CN108659679A - A kind of high-strength wearable aqueous epoxy floor paint and preparation method thereof - Google Patents
A kind of high-strength wearable aqueous epoxy floor paint and preparation method thereof Download PDFInfo
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- CN108659679A CN108659679A CN201810630029.6A CN201810630029A CN108659679A CN 108659679 A CN108659679 A CN 108659679A CN 201810630029 A CN201810630029 A CN 201810630029A CN 108659679 A CN108659679 A CN 108659679A
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- 239000004593 Epoxy Substances 0.000 title claims abstract description 58
- 239000003973 paint Substances 0.000 title claims abstract description 49
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000000945 filler Substances 0.000 claims abstract description 23
- 239000001913 cellulose Substances 0.000 claims abstract description 22
- 229920002678 cellulose Polymers 0.000 claims abstract description 22
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 19
- 239000003822 epoxy resin Substances 0.000 claims abstract description 18
- 239000013078 crystal Substances 0.000 claims abstract description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 14
- 239000000080 wetting agent Substances 0.000 claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 claims abstract description 10
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 17
- 239000002270 dispersing agent Substances 0.000 claims description 13
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical group O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000006004 Quartz sand Substances 0.000 claims description 4
- 239000013081 microcrystal Substances 0.000 claims description 4
- 238000004806 packaging method and process Methods 0.000 claims description 3
- 230000009467 reduction Effects 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 239000010456 wollastonite Substances 0.000 claims description 2
- 229910052882 wollastonite Inorganic materials 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 2
- 229930185605 Bisphenol Natural products 0.000 claims 1
- 150000001450 anions Chemical class 0.000 claims 1
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 1
- 239000002121 nanofiber Substances 0.000 claims 1
- 239000002689 soil Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 8
- 239000013530 defoamer Substances 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- -1 color Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000005995 Aluminium silicate Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 2
- 235000003140 Panax quinquefolius Nutrition 0.000 description 2
- 240000005373 Panax quinquefolius Species 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000003260 anti-sepsis Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 150000002170 ethers Chemical group 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to technical field of coatings, more particularly to a kind of high-strength wearable aqueous epoxy floor paint and preparation method thereof.The aqueous epoxy floor paint is made of component A and B component；The raw material for preparing of the component A includes：10~30 parts of 30~50 parts of aqueous epoxy resins and water；The raw material for preparing of the B component includes 0.5~2 part of 20~50 parts of aqueous epoxy curing agent, 10~30 parts of water, 10~60 parts of filler, 2~6 parts of wetting agent, 0.2~0.4 part of antifoaming agent, 5~15 parts of calcium sulfate crystal whiskers, 1~5 part of diatomite and nano-cellulose.The aqueous epoxy floor paint has preferable impact resistance and wearability, and will not significantly improve production cost, and the preparation method is simple and practical, easily operated, has very high economy and practical value.
Description
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of high-strength wearable aqueous epoxy floor paint and its preparation side
Method.
Background technology
Floor paint was invented in 1934 by Germany earliest, mainly by a variety of differences such as oil plant, tree material, color, solvents
Substance is fabricated through many end production process such as mixing, dissolving, dispersion, can be divided into decorative floor paint, heavy antisepsis floor paint,
Resistance to heavy duty floor paint etc., has the characteristics that beautiful, true, beautiful, wear-resisting, waterproof, anti-corrosion.Aqueous epoxy floor paint is attached with its
It is excellent to put forth effort height, corrosion resistance, electrical insulation properties, using water as decentralized medium, smell is small, meets environmental requirement, in addition, water
Property epoxide terrace paint solidification after have a small amount of moisture in film and exist, so dense lead can be cured to avoid solvent type floor coatings
The defects of bubbling caused by causing the steam in concrete to rise, deformation and stripping.
It has been more than solvent type epoxy floor paint in the dosage of developed country, aqueous epoxy floor paint.But China's water-base epoxy
The promotion and application of terrace product are not also very fully that occupation rate of market is not high, and reason is mainly the country in aqueous epoxy floor
The input for painting research and development of products, increased quality etc. is very little so that the performance of this province of product is insufficient, such as intensity is poor and wear-resisting
Performance is bad, while the price of aqueous epoxy floor paint product is generally higher, leads to the competitive advantage of aqueous epoxy floor paint not
Obviously.Therefore, exploitation is good with high intensity and wearability, and moderate aqueous epoxy floor paint is especially necessary.
Invention content
In order to solve the above technical problem, the present invention provides a kind of high-strength wearable aqueous epoxy floor paint and its preparation sides
Method.The aqueous epoxy floor paint has preferable impact resistance and wearability, and will not significantly improve production cost, the system
Preparation Method is simple and practical, easily operated, has very high economy and practical value.
High-strength wearable aqueous epoxy floor paint of the present invention, the aqueous epoxy floor paint is by component A and B component group
At；
Wherein, in parts by weight, the raw material for preparing of the component A includes：30~50 parts of aqueous epoxy resins and water 10~
30 parts；
In parts by weight, the raw material for preparing of the B component includes：20~50 parts of aqueous epoxy curing agent, 10~30 parts of water,
10~60 parts of filler, 2~6 parts of wetting agent, 0.2~0.4 part of antifoaming agent, 5~15 parts of calcium sulfate crystal whiskers, 1~5 part of diatomite and
0.5~2 part of nano-cellulose.
In above-mentioned formula, involved base stock and additive, such as wetting agent, antifoaming agent, filler, this can be selected
Field known common type in preparing aqueous epoxy floor paint, but in order to realize between each component preferably cooperation/collaboration effect
Fruit, the present invention have made following preferred restriction to each component in formula：
Preferably, the aqueous epoxy resins are bisphenol A type epoxy resin, and the bisphenol A type epoxy resin resin is selected from
E44 types (being purchased from Shandong De Yuan epoxies Science and Technology Ltd.), GEM02 or GEM03 (are purchased from the upper sea green good limited public affairs of water paint
Department) in it is one or more.
Preferably, the aqueous epoxy curing agent be selected from GCA02 (be purchased from upper sea green good water paint Co., Ltd) or
Sunmide WH-900；SunmideWH-900 is low viscosity, and the modified polyamine system aqueous epoxy curing agent of high molecular weight has
Emulsify the function of various epoxy resin.Coordinate with solid epoxy under the conditions of low temperature, high humidity, has good attachment
Property.
Suitable filler that is added can not only reduce the cost of aqueous epoxy floor paint, shorten film surface drying time, can be with
The mechanical strength of film, wearability, gloss and covering power are improved, reduces volume contraction when solidification, and assign its good storage
Stability is deposited, but excessive addition can then increase the viscosity of water paint, and the levelability of coating is caused to be deteriorated, constructional difficulties, film
Surface effect be deteriorated.Preferably, the filler is talcum powder, barium sulfate, kaolin, quartz sand, sericite, alumina silicate, carbon
One or more of sour calcium, wollastonite；Wherein, hardness can be improved in kaolin, and talcum powder can be improved the suspension of coating, reduce
Crack and gap, quartz sand and barium sulfate can increase the wear-resisting property and hardness of terrace, and sericite can improve the resistance to of terrace
Hou Xing, it reduces permeability, improve chemicals-resistant ability, can be as needed, select suitable cooperation and dosage.
Dispersant is a kind of filler stabilizer, and can be adsorbed on filler grain surface makes to generate repulsion between filler grain
Power makes filler grain stablize by electrostatic repulsion or steric hindrance, avoids filler agglomerating due to flocculation aggregation so that
Filler systems keep stablizing；It therefore, can also be in B component in order to avoid the aggregation of filler causes paint film floating, film to be bubbled
Suitable dispersant is added to increase the uniform and stable property of filler；Preferably, the B component further includes dispersant 0.1~0.7
Part；It is highly preferred that the dispersant is polycarboxylic acids ammonium salt type dispersant, in the preference of the present invention, select Sheng Ruopu sections public
The SN-5029 of department is as dispersant.
Preferably, the antifoaming agent is selected from ethers, long-chain alcohols, fatty acid acyl amine, phosphoric acid ester and organic silicon；
In the preferred embodiment of the present invention, the antifoaming agent is the SN-DEFOAMER318 or SN-DEFOAMER of company of Sheng Ruopu sections
319, this kind of antifoaming agent can quickly defoam and duration suds effect is good, and the film coated surface of formation is smooth pin-free.
It is poor to the wetability of ground since the surface tension of water is higher, especially there is the surface of grease remnants to be more difficult to
Wetting, should be added wetting agent to improve the compatibility of paint and ground；In a preferred embodiment of the invention, the wetting agent is
The wetting agent of BYK-346, BYK-333 of German Bi Ke.
Preferably, the average aspect ratio of the calcium sulfate crystal whiskers be 30~50, a diameter of 1~4 μm；Purchased from the excellent conjunction in Foshan City
Chemical Industry Science Co., Ltd.Calcium sulfate crystal whiskers be it is a kind of with single crystal form grow it is novel it is needle-shaped, there is uniform crosssection, complete
The perfect fiber sub-nanometer material of shape, internal structure.The advantage for integrating both reinforcing fiber and ultra-fine inorganic filler, adds
The effects that enhancing, toughening, thickening, heat-resisting, wear-resisting, oil resistant can be played, is added in aqueous epoxy floor paint, and cost is relatively low.
Preferably, the diatomaceous fineness is 200~300 mesh, and diatomite is common coating additive, has hole
The features such as degree is big, absorbability is strong, chemical property is stable, wear-resisting, heat-resisting, can provide excellent surface property for coating, and increase-volume increases
Thick and raising adhesive force.Since it has larger pore volume, film can be made to shorten drying time.The use of resin can also be reduced
Amount, reduces cost.
Preferably, the nano-cellulose be selected from nanofibrils cellulose (NFC), nano micro crystal cellulose (CNC), it is cloudy from
One or several kinds in sub- nanofibrils cellulose (NFC)；It is highly preferred that the nano-cellulose is nanofibrils fiber
Element.Nano-cellulose is added in aqueous epoxy floor paint can increase the intensity of product, largely be exposed due to its surface
Hydroxyl generates stronger hydrophily, therefore also certain thickening and peptizaiton, additionally it is possible to increase the lower temperature resistance of product
Energy.
The present invention also provides the preparation methods of aqueous epoxy floor paint, include the following steps：
Component A manufacturing method is：Aqueous epoxy resins are mixed for 30~50 parts with water 10~30, at 300~500rpm
It is stirred 5~10min, is packed；
B component manufacturing method is：To 10~60 parts of filler, 5~15 parts of calcium sulfate crystal whiskers, 1~5 part of diatomite and nanometer
0.5~2 part of cellulose carries out that 10~30 parts of water is added after tentatively mixing, the reduction of speed after 1000~1800rpm stirs 15~25min
To 500~800rpm, 20~50 parts of aqueous epoxy curing agent is added, 0.2~0.4 part of 2~6 parts of wetting agent and antifoaming agent continue to stir
5~10min is mixed, is packed.
When in use, component A and B component are mixed, the mass ratio of the component A and B component is 1:(2.5~
4)。
Compared with prior art, it is an advantage of the invention that：
(1) it is formulated reasonable design, indices meet the national standard of epoxy flooring coating；In addition, it has been found that
The wear-resisting property of product and resistance to punching can be significantly improved by adding suitable calcium sulfate crystal whiskers, diatomite and nano-cellulose
Performance is hit, and the inexpensive manufacturing cost of product raw material is relatively low.
(2) due to using double aqueous components, having the characteristics that Environmental Safety, energy saving.
(3) it is formulated by improving, adjusts the ratio between each component, drying time is short, hard after obtained water paint application
It is fast to change speed.
Specific implementation mode
The invention discloses a kind of high-strength wearable aqueous epoxy floor paint and preparation method thereof, those skilled in the art can be with
Present disclosure is used for reference, technological parameter realization is suitably modified.In particular, it should be pointed out that all similar substitutions and modifications are to ability
It is it will be apparent that they are considered as being included in the present invention for field technique personnel.The method and application of the present invention has been led to
Preferred embodiment is crossed to be described, related personnel obviously can not depart from the content of present invention, in spirit and scope to this paper institutes
The methods and applications stated are modified or suitably change and combine, to realize and apply the technology of the present invention.
It is common commercially available product in supplementary material according to the present invention if not specified, can be bought and be obtained by market.
The above case study on implementation be to the present invention be specifically described for example, technical staff belonging to the present invention can be with
Various concrete cases are modified or supplemented.
Embodiment 1
1) aqueous epoxy floor paint formula (in parts by weight)：
Component A：20 parts of 40 parts of bisphenol A type epoxy resin (GEM02 types) and water；
B component：35 parts of aqueous epoxy curing agent (GCA02 types), 20 parts of water, 35 parts of filler (talcum powder), wetting agent (BYK-
346) 4 parts, 0.4 part of dispersant (SN-5029), 0.3 part of antifoaming agent (SN-DEFOAMER 319), 10 parts of calcium sulfate crystal whiskers, diatom
Native 3.5 parts and 1.0 parts of nanofibrils cellulose.
2) preparation method includes the following steps：
Component A manufacturing method is：The epoxy resin and water of formula ratio are added in material-compound tank, by the rotational speed regulation of blender
To 300~500rpm, it is stirred 5~10min, is packed；
B component manufacturing method is：Be added in material-compound tank the filler of formula ratio, dispersant, calcium sulfate crystal whiskers, diatomite with
And nanofibrils cellulose, it is slowly stirred lower addition water, after water is added, mixing speed is opened to 1000~1800rpm, stirs
Reduction of speed is mixed after 15~25min to 500~800rpm, be added aqueous epoxy curing agent and remaining additive continue stirring 5~
10min, packaging.
Embodiment 2
1) aqueous epoxy floor paint formula (in parts by weight)：
Component A：10 parts of 30 parts of bisphenol A type epoxy resin (GEM02 types) and water；
B component：20 parts of aqueous epoxy curing agent (Sunmide WH-900), 20 parts of water, 10 parts of filler (quartz sand), wetting
2 parts of agent (BYK-333), 0.2 part of dispersant (SN-5029), 0.2 part of antifoaming agent (SN-DEFOAMER 318), calcium sulfate crystal whiskers 5
0.5 part of part, 1 part of diatomite and nano micro crystal cellulose.
2) the preparation method is the same as that of Example 1.
Embodiment 3
1) aqueous epoxy floor paint formula (in parts by weight)：
Component A：30 parts of 50 parts of bisphenol A type epoxy resin (GEM02 types) and water；
B component：50 parts of aqueous epoxy curing agent (Sunmide WH-900), 30 parts of water, 60 parts of filler (talcum powder), wetting
6 parts of agent (BYK-333), 0.4 part of dispersant (SN-5029), 0.4 part of antifoaming agent (SN-DEFOAMER 318), calcium sulfate crystal whiskers 15
2 parts of part, 5 parts of diatomite and nano-cellulose.
2) the preparation method is the same as that of Example 1.
Embodiment 4
1) aqueous epoxy floor paint formula (in parts by weight)：
Component A：27 parts of 40 parts of bisphenol A type epoxy resin (GEM02 types) and water；
B component：48 parts of aqueous epoxy curing agent (GCA02 types), 18 parts of water, 50 parts of filler (kaolin), wetting agent (BYK-
346) 4.5 parts, 0.4 part of dispersant (SN-5029), 0.25 part of antifoaming agent (SN-DEFOAMER 319), 13 parts of calcium sulfate crystal whiskers,
1.6 parts of 4 parts of diatomite and nano micro crystal cellulose.
2) the preparation method is the same as that of Example 1.
Embodiment 5
1) aqueous epoxy floor paint formula (in parts by weight)：
Component A：25 parts of 35 parts of bisphenol A type epoxy resin (GEM02 types) and water；
B component：50 parts of aqueous epoxy curing agent (GCA02 types), 15 parts of water, 35 parts of filler (talcum powder), wetting agent (BYK-
346) 5 parts, 0.6 part of dispersant (SN-5029), 0.35 part of antifoaming agent (SN-DEFOAMER 319), 7 parts of calcium sulfate crystal whiskers, diatom
Native 2 parts and 1.2 parts of nano-cellulose.
2) the preparation method is the same as that of Example 1.
Embodiment 6
By the two component epoxy floor paint of embodiment 1 according to component A and B component 1:3 mass ratio is mixed, then
It tests according to GB/T22374-2008, while that detects also has comparative example 1-2, comparative example 1 (component A and B component=1:3)
Formula in, do not add diatomite and nano-cellulose, remaining formula and the preparation method is the same as that of Example 1；Comparative example 2 (component A with
B component=1:3) in formula, calcium sulfate crystal whiskers are not added, remaining is formulated and the preparation method is the same as that of Example 1, as a result such as the following table 1
It is shown：
Table 1
By table 1 it is found that the test event that aqueous epoxy floor paint provided by the invention is carried out meets national standard,
Compared with comparative example 1-2, has in terms of wearability, impact resistance and increase significantly.
Claims (9)
1. a kind of high-strength wearable aqueous epoxy floor paint, which is characterized in that the aqueous epoxy floor paint is by component A and B component
Composition；
Wherein, in parts by weight, the raw material for preparing of the component A includes：10~30 parts of 30~50 parts of aqueous epoxy resins and water；
In parts by weight, the raw material for preparing of the B component includes：20~50 parts of aqueous epoxy curing agent, 10~30 parts of water, filler
10~60 parts, 2~6 parts of wetting agent, 0.2~0.4 part of antifoaming agent, 5~15 parts of calcium sulfate crystal whiskers, 1~5 part of diatomite and nanometer
0.5~2 part of cellulose.
2. aqueous epoxy floor paint according to claim 1, which is characterized in that the aqueous epoxy resins are bisphenol A-type
Epoxy resin, the bisphenol A type epoxy resin resin are one or more in E44 types, GEM02 or GEM03.
3. aqueous epoxy floor paint according to claim 1, which is characterized in that the aqueous epoxy curing agent is selected from
GCA02 or Sunmide WH-900.
4. aqueous epoxy floor paint according to claim 1, which is characterized in that the filler is talcum powder, barium sulfate, height
One or more of ridge soil, quartz sand, sericite, alumina silicate, calcium carbonate, wollastonite.
5. aqueous epoxy floor paint according to claim 1, which is characterized in that the B component further include dispersant 0.1~
0.7 part.
6. aqueous epoxy floor paint according to claim 1, which is characterized in that the average aspect ratio of the calcium sulfate crystal whiskers
It is 30~50, a diameter of 1~4 μm.
7. aqueous epoxy floor paint according to claim 1, which is characterized in that the diatomaceous fineness is 200~300
Mesh.
8. aqueous epoxy floor paint according to claim 1, which is characterized in that the nano-cellulose is selected from nanofibrils
One or several kinds in cellulose (NFC), nano micro crystal cellulose (CNC), anion nanofibrils cellulose (NFC).
9. a kind of preparation method of high-strength wearable aqueous epoxy floor paint, which is characterized in that include the following steps：
Component A manufacturing method is：Aqueous epoxy resins are mixed for 30~50 parts with water 10~30, are stirred at 300~500rpm
Mix 5~10min, packaging；
B component manufacturing method is：To 10~60 parts of filler, 5~15 parts of calcium sulfate crystal whiskers, 1~5 part of diatomite and nanofiber
Element 0.5~2 part carry out tentatively mix after be added 10~30 parts of water, 1000~1800rpm stir 15~25min after reduction of speed extremely
500~800rpm, is added 20~50 parts of aqueous epoxy curing agent, and 0.2~0.4 part of 2~6 parts of wetting agent and antifoaming agent continue to stir
5~10min, packaging.
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109836969A (en) * | 2019-03-12 | 2019-06-04 | 严勇 | A kind of anti-static and abrasion-resistant epoxy flooring coating |
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| CN111574908A (en) * | 2020-06-30 | 2020-08-25 | 咸阳师范学院 | Playground runway floor paint |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104962173A (en) * | 2015-07-10 | 2015-10-07 | 刘善江 | Epoxy floor water-based paint and preparation method thereof |
| CN105038337A (en) * | 2015-07-14 | 2015-11-11 | 温州市汇泰隆科技有限公司 | Diatom mud coating component and diatom mud coating compirsing same |
| CN105199591A (en) * | 2015-09-22 | 2015-12-30 | 天长市开林化工有限公司 | Water-resistant acrylate modified waterborne polyurethane emulsion paint |
| CN105273557A (en) * | 2015-10-13 | 2016-01-27 | 中国林业科学研究院木材工业研究所 | Waterborne wood paint and preparation method thereof |
| CN107936741A (en) * | 2017-12-05 | 2018-04-20 | 安徽建邦建材有限公司 | A kind of environmental protection high tenacity method of producing exterior wall paint |
-
2018
- 2018-06-19 CN CN201810630029.6A patent/CN108659679A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104962173A (en) * | 2015-07-10 | 2015-10-07 | 刘善江 | Epoxy floor water-based paint and preparation method thereof |
| CN105038337A (en) * | 2015-07-14 | 2015-11-11 | 温州市汇泰隆科技有限公司 | Diatom mud coating component and diatom mud coating compirsing same |
| CN105199591A (en) * | 2015-09-22 | 2015-12-30 | 天长市开林化工有限公司 | Water-resistant acrylate modified waterborne polyurethane emulsion paint |
| CN105273557A (en) * | 2015-10-13 | 2016-01-27 | 中国林业科学研究院木材工业研究所 | Waterborne wood paint and preparation method thereof |
| CN107936741A (en) * | 2017-12-05 | 2018-04-20 | 安徽建邦建材有限公司 | A kind of environmental protection high tenacity method of producing exterior wall paint |
Cited By (11)
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|---|---|---|---|---|
| CN109836969A (en) * | 2019-03-12 | 2019-06-04 | 严勇 | A kind of anti-static and abrasion-resistant epoxy flooring coating |
| CN111040575A (en) * | 2019-12-27 | 2020-04-21 | 刘大刚 | High-toughness epoxy resin decorative coating with heat resistance |
| CN111574908A (en) * | 2020-06-30 | 2020-08-25 | 咸阳师范学院 | Playground runway floor paint |
| CN113512340A (en) * | 2021-08-03 | 2021-10-19 | 广东宝伯力新材料科技有限公司 | Water-based colored ultraviolet-proof finish paint and preparation method thereof |
| CN115286969A (en) * | 2022-03-23 | 2022-11-04 | 王波 | Anti-cracking antioxidant antirust epoxy coating and preparation method thereof |
| JP7206442B1 (en) * | 2022-07-12 | 2023-01-17 | 日立Astemo株式会社 | Coating composition, coated member, and method for producing coated member |
| WO2024013840A1 (en) * | 2022-07-12 | 2024-01-18 | 日立Astemo株式会社 | Coating composition, coated member, and method for producing coated member |
| CN115785769A (en) * | 2022-11-21 | 2023-03-14 | 攀枝花环业冶金渣开发有限责任公司 | High-titanium type blast furnace slag micro-powder type water-based epoxy floor paint |
| CN116875147A (en) * | 2023-07-12 | 2023-10-13 | 广东丰硕新材料有限公司 | High-gloss high-wear-resistance water-based epoxy floor paint |
| CN119192952A (en) * | 2024-10-21 | 2024-12-27 | 海丰县美达化工涂料有限公司 | A kind of permeable floor paint and preparation method thereof |
| CN119192952B (en) * | 2024-10-21 | 2025-05-30 | 海丰县美达化工涂料有限公司 | Water-permeable floor paint and preparation method thereof |
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Application publication date: 20181016 |