CN108166006A - A kind of process of surface treatment of the automobile metal parts of surface texture complexity - Google Patents

A kind of process of surface treatment of the automobile metal parts of surface texture complexity Download PDF

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Publication number
CN108166006A
CN108166006A CN201711438063.5A CN201711438063A CN108166006A CN 108166006 A CN108166006 A CN 108166006A CN 201711438063 A CN201711438063 A CN 201711438063A CN 108166006 A CN108166006 A CN 108166006A
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China
Prior art keywords
components
auto parts
parts
automobile
rinsed
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Pending
Application number
CN201711438063.5A
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Chinese (zh)
Inventor
王光祥
王玉成
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HEFEI NANFANG AUTO PARTS Co Ltd
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HEFEI NANFANG AUTO PARTS Co Ltd
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Priority to CN201711438063.5A priority Critical patent/CN108166006A/en
Publication of CN108166006A publication Critical patent/CN108166006A/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/14Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08Orthophosphates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F3/00Brightening metals by chemical means
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Vehicle Cleaning, Maintenance, Repair, Refitting, And Outriggers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Cleaning By Liquid Or Steam (AREA)

Abstract

The present invention discloses a kind of process of surface treatment of the automobile metal parts of surface texture complexity, after surface grease removal processing is carried out to auto parts and components, it is used by the collocation of deburring liquid and ultrasonic wave, quickly and effectively remove the burr of surface of automobile part, and handled by the alkali metal salt processing of subsequent melting and metal phosphorizing, make auto parts and components that there is good resistance to corrosion and good image appearance while the smoothness for ensureing surface of automobile part.A kind of process of surface treatment of the automobile metal parts of surface texture complexity provided by the present invention, the surface of auto parts and components can quickly and effectively be handled, effectively remove the burr of surface of automobile part, the surface for making auto parts and components is smooth, and passing through subsequent processing makes auto parts and components have outstanding resistance to corrosion, rich in gloss, image appearance is excellent on surface.

Description

A kind of process of surface treatment of the automobile metal parts of surface texture complexity
Technical field
The invention belongs to automobile metal parts machining technical field, specifically, being related to a kind of vapour of surface texture complexity The process of surface treatment of vehicle metal parts.
Background technology
Basis of the auto parts and components as auto industry is the necessary factor for supporting auto industry sustainable and healthy development, special It is not that present auto industry is in a fast-developing stage, even more needs a powerful parts system as support.
Auto parts and components wide variety has simple in structure, the parts of regular shape, also there is the more complicated class of structure Type, for some automobile metal parts due to functional requirements or appearance demand, the surface texture of metal parts is more multiple It is miscellaneous, thus also cause the metal parts of this type surface generally deal with it is relatively difficult, by mechanical means to zero When the surface of part is handled, time and energy are very expended, improves the production cost of enterprise, quality can not also be protected Barrier does not meet enterprise and produces pursued speed and quality, a kind of simple and quick in order to provide, can be to batch surface texture The technique that the surface of complicated automobile metal parts is handled, the present invention provides following technical schemes.
Invention content
The purpose of the present invention is to provide a kind of process of surface treatment of the automobile metal parts of surface texture complexity.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of process of surface treatment of the automobile metal parts of surface texture complexity, includes the following steps:
(1) ungrease treatment is carried out to the surfaces of auto parts and components by alkaline defatting agent, after ungrease treatment, with slow Electuary is rinsed, and after flushing, auto parts and components is rinsed with deionized water, are dried after cleaning;
(2) auto parts and components are completely immersed in deburring liquid 1.5-3 minutes, ultrasonication is used in soaking process Burr liquid, accelerate burr falls speed;
(3) auto parts and components handled in step (2) are rinsed with deionized water, when flushing uses high pressure spray Auto parts and components are dried after flushing processing in head;
(4) auto parts and components handled in step (3) are completely immersed in the alkali metal salt of melting, the vapour after taking-up Natural cooling in the vacuum drying oven that vehicle parts are 0.45Torr-0.55Torr in vacuum degree is passed through helium in vacuum drying oven and protects Gas;
(5) it will be rinsed after auto parts and components removal handled in step (4) with acidic buffer, flushing terminates It is followed by rinsed with deionized water, after cleaning auto parts and components is dried with processing;
(6) it will be added in metal phosphorizing liquid by the part of step (5) processing and 5-15 handled at a temperature of 50-75 DEG C Minute;
(7) it takes out through metal phosphorizing liquid treated auto parts and components, is rinsed with deionized water, the vapour after flushing Vehicle parts are rinsed again with potassium chromate solution, then with deionized water that Cleaning of Parts is clean, finally to zero, automobile Processing is dried in part.
Further, it is described to be dried as one kind in the dry drying with cold wind of drying.
Further, the temperature of deburring liquid is 18-30 degrees Celsius in the step (2).
Further, the deburring liquid for the hydrogen peroxide of mass fraction 70g/L, the citric acid of 15g/L, 7g/L third The sulfuric acid and cetyl trimethyl ammonia bromide of diacid and 2g/L, benzoic acid, postassium hypochlorite mixture 6g/L.
Further, auto parts and components place 60- in 300 ± 20 DEG C of molten alkali matel salt in the step (4) It is taken out after 90s.
Further, CrO in the potassium chromate solution in the step (7)4 -2A concentration of 0.05-0.08mol/L.
Beneficial effects of the present invention:A kind of table of the automobile metal parts of surface texture complexity provided by the present invention Surface treatment technique can quickly and effectively handle the surface of auto parts and components, effectively remove the burr of surface of automobile part, The surface for making auto parts and components is smooth, and passing through subsequent processing makes auto parts and components be not easy to get rusty, rich in gloss.
Specific embodiment
The technical solution in the embodiment of the present invention will be clearly and completely described below, it is clear that described reality It is only part of the embodiment of the present invention to apply example, instead of all the embodiments.Based on the embodiments of the present invention, this field All other embodiment that those of ordinary skill is obtained without creative efforts, belongs to guarantor of the present invention The range of shield.
Embodiment 1:
A kind of process of surface treatment of the automobile metal parts of surface texture complexity, includes the following steps:
(1) ungrease treatment is carried out to the surfaces of auto parts and components by alkaline defatting agent, after ungrease treatment, with slow Electuary is rinsed, and after flushing, auto parts and components is rinsed with deionized water, drying is dried after cleaning;
(2) auto parts and components are completely immersed in 18 degrees Celsius of deburring liquid 3 minutes, with ultrasound in soaking process Wave handles burr liquid, and accelerate burr falls speed;
(3) auto parts and components handled in step (2) are rinsed with deionized water, when flushing uses high pressure spray Head, removal are sticked to the metal fragment of component surface and deburring liquid residual, auto parts and components are got rid of after flushing Dry drying;
(4) it is placed in the alkali metal salt of melting that auto parts and components handled in step (3) are completely immersed in 480 DEG C It takes out after 90s, natural cooling in the vacuum drying oven that the auto parts and components after taking-up are 0.5Torr in vacuum degree, is passed through in vacuum drying oven Helium makees protection gas;
(5) it will be rinsed after auto parts and components removal handled in step (4) with acidic buffer, flushing terminates It is followed by rinsed with deionized water, drying drying is carried out to auto parts and components after cleaning;
(6) it will pass through in the part addition metal phosphorizing liquid of step (5) processing and be handled 15 minutes at a temperature of 50 DEG C;
(7) it takes out through metal phosphorizing liquid treated auto parts and components, is rinsed with deionized water, the vapour after flushing Vehicle parts are rinsed again with potassium chromate solution, then with deionized water that Cleaning of Parts is clean, finally to zero, automobile Part carries out drying drying.
The deburring liquid for the hydrogen peroxide of mass fraction 70g/L, the citric acid of 15g/L, 7g/L malonic acid and The sulfuric acid and cetyl trimethyl ammonia bromide of 2g/L, benzoic acid, postassium hypochlorite mixture 6g/L.
Embodiment 2:
A kind of process of surface treatment of the automobile metal parts of surface texture complexity, includes the following steps:
(1) ungrease treatment is carried out to the surfaces of auto parts and components by alkaline defatting agent, after ungrease treatment, with slow Electuary is rinsed, and after flushing, auto parts and components are rinsed with deionized water, and cold wind dries up after cleaning;
(2) auto parts and components are completely immersed in 30 degrees Celsius of deburring liquid 1.5 minutes, with super in soaking process Sonicated burr liquid, accelerate burr falls speed;
(3) auto parts and components handled in step (2) are rinsed with deionized water, when flushing uses high pressure spray Head, removal are sticked to the metal fragment of component surface and deburring liquid residual, auto parts and components are carried out after flushing cold Wind is done;
(4) it is placed in the alkali metal salt of melting that auto parts and components handled in step (3) are completely immersed in 320 DEG C It takes out after 60s, natural cooling in the vacuum drying oven that the auto parts and components after taking-up are 0.5Torr in vacuum degree, is passed through in vacuum drying oven Helium makees protection gas;
(5) it will be rinsed after auto parts and components removal handled in step (4) with acidic buffer, flushing terminates It is followed by rinsed with deionized water, cold wind drying is carried out to auto parts and components after cleaning;
(6) it will pass through in the part addition metal phosphorizing liquid of step (5) processing and be handled 5 minutes at a temperature of 75 DEG C;
(7) it takes out through metal phosphorizing liquid treated auto parts and components, is rinsed with deionized water, the vapour after flushing Vehicle parts are rinsed again with potassium chromate solution, then with deionized water that Cleaning of Parts is clean, finally to zero, automobile Part carries out cold wind drying.
The deburring liquid for the hydrogen peroxide of mass fraction 70g/L, the citric acid of 15g/L, 7g/L malonic acid and The sulfuric acid and cetyl trimethyl ammonia bromide of 2g/L, benzoic acid, postassium hypochlorite mixture 6g/L.
Present invention disclosed above preferred embodiment is only intended to help to illustrate the present invention.There is no detailed for preferred embodiment All details are described to the greatest extent, are not limited the invention to the specific embodiments described.Obviously, according in this specification Hold, can make many modifications and variations.This specification is chosen and specifically describes these embodiments, is in order to preferably explain this The principle and practical application of invention, so as to which skilled artisan be enable to be best understood by and utilize the present invention.This hair It is bright to be limited only by the claims and their full scope and equivalents.

Claims (6)

1. a kind of process of surface treatment of the automobile metal parts of surface texture complexity, which is characterized in that include the following steps:
(1) ungrease treatment is carried out to the surfaces of auto parts and components by alkaline defatting agent, after ungrease treatment, with buffer into Row rinses, and after flushing, auto parts and components is rinsed with deionized water, are dried after cleaning;
(2) auto parts and components are completely immersed in deburring liquid 1.5-3 minutes, ultrasonication burr is used in soaking process Liquid;
(3) auto parts and components handled in step (2) are rinsed with deionized water, using high-pressure nozzle, punching during flushing After washing auto parts and components are dried with processing;
(4) auto parts and components handled in step (3) are completely immersed in the alkali metal salt of melting, zero, the automobile after taking-up Natural cooling in the vacuum drying oven that part is 0.45Torr-0.55Torr in vacuum degree is passed through helium in vacuum drying oven and makees protection gas;
(5) it will be rinsed after auto parts and components removal handled in step (4) with acidic buffer, rinse and terminate followed by It is rinsed with deionized water, after cleaning auto parts and components is dried with processing;
(6) it will pass through in the part addition metal phosphorizing liquid of step (5) processing and be handled 5-15 minutes at a temperature of 50-75 DEG C;
(7) it takes out through metal phosphorizing liquid treated auto parts and components, is rinsed with deionized water, zero, the automobile after flushing Part is rinsed again with potassium chromate solution, then with deionized water that Cleaning of Parts is clean, and finally auto parts and components are done Dry processing.
2. a kind of process of surface treatment of the automobile metal parts of surface texture complexity according to claim 1, special Sign is, described to be dried as one kind in the dry drying with cold wind of drying.
3. a kind of process of surface treatment of the automobile metal parts of surface texture complexity according to claim 1, special Sign is that the temperature of deburring liquid is 18-30 degrees Celsius in the step (2).
4. a kind of process of surface treatment of the automobile metal parts of surface texture complexity according to claim 1, special Sign is that the deburring liquid is the hydrogen peroxide of mass fraction 70g/L, the malonic acid and 2g/L of the citric acid of 15g/L, 7g/L Sulfuric acid and cetyl trimethyl ammonia bromide, benzoic acid, postassium hypochlorite mixture 6g/L.
5. a kind of process of surface treatment of the automobile metal parts of surface texture complexity according to claim 1, special Sign is that auto parts and components take out after placing 60-90s in 300 ± 20 DEG C of molten alkali matel salt in the step (4).
6. a kind of process of surface treatment of the automobile metal parts of surface texture complexity according to claim 1, special Sign is, CrO in the potassium chromate solution in the step (7)4 -2A concentration of 0.05-0.08mol/L.
CN201711438063.5A 2017-12-26 2017-12-26 A kind of process of surface treatment of the automobile metal parts of surface texture complexity Pending CN108166006A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110172699A (en) * 2019-07-06 2019-08-27 太仓欧克仓储设备有限公司 A kind of metal plate burr removing method of simple and efficient
WO2020253270A1 (en) * 2019-06-15 2020-12-24 嘉兴敏实机械有限公司 Cleaning process for irregular tubular automobile parts
US20230002912A1 (en) * 2020-06-18 2023-01-05 Jiangsu Xcmg Construction Machinery Research Institute Ltd. Workpiece cleaning apparatus and cleaning method

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CN104454996A (en) * 2014-11-05 2015-03-25 芜湖金龙模具锻造有限责任公司 Anti-corrosion treatment method for sliding bearing shaft sleeve
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CN105065626A (en) * 2015-07-08 2015-11-18 盐城市禾鼎机械有限公司 Energy saving engine driving wheel with high transmission efficiency and surface treatment method thereof
CN105256316A (en) * 2015-10-14 2016-01-20 哈尔滨飞机工业集团有限责任公司 Phosphorization pretreatment method for alloy steel parts

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CN104454996A (en) * 2014-11-05 2015-03-25 芜湖金龙模具锻造有限责任公司 Anti-corrosion treatment method for sliding bearing shaft sleeve
CN105065626A (en) * 2015-07-08 2015-11-18 盐城市禾鼎机械有限公司 Energy saving engine driving wheel with high transmission efficiency and surface treatment method thereof
CN105039990A (en) * 2015-07-24 2015-11-11 苏州华冲精密机械有限公司 Deburring method for joint accessories
CN105256316A (en) * 2015-10-14 2016-01-20 哈尔滨飞机工业集团有限责任公司 Phosphorization pretreatment method for alloy steel parts

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020253270A1 (en) * 2019-06-15 2020-12-24 嘉兴敏实机械有限公司 Cleaning process for irregular tubular automobile parts
CN110172699A (en) * 2019-07-06 2019-08-27 太仓欧克仓储设备有限公司 A kind of metal plate burr removing method of simple and efficient
US20230002912A1 (en) * 2020-06-18 2023-01-05 Jiangsu Xcmg Construction Machinery Research Institute Ltd. Workpiece cleaning apparatus and cleaning method

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Application publication date: 20180615