaching required value, preservative is added and is packed.
The ratio 1:2 for the water that the water and step 3 that the step 1 is added are added.
The temperature of heating stirring is 50 degree in step 2 reaction kettle.
The catalyst solution of the step 5 be added dropwise into reaction kettle time be 1 hour.
Partial size is measured by sampling in midway when the step 7 homogenizer homogeneous, and warming temperature is arranged at 65 degree, is persistently stirred to react
Time is 6 hours.
Particle size diameter size is measured by sampling by particle size analyzer in the step 7.
The step 8 passes through thunder magnetic PH meter detection pH value.
Embodiment 2
A kind of novel polymeric silicone oil emulsion, the novel polymeric silicone oil emulsion contain by weight percentage:
Hydroxy silicon oil: 60%；
The basic sulfonic acid of dodecane: 2%；
Fatty alcohol ether: 2%；
Catalyst: 0.5%；
Triethanolamine: 3%；
Preservative: 0.3%；
Water: 32.2%.
A kind of preparation method of novel polymeric silicone oil emulsion, the procedure of processing are as follows:
Step 1: the water of hydroxy silicon oil, fatty alcohol ether, dodecyl benzene sulfonic acid and formula ratio is put in proportion into reaction
Kettle；
Step 2: opening reaction kettle, heating stirring；
Step 3: water and catalyst being added in blender, are uniformly mixed；
Step 4: catalyst solution obtained in step 3 is drawn into gravity tank；
Step 5: the catalyst solution in step 4 in gravity tank is added drop-wise in the reaction kettle of step 2；
Step 6: mixed solution obtained in step 5 being transferred in homogenizer, homogenizer fast homogeneous is opened；
Step 7: after homogeneous index reaches requirement, the good mixed solution of homogeneous being transferred in the reaction kettle of step 2, is started
Continue to heat up, sustained response；
Step 8: after the reaction was completed, triethanolamine is added, adjusts pH value, stop reaction；
Step 9: finished product being detected, after reaching required value, preservative is added and is packed.
The ratio 1:2 for the water that the water and step 3 that the step 1 is added are added.
The temperature of heating stirring is 70 degree in step 2 reaction kettle.
The catalyst solution of the step 5 be added dropwise into reaction kettle time be 2 hours.
Partial size is measured by sampling in midway when the step 7 homogenizer homogeneous, and warming temperature is arranged at 70 degree, is persistently stirred to react
Time is 6 hours.
Particle size diameter size is measured by sampling by particle size analyzer in the step 7.
The step 8 passes through thunder magnetic PH meter detection pH value.
Embodiment 3
A kind of novel polymeric silicone oil emulsion, the novel polymeric silicone oil emulsion contain by weight percentage:
Hydroxy silicon oil: 53%；
The basic sulfonic acid of dodecane: 3%；
Fatty alcohol ether: 4%；
Catalyst: 0.4%；
Triethanolamine: 2；
Preservative: 0.2%；
Water: 37.4%.
A kind of preparation method of novel polymeric silicone oil emulsion, the procedure of processing are as follows:
Step 1: the water of hydroxy silicon oil, fatty alcohol ether, dodecyl benzene sulfonic acid and formula ratio is put in proportion into reaction
Kettle；
Step 2: opening reaction kettle, heating stirring；
Step 3: water and catalyst being added in blender, are uniformly mixed；
Step 4: catalyst solution obtained in step 3 is drawn into gravity tank；
Step 5: the catalyst solution in step 4 in gravity tank is added drop-wise in the reaction kettle of step 2；
Step 6: mixed solution obtained in step 5 being transferred in homogenizer, homogenizer fast homogeneous is opened；
Step 7: after homogeneous index reaches requirement, the good mixed solution of homogeneous being transferred in the reaction kettle of step 2, is started
Continue to heat up, sustained response；
Step 8: after the reaction was completed, triethanolamine is added, adjusts pH value, stop reaction；
Step 9: finished product being detected, after reaching required value, preservative is added and is packed.
The ratio 1:2 for the water that the water and step 3 that the step 1 is added are added.
The temperature of heating stirring is 60 degree in step 2 reaction kettle.
The catalyst solution of the step 5 be added dropwise into reaction kettle time be 1.3 hours.
Partial size is measured by sampling in midway when the step 7 homogenizer homogeneous, and warming temperature is arranged at 68 degree, is persistently stirred to react
Time is 6 hours.
Particle size diameter size is measured by sampling by particle size analyzer in the step 7.
The step 8 passes through thunder magnetic PH meter detection pH value.
Embodiment 4
The present embodiment is that shampoo, the formula group of shampoo are prepared using novel polymeric silicone oil emulsion of the present invention
Divide and contain by weight percentage:
Hydroxy silicon oil: 50%；
The basic sulfonic acid of dodecane: 1.5%；
Fatty alcohol ether: 1.4%；
Catalyst: 0.2%；
Triethanolamine: 1.7%；
Fatty alcohol-ether sodium sulfate: 1.1%；
Sodium alkyl sulfate: 4%；
Cocounut oil propyl betaine: 4%；
Glycol distearate: 1.2%；
Coconut oleoyl amine methyl MEA:1.8%；
Cation guar gum: 0.4%；
Polyquaternium 7:1%；
Glycerol: 1.5%；
Citric acid: 0.1%；
Preservative: 0.1%；
Water: 30%.
Novel polymeric silicone oil emulsion mixes the preparation method that other raw materials prepare shampoo, and the procedure of processing is as follows:
Step 1: hydroxy silicon oil, fatty alcohol ether, dodecyl benzene sulfonic acid, fatty alcohol-ether sodium sulfate, sodium alkyl sulfate,
Cocounut oil propyl betaine, glycol distearate, coconut oleoyl amine methyl MEA, cation guar gum, polyquaternium 7, glycerol,
The water of citric acid and formula ratio is put in proportion into reaction kettle；
Step 2: opening reaction kettle, heating stirring；
Step 3: water and catalyst being added in blender, are uniformly mixed；
Step 4: catalyst solution obtained in step 3 is drawn into gravity tank；
Step 5: the catalyst solution in step 4 in gravity tank is added drop-wise in the reaction kettle of step 2；
Step 6: mixed solution obtained in step 5 being transferred in homogenizer, homogenizer fast homogeneous is opened；
Step 7: after homogeneous index reaches requirement, the good mixed solution of homogeneous being transferred in the reaction kettle of step 2, is started
Continue to heat up, sustained response；
Step 8: after the reaction was completed, triethanolamine is added, adjusts pH value, stop reaction；
Step 9: finished product being detected, after reaching required value, preservative is added and is packed.
The ratio 1:2 for the water that the water and step 3 that the step 1 is added are added.
The temperature of heating stirring is 67 degree in step 2 reaction kettle.
The catalyst solution of the step 5 be added dropwise into reaction kettle time be 1-2 hours.
Partial size is measured by sampling in midway when the step 7 homogenizer homogeneous, and warming temperature is arranged at 70 degree, is persistently stirred to react
Time is 6 hours.
Particle size diameter size is measured by sampling by particle size analyzer in the step 7.
The step 8 passes through thunder magnetic PH meter detection pH value.
Embodiment 5
The present embodiment is that liquid detergent, the formula group of liquid detergent are prepared using novel polymeric silicone oil emulsion of the present invention
Divide and contain by weight percentage:
Hydroxy silicon oil: 52%；
The basic sulfonic acid of dodecane: 3%；
Fatty alcohol ether: 4%；
Catalyst: 0.35%；
Triethanolamine: 2.8%；
Fatty alcohol-ether sodium sulfate: 1.75%；
Fatty alcohol polyoxyethylene ether -7:4%；
Cocamide diethanolamine: 2%；
Preservative: 0.1%；
Water: 30%.
Novel polymeric silicone oil emulsion mixes the preparation method that other raw materials prepare liquid detergent, and the procedure of processing is as follows:
Step 1: hydroxy silicon oil, fatty alcohol ether, dodecyl benzene sulfonic acid, fatty alcohol-ether sodium sulfate, fatty alcohol polyoxy second
The water of alkene ether -7, cocamide diethanolamine and formula ratio is put in proportion into reaction kettle；
Step 2: opening reaction kettle, heating stirring；
Step 3: water and catalyst being added in blender, are uniformly mixed；
Step 4: catalyst solution obtained in step 3 is drawn into gravity tank；
Step 5: the catalyst solution in step 4 in gravity tank is added drop-wise in the reaction kettle of step 2；
Step 6: mixed solution obtained in step 5 being transferred in homogenizer, homogenizer fast homogeneous is opened；
Step 7: after homogeneous index reaches requirement, the good mixed solution of homogeneous being transferred in the reaction kettle of step 2, is started
Continue to heat up, sustained response；
Step 8: after the reaction was completed, triethanolamine is added, adjusts pH value, stop reaction；
Step 9: finished product being detected, after reaching required value, preservative is added and is packed.
The ratio 1:2 for the water that the water and step 3 that the step 1 is added are added.
The temperature of heating stirring is 59 degree in step 2 reaction kettle.
The catalyst solution of the step 5 be added dropwise into reaction kettle time be 1.8 hours.
Partial size is measured by sampling in midway when the step 7 homogenizer homogeneous, and warming temperature is arranged at 68 degree, is persistently stirred to react
Time is 6 hours.
Particle size diameter size is measured by sampling by particle size analyzer in the step 7.
The step 8 passes through thunder magnetic PH meter detection pH value.
Embodiment 4 can be also used for shampoo, and embodiment 5 can also apply to liquid detergent, submissive do not hurt hands of doing washing.
The present embodiment 4 is novel polymeric silicone oil emulsion of the present invention and other necessary material allocations, applies to prepare shampoo；
The present embodiment 5 is novel polymeric silicone oil emulsion of the present invention and other necessary material allocations, applies to prepare liquid detergent.
The following are data and equipment involved by novel polymeric silicone oil emulsion data experiment of the present invention.
Examine equipment and laboratory apparatus as follows:
IKA homogenizer, IKA blender, Gongyi magnetic force constant temperature electric heating set, infrared moisture meter (German import), Lei Ci
PH counts (Shanghai instrument company), particle size analyzer (Zhuhai America and Europe gram instrument company).
Novel polymeric silicone oil emulsion related data of the present invention is as follows:
The partial size of silicone emulsion is smaller, and the specific surface area of lotion is bigger, and silicone oil is more evenly distributed.The common silicone emulsion in market
Partial size be about 20 microns, the present invention and 20 microns of silicone emulsion specific surface area can be calculated by the following formula:
Sphere volume: V=(4/3) π r3；
Ball surface product: S=4 π r2；
R: the radius of a ball；
Regard emulsion particle as sphere, polymerization silicone oil emulsion partial size of the present invention is about 150nm, common silicone emulsion
Partial size is about 20 μm.
VIt is general=(4/3) π rIt is general 3=XV=X (4/3) π r3；
X=2370370.37；
X·S/SIt is general=133.3 times；
Specific surface area of the invention is 133.3 times of common silicone emulsion, and silicone oil is more evenly distributed.
The preferred embodiment of the present invention above described embodiment only expresses, the description thereof is more specific and detailed, but simultaneously
Limitations on the scope of the patent of the present invention therefore cannot be interpreted as.It should be pointed out that for those of ordinary skill in the art
For, without departing from the inventive concept of the premise, several deformations can also be made, improves and substitutes, these belong to this hair
Bright protection scope.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.
Claims (8)
1. a kind of novel polymeric silicone oil emulsion, which is characterized in that the novel polymeric silicone oil emulsion contains by weight percentage:
Hydroxy silicon oil: 50%-60%；
The basic sulfonic acid of dodecane: 1%-5%；
Fatty alcohol ether: 1%-5%；
Catalyst: 0.1%-0.5%；
Triethanolamine: 1%-5%；
Preservative: 0.1%-0.3%；
Water: 30%-50%.
2. a kind of preparation method of novel polymeric silicone oil emulsion according to claim 1, which is characterized in that the procedure of processing
It is as follows:
Step 1: the water of hydroxy silicon oil, fatty alcohol ether, dodecyl benzene sulfonic acid and formula ratio is put in proportion into reaction kettle；
Step 2: opening reaction kettle, heating stirring；
Step 3: water and catalyst being added in blender, are uniformly mixed；
Step 4: catalyst solution obtained in step 3 is drawn into gravity tank；
Step 5: the catalyst solution in step 4 in gravity tank is added drop-wise in the reaction kettle of step 2；
Step 6: mixed solution obtained in step 5 being transferred in homogenizer, homogenizer fast homogeneous is opened；
Step 7: after homogeneous index reaches requirement, the good mixed solution of homogeneous being transferred in the reaction kettle of step 2, starts to continue
Heating, sustained response；
Step 8: after the reaction was completed, triethanolamine is added, adjusts pH value, stop reaction；
Step 9: finished product being detected, after reaching required value, preservative is added and is packed.
3. a kind of preparation method of novel polymeric silicone oil emulsion according to claim 2, which is characterized in that the step 1
The ratio 1:2 for the water that the water and step 3 of addition are added.
4. a kind of preparation method of novel polymeric silicone oil emulsion according to claim 2, which is characterized in that the step 2
The temperature of heating stirring is 50-70 degree in reaction kettle.
5. a kind of preparation method of novel polymeric silicone oil emulsion according to claim 2, which is characterized in that the step 5
Catalyst solution be added dropwise into reaction kettle time be 1-2 hours.
6. a kind of preparation method of novel polymeric silicone oil emulsion according to claim 2, which is characterized in that the step 7
Partial size is measured by sampling in midway when homogenizer homogeneous, and warming temperature is arranged in 65-70 degree, and being persistently stirred to react the time is 6 hours.
7. a kind of preparation method of novel polymeric silicone oil emulsion according to claim 2, which is characterized in that the step 7
Particle size diameter size is measured by sampling by particle size analyzer.
8. a kind of preparation method of novel polymeric silicone oil emulsion according to claim 2, which is characterized in that the step 8
Detection pH value is counted by thunder magnetic PH.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910839624.5A CN110403853A (en) | 2019-09-06 | 2019-09-06 | A kind of novel polymeric silicone oil emulsion and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910839624.5A CN110403853A (en) | 2019-09-06 | 2019-09-06 | A kind of novel polymeric silicone oil emulsion and preparation method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110403853A true CN110403853A (en) | 2019-11-05 |
Family
ID=68370473
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910839624.5A Pending CN110403853A (en) | 2019-09-06 | 2019-09-06 | A kind of novel polymeric silicone oil emulsion and preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110403853A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116987270A (en) * | 2023-08-11 | 2023-11-03 | 宏翼(广东)新材料有限公司 | Polymerized silicone oil emulsion and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5951916A (en) * | 1982-09-17 | 1984-03-26 | Toray Silicone Co Ltd | Production of diorganopolysiloxane emulsion |
| JPH11228831A (en) * | 1998-02-16 | 1999-08-24 | Kanegafuchi Chem Ind Co Ltd | Aqueous dispersion composition of polydiorganosiloxane and method for producing the same |
| JP2005281409A (en) * | 2004-03-29 | 2005-10-13 | Ge Toshiba Silicones Co Ltd | Silicone release agent composition |
| CN1738597A (en) * | 2003-01-14 | 2006-02-22 | 荷兰联合利华有限公司 | Household and personal care compositions comprising silicone-based lubricants |
| CN101142279A (en) * | 2005-03-17 | 2008-03-12 | 陶氏康宁公司 | Silicone emulsion, its preparation method and cosmetic composition |
| CN102284198A (en) * | 2011-05-18 | 2011-12-21 | 黄山市强力化工有限公司 | Water-soluble polyether modified organic silicon defoaming agent as well as preparation and compounding methods thereof |
| CN106633103A (en) * | 2016-12-30 | 2017-05-10 | 江西蓝星星火有机硅有限公司 | Preparation method of high-internal-phase-viscosity polysiloxane emulsion |
-
2019
- 2019-09-06 CN CN201910839624.5A patent/CN110403853A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5951916A (en) * | 1982-09-17 | 1984-03-26 | Toray Silicone Co Ltd | Production of diorganopolysiloxane emulsion |
| JPH11228831A (en) * | 1998-02-16 | 1999-08-24 | Kanegafuchi Chem Ind Co Ltd | Aqueous dispersion composition of polydiorganosiloxane and method for producing the same |
| CN1738597A (en) * | 2003-01-14 | 2006-02-22 | 荷兰联合利华有限公司 | Household and personal care compositions comprising silicone-based lubricants |
| JP2005281409A (en) * | 2004-03-29 | 2005-10-13 | Ge Toshiba Silicones Co Ltd | Silicone release agent composition |
| CN101142279A (en) * | 2005-03-17 | 2008-03-12 | 陶氏康宁公司 | Silicone emulsion, its preparation method and cosmetic composition |
| CN102284198A (en) * | 2011-05-18 | 2011-12-21 | 黄山市强力化工有限公司 | Water-soluble polyether modified organic silicon defoaming agent as well as preparation and compounding methods thereof |
| CN106633103A (en) * | 2016-12-30 | 2017-05-10 | 江西蓝星星火有机硅有限公司 | Preparation method of high-internal-phase-viscosity polysiloxane emulsion |
Non-Patent Citations (2)
| Title |
|---|
| 彭忠利: "《羟基封端聚二甲基硅氧烷低聚物阴离子乳液聚合研究》", 《中山大学学报（自然科学版）》 * |
| 汪多仁: "《绿色轻工助剂》", 28 February 2006 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116987270A (en) * | 2023-08-11 | 2023-11-03 | 宏翼(广东)新材料有限公司 | Polymerized silicone oil emulsion and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5763762B2 (en) | Hair washing method | |
| CN107693433B (en) | Moisturizing essence and preparation method thereof | |
| CN104800100B (en) | A kind of gentle disposable make-up remover and preparation method thereof | |
| JP5468314B2 (en) | Skin cleanser composition | |
| CN107595761B (en) | A kind of suspension oil droplet toner and preparation method thereof | |
| CN1233951A (en) | Liquid personal cleansing composition containing lipophilic skin moisturizing agent composed of relatively large droplets | |
| CN103585040B (en) | Emulsion composition used for water resistant liquid crystal cosmetics and application thereof | |
| CN1173127A (en) | Storage-stable liquid skin cleansing compositions comprising gel-forming polymers and lipids | |
| DE212014000234U1 (en) | cleaning structures | |
| WO2014177189A1 (en) | Translucent gel system | |
| CN109602639A (en) | A kind of amino pickling shield shampoo and preparation method thereof | |
| CN104107375B (en) | Chinese medicine composition that hair care is sent out admittedly and its preparation method and application | |
| CN106344434A (en) | Nutritious supple shampoo without silicon oil and preparation method thereof | |
| CN103462858A (en) | Oat paste having effects of cleaning and skin care, mask and their preparation methods | |
| CN110403853A (en) | A kind of novel polymeric silicone oil emulsion and preparation method | |
| Gahlawat et al. | Formulation and evaluation of polyherbal liquid shampoo | |
| JP2886665B2 (en) | Shampoo containing siloxane polymer having amine function | |
| CN108624417A (en) | A kind of instant softening laundry liquid easily floated | |
| CN103565662B (en) | A kind of water-resistant liquid crystal cosmetic | |
| CN104367516B (en) | A kind of gentle eye lip makeup removing gel and preparation method thereof | |
| CN114569494B (en) | Composition for removing makeup, preparation method, packaging method and using method thereof, and makeup removing gel | |
| CN110511396A (en) | A kind of polymerization silicone oil emulsion and its preparation process | |
| CN108294966A (en) | A kind of transparent lotions and preparation method thereof | |
| CN114395449A (en) | A kind of herbal ash handmade soap containing traditional Chinese medicine fermented product and preparation method thereof | |
| CN106491391B (en) | A kind of high viscosity clear transdermal cleaning gel and its preparation method and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20191105 |
|
| RJ01 | Rejection of invention patent application after publication |