CN108873135A - A kind of near-infrared narrow band filter and infrared imaging system - Google Patents

A kind of near-infrared narrow band filter and infrared imaging system Download PDF

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CN108873135A
CN108873135A CN201810884789.XA CN201810884789A CN108873135A CN 108873135 A CN108873135 A CN 108873135A CN 201810884789 A CN201810884789 A CN 201810884789A CN 108873135 A CN108873135 A CN 108873135A
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band
refractive index
passband
infrared
film
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陈策
丁维红
肖念恭
陈吉利
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Xinyang Sunny Optics Co Ltd
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Xinyang Sunny Optics Co Ltd
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/20Filters
    • G02B5/208Filters for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11Anti-reflection coatings
    • G02B1/113Anti-reflection coatings using inorganic layer materials only
    • G02B1/115Multilayers

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Abstract

The present invention relates to a kind of near-infrared narrow band filter and infrared imaging system, wherein near-infrared narrow band filter includes:The IR membrane system of the substrate side is arranged in substrate;The IR membrane system includes the first high refractive index layer and the first low-index film being alternately coated with, and the outermost layer of the IR membrane system is the first low-index film;In the wave-length coverage of 800~1200nm, the IR membrane system has a passband wave band, two transition wave bands and two cut-off wave bands, the passband wave band is located between two described two cut-off wave bands, and the little bellow section is between the passband wave band and the cut-off wave band;The passband wave band has central wavelength, and in the range of incidence angle changes from 0 ° to 30 °, the central wavelength drift band of the passband wave band is between 7nm~13nm.Under the premise of guaranteeing high transmittance, narrow band filter passband center wavelengths are reduced with angle drift amount, improve image quality.

Description

一种近红外窄带滤光片及红外成像系统A near-infrared narrow-band filter and an infrared imaging system

技术领域technical field

本发明涉及一种滤光片及红外成像系统,尤其涉及一种近红外窄带滤光片及红外成像系统。The invention relates to an optical filter and an infrared imaging system, in particular to a near-infrared narrow-band optical filter and an infrared imaging system.

背景技术Background technique

随着科技的发展,在智能手机、车载激光雷达、安防门禁、智能家居、虚拟现实/增强现实/混合现实、3D体感游戏、3D摄像与显示等终端中逐步嵌入了人脸设备、手势识别等功能。With the development of science and technology, face devices, gesture recognition, etc. Function.

在人脸识别、手势识别时需要用到近红外窄带滤光片,其能起到增透铜带中近红外光线,截止环境中可见光的作用。通常近红外窄带滤光片包括两个膜系,分别为IR带通膜系和长波通AR膜系。然而现有技术中的滤光片对近红外光线的增透效果以及截止可见光的效果较差,同时存在膜系膜层厚度较厚的问题,从而导致将滤光片组装到人脸识别、手势识别等装置后,成像效果较差、识别精度不高。Near-infrared narrow-band filters are required for face recognition and gesture recognition, which can enhance the near-infrared light in the copper strip and cut off the visible light in the environment. Usually near-infrared narrow-band filters include two film systems, namely IR band-pass film system and long-wave pass AR film system. However, the optical filter in the prior art has poor anti-reflection effect on near-infrared light and visible light cut-off effect, and there is a problem that the thickness of the film system is relatively thick, which leads to the assembly of the optical filter in face recognition, gesture recognition, etc. After recognition and other devices, the imaging effect is poor and the recognition accuracy is not high.

发明内容Contents of the invention

本发明的目的在于提供一种近红外窄带滤光片及红外成像系统,解决近红外滤光片成像效果差的问题。The object of the present invention is to provide a near-infrared narrow-band filter and an infrared imaging system to solve the problem of poor imaging effect of the near-infrared filter.

为实现上述发明目的,本发明提供一种近红外窄带滤光片,包括:基板,设置在所述基板一侧的IR膜系;In order to achieve the purpose of the above invention, the present invention provides a near-infrared narrow-band filter, including: a substrate, an IR film system arranged on one side of the substrate;

所述IR膜系包括交替镀制的第一高折射率膜层和第一低折射率膜层,所述IR膜系的最外层均为第一低折射率膜层;在800~1200nm的波长范围内,所述IR膜系具有一个通带波段、两个过渡波段和两个截止波段,所述通带波段位于两个所述两个截止波段之间,所述过渡波段位于所述通带波段与所述截止波段之间;The IR film system includes alternately plated first high-refractive index film layers and first low-refractive-index film layers, and the outermost layers of the IR film system are all first low-refractive index film layers; In the wavelength range, the IR film system has a pass band, two transition bands and two cut-off bands, the pass band is located between the two cut-off bands, and the transition band is located between the pass bands. between the band band and the cut-off band;

所述通带波段具有中心波长,且在入射角从0°改变至30°的范围内,所述通带波段的中心波长漂移幅度介于7nm~13nm之间。The passband band has a central wavelength, and within the range where the incident angle changes from 0° to 30°, the central wavelength shift range of the passband band is between 7nm and 13nm.

根据本发明的一个方面,在入射角从20°改变至30°的范围内,入射角每变化1°,所述通带波段的中心波长漂移幅度小于5nm。According to one aspect of the present invention, within the range where the incident angle changes from 20° to 30°, for every 1° change in the incident angle, the shift amplitude of the central wavelength of the passband band is less than 5 nm.

根据本发明的一个方面,所述通带波段带宽小于400nm。According to an aspect of the present invention, the bandwidth of the passband band is less than 400nm.

根据本发明的一个方面,在800~1200nm的波长范围内,所述通带波段透过率大于90%,所述截止波段透过率小于0.1%。According to one aspect of the present invention, within the wavelength range of 800-1200 nm, the transmittance in the passband band is greater than 90%, and the transmittance in the cutoff band is less than 0.1%.

根据本发明的一个方面,所述通带波段UV侧和IR侧曲线陡度介于7nm~13nm之间。According to one aspect of the present invention, the steepness of the curves at the UV side and the IR side of the passband band is between 7nm and 13nm.

根据本发明的一个方面,所述第一高折射率膜层为氢化硅层;According to one aspect of the present invention, the first high refractive index film layer is a hydrogenated silicon layer;

在800~1200nm的波长范围内,所述第一高折射率膜层的折射率大于3.5,且消光系数小于0.002。In the wavelength range of 800-1200 nm, the refractive index of the first high-refractive index film layer is greater than 3.5, and the extinction coefficient is less than 0.002.

根据本发明的一个方面,在850nm波长处,所述第一高折射率膜层折射率大于3.6;According to one aspect of the present invention, at a wavelength of 850nm, the refractive index of the first high refractive index film layer is greater than 3.6;

在940nm波长处,所述第一高折射率膜层折射率大于3.55。At the wavelength of 940nm, the refractive index of the first high refractive index film layer is greater than 3.55.

根据本发明的一个方面,所述第一高折射率膜层为溅射反应膜层,在氢气存在的条件下,其溅射反应温度为80℃~300℃,溅射速率为0.1nm/s≤v≤1nm/s。According to one aspect of the present invention, the first high refractive index film layer is a sputtering reaction film layer, and in the presence of hydrogen, the sputtering reaction temperature is 80°C-300°C, and the sputtering rate is 0.1nm/s ≤v≤1nm/s.

根据本发明的一个方面,所述氢气以可调整的流量引入,且其流量满足10sccm≤v1≤50sccm。According to one aspect of the present invention, the hydrogen gas is introduced at an adjustable flow rate, and the flow rate satisfies 10sccm≤v1≤50sccm.

根据本发明的一个方面,所述第一高折射率膜层和所述第一低折射率膜层的物理厚度关系满足:0.01≤DL/DH≤100,其中,DL、DH分别表示第一低折射率膜层和第一高折射率膜层的物理厚度。According to one aspect of the present invention, the physical thickness relationship between the first high refractive index film layer and the first low refractive index film layer satisfies: 0.01≤D L /D H ≤100, where D L and D H are respectively Indicates the physical thickness of the first low-refractive-index film layer and the first high-refractive-index film layer.

根据本发明的一个方面,在入射角从0°改变至10°的范围内,所述通带波段的中心波长漂移幅度介于0.5nm~1.5nm之间,入射角每变化1°,所述通带波段的中心波长漂移幅度小于1.5nm;According to one aspect of the present invention, within the range where the incident angle changes from 0° to 10°, the central wavelength shift amplitude of the passband band is between 0.5nm and 1.5nm, and for every 1° change in the incident angle, the The central wavelength drift of the passband band is less than 1.5nm;

在入射角从0°改变至20°的范围内,所述通带波段的中心波长漂移幅度介于2.5nm~8nm之间,从10°改变至20°的范围内,入射角每变化1°,所述通带波段的中心波长漂移幅度小于6nm;In the range where the incident angle changes from 0° to 20°, the central wavelength shift range of the passband band is between 2.5nm and 8nm, and in the range where the incident angle changes from 10° to 20°, every 1° change in the incident angle , the central wavelength shift amplitude of the passband band is less than 6nm;

在入射角从0°改变至40°的范围内,所述通带波段的中心波长漂移幅度介于12nm~20nm之间,从0°改变至10°的范围内,入射角每变化1°,所述通带波段的中心波长漂移幅度小于8nm。In the range where the incident angle changes from 0° to 40°, the central wavelength shift amplitude of the passband band is between 12nm and 20nm, and in the range where the incident angle changes from 0° to 10°, every time the incident angle changes by 1°, The central wavelength shift amplitude of the passband band is less than 8nm.

根据本发明的一个方面,还包括AR膜系;According to an aspect of the present invention, it also includes an AR film system;

所述IR膜系和所述AR膜系相对的位于所述所述基板的两侧;The IR film system and the AR film system are oppositely located on both sides of the substrate;

所述AR膜系包括交替镀制的第二高折射率膜层和第二低折射率膜层,所述AR膜系的最外层均为第二低折射率膜层。The AR film system includes alternately plated second high-refractive-index film layers and second low-refractive-index film layers, and the outermost layers of the AR film system are both second low-refractive index film layers.

根据本发明的一个方面,在350~1200nm的波长范围内,所述AR膜系具有一个通带区域,且其透过率大于90%,一个截止区域,且其透过率小于0.1%;According to one aspect of the present invention, in the wavelength range of 350-1200nm, the AR film system has a passband region, and its transmittance is greater than 90%, and a cutoff region, and its transmittance is less than 0.1%;

在800~1200nm的波长范围内,所述AR膜系还具有一个过渡区域,且其透过率介于0.1%~90%之间。In the wavelength range of 800-1200nm, the AR film system also has a transition region, and its transmittance is between 0.1%-90%.

根据本发明的一个方面,所述IR膜系和所述AR膜系的膜层总厚度小于9.8μm。According to one aspect of the present invention, the total thickness of the film layers of the IR film system and the AR film system is less than 9.8 μm.

根据本发明的一个方面,所述近红外窄带滤光片的半高全宽值小于120nm。According to one aspect of the present invention, the full width at half maximum of the near-infrared narrow-band filter is less than 120nm.

根据本发明的一个方面,所述第一低折射率膜层的折射率小于3,且其材料为SiO2、Nb2O5、Ta2O5、TiO2、Al2O3、ZrO2、Pr6O11、La2O3、Si2N、SiN、Si2N3、Si3N4中的一种或多种的组合;According to one aspect of the present invention, the refractive index of the first low refractive index film layer is less than 3, and its material is SiO 2 , Nb 2 O 5 , Ta 2 O 5 , TiO 2 , Al 2 O 3 , ZrO 2 , A combination of one or more of Pr 6 O 11 , La 2 O 3 , Si 2 N, SiN, Si 2 N 3 , Si 3 N 4 ;

所述第二低折射率膜层的折射率小于3,且其材料为SiO2、Nb2O5、Ta2O5、TiO2、Al2O3、ZrO2、Pr6O11、La2O3、Si2N、SiN、Si2N3、Si3N4中的一种或多种的组合。The refractive index of the second low refractive index film layer is less than 3, and its material is SiO 2 , Nb 2 O 5 , Ta 2 O 5 , TiO 2 , Al 2 O 3 , ZrO 2 , Pr 6 O 11 , La 2 A combination of one or more of O 3 , Si 2 N, SiN, Si 2 N 3 , and Si 3 N 4 .

为实现上述发明目的,本发明提供一种红外成像系统,其特征在于,包括IR发射系统和IR接收系统;In order to achieve the purpose of the above invention, the present invention provides an infrared imaging system, which is characterized in that it includes an IR emitting system and an IR receiving system;

所述IR发射系统包括IR发射光源和用于投射所述IR发射光源发出的光的第一镜头组件;The IR emitting system includes an IR emitting light source and a first lens assembly for projecting light emitted by the IR emitting light source;

所述IR接收系统包括近红外窄带滤光片、第二镜头组件和红外图像传感器;The IR receiving system includes a near-infrared narrow-band filter, a second lens assembly and an infrared image sensor;

所述红外窄带滤光片位于所述第二镜头组件和所述红外图像传感器之间。The infrared narrowband filter is located between the second lens assembly and the infrared image sensor.

根据本发明的一个方面,所述第一镜头组件包括红外光源准直镜头和设置在所述红外光源准直镜头上的衍射组件。According to one aspect of the present invention, the first lens component includes an infrared light source collimating lens and a diffraction component disposed on the infrared light source collimating lens.

根据本发明的一种方案,在保证本发明的近红外滤光片高透过率的前提下,能极大地降低窄带滤光片通带中心波长随角度漂移量,提升了窄带滤光片过渡区的陡度,从而提高了成像质量,进一步提高人脸识别、手势识别系统中信噪比,降低了膜层总厚度和镀膜总时间,降低了生产成本,为终端客户节约了使用成本。According to a solution of the present invention, under the premise of ensuring the high transmittance of the near-infrared filter of the present invention, the drift of the passband center wavelength of the narrow-band filter with angle can be greatly reduced, and the transition of the narrow-band filter is improved. The steepness of the area improves the imaging quality, further improves the signal-to-noise ratio in face recognition and gesture recognition systems, reduces the total thickness of the film layer and the total time of coating, reduces the production cost, and saves the use cost for end customers.

根据本发明的一种方案,通过将IR膜系和AR膜系的外侧分别设置成第一低折射率膜层和第二低折射率膜层,有利于IR膜系和AR膜系附着在基板上,并且其硬度高,耐磨性好,抗腐蚀性强,从而有利于保证本发明的IR膜系和AR膜系的结构稳定,以及提高IR膜系和AR膜系的使用寿命,进一步提高了本发明的红外窄带滤光片的使用寿命。同时,本发明的近红外窄带滤光片的厚度小,节约了本发明的生产成本。According to a solution of the present invention, by setting the outer sides of the IR film system and the AR film system respectively as the first low refractive index film layer and the second low refractive index film layer, it is beneficial for the IR film system and the AR film system to adhere to the substrate. On, and its hardness is high, wear resistance is good, and corrosion resistance is strong, thereby helps to guarantee the structural stability of IR film system and AR film system of the present invention, and improves the service life of IR film system and AR film system, further improves The service life of the infrared narrowband filter of the present invention is improved. At the same time, the thickness of the near-infrared narrow-band filter of the present invention is small, which saves the production cost of the present invention.

根据本发明的一种方案,通过上述条件设置,使得镀制的第一高折射率膜层具有良好的膜层特性,使得第一高折射率膜层达到较高的折射率,进一步使得本发明的近红外窄带滤光片的成像效果更好。According to a solution of the present invention, through the setting of the above conditions, the plated first high-refractive index film layer has good film properties, so that the first high-refractive index film layer reaches a relatively high refractive index, further enabling the present invention The imaging effect of the near-infrared narrow-band filter is better.

附图说明Description of drawings

图1示意性表示根据本发明的一种实施方式的近红外滤光片的结构图;Fig. 1 schematically represents the structural diagram of the near-infrared filter according to an embodiment of the present invention;

图2示意性表示根据本发明的一种实施方式的近红外滤光片的IR膜系的波长与透过曲线关系图;Fig. 2 schematically represents the wavelength and transmission curve relation diagram of the IR film system of the near-infrared optical filter according to an embodiment of the present invention;

图3示意性表示根据本发明的另一种实施方式的近红外滤光片的结构图;Fig. 3 schematically represents the structure diagram of the near-infrared filter according to another embodiment of the present invention;

图4示意性表示根据本发明的一种实施方式的红外成像系统的结构图。Fig. 4 schematically shows a structure diagram of an infrared imaging system according to an embodiment of the present invention.

图5示意性表示根据本发明的实施例1的IR膜层透过率与波长的曲线关系图;Fig. 5 schematically represents the graph of the relationship between the transmittance of the IR film layer and the wavelength according to Embodiment 1 of the present invention;

图6示意性表示根据本发明的实施例2的IR膜层透过率与波长的曲线关系图;Fig. 6 schematically represents the graph of the relationship between the transmittance of the IR film layer and the wavelength according to Embodiment 2 of the present invention;

图7示意性表示根据本发明的实施例3的IR膜层透过率与波长的曲线关系图;Fig. 7 schematically represents the graph of the relationship between the transmittance of the IR film layer and the wavelength according to Embodiment 3 of the present invention;

图8示意性表示根据本发明的实施例4的IR膜层透过率与波长的曲线关系图;Fig. 8 schematically represents the graph of the relationship between the transmittance of the IR film layer and the wavelength according to Embodiment 4 of the present invention;

图9示意性表示根据本发明的实施例4的AR膜层透过率与波长的曲线关系图;Fig. 9 schematically shows the graph of the relationship between the transmittance of the AR film layer and the wavelength according to Embodiment 4 of the present invention;

图10示意性表示根据本发明的实施例5的IR膜层透过率与波长的曲线关系图;Fig. 10 schematically represents the graph of the relationship between the transmittance of the IR film layer and the wavelength according to Embodiment 5 of the present invention;

图11示意性表示根据本发明的实施例5的AR膜层透过率与波长的曲线关系图。FIG. 11 schematically shows the relationship between the transmittance of the AR film layer and the wavelength according to Embodiment 5 of the present invention.

具体实施方式Detailed ways

为了更清楚地说明本发明实施方式或现有技术中的技术方案,下面将对实施方式中所需要使用的附图作简单地介绍。显而易见地,下面描述中的附图仅仅是本发明的一些实施方式,对于本领域普通技术人员而言,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to more clearly describe the embodiments of the present invention or the technical solutions in the prior art, the following will briefly introduce the drawings that are used in the embodiments. Apparently, the drawings in the following description are only some embodiments of the present invention, and those skilled in the art can also obtain other drawings according to these drawings without creative efforts.

在针对本发明的实施方式进行描述时,术语“纵向”、“横向”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”“内”、“外”所表达的方位或位置关系是基于相关附图所示的方位或位置关系,其仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此上述术语不能理解为对本发明的限制。When describing the embodiments of the present invention, the terms "vertical", "transverse", "upper", "lower", "front", "rear", "left", "right", "vertical", " The orientation or positional relationship expressed by "horizontal", "top", "bottom", "inner" and "outer" is based on the orientation or positional relationship shown in the relevant drawings, which are only for the convenience of describing the present invention and simplifying the description, and It is not to indicate or imply that the device or element referred to must have a particular orientation, be constructed, or operate in a particular orientation, and thus the above terms should not be construed as limiting the invention.

下面结合附图和具体实施方式对本发明作详细地描述,实施方式不能在此一一赘述,但本发明的实施方式并不因此限定于以下实施方式。The present invention will be described in detail below in conjunction with the accompanying drawings and specific embodiments, and the embodiments cannot be repeated here one by one, but the embodiments of the present invention are not therefore limited to the following embodiments.

如图1所示,根据本发明的一种实施方式,本发明的一种近红外窄带滤光片,包括基板11和IR膜系12。在本实施方式中,IR膜系12设置在基板11的一侧面上。IR膜系12为多层膜构成的结构。在本实施方式中,IR膜系12包括交替镀制的第一高折射率膜层121和第一低折射率膜层122。在本实施方式中,第一高折射率膜层121的折射率大于3,第一低折射率膜层122的折射率小于3。在IR膜系12中,处于IR膜系12最外层(即IR膜系12与基板11和入射介质相接触的位置)均为第一低折射率膜层122。在本实施方式中,近红外窄带滤光片的IR膜系12膜层总厚度小于9.8μm。在本实施方式中,近红外窄带滤光片的半高全宽值小于120nm。进一步的,近红外窄带滤光片的IR膜系12膜层总厚度小于8μm。在本实施方式中,近红外窄带滤光片的半高全宽值小于114nm。通过将IR膜系12的外侧设置成第一低折射率膜层122有利于IR膜系12附着在基板11上,并且其硬度高,耐磨性好,抗腐蚀性强,从而有利于保证本发明的IR膜系12的结构稳定,以及提高IR膜系12的使用寿命,进一步提高了本发明的红外窄带滤光片的使用寿命。同时,本发明的近红外窄带滤光片的厚度小,节约了本发明的生产成本。As shown in FIG. 1 , according to an embodiment of the present invention, a near-infrared narrow-band filter of the present invention includes a substrate 11 and an IR film system 12 . In this embodiment, the IR film system 12 is disposed on one side of the substrate 11 . The IR film system 12 is a multi-layer film structure. In this embodiment, the IR film system 12 includes first high-refractive-index film layers 121 and first low-refractive-index film layers 122 that are plated alternately. In this embodiment, the refractive index of the first high refractive index film layer 121 is greater than 3, and the refractive index of the first low refractive index film layer 122 is less than 3. In the IR film system 12 , the outermost layer of the IR film system 12 (ie the position where the IR film system 12 is in contact with the substrate 11 and the incident medium) is the first low refractive index film layer 122 . In this embodiment, the total thickness of the IR film system 12 of the near-infrared narrow-band filter is less than 9.8 μm. In this embodiment, the full width at half maximum of the near-infrared narrow-band filter is less than 120 nm. Further, the total thickness of the IR film system 12 of the near-infrared narrow-band filter is less than 8 μm. In this embodiment, the full width at half maximum of the near-infrared narrow-band filter is less than 114 nm. By setting the outside of the IR film system 12 as the first low refractive index film layer 122, it is beneficial for the IR film system 12 to be attached to the substrate 11, and it has high hardness, good wear resistance, and strong corrosion resistance, which is beneficial to ensure this The structure of the inventive IR film system 12 is stable, and the service life of the IR film system 12 is improved, further improving the service life of the infrared narrowband filter of the present invention. At the same time, the thickness of the near-infrared narrow-band filter of the present invention is small, which saves the production cost of the present invention.

根据本发明的一种实施方式,第一低折射率膜层122的折射率小于3。在本实施方式中,第一低折射率膜层122的材料为SiO2、Nb2O5、Ta2O5、TiO2、Al2O3、ZrO2、Pr6O11、La2O3、Si2N、SiN、Si2N3、Si3N4中的一种或多种的组合。According to an embodiment of the present invention, the refractive index of the first low refractive index film layer 122 is less than 3. In this embodiment, the material of the first low refractive index film layer 122 is SiO 2 , Nb 2 O 5 , Ta 2 O 5 , TiO 2 , Al 2 O 3 , ZrO 2 , Pr 6 O 11 , La 2 O 3 , Si 2 N, SiN, Si 2 N 3 , Si 3 N 4 or a combination of one or more.

根据本发明的一种实施方式,在800~1200nm的波长范围内,由于IR膜系12通过交替镀制第一高折射率膜层121和第一低折射率膜层122,因此通过入射光的干涉效应从而产生通带波段、过渡波段和截止波段。在本实施方式中,在800~1200nm的波长范围内,IR膜系12具有一个通带波段两个过渡波段和两个截止波段,通带波段位于两个两个截止波段之间,即两个截止波段位于所述通带波段的两侧,过渡波段位于通带波段与截止波段之间。在本实施方式中,通带波段具有中心波长,且在入射角从0°改变至30°的范围内,通带波段的中心波长漂移幅度介于7nm~13nm之间,即通带波段的中心波长漂移幅度大于7nm,并且小于13nm。同时,在入射角从20°改变至30°的范围内,入射角每变化1°,通带波段的中心波长漂移幅度小于5nm。According to one embodiment of the present invention, in the wavelength range of 800-1200nm, since the IR film system 12 alternately coats the first high-refractive-index film layer 121 and the first low-refractive-index film layer 122, the Interference effects thus produce passband, transition and cutoff bands. In this embodiment, in the wavelength range of 800-1200nm, the IR film system 12 has a passband band, two transition bands and two cutoff bands, and the passband band is located between the two cutoff bands, that is, two The cut-off band is located on both sides of the pass-band band, and the transition band is located between the pass-band band and the cut-off band. In this embodiment, the passband band has a central wavelength, and within the range where the incident angle changes from 0° to 30°, the central wavelength shift range of the passband band is between 7nm and 13nm, that is, the center of the passband band The amplitude of wavelength shift is greater than 7nm and less than 13nm. At the same time, within the range where the incident angle changes from 20° to 30°, the central wavelength shift of the passband band is less than 5nm when the incident angle changes by 1°.

根据本发明的一种实施方式,第一高折射率膜层121和第一低折射率膜层122的物理关系满足:0.01≤DL/DH≤100,其中,DL、DH分别表示第一低折射率膜层和第一高折射率膜层的物理厚度。通过将第一高折射率膜层121和第一低折射率膜层122的物理厚度设置在上述范围内,从而有利于减小IR膜系12通带波段中心波长的漂移幅度,提高了本发明的成像质量。本发明的在本实施方式中,第一低折射率膜层122为氮化硅层。第一低折射率膜层122采用氮化硅材料其具有附着力优秀、硬度高、耐磨性好、抗腐蚀能力强,因此保证了IR膜系12与基板11的连接强度与结构强度,并且提高了IR膜系12的使用寿命。According to one embodiment of the present invention, the physical relationship between the first high-refractive index film layer 121 and the first low-refractive index film layer 122 satisfies: 0.01≤D L /D H ≤100, where DL and D H represent The physical thickness of the first low refractive index film layer and the first high refractive index film layer. By setting the physical thicknesses of the first high-refractive index film layer 121 and the first low-refractive index film layer 122 within the above-mentioned range, it is beneficial to reduce the drift amplitude of the central wavelength of the passband band of the IR film system 12, which improves the present invention. image quality. In this embodiment of the present invention, the first low refractive index film layer 122 is a silicon nitride layer. The first low refractive index film layer 122 is made of silicon nitride material, which has excellent adhesion, high hardness, good wear resistance, and strong corrosion resistance, thus ensuring the connection strength and structural strength of the IR film system 12 and the substrate 11, and The service life of the IR film system 12 is improved.

需要指出的是,IR膜系为红外截止膜。It should be pointed out that the IR film is an infrared cut film.

进一步的,在本实施方式中,在800~1200nm的波长范围内,IR膜系12具有一个通带波段两个过渡波段和两个截止波段,通带波段位于两个两个截止波段之间,即两个截止波段位于所述通带波段的两侧,过渡波段位于通带波段与截止波段之间。在本实施方式中,通带波段具有中心波长,且在入射角从0°改变至30°的范围内,通带波段的中心波长漂移幅度介于8nm~12nm之间,即通带波段的中心波长漂移幅度大于8nm,并且小于12nm。同时,在入射角从20°改变至30°的范围内,入射角每变化1°,通带波段的中心波长漂移幅度小于5nm。Further, in this embodiment, within the wavelength range of 800-1200nm, the IR film system 12 has a pass band, two transition bands and two cut-off bands, the pass band is located between the two cut-off bands, That is, the two cut-off bands are located on both sides of the pass-band band, and the transition band is located between the pass-band band and the cut-off band. In this embodiment, the passband band has a central wavelength, and within the range where the incident angle changes from 0° to 30°, the central wavelength drift range of the passband band is between 8nm and 12nm, that is, the center of the passband band The amplitude of wavelength shift is greater than 8nm and less than 12nm. At the same time, within the range where the incident angle changes from 20° to 30°, the central wavelength shift of the passband band is less than 5nm when the incident angle changes by 1°.

在本实施方式中,在入射角从0°改变至10°的范围内,通带波段的中心波长漂移幅度介于0.5nm~1.5nm之间,入射角每变化1°,通带波段的中心波长漂移幅度小于1.5nm。In this embodiment, within the range where the incident angle changes from 0° to 10°, the central wavelength shift range of the passband band is between 0.5nm and 1.5nm, and every time the incident angle changes by 1°, the center wavelength of the passband band The amplitude of wavelength shift is less than 1.5nm.

在本实施方式中,在入射角从0°改变至20°的范围内,通带波段的中心波长漂移幅度介于2.5nm~8nm之间,从10°改变至20°的范围内,入射角每变化1°,通带波段的中心波长漂移幅度小于6nm。In this embodiment, within the range where the incident angle changes from 0° to 20°, the central wavelength shift amplitude of the passband band is between 2.5nm and 8nm, and within the range where the incident angle changes from 10° to 20°, the incident angle For every 1° change, the central wavelength shift of the passband band is less than 6nm.

在本实施方式中,在入射角从0°改变至40°的范围内,通带波段的中心波长漂移幅度介于12nm~20nm之间,从0°改变至10°的范围内,入射角每变化1°,通带波段的中心波长漂移幅度小于8nm。In this embodiment, when the incident angle changes from 0° to 40°, the central wavelength shift range of the passband band is between 12nm and 20nm; within the range from 0° to 10°, the incident angle With a change of 1°, the central wavelength shift of the passband band is less than 8nm.

根据本发明的一种实施方式,通带波段带宽小于400nm。在本实施方式中,在800~1200nm的波长范围内,通带波段透过率大于90%,所述截止波段透过率小于0.1%。参见图2所示,在本实施方式中,通带波段UV侧(靠近短波长的一侧)和IR侧(靠近长波长的一侧)曲线陡度介于7nm~13nm之间。According to an embodiment of the present invention, the bandwidth of the passband band is less than 400 nm. In this embodiment, in the wavelength range of 800-1200 nm, the transmittance in the passband band is greater than 90%, and the transmittance in the cutoff band is less than 0.1%. Referring to FIG. 2 , in this embodiment, the steepness of the curves on the UV side (near the short wavelength side) and IR side (near the long wavelength side) of the passband band ranges from 7nm to 13nm.

根据本发明的一种实施方式,第一高折射率膜层121为氢化硅(Si:H)层。在本实施方式中,在800~1200nm的波长范围内,第一高折射率膜层121的折射率大于3.5,且消光系数小于0.002。其中,在850nm波长处,第一高折射率膜层121折射率大于3.6。在940nm波长处,第一高折射率膜层121折射率大于3.55。According to an embodiment of the present invention, the first high refractive index film layer 121 is a hydrogenated silicon (Si:H) layer. In this embodiment, within the wavelength range of 800-1200 nm, the refractive index of the first high-refractive index film layer 121 is greater than 3.5, and the extinction coefficient is less than 0.002. Wherein, at the wavelength of 850 nm, the refractive index of the first high refractive index film layer 121 is greater than 3.6. At the wavelength of 940nm, the refractive index of the first high refractive index film layer 121 is greater than 3.55.

根据本发明的一种实施方式,第一高折射率膜层121为溅射反应膜层。在本实施方式中,第一高折射率膜层121通过溅射反应设备镀制。第一高折射率膜层121采用的材料为硅化氢。将表面洁净的基板11放置在溅射反应设备中,在存在硅靶和氢气的条件下在基板11上镀制第一高折射率膜层121。在本实施方式中,通过可调整的流量引入反应设备中,其溅射反应温度为80℃~300℃,硅化氢的溅射速率为0.1nm/s≤v≤1nm/s。在本实施方式中,氢气引入的流量满足10sccm≤v1≤50sccm。通过上述条件设置,使得镀制的第一高折射率膜层121具有良好的膜层特性,使得第一高折射率膜层121达到较高的折射率,进一步使得本发明的近红外窄带滤光片的成像效果更好。According to an embodiment of the present invention, the first high refractive index film layer 121 is a sputtering reaction film layer. In this embodiment, the first high refractive index film layer 121 is plated by sputtering reaction equipment. The material used for the first high refractive index film layer 121 is hydrogen silicide. The substrate 11 with a clean surface is placed in a sputtering reaction device, and the first high-refractive-index film layer 121 is plated on the substrate 11 in the presence of a silicon target and hydrogen gas. In this embodiment, the adjustable flow rate is introduced into the reaction equipment, the sputtering reaction temperature is 80°C-300°C, and the sputtering rate of silicide is 0.1nm/s≤v≤1nm/s. In this embodiment, the flow rate of hydrogen introduction satisfies 10 sccm≦v1≦50 sccm. Through the setting of the above conditions, the plated first high refractive index film layer 121 has good film layer characteristics, so that the first high refractive index film layer 121 reaches a higher refractive index, and further makes the near-infrared narrow-band filtering of the present invention The imaging effect of the film is better.

如图3所示,根据本发明的另一种实施方式,本发明的一种近红外窄带滤光片,包括基板11、IR膜系12和AR膜系13。在本实施方式中,IR膜系12和AR膜系13分别设置在基板11相对的两侧。IR膜系12和AR膜系13分别为多层膜构成的结构。在本实施方式中,IR膜系12包括交替镀制的第一高折射率膜层121和第一低折射率膜层122。在本实施方式中,第一高折射率膜层121的折射率大于3,第一低折射率膜层122的折射率小于3。在IR膜系12中,处于IR膜系12最外层的均为第一低折射率膜层122。AR膜系13包括交替镀制的第二高折射率膜层131和第二低折射率膜层132,第二高折射率膜层131的折射率可以大于3,也可以小于3,第二低折射率膜层132的折射率小于3,需要指出的是,第二高折射率膜层131的折射率小于3时,第二高折射率膜层131所用的材料与第二低折射率膜层132的材料不同,且第二高折射率膜层131的折射率要高于第二低折射率膜层132。在AR膜系13中,处于AR膜系13最外层(AR膜系13分别与基板11和入射介质相接触的位置)均为第二低折射率膜层132。在本实施方式中,近红外窄带滤光片的IR膜系12和AR膜系13的膜层总厚度小于9.8μm。在本实施方式中,近红外窄带滤光片的半高全宽值小于120nm。进一步的,在本实施方式中,近红外窄带滤光片的IR膜系12和AR膜系13的膜层总厚度小于8μm。在本实施方式中,近红外窄带滤光片的半高全宽值小于114nm。通过将IR膜系12和AR膜系13的外侧分别设置成第一低折射率膜层122和第二低折射率膜层132,有利于IR膜系12和AR膜系13附着在基板11上,并且其硬度高,耐磨性好,抗腐蚀性强,从而有利于保证本发明的IR膜系12和AR膜系13的结构稳定,以及提高IR膜系12和AR膜系13的使用寿命,进一步提高了本发明的红外窄带滤光片的使用寿命。同时,本发明的近红外窄带滤光片的厚度小,节约了本发明的生产成本。在本实施方式中,IR膜系12的设置结构与前述实施方式保持一致,在此不再赘述。As shown in FIG. 3 , according to another embodiment of the present invention, a near-infrared narrow-band filter of the present invention includes a substrate 11 , an IR film system 12 and an AR film system 13 . In this embodiment, the IR film system 12 and the AR film system 13 are respectively disposed on opposite sides of the substrate 11 . The IR film system 12 and the AR film system 13 are structures composed of multilayer films respectively. In this embodiment, the IR film system 12 includes first high-refractive-index film layers 121 and first low-refractive-index film layers 122 that are plated alternately. In this embodiment, the refractive index of the first high refractive index film layer 121 is greater than 3, and the refractive index of the first low refractive index film layer 122 is less than 3. In the IR film system 12 , the outermost layer of the IR film system 12 is the first low refractive index film layer 122 . The AR film system 13 includes alternately plated second high-refractive-index film layers 131 and second low-refractive-index film layers 132, the refractive index of the second high-refractive index film layer 131 can be greater than 3 or less than 3, and the second lowest The refractive index of the refractive index film layer 132 is less than 3. It should be pointed out that when the refractive index of the second high refractive index film layer 131 is less than 3, the material used for the second high refractive index film layer 131 is the same as that of the second low refractive index film layer. The materials 132 are different, and the refractive index of the second high refractive index film layer 131 is higher than that of the second low refractive index film layer 132 . In the AR film system 13 , the outermost layer of the AR film system 13 (the position where the AR film system 13 is in contact with the substrate 11 and the incident medium respectively) is the second low refractive index film layer 132 . In this embodiment, the total thickness of the IR film system 12 and the AR film system 13 of the near-infrared narrow-band filter is less than 9.8 μm. In this embodiment, the full width at half maximum of the near-infrared narrow-band filter is less than 120 nm. Further, in this embodiment, the total thickness of the IR film system 12 and the AR film system 13 of the near-infrared narrow-band filter is less than 8 μm. In this embodiment, the full width at half maximum of the near-infrared narrow-band filter is less than 114 nm. By setting the outer sides of the IR film system 12 and the AR film system 13 respectively as the first low refractive index film layer 122 and the second low refractive index film layer 132, it is beneficial for the IR film system 12 and the AR film system 13 to adhere to the substrate 11 , and its hardness is high, wear resistance is good, corrosion resistance is strong, thereby helps to guarantee the structural stability of IR film system 12 and AR film system 13 of the present invention, and improves the service life of IR film system 12 and AR film system 13 , further improving the service life of the infrared narrowband filter of the present invention. At the same time, the thickness of the near-infrared narrow-band filter of the present invention is small, which saves the production cost of the present invention. In this embodiment, the arrangement structure of the IR film system 12 is consistent with the foregoing embodiments, and will not be repeated here.

需要指出的是,IR膜系为红外截止膜,AR膜系为减反膜,即增透膜。It should be pointed out that the IR film is an infrared cut-off film, and the AR film is an anti-reflection film, that is, an anti-reflection film.

根据本发明的一种实施方式,第二低折射率膜层132的折射率小于3。在本实施方式中,第二低折射率膜层132的材料为SiO2、Nb2O5、Ta2O5、TiO2、Al2O3、ZrO2、Pr6O11、La2O3、Si2N、SiN、Si2N3、Si3N4中的一种或多种的组合。According to an embodiment of the present invention, the refractive index of the second low refractive index film layer 132 is less than 3. In this embodiment, the material of the second low refractive index film layer 132 is SiO 2 , Nb 2 O 5 , Ta 2 O 5 , TiO 2 , Al 2 O 3 , ZrO 2 , Pr 6 O 11 , La 2 O 3 , Si 2 N, SiN, Si 2 N 3 , Si 3 N 4 or a combination of one or more.

根据本发明的一种实施方式,在350~1200nm的波长范围内,由于AR膜系13通过交替镀制第二高折射率膜层131和第二低折射率膜层132,因此通过入射光的干涉效应从而产生通带区域和截止区域。在本实施方式中,AR膜系13具有一个通带区域,且其透过率大于90%,一个截止区域,且其透过率小于0.1%。在本实施方式中,在800~1200nm的波长范围内,AR膜系13中的过渡区域透过率介于0.1%~90%之间。According to one embodiment of the present invention, in the wavelength range of 350-1200nm, since the AR film system 13 is alternately coated with the second high refractive index film layer 131 and the second low refractive index film layer 132, the incident light Interference effects thus create passband regions and cutoff regions. In this embodiment, the AR film system 13 has a passband region with a transmittance greater than 90%, and a cutoff region with a transmittance of less than 0.1%. In this embodiment, within the wavelength range of 800-1200 nm, the transmittance of the transition region in the AR film system 13 is between 0.1%-90%.

如图4所示,根据本发明的一种实施方式,本发明的红外成像系统,包括IR发射系统和IR接收系统。在本实施方式中,IR发射系统包括IR发射光源2和第一镜头组件3。第一镜头组件3与IR发射光源2相对设设置,第一镜头组件3用于传输IR发射光源2发出的光并将所传输的光投射到物体A(例如人脸、手等)上。在本实施方式中,IR发射光源2为VCSEL、LD、LED中的一种。在本实施方式中,第一镜头组件3包括红外光源准直镜头31和衍射组件32。在本实施方式中,衍射组件32设置在红外光源准直镜头31上。IR发射光源2发出的光通过红外光源准直镜头31进行校正准直,并且经过准直的光通过衍射组件32投射到物体上。As shown in FIG. 4 , according to an embodiment of the present invention, the infrared imaging system of the present invention includes an IR emitting system and an IR receiving system. In this embodiment, the IR emitting system includes an IR emitting light source 2 and a first lens assembly 3 . The first lens assembly 3 is arranged opposite to the IR emitting light source 2, and the first lens assembly 3 is used to transmit the light emitted by the IR emitting light source 2 and project the transmitted light onto an object A (such as a human face, a hand, etc.). In this embodiment, the IR emitting light source 2 is one of VCSEL, LD, and LED. In this embodiment, the first lens assembly 3 includes an infrared light source collimating lens 31 and a diffraction assembly 32 . In this embodiment, the diffraction component 32 is arranged on the infrared light source collimating lens 31 . The light emitted by the IR emitting light source 2 is corrected and collimated through the infrared light source collimating lens 31 , and the collimated light is projected onto the object through the diffraction component 32 .

根据本发明的一种实施方式,IR接收系统包括近红外窄带滤光片1、第二镜头组件4和红外图像传感器5。在本实施方式中,红外窄带滤光片1位于第二镜头组件4和红外图像传感器5之间。第二镜头组件4可以为普通镜头。物体上的光线被传输到第二镜头组件4中,第二镜头组件4镜接收的光线传输到红外窄带滤光片1,经过红外窄带滤光片1的作用使光线投射到红外图像传感器5上进行成像。在本实施方式中,红外图像传感器5为3D红外图像传感器。在本实施方式中,红外图像传感器5通过复杂的算法,包括但不限于结构光(Structured light)、TOF和双目测距法等3D成像算法模式,将第二镜头组件4采集的空间信息和镜头成像端采集的色彩信息相结合,生成具备空间信息的3D图像,进行人脸识别、手势识别等。According to an embodiment of the present invention, the IR receiving system includes a near-infrared narrow-band filter 1 , a second lens assembly 4 and an infrared image sensor 5 . In this embodiment, the infrared narrowband filter 1 is located between the second lens assembly 4 and the infrared image sensor 5 . The second lens assembly 4 can be an ordinary lens. The light on the object is transmitted to the second lens assembly 4, and the light received by the second lens assembly 4 is transmitted to the infrared narrow-band filter 1, and the light is projected onto the infrared image sensor 5 through the action of the infrared narrow-band filter 1 for imaging. In this embodiment, the infrared image sensor 5 is a 3D infrared image sensor. In this embodiment, the infrared image sensor 5 combines the spatial information collected by the second lens assembly 4 and The color information collected by the lens imaging end is combined to generate a 3D image with spatial information for face recognition, gesture recognition, etc.

为进一步说明本发明,对本发明的近红外窄带滤光片进行举例说明。In order to further illustrate the present invention, the near-infrared narrow-band filter of the present invention is illustrated.

实施例1:Example 1:

第一高折射率膜层121和第一低折射率膜层122交替镀制形成近红外窄带滤光片的IR膜系。在本实施方式中,第一高折射率膜层121采用氢化硅(Si:H)材料,第一低折射率膜层122采用氮化硅(即SiN)材料,以L(HL)m形式交替排列组成滤光片IR带通膜系;其中,L表示第一低折射率膜层122以1/4参考波长厚度的高,H表示第一高折射率膜层121以1/4参考波长厚度的高,m表示交替镀制的次数。The first high-refractive-index film layer 121 and the first low-refractive-index film layer 122 are alternately plated to form an IR film system of a near-infrared narrow-band filter. In this embodiment, the first high refractive index film layer 121 is made of hydrogenated silicon (Si:H) material, and the first low refractive index film layer 122 is made of silicon nitride (ie SiN) material, alternately in the form of L(HL) m Arrange to form the filter IR band-pass film system; wherein, L represents the height of the first low refractive index film layer 122 with a thickness of 1/4 reference wavelength, and H represents the thickness of the first high refractive index film layer 121 with a reference wavelength of 1/4 The height, m represents the number of alternate plating.

在本实施方式中,在入射角从0°改变至10°的范围内,通带波段的中心波长漂移幅度介于0.5nm~1.5nm之间,入射角每变化1°,通带波段的中心波长漂移幅度小于1.5nm。In this embodiment, within the range where the incident angle changes from 0° to 10°, the central wavelength shift range of the passband band is between 0.5nm and 1.5nm, and every time the incident angle changes by 1°, the center wavelength of the passband band The amplitude of wavelength shift is less than 1.5nm.

在本实施方式中,在入射角从0°改变至20°的范围内,通带波段的中心波长漂移幅度介于2.5nm~8nm之间,从10°改变至20°的范围内,入射角每变化1°,通带波段的中心波长漂移幅度小于6nm。In this embodiment, within the range where the incident angle changes from 0° to 20°, the central wavelength shift amplitude of the passband band is between 2.5nm and 8nm, and within the range where the incident angle changes from 10° to 20°, the incident angle For every 1° change, the central wavelength shift of the passband band is less than 6nm.

在本实施方式中,在入射角从0°改变至30°的范围内,通带波段的中心波长漂移幅度介于8nm~12nm之间,从20°改变至30°的范围内,入射角每变化1°,通带波段的中心波长漂移幅度小于5nm。In this embodiment, within the range where the incident angle changes from 0° to 30°, the central wavelength shift range of the passband band is between 8nm and 12nm, and within the range where the incident angle changes from 20° to 30°, every With a change of 1°, the central wavelength shift of the passband band is less than 5nm.

在本实施方式中,在入射角从0°改变至40°的范围内,通带波段的中心波长漂移幅度介于12nm~20nm之间,从0°改变至10°的范围内,入射角每变化1°,通带波段的中心波长漂移幅度小于8nm。In this embodiment, when the incident angle changes from 0° to 40°, the central wavelength shift range of the passband band is between 12nm and 20nm; within the range from 0° to 10°, the incident angle With a change of 1°, the central wavelength shift of the passband band is less than 8nm.

通过采用以下计算公式:By using the following calculation formula:

OTi=OT0(1+Acos(2×pi×f×i)sin(2×pi×f×i)),OT i =OT 0 (1+Acos(2×pi×f×i)sin(2×pi×f×i)),

其中,OTi表示第i层膜层的光学厚度,OT0表示四分之一设计波长大小的光学厚度,pi表示圆周率,f表示调制因子,大小介于0到1之间。Among them, OT i represents the optical thickness of the i-th film layer, OT 0 represents the optical thickness of a quarter of the design wavelength, pi represents the circumference ratio, and f represents the modulation factor, which is between 0 and 1.

代入一下方程:Substitute into the equation:

获得膜层参数如下:The obtained film layer parameters are as follows:

11 22 33 44 55 膜料film material SiNSiN Si:HSi:H SiNSiN Si:HSi:H SiNSiN 厚度/nmThickness/nm 3030 232.89232.89 152.83152.83 118.43118.43 73.6173.61 66 77 88 99 1010 膜料film material Si:HSi:H SiNSiN Si:HSi:H SiNSiN Si:HSi:H 厚度/nmThickness/nm 82.6782.67 110.81110.81 125.06125.06 143.63143.63 241.24241.24 1111 1212 1313 1414 1515 膜料film material SiNSiN Si:HSi:H SiNSiN Si:HSi:H SiNSiN 厚度/nmThickness/nm 79.4879.48 150.7150.7 56.1856.18 232.67232.67 103.84103.84 1616 1717 1818 1919 2020 膜料film material Si:HSi:H SiNSiN Si:HSi:H SiNSiN Si:HSi:H 厚度/nmThickness/nm 244.31244.31 313.36313.36 272.26272.26 76.2976.29 73.3973.39 21twenty one 22twenty two 23twenty three 24twenty four 2525 膜料film material SiNSiN Si:HSi:H SiNSiN Si:HSi:H SiNSiN 厚度/nmThickness/nm 371.49371.49 84.7284.72 26.2126.21 288.09288.09 122.32122.32 2626 2727 2828 2929 3030 膜料film material Si:HSi:H SiNSiN Si:HSi:H SiNSiN Si:HSi:H 厚度/nmThickness/nm 66.866.8 382.21382.21 142.68142.68 191.9191.9 262.73262.73 3131 3232 3333 3434 3535 膜料film material SiNSiN Si:HSi:H SiNSiN Si:HSi:H SiNSiN 厚度/nmThickness/nm 118.05118.05 64.9864.98 376.7376.7 167.58167.58 27.727.7

表1Table 1

如图5所示,以及通过上述计算结果(即表1中代表的IR膜系厚度即IR膜系镀制的物理厚度,单位:nm),在本实施方式中,在满足IR膜层透过率的条件下,取m=17,IR膜系的总厚度为5.61μm,从而使本发明的IR膜系厚度满足设计要求,同时还保证了在不同入射角的条件下,IR膜系通带波段上中心波长漂移幅度也满足上述设计要求,并且IR膜系在800~1200nm范围内有一个通带波段,透过率大于90%;通带波段带宽小于120nm;通带两侧各有1个截止波段,其透过率小于0.1%,更低的透过率可小于0.001%,保证了本发明的近红外滤光片的成像质量。As shown in Figure 5, and through the above calculation results (that is, the thickness of the IR film system represented in Table 1, that is, the physical thickness of the IR film system plating, unit: nm), in this embodiment, when the IR film layer is passed through Under the condition of the ratio of m=17, the total thickness of the IR film system is 5.61 μm, so that the thickness of the IR film system of the present invention meets the design requirements, and it also ensures that the passband of the IR film system under the conditions of different incident angles The central wavelength drift on the band also meets the above design requirements, and the IR film has a passband in the range of 800-1200nm, and the transmittance is greater than 90%; the bandwidth of the passband is less than 120nm; there is one on each side of the passband In the cut-off band, the transmittance is less than 0.1%, and the lower transmittance can be less than 0.001%, which ensures the imaging quality of the near-infrared filter of the present invention.

实施例2:Example 2:

第一高折射率膜层121和第一低折射率膜层122交替镀制形成近红外窄带滤光片的IR膜系。在本实施方式中,第一高折射率膜层121采用氢化硅(Si:H)材料,第一低折射率膜层122采用氮化硅(即Si3N4)材料,以L(HL)m形式交替排列组成滤光片IR带通膜系;其中,L表示第一低折射率膜层122以1/4参考波长厚度的高,H表示第一高折射率膜层121以1/4参考波长厚度的高,m表示交替镀制的次数。The first high-refractive-index film layer 121 and the first low-refractive-index film layer 122 are alternately plated to form an IR film system of a near-infrared narrow-band filter. In this embodiment, the first high refractive index film layer 121 is made of hydrogenated silicon (Si:H) material, and the first low refractive index film layer 122 is made of silicon nitride (ie Si 3 N 4 ) material. m forms are alternately arranged to form the filter IR bandpass film system; wherein, L represents the thickness of the first low refractive index film layer 122 at 1/4 of the reference wavelength, and H represents the thickness of the first high refractive index film layer 121 at 1/4 Referring to the height of the wavelength thickness, m represents the number of times of alternate plating.

在本实施方式中,在入射角从0°改变至10°的范围内,通带波段的中心波长漂移幅度介于0.5nm~1.5nm之间,入射角每变化1°,通带波段的中心波长漂移幅度小于1.5nm。In this embodiment, within the range where the incident angle changes from 0° to 10°, the central wavelength shift range of the passband band is between 0.5nm and 1.5nm, and every time the incident angle changes by 1°, the center wavelength of the passband band The amplitude of wavelength shift is less than 1.5nm.

在本实施方式中,在入射角从0°改变至20°的范围内,通带波段的中心波长漂移幅度介于2.5nm~8nm之间,从10°改变至20°的范围内,入射角每变化1°,通带波段的中心波长漂移幅度小于6nm。In this embodiment, within the range of the incident angle changing from 0° to 20°, the central wavelength shift amplitude of the passband band is between 2.5nm and 8nm, and within the range of changing from 10° to 20°, the incident angle For every 1° change, the central wavelength shift of the passband band is less than 6nm.

在本实施方式中,在入射角从0°改变至30°的范围内,通带波段的中心波长漂移幅度介于8nm~12nm之间,从20°改变至30°的范围内,入射角每变化1°,通带波段的中心波长漂移幅度小于5nm。In this embodiment, within the range where the incident angle changes from 0° to 30°, the center wavelength shift range of the passband band is between 8nm and 12nm, and within the range where the incident angle changes from 20° to 30°, every With a change of 1°, the central wavelength shift of the passband band is less than 5nm.

在本实施方式中,在入射角从0°改变至40°的范围内,通带波段的中心波长漂移幅度介于12nm~20nm之间,从0°改变至10°的范围内,入射角每变化1°,通带波段的中心波长漂移幅度小于8nm。In this embodiment, when the incident angle changes from 0° to 40°, the central wavelength shift range of the passband band is between 12nm and 20nm; within the range from 0° to 10°, the incident angle With a change of 1°, the central wavelength shift of the passband band is less than 8nm.

通过采用以下计算公式:By using the following calculation formula:

OTi=OT0(1+Acos(2×pi×f×i)sin(2×pi×f×i)),OT i =OT 0 (1+Acos(2×pi×f×i)sin(2×pi×f×i)),

其中,OTi表示第i层膜层的光学厚度,OT0表示四分之一设计波长大小的光学厚度,pi表示圆周率,f表示调制因子,大小介于0到1之间。Among them, OT i represents the optical thickness of the i-th film layer, OT 0 represents the optical thickness of a quarter of the design wavelength, pi represents the circumference ratio, and f represents the modulation factor, which is between 0 and 1.

代入一下方程:Substitute into the equation:

获得膜层参数如下:The obtained film layer parameters are as follows:

11 22 33 44 55 膜料film material Si3N4Si3N4 Si:HSi:H Si3N4Si3N4 Si:HSi:H Si3N4Si3N4 膜厚film thickness 234.05234.05 73.1273.12 193.41193.41 79.5879.58 113.2113.2 66 77 88 99 1010 膜料film material Si:HSi:H Si3N4Si3N4 Si:HSi:H Si3N4Si3N4 Si:HSi:H 膜厚film thickness 196.33196.33 111.74111.74 100.62100.62 8686 115.42115.42 1111 1212 1313 1414 1515 膜料film material Si3N4Si3N4 Si:HSi:H Si3N4Si3N4 Si:HSi:H Si3N4Si3N4 膜厚film thickness 107107 64.4464.44 112.56112.56 64.9864.98 107.61107.61 1616 1717 1818 1919 2020 膜料film material Si:HSi:H Si3N4Si3N4 Si:HSi:H Si3N4Si3N4 Si:HSi:H 膜厚film thickness 128.77128.77 64.3164.31 87.5487.54 111.36111.36 199.79199.79 21twenty one 22twenty two 23twenty three 24twenty four 2525 膜料film material Si3N4Si3N4 Si:HSi:H Si3N4Si3N4 Si:HSi:H Si3N4Si3N4 膜厚film thickness 114.06114.06 151.56151.56 63.5163.51 277.82277.82 109.72109.72 2626 2727 2828 2929 3030 膜料film material Si:HSi:H Si3N4Si3N4 Si:HSi:H Si3N4Si3N4 Si:HSi:H 膜厚film thickness 66.1566.15 106.45106.45 365365 340.12340.12 78.7778.77 3131 3232 3333 3434 3535 膜料film material Si3N4Si3N4 Si:HSi:H Si3N4Si3N4 Si:HSi:H Si3N4Si3N4 膜厚film thickness 110.3110.3 226.9226.9 110.56110.56 95.1995.19 45.3845.38

表2Table 2

如图6所示,以及通过上述计算结果(即表2中代表的IR膜系厚度即IR膜系镀制的物理厚度,单位:nm),在本实施方式中,在满足IR膜层透过率的条件下,取m=17,IR膜系的总厚度为4.62μm,从而使本发明的IR膜系厚度满足设计要求,同时还保证了在不同入射角的条件下,IR膜系通带波段上中心波长漂移幅度也满足上述设计要求,并且IR膜系在800~1200nm范围内有一个通带波段,透过率大于90%;通带波段带宽小于120nm;通带两侧各有1个截止波段,其透过率小于0.1%,更低的透过率可小于0.001%,保证了本发明的近红外滤光片的成像质量。As shown in Figure 6, and through the above calculation results (that is, the thickness of the IR film system represented in Table 2, that is, the physical thickness of the IR film system plating, unit: nm), in this embodiment, when the IR film layer is satisfied Under the condition of the ratio of m=17, the total thickness of the IR film system is 4.62 μm, so that the thickness of the IR film system of the present invention meets the design requirements, and it also ensures that the passband of the IR film system under the conditions of different incident angles The central wavelength drift on the band also meets the above design requirements, and the IR film has a passband in the range of 800-1200nm, and the transmittance is greater than 90%; the bandwidth of the passband is less than 120nm; there is one on each side of the passband In the cut-off band, the transmittance is less than 0.1%, and the lower transmittance can be less than 0.001%, which ensures the imaging quality of the near-infrared filter of the present invention.

实施例3:Example 3:

第一高折射率膜层121和第一低折射率膜层122交替镀制形成近红外窄带滤光片的IR膜系。在本实施方式中,第一高折射率膜层121采用氢化硅(Si:H)材料,第一低折射率膜层122采用混合材料,如氮化硅(即SiN)和二氧化硅(SiO2)混合材料,或者氮化硅(即SiN和Si3N4)混合材料,以L(HL)m形式交替排列组成滤光片IR带通膜系;其中,L表示第一低折射率膜层122以1/4参考波长厚度的高,H表示第一高折射率膜层121以1/4参考波长厚度的高,m表示交替镀制的次数。The first high-refractive-index film layer 121 and the first low-refractive-index film layer 122 are alternately plated to form an IR film system of a near-infrared narrow-band filter. In this embodiment, the first high refractive index film layer 121 is made of hydrogenated silicon (Si:H) material, and the first low refractive index film layer 122 is made of mixed materials, such as silicon nitride (SiN) and silicon dioxide (SiO 2 ) Mixed materials, or silicon nitride (ie SiN and Si 3 N 4 ) mixed materials, alternately arranged in the form of L(HL) m to form an IR band-pass film system for filters; where L represents the first low refractive index film The height of the layer 122 is 1/4 of the reference wavelength thickness, H represents the height of the first high refractive index film layer 121 of 1/4 reference wavelength thickness, and m represents the number of times of alternate plating.

在本实施方式中,在入射角从0°改变至10°的范围内,通带波段的中心波长漂移幅度介于0.5nm~1.5nm之间,入射角每变化1°,通带波段的中心波长漂移幅度小于1.5nm。In this embodiment, within the range where the incident angle changes from 0° to 10°, the central wavelength shift range of the passband band is between 0.5nm and 1.5nm, and every time the incident angle changes by 1°, the center wavelength of the passband band The amplitude of wavelength shift is less than 1.5nm.

在本实施方式中,在入射角从0°改变至20°的范围内,通带波段的中心波长漂移幅度介于2.5nm~8nm之间,从10°改变至20°的范围内,入射角每变化1°,通带波段的中心波长漂移幅度小于6nm。In this embodiment, within the range where the incident angle changes from 0° to 20°, the central wavelength shift amplitude of the passband band is between 2.5nm and 8nm, and within the range where the incident angle changes from 10° to 20°, the incident angle For every 1° change, the central wavelength shift of the passband band is less than 6nm.

在本实施方式中,在入射角从0°改变至30°的范围内,通带波段的中心波长漂移幅度介于8nm~12nm之间,从20°改变至30°的范围内,入射角每变化1°,通带波段的中心波长漂移幅度小于5nm。In this embodiment, within the range where the incident angle changes from 0° to 30°, the center wavelength shift range of the passband band is between 8nm and 12nm, and within the range where the incident angle changes from 20° to 30°, every With a change of 1°, the central wavelength shift of the passband band is less than 5nm.

在本实施方式中,在入射角从0°改变至40°的范围内,通带波段的中心波长漂移幅度介于12nm~20nm之间,从0°改变至10°的范围内,入射角每变化1°,通带波段的中心波长漂移幅度小于8nm。In this embodiment, when the incident angle changes from 0° to 40°, the central wavelength shift range of the passband band is between 12nm and 20nm; within the range from 0° to 10°, the incident angle With a change of 1°, the central wavelength shift of the passband band is less than 8nm.

通过采用以下计算公式:By using the following calculation formula:

OTi=OT0(1+Acos(2×pi×f×i)sin(2×pi×f×i)),OT i =OT 0 (1+Acos(2×pi×f×i)sin(2×pi×f×i)),

其中,OTi表示第i层膜层的光学厚度,OT0表示四分之一设计波长大小的光学厚度,pi表示圆周率,f表示调制因子,大小介于0到1之间。Among them, OT i represents the optical thickness of the i-th film layer, OT 0 represents the optical thickness of a quarter of the design wavelength, pi represents the circumference ratio, and f represents the modulation factor, which is between 0 and 1.

代入一下方程:Substitute into the equation:

获得膜层参数如下:The obtained film layer parameters are as follows:

表3table 3

如图7所示,以及通过上述计算结果(即表3中代表的IR膜系厚度即IR膜系镀制的物理厚度,单位:nm,并且Mixture表示混合材料),在本实施方式中,在满足IR膜层透过率的条件下,取m=16,IR膜系的总厚度为5.11μm,从而使本发明的IR膜系厚度满足设计要求,同时还保证了在不同入射角的条件下,IR膜系通带波段上中心波长漂移幅度也满足上述设计要求,并且IR膜系在800~1200nm范围内有一个通带波段,透过率大于90%;通带波段带宽小于120nm;通带两侧各有1个截止波段,其透过率小于0.1%,更低的透过率可小于0.001%,保证了本发明的近红外滤光片的成像质量。As shown in Figure 7, and through the above calculation results (that is, the thickness of the IR film system represented in Table 3, that is, the physical thickness of the IR film system plating, unit: nm, and Mixture represents the mixed material), in this embodiment, in Under the condition of satisfying the transmittance of the IR film layer, m=16 is taken, and the total thickness of the IR film system is 5.11 μm, so that the thickness of the IR film system of the present invention meets the design requirements, and it also ensures that under the conditions of different incident angles , the central wavelength drift on the passband band of the IR film system also meets the above design requirements, and the IR film system has a passband band in the range of 800-1200nm, and the transmittance is greater than 90%; the bandwidth of the passband band is less than 120nm; There is a cut-off band on both sides, and its transmittance is less than 0.1%, and the lower transmittance can be less than 0.001%, which ensures the imaging quality of the near-infrared filter of the present invention.

实施例4:Example 4:

第一高折射率膜层121和第一低折射率膜层122交替镀制形成近红外窄带滤光片的IR膜系。在本实施方式中,第一高折射率膜层121采用氢化硅(Si:H)材料,第一低折射率膜层122采用二氧化硅(SiO2)材料,以(LH)mL形式交替排列组成滤光片IR带通膜系;其中,L表示第一低折射率膜层122以1/4参考波长厚度的高,H表示第一高折射率膜层121以1/4参考波长厚度的高,m表示交替镀制的次数。The first high-refractive-index film layer 121 and the first low-refractive-index film layer 122 are alternately plated to form an IR film system of a near-infrared narrow-band filter. In this embodiment, the first high refractive index film layer 121 is made of hydrogenated silicon (Si:H) material, and the first low refractive index film layer 122 is made of silicon dioxide (SiO 2 ) material, alternately in the form of (LH) m L Arrange to form the filter IR band-pass film system; wherein, L represents the height of the first low refractive index film layer 122 with a thickness of 1/4 reference wavelength, and H represents the thickness of the first high refractive index film layer 121 with a reference wavelength of 1/4 The height, m represents the number of alternate plating.

第二高折射率膜层131和第二低折射率膜层132交替镀制形成近红外窄带滤光片的AR膜系。在本实施方式中,第二高折射率膜层131采用五氧化二铌(Nb2O5)材料,第二低折射率膜层132采用二氧化硅(SiO2)材料(需要指出的是,由于五氧化二铌(Nb2O5)的折射率高于二氧化硅(SiO2)的折射率,因此五氧化二铌(Nb2O5)也可作为第二高折射率膜层131的材料。),以(LH)sL形式交替排列组成滤光片AR带通膜系;其中,L表示第二低折射率膜层132以1/4参考波长厚度的高,H表示第二高折射率膜层131以1/4参考波长厚度的高,s表示交替镀制的次数。The second high-refractive-index film layer 131 and the second low-refractive-index film layer 132 are alternately plated to form an AR film system of a near-infrared narrow-band filter. In this embodiment, the second high refractive index film layer 131 is made of niobium pentoxide (Nb 2 O 5 ) material, and the second low refractive index film layer 132 is made of silicon dioxide (SiO 2 ) material (it should be noted that Since the refractive index of niobium pentoxide (Nb 2 O 5 ) is higher than that of silicon dioxide (SiO 2 ), niobium pentoxide (Nb 2 O 5 ) can also be used as the second high refractive index film layer 131. material.), alternately arranged in the form of (LH) s L to form the filter AR bandpass film system; wherein, L represents the height of the second low refractive index film layer 132 with a thickness of 1/4 reference wavelength, and H represents the second highest The thickness of the refractive index film layer 131 is 1/4 of the reference wavelength, and s represents the number of times of alternate plating.

在本实施方式中,在入射角从0°改变至10°的范围内,通带波段的中心波长漂移幅度介于0.5nm~1.5nm之间,入射角每变化1°,通带波段的中心波长漂移幅度小于1.5nm。In this embodiment, within the range where the incident angle changes from 0° to 10°, the central wavelength shift range of the passband band is between 0.5nm and 1.5nm, and every time the incident angle changes by 1°, the center wavelength of the passband band The amplitude of wavelength shift is less than 1.5nm.

在本实施方式中,在入射角从0°改变至20°的范围内,通带波段的中心波长漂移幅度介于2.5nm~8nm之间,从10°改变至20°的范围内,入射角每变化1°,通带波段的中心波长漂移幅度小于6nm。In this embodiment, within the range where the incident angle changes from 0° to 20°, the central wavelength shift amplitude of the passband band is between 2.5nm and 8nm, and within the range where the incident angle changes from 10° to 20°, the incident angle For every 1° change, the central wavelength shift of the passband band is less than 6nm.

在本实施方式中,在入射角从0°改变至30°的范围内,通带波段的中心波长漂移幅度介于8nm~12nm之间,从20°改变至30°的范围内,入射角每变化1°,通带波段的中心波长漂移幅度小于5nm。In this embodiment, within the range where the incident angle changes from 0° to 30°, the center wavelength shift range of the passband band is between 8nm and 12nm, and within the range where the incident angle changes from 20° to 30°, every With a change of 1°, the central wavelength shift of the passband band is less than 5nm.

在本实施方式中,在入射角从0°改变至40°的范围内,通带波段的中心波长漂移幅度介于12nm~20nm之间,从0°改变至10°的范围内,入射角每变化1°,通带波段的中心波长漂移幅度小于8nm。In this embodiment, when the incident angle changes from 0° to 40°, the central wavelength shift range of the passband band is between 12nm and 20nm; within the range from 0° to 10°, the incident angle With a change of 1°, the central wavelength shift of the passband band is less than 8nm.

通过采用以下计算公式:By using the following calculation formula:

OTi=OT0(1+Acos(2×pi×f×i)sin(2×pi×f×i)),OT i =OT 0 (1+Acos(2×pi×f×i)sin(2×pi×f×i)),

其中,OTi表示第i层膜层的光学厚度,OT0表示四分之一设计波长大小的光学厚度,pi表示圆周率,f表示调制因子,大小介于0到1之间。Among them, OT i represents the optical thickness of the i-th film layer, OT 0 represents the optical thickness of a quarter of the design wavelength, pi represents the circumference ratio, and f represents the modulation factor, which is between 0 and 1.

代入一下方程:Substitute into the equation:

获得膜层参数如下:The obtained film parameters are as follows:

表4Table 4

11 22 33 44 55 材料Material SiO2 SiO 2 Nb2O5 Nb 2 O 5 SiO2 SiO 2 Nb2O5 Nb 2 O 5 SiO2 SiO 2 厚度(nm)Thickness (nm) 177.36177.36 29.0129.01 86.2486.24 34.2634.26 137.61137.61 66 77 88 99 1010 材料Material Nb2O5 Nb 2 O 5 SiO2 SiO 2 Nb2O5 Nb 2 O 5 SiO2 SiO 2 Nb2O5 Nb 2 O 5 厚度(nm)Thickness (nm) 42.5742.57 105.57105.57 32.6332.63 124.57124.57 39.3839.38 1111 1212 1313 1414 1515 材料Material SiO2 SiO 2 Nb2O5 Nb 2 O 5 SiO2 SiO 2 Nb2O5 Nb 2 O 5 SiO2 SiO 2 厚度(nm)Thickness (nm) 127.56127.56 36.3836.38 121.12121.12 36.3836.38 123.16123.16 1616 1717 1818 1919 2020 材料Material Nb2O5 Nb 2 O 5 SiO2 SiO 2 Nb2O5 Nb 2 O 5 SiO2 SiO 2 Nb2O5 Nb 2 O 5 厚度(nm)Thickness (nm) 31.731.7 132.74132.74 44.244.2 128.03128.03 27.6927.69 21twenty one 22twenty two 23twenty three 24twenty four 2525 材料Material SiO2 SiO 2 Nb2O5 Nb 2 O 5 SiO2 SiO 2 Nb2O5 Nb 2 O 5 SiO2 SiO 2 厚度(nm)Thickness (nm) 110.12110.12 44.0144.01 131.96131.96 36.7636.76 76.9876.98

表5table 5

结合图8和图9所示,以及通过上述计算结果(即表4中代表的IR膜层厚度即IR膜系镀制的物理厚度(单位:nm)和表5中代表的AR膜层厚度即AR膜系镀制的物理厚度(单位:nm)),在本实施方式中,在满足IR膜层透过率和AR膜层透过率的条件下,取m=15,s=12,IR膜系和AR膜系的总厚度分别为5.19μm和2.02μm,从而使本发明的IR膜系和AR膜系厚度均满足设计要求,同时还保证了在不同入射角的条件下,IR膜系通带波段上中心波长漂移幅度也满足上述设计要求,并且IR膜系在800~1200nm范围内有一个通带波段,透过率大于90%;通带波段带宽小于400nm;有2个截止波段,分别在通带两侧,其透过率小于0.1%,AR膜系在350~1200nm范围内有一个通带区域,一个截至区域,透过率分别大于90%和小于0.1%;在800~1200存在一个过渡区域,透过率介于0.1%~90%之间,保证了本发明的近红外滤光片的成像质量。Shown in conjunction with Fig. 8 and Fig. 9, and through above-mentioned calculation result (being the physical thickness (unit: nm) of the IR film system coating of representative IR film thickness in Table 4 and the AR film thickness of representative in Table 5 namely AR film system plated physical thickness (unit: nm)), in the present embodiment, under the condition that satisfies IR film transmittance and AR film transmittance, get m=15, s=12, IR The total thicknesses of the film system and the AR film system are 5.19 μm and 2.02 μm respectively, so that the thicknesses of the IR film system and the AR film system of the present invention all meet the design requirements, and at the same time ensure that the IR film system is The central wavelength drift on the passband band also meets the above design requirements, and the IR film has a passband band in the range of 800-1200nm, and the transmittance is greater than 90%; the bandwidth of the passband band is less than 400nm; there are 2 cut-off bands, On both sides of the passband, the transmittance is less than 0.1%. The AR film system has a passband area and a cut-off area in the range of 350-1200nm, and the transmittance is greater than 90% and less than 0.1%. There is a transition region, and the transmittance is between 0.1% and 90%, which ensures the imaging quality of the near-infrared filter of the present invention.

实施例5:Example 5:

第一高折射率膜层121和第一低折射率膜层122交替镀制形成近红外窄带滤光片的IR膜系。在本实施方式中,第一高折射率膜层121采用氢化硅(Si:H)材料,第一低折射率膜层122采用二氧化硅(SiO2)材料,以(LH)mL形式交替排列组成滤光片IR带通膜系;其中,L表示第一低折射率膜层122以1/4参考波长厚度的高,H表示第一高折射率膜层121以1/4参考波长厚度的高,m表示交替镀制的次数。The first high-refractive-index film layer 121 and the first low-refractive-index film layer 122 are alternately plated to form an IR film system of a near-infrared narrow-band filter. In this embodiment, the first high refractive index film layer 121 is made of hydrogenated silicon (Si:H) material, and the first low refractive index film layer 122 is made of silicon dioxide (SiO 2 ) material, alternately in the form of (LH) m L Arrange to form the filter IR band-pass film system; wherein, L represents the height of the first low refractive index film layer 122 with a thickness of 1/4 reference wavelength, and H represents the thickness of the first high refractive index film layer 121 with a reference wavelength of 1/4 The height, m represents the number of alternate plating.

第二高折射率膜层131和第二低折射率膜层132交替镀制形成近红外窄带滤光片的AR膜系。在本实施方式中,第二高折射率膜层131采用氢化硅(Si:H)材料,第二低折射率膜层132采用二氧化硅(SiO2)材料,以(LH)sL形式交替排列组成滤光片AR带通膜系;其中,L表示第二低折射率膜层132以1/4参考波长厚度的高,H表示第二高折射率膜层131以1/4参考波长厚度的高,s表示交替镀制的次数。The second high-refractive-index film layer 131 and the second low-refractive-index film layer 132 are alternately plated to form an AR film system of a near-infrared narrow-band filter. In this embodiment, the second high refractive index film layer 131 is made of hydrogenated silicon (Si:H) material, and the second low refractive index film layer 132 is made of silicon dioxide (SiO 2 ) material, alternately in the form of (LH) s L Arrange to form the filter AR band-pass film system; wherein, L represents the height of the second low refractive index film layer 132 with a thickness of 1/4 reference wavelength, and H represents the thickness of the second high refractive index film layer 131 with a reference wavelength of 1/4 The high, s represents the number of alternate plating.

在本实施方式中,在入射角从0°改变至10°的范围内,通带波段的中心波长漂移幅度介于0.5nm~1.5nm之间,入射角每变化1°,通带波段的中心波长漂移幅度小于1.5nm。In this embodiment, within the range where the incident angle changes from 0° to 10°, the central wavelength shift range of the passband band is between 0.5nm and 1.5nm, and every time the incident angle changes by 1°, the center wavelength of the passband band The amplitude of wavelength shift is less than 1.5nm.

在本实施方式中,在入射角从0°改变至20°的范围内,通带波段的中心波长漂移幅度介于2.5nm~8nm之间,从10°改变至20°的范围内,入射角每变化1°,通带波段的中心波长漂移幅度小于6nm。In this embodiment, within the range where the incident angle changes from 0° to 20°, the central wavelength shift amplitude of the passband band is between 2.5nm and 8nm, and within the range where the incident angle changes from 10° to 20°, the incident angle For every 1° change, the central wavelength shift of the passband band is less than 6nm.

在本实施方式中,在入射角从0°改变至30°的范围内,通带波段的中心波长漂移幅度介于8nm~12nm之间,从20°改变至30°的范围内,入射角每变化1°,通带波段的中心波长漂移幅度小于5nm。In this embodiment, within the range where the incident angle changes from 0° to 30°, the central wavelength shift range of the passband band is between 8nm and 12nm, and within the range where the incident angle changes from 20° to 30°, every With a change of 1°, the central wavelength shift of the passband band is less than 5nm.

在本实施方式中,在入射角从0°改变至40°的范围内,通带波段的中心波长漂移幅度介于12nm~20nm之间,从0°改变至10°的范围内,入射角每变化1°,通带波段的中心波长漂移幅度小于8nm。In this embodiment, when the incident angle changes from 0° to 40°, the central wavelength shift range of the passband band is between 12nm and 20nm; within the range from 0° to 10°, the incident angle With a change of 1°, the central wavelength shift of the passband band is less than 8nm.

通过采用以下计算公式:By using the following calculation formula:

OTi=OT0(1+Acos(2×pi×f×i)sin(2×pi×f×i)),OT i =OT 0 (1+Acos(2×pi×f×i)sin(2×pi×f×i)),

其中,OTi表示第i层膜层的光学厚度,OT0表示四分之一设计波长大小的光学厚度,pi表示圆周率,f表示调制因子,大小介于0到1之间。Among them, OT i represents the optical thickness of the i-th film layer, OT 0 represents the optical thickness of a quarter of the design wavelength, pi represents the circumference ratio, and f represents the modulation factor, which is between 0 and 1.

代入一下方程:Substitute this into the equation:

获得膜层参数如下:The obtained film parameters are as follows:

表6Table 6

11 22 33 44 55 膜料film material SiO2SiO2 Si:HSi:H SiO2SiO2 Si:HSi:H SiO2SiO2 膜厚film thickness 118.99118.99 144.41144.41 121.91121.91 40.9840.98 99.7699.76 66 77 88 99 1010 膜料film material Si:HSi:H SiO2SiO2 Si:HSi:H SiO2SiO2 Si:HSi:H 膜厚film thickness 38.1338.13 108.77108.77 46.7646.76 96.7296.72 4040 1111 1212 1313 1414 1515 膜料film material SiO2SiO2 Si:HSi:H SiO2SiO2 Si:HSi:H SiO2SiO2 膜厚film thickness 21twenty one 105105 114.2114.2 162.36162.36 134.9134.9 1616 1717 1818 1919 2020 膜料film material Si:HSi:H SiO2SiO2 Si:HSi:H SiO2SiO2 Si:HSi:H 膜厚film thickness 2020 2020 2020 86.7386.73 41.2441.24 21twenty one 22twenty two 23twenty three 24twenty four 2525 膜料film material SiO2SiO2 Si:HSi:H SiO2SiO2 Si:HSi:H SiO2SiO2 膜厚film thickness 117.94117.94 60.0560.05 45.6545.65 53.8953.89 139.6139.6

表7Table 7

结合图10和图11所示,以及通过上述计算结果(即表6中代表的IR膜层厚度即IR膜系镀制的物理厚度(单位:nm)和表7中代表的AR膜层厚度即AR膜系镀制的物理厚度(单位:nm)),在本实施方式中,在满足IR膜层透过率和AR膜层透过率的条件下,取m=10,s=12,IR膜系和AR膜系的总厚度分别为3.16μm和2μm,从而使本发明的IR膜系和AR膜系厚度均满足设计要求,并且IR膜系在800~1200nm范围内有一个通带波段,透过率大于90%;通带波段带宽小于400nm;有2个截止波段,分别在通带两侧,其透过率小于0.1%,AR膜系在350~1200nm范围内有一个通带区域,一个截至区域,透过率分别大于90%和小于0.1%;在800~1200存在一个过渡区域,透过率介于0.1%~90%之间,同时还保证了在不同入射角的条件下,IR膜系通带波段上中心波长漂移幅度也满足上述设计要求,保证了本发明的近红外滤光片的成像质量。Shown in conjunction with Fig. 10 and Fig. 11, and through the above-mentioned calculation result (that is, the physical thickness (unit: nm) of the IR film system plating of the IR film thickness represented in Table 6 and the AR film thickness represented in Table 7 are AR film system plated physical thickness (unit: nm)), in the present embodiment, under the condition that satisfies IR film layer transmittance and AR film layer transmittance, get m=10, s=12, IR The total thicknesses of the film system and the AR film system are 3.16 μm and 2 μm respectively, so that the thicknesses of the IR film system and the AR film system of the present invention all meet the design requirements, and the IR film system has a passband band in the range of 800-1200 nm, The transmittance is greater than 90%; the bandwidth of the pass band is less than 400nm; there are 2 cut-off bands, which are respectively on both sides of the pass band, and the transmittance is less than 0.1%. A cut-off area, the transmittance is greater than 90% and less than 0.1% respectively; there is a transition area between 800 and 1200, the transmittance is between 0.1% and 90%, and it also ensures that under the conditions of different incident angles, The central wavelength shift amplitude in the passband band of the IR film system also meets the above design requirements, which ensures the imaging quality of the near-infrared filter of the present invention.

上述内容仅为本发明的具体方案的例子,对于其中未详尽描述的设备和结构,应当理解为采取本领域已有的通用设备及通用方法来予以实施。The above content is only an example of the specific solutions of the present invention. For the equipment and structures not described in detail therein, it should be understood that they are implemented by adopting the existing general equipment and general methods in the art.

以上所述仅为本发明的一个方案而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above description is only a solution of the present invention, and is not intended to limit the present invention. For those skilled in the art, the present invention may have various modifications and changes. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the present invention shall be included within the protection scope of the present invention.

Claims (18)

1. a kind of near-infrared narrow band filter, which is characterized in that including:Substrate (11) is arranged in the substrate (11) side IR membrane system (12);
The IR membrane system (12) includes the first high refractive index layer (121) and the first low-index film (122) being alternately coated with, The outermost layer of the IR membrane system (12) is the first low-index film (122);In the wave-length coverage of 800~1200nm, institute IR membrane system (12) are stated with a passband wave band, two transition wave bands and two cut-off wave bands, the passband wave band is located at two Between described two cut-off wave bands, the little bellow section is between the passband wave band and the cut-off wave band;
The passband wave band has central wavelength, and in the range of incidence angle changes from 0 ° to 30 °, in the passband wave band Heart wave length shift amplitude is between 7nm~13nm.
2. near-infrared narrow band filter according to claim 1, which is characterized in that change from 20 ° to 30 ° in incidence angle In range, every 1 ° of the variation of incidence angle, the central wavelength drift band of the passband wave band is less than 5nm.
3. near-infrared narrow band filter according to claim 2, which is characterized in that the passband band is less than 400nm。
4. near-infrared narrow band filter according to claim 3, which is characterized in that in the wave-length coverage of 800~1200nm Interior, the passband wave band transmitance is greater than 90%, and the cut-off wave band transmitance is less than 0.1%.
5. near-infrared narrow band filter according to claim 4, which is characterized in that the side passband wave band UV and IR lateral curvature Line steepness is between 7nm~13nm.
6. near-infrared narrow band filter according to any one of claims 1 to 5, which is characterized in that first high refractive index Film layer (121) is layer of hydrogenated;
In the wave-length coverage of 800~1200nm, the refractive index of first high refractive index layer (121) is greater than 3.5, and delustring Coefficient is less than 0.002.
7. near-infrared narrow band filter according to claim 6, which is characterized in that at 850nm wavelength, described first is high Refractivity film layer (121) refractive index is greater than 3.6;
At 940nm wavelength, the first high refractive index layer (121) refractive index is greater than 3.55.
8. near-infrared narrow band filter according to claim 6, which is characterized in that first high refractive index layer It (121) is sputtering reaction film layer, in the presence of hydrogen, sputtering reaction temperature is 80 DEG C~300 DEG C, and sputter rate is 0.1nm/s≤v≤1nm/s。
9. near-infrared narrow band filter according to claim 8, which is characterized in that the hydrogen is drawn with adjustable flow Enter, and its flow meets 10sccm≤v1≤50sccm.
10. according to claim 1 or near-infrared narrow band filter described in 9, which is characterized in that first high refractive index layer (121) meet with the physical thickness relationship of first low-index film (122):0.01≤DL/DH≤ 100, wherein DL、DH Respectively indicate the physical thickness of the first low-index film and the first high refractive index layer.
11. near-infrared narrow band filter according to claim 1, which is characterized in that change from 0 ° to 10 ° in incidence angle In range, the central wavelength drift band of the passband wave band is between 0.5nm~1.5nm, and every 1 ° of the variation of incidence angle is described The central wavelength drift band of passband wave band is less than 1.5nm;
In the range of incidence angle changes from 0 ° to 20 °, the central wavelength drift band of the passband wave band between 2.5nm~ Between 8nm, change from 10 ° in the range of 20 °, every 1 ° of the variation of incidence angle, the central wavelength drift band of the passband wave band Less than 6nm;
In the range of incidence angle changes from 0 ° to 40 °, the central wavelength drift band of the passband wave band between 12nm~ Between 20nm, change from 0 ° in the range of 10 °, every 1 ° of the variation of incidence angle, the central wavelength drift band of the passband wave band Less than 8nm.
12. near-infrared narrow band filter according to claim 1, which is characterized in that further include AR membrane system (13);
The IR membrane system (12) and the opposite two sides positioned at the substrate (11) of the AR membrane system (13);
The AR membrane system (13) includes the second high refractive index layer (131) and the second low-index film (132) being alternately coated with, The outermost layer of the AR membrane system (13) is the second low-index film (132).
13. near-infrared narrow band filter according to claim 12, which is characterized in that in the wavelength model of 350~1200nm In enclosing, the AR membrane system (13) has a pass band areas, and its transmitance is greater than 90%, a cut-off region, and it is penetrated Rate is less than 0.1%;
In the wave-length coverage of 800~1200nm, the AR membrane system (13) also have a transitional region, and its transmitance between Between 0.1%~90%.
14. near-infrared narrow band filter according to claim 12 or 13, which is characterized in that the IR membrane system (12) and institute The film layer overall thickness of AR membrane system (13) is stated less than 9.8 μm.
15. near-infrared narrow band filter according to claim 14, which is characterized in that the near-infrared narrow band filter Full width at half maximum value is less than 120nm.
16. near-infrared narrow band filter according to claim 12 or 13, which is characterized in that first low refractive index film The refractive index of layer (122) is less than 3, and its material is SiO2、Nb2O5、Ta2O5、TiO2、Al2O3、ZrO2、Pr6O11、La2O3、Si2N、 SiN、Si2N3、Si3N4One of or a variety of combinations;
The refractive index of second low-index film (132) is less than 3, and its material is SiO2、Nb2O5、Ta2O5、TiO2、 Al2O3、ZrO2、Pr6O11、La2O3、Si2N、SiN、Si2N3、Si3N4One of or a variety of combinations.
17. a kind of infrared imaging system using any near-infrared narrow band filter of claim 1 to 16, feature exist In, including IR emission system and IR reception system;
The IR emission system includes the first of IR transmitting light source (2) and the light for projecting IR transmitting light source (2) sending Lens assembly (3);
It includes near-infrared narrow band filter (1), the second lens assembly (4) and infrared image sensor (5) that the IR, which receives system,;
The infrared narrow band filter (1) is between second lens assembly (4) and the infrared image sensor (5).
18. infrared imaging system according to claim 17, which is characterized in that first lens assembly (3) includes red Outer light source collimates the diffraction component (32) of camera lens (31) and setting on infrared light supply collimation camera lens (31).
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