CN107287609B - Continuity hydrogen-rich water preparation apparatus for household RO water purification machines - Google Patents
Continuity hydrogen-rich water preparation apparatus for household RO water purification machines Download PDFInfo
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- CN107287609B CN107287609B CN201610225834.1A CN201610225834A CN107287609B CN 107287609 B CN107287609 B CN 107287609B CN 201610225834 A CN201610225834 A CN 201610225834A CN 107287609 B CN107287609 B CN 107287609B
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 101
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 64
- 239000001257 hydrogen Substances 0.000 title claims abstract description 61
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 61
- 238000000746 purification Methods 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000003610 charcoal Substances 0.000 claims abstract description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000001301 oxygen Substances 0.000 claims abstract description 6
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 6
- 239000002351 wastewater Substances 0.000 claims abstract description 4
- 238000012544 monitoring process Methods 0.000 claims description 3
- 239000002699 waste material Substances 0.000 claims description 2
- 230000003245 working effect Effects 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 238000005868 electrolysis reaction Methods 0.000 description 11
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 230000007721 medicinal effect Effects 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 230000005611 electricity Effects 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 238000001223 reverse osmosis Methods 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 239000003651 drinking water Substances 0.000 description 2
- 235000020188 drinking water Nutrition 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 108010006533 ATP-Binding Cassette Transporters Proteins 0.000 description 1
- 102000005416 ATP-Binding Cassette Transporters Human genes 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 102000015779 HDL Lipoproteins Human genes 0.000 description 1
- 108010010234 HDL Lipoproteins Proteins 0.000 description 1
- 208000035150 Hypercholesterolemia Diseases 0.000 description 1
- 208000001647 Renal Insufficiency Diseases 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000013210 evaluation model Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 230000008821 health effect Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 201000006370 kidney failure Diseases 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 229940068196 placebo Drugs 0.000 description 1
- 239000000902 placebo Substances 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The present invention relates to hydrogen-rich water preparation apparatus more particularly to a kind of hydrogen-rich water preparation apparatus of household.A kind of continuity hydrogen-rich water preparation apparatus for household RO water purification machines, it is connected on household RO water purification machine rear class charcoal canisters position, it includes a chamber, middle part is equipped with SPE electrode electrolysers in chamber, chamber is divided into two Room by the SPE electrode electrolysers, its cathode side is equipped with pure water entrance and hydrogen-rich water out, and anode-side is equipped with the oxygen outlet for leading to RO water purification machine wastewater discharge pipes.Structure of the invention is exquisite, can be substituted for " the rear class charcoal canister " of household RO water purification machines so that consumer can produce the hydrogen-rich water that concentration meets hydrogen molecule biomedicine meaning at homeNote is 1.。
Description
Technical field
The present invention relates to hydrogen-rich water preparation apparatus more particularly to a kind of hydrogen-rich water preparation apparatus of household.
Background technology
Biomedical scientific research shows that hydrogen-rich water has prodigious biological significance to promoting health, in the market therewith
Start various pre-packaged hydrogen-rich waters, hydrogen-rich cup and equipment occur, but ordinary consumer is limited to price reasons, and to hydrogen
The scarcity of biological medical effect knowledge, which is difficult to which kind of product be applicable in, forms decision.
Sun Xuejun professors'《Hydrogen molecule biology》It mentions and being roughly divided into the method for production hydrogen-rich water：
（One）, water electrolysis method
Electrolysis water is to be used for the hydrogen water of human body earliest, and electrolysis water is drunk for the purpose of health care and originates from Japan earliest.Through
It crosses several years application to summarize, Japanese government's labour Health and human services department approval electrolyzed water machine of new generation is medical apparatus, pays close attention to and drinks electricity
The medical health effect of Xie Shui.
The basic reason that electrolysis water treats disease is that electrolysis water contains hydrogen.The certain density hydrogen of content in electrolysis water,
Trying to meet the deadline for the project for this concentration reaches the oxidation resistant level of hydrogen enough.Alkalescent water is neutralized into neutrality, its antioxygen is not influenced and is turned into
With.
（Two）, magnesium metal react hydrogen
The slow chemical reaction for being generated hydrogen and magnesium hydroxide under long article using magnesium metal and water, is prepared easy to use
Hydrogen water.Main problem existing for this hydrogen water is the stability that hydrogen generates, and is beginning to use the stage effectiveness may
It is more satisfactory, but after a period of use, the generation meeting of hydrogen
It gradually decreases.About the safety issue of magnesium ion, since magnesium ion belongs to human body needs as calcium ion
Metallic element, will not generally lead to the harm of body, but have the patient of kidney failure that must be drunk under physician guidance.
Therefore, electrolysis is safer, also complies with the definition of food additives standard GB31633-2014 but is limited to electricity
Solve some drawbacks of aquatic products：Anode metal is easily precipitated；It is also easy to produce ozone, chlorine；Regular pickling is needed to safeguard electrode；Hydrogen molecule
Content is extremely low；Water ph value etc. is drunk in change, and family is widely available more difficult.
CN104968608A discloses a kind of hydrogen water preparation apparatus, which includes being configured to electrolysis water
Electrolysis installation, and the electrolysis installation includes the electricity formed by anode, cathode, solid polyelectrolyte membrane and auxiliary electrode
Pole module, wherein the electrolysis installation is divided into the first Room and second Room centered on the electrode module；It is configured to lead to
Setting is crossed in first interior, discharges the hydrogen water discharge port of hydrogen water, the hydrogen water is included in the cathode of first Room
Locate the reactive hydrogen generated；It is configured to through setting in first interior, to the injection tip of cathode injection water；It is configured
To discharge the Ozone Water discharge port of the water containing the ozone generated in the second Room anode；It is disposed therein portion space
Store hydrogen water and disinfectant holding tank, by be connected to the first flow channel being connect with the hydrogen water discharge port and with
The second flow path of first flow channel connection, and receive the hydrogen water in the described first indoor generation, and by with
4th flow channel of the Ozone Water discharge port connection, receives the disinfectant generated in the second Room；And comprising
The pump of output end and input terminal, the output end are connected to the third flow channel being connect with the injection tip, the input
End is connected to the 5th flow channel being connect with the storage groove bottom, wherein the injection tip is sprayed using the pump pressure
The hydrogen water being stored in the holding tank, the flow velocity than discharging hydrogen water by the hydrogen water discharge port are fast.According to analysis, the skill
The hydrogen-rich water pH of art scheme
Value changes, and can generate ozone.
Invention content
Present invention seek to address that drawbacks described above, provides a kind of continuity hydrogen-rich water preparation dress for household RO water purification machines
It sets.Structure of the invention is small and exquisite, simple, can be substituted for " the rear class charcoal canister " of household RO water purification machines so that consumer can be
Concentration is produced in family meets the hydrogen-rich water note of hydrogen molecule biomedicine meaning 1..
The present invention is mounted on household RO water purification machine rear class charcoal canisters position, it includes a chamber, during chamber is interior
Portion is equipped with SPE electrode electrolysers, which is divided into mutual disconnected two chamber, cathode side chamber by chamber
Room lower part is equipped with pure water entrance, top is equipped with hydrogen-rich water out, and anode side room, which is equipped with, leads to RO water purification machine waste water outlet sides
Oxygen outlet, it is 0.6mM (± 0.1mM) to prepare in the hydrogen-rich water of generation density of hydrogen.
The continuity hydrogen-rich water preparation apparatus for household RO water purification machines, there are one monitoring for the cathode side band
The flow sensing meter of pure water.
The present invention need to cannot be used alone together with the device that household RO water purification machines work；It can replace household
RO water purification machines " rear class charcoal canister ".The original pure water for flowing into " rear class charcoal canister " flows into the present invention.It is filled by flow sensing
It sets（Can be preposition, it can also postposition）Enter SPE electric tank cathodes side afterwards, is hydrogen-rich water after outflow, and anode-side detaches
The oxygen gone out is incorporated to the waste discharge end discharge of RO water purification machines.Judge RO water purification machine working conditions by flow sensing device, and
SPE electric tank workings are controlled accordingly.The present invention not output ozone, will not change the acid-base value of water, consumer is allowed to stay at home
Reliably and effectively hydrogen-rich water can be produced.It is different from other electrolytic hydrogen production water modes, following features of the present invention：First, only
Suitable for being used in conjunction with the equipment for meeting QB/T4144-2010 (household or similar applications reverse osmosis water purifier).Second, drinking water
Only contact SPE cathode sides, wholesomeness meet《Drinking Water water quality treater is safe and healthy to advise with functional evaluation
Model --- reverse osmosis treatment device》It is required that.Third does not change and drinks water ph value.4th, it is low in energy consumption, ozone is not generated, no
Generate sour water.5th, this product meets GB4706.1-2005 households and similar applications security appliance relevant criterion.And it is equipped with
Alarm design, can pass through sound（Buzzer）, light（LED indicator lights）Clear information is provided the consumer with, has EMC certifications, it can
The automatic protection when breaking down；6th, can concentration without interruption 0.6mM or so hydrogen-rich water, be suitble to family in more people
It uses；7th, without consumables, Maintenance free.
Description of the drawings
Fig. 1 is the structural schematic diagram of the present invention；
Fig. 2 is moment flow pulse characteristic figure.
Specific implementation mode
As shown in Figure 1, a kind of continuity hydrogen-rich water preparation apparatus for household RO water purification machines, it is connected on household RO
On water purification machine rear class charcoal canister position, it includes a chamber 1, and the interior middle part of chamber is equipped with SPE electrode electrolysers 2, should
Chamber is divided into mutual disconnected two chamber by SPE electrode electrolysers, and cathode side chamber lower portion is equipped with pure water entrance 3, top
Hydrogen-rich water out 4, anode-side are equipped with the oxygen outlet 5 for leading to RO water purification machine waste water drains.Described is used for household
The continuity hydrogen-rich water preparation apparatus of RO water purification machines, there are one the flow sensing meters 6 of monitoring pure water for the cathode side band.This hair
It is bright to control and generation hydrogen water concentration be maintained 0.6mM（±0.1mM）Used method is as follows：Known flow gauge is special
Property is shown in Fig. 2：Umber of pulse corresponds to flow velocity in figure, and flow velocity is obtained by flow sensing meter.
From Fig. 2 it is found that it is about the corresponding 7ml of 1A that electrolyzing pure water, which generates its current strength of hydrogen and gas production,.Therefore, exist
Step-by-step counting is combined with current regulation in control, adjustment is changed to the output current intensity of SPE according to flow velocity, passes through production
The change of tolerance maintains the homogeneity of hydrogen molecule concentration in solution.
Such as：It is required according to QT/4144-2010 standards, household or similar applications reverse osmosis water purifier net water flux are
0.8L/min, but actually this flow velocity and unstable, can slow down in the overall process of production water because of the rising of system pressure, because
This, detects flow velocity, and it is the way for realizing concentration control that change in flow this objective circumstances, which are reacted in the change of current strength,
Diameter.
The present invention is that prepared hydrogen solution concentration is adjusted using this principle.
Note is 1.：Term and explanation：
1, concentration meets the hydrogen-rich water of biological medical effect：
Density of hydrogen is the hydrogen-rich water of 0.6mM (± 0.1mM) in solution.
2, say that the hydrogen-rich water of a concentration of 0.6mM (± 0.1mM) is that have the representative of biological medical effect why：
Because clinical scholar is proved by the clinical random-stringent check experiment of doubleblind-placebo of newest people, this concentration
With specific biological medical effect.（Hydrogen activates ATP-binding cassette transporter
A1-dependent efflux ex vivo and improves highdensity lipoprotein function in
patients with hypercholesterolemia: adouble-blinded, randomized and placebo-
controlled trial.
（J Clin Endocrinol Metab：May 15, 2015）
3, hydrogen solution Concentration Testing method
It is detected using Denmark Unisense microelectrode systems according to document.
Claims (1)
1. a kind of continuity hydrogen-rich water preparation apparatus for household RO water purification machines, it is mounted on household RO water purification machine rear classes
On charcoal canister position, which is characterized in that it includes a chamber, and the interior middle part of chamber is equipped with SPE electrode electrolysers, the SPE
Chamber is divided into mutual disconnected two chamber by electrode electrolyser, and cathode side chamber lower portion is equipped with pure water entrance, top is equipped with richness
Hydrogen water out, anode side cavity are equipped with the oxygen outlet for leading to RO water purification machine waste water outlet sides, and the cathode side also carries
The flow sensing meter of one monitoring pure water；The pure water of household RO water purification machines outflow enters SPE after the flow sensing meter
Electric tank cathode side is hydrogen-rich water after outflow, and the oxygen that anode-side is isolated is incorporated to the waste discharge end discharge of RO water purification machines；
Judge RO water purification machine working conditions by flow sensing meter, and controls SPE electric tank workings accordingly.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610225834.1A CN107287609B (en) | 2016-04-13 | 2016-04-13 | Continuity hydrogen-rich water preparation apparatus for household RO water purification machines |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610225834.1A CN107287609B (en) | 2016-04-13 | 2016-04-13 | Continuity hydrogen-rich water preparation apparatus for household RO water purification machines |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107287609A CN107287609A (en) | 2017-10-24 |
| CN107287609B true CN107287609B (en) | 2018-09-07 |
Family
ID=60095897
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610225834.1A Active CN107287609B (en) | 2016-04-13 | 2016-04-13 | Continuity hydrogen-rich water preparation apparatus for household RO water purification machines |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107287609B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102186781A (en) * | 2008-10-17 | 2011-09-14 | 有限会社春天 | Apparatus for producing hydrogen-dissolved drinking water and process for producing the dissolved drinking water |
| CN103101994A (en) * | 2011-10-05 | 2013-05-15 | 三星电子株式会社 | Apparatus for producing reducing water |
| CN205603687U (en) * | 2016-04-13 | 2016-09-28 | 上海紫盒生物科技有限公司 | A continuity hydrogen -rich water preparation facilities for domestic RO water purification machine |
-
2016
- 2016-04-13 CN CN201610225834.1A patent/CN107287609B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102186781A (en) * | 2008-10-17 | 2011-09-14 | 有限会社春天 | Apparatus for producing hydrogen-dissolved drinking water and process for producing the dissolved drinking water |
| CN103101994A (en) * | 2011-10-05 | 2013-05-15 | 三星电子株式会社 | Apparatus for producing reducing water |
| CN205603687U (en) * | 2016-04-13 | 2016-09-28 | 上海紫盒生物科技有限公司 | A continuity hydrogen -rich water preparation facilities for domestic RO water purification machine |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107287609A (en) | 2017-10-24 |
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Effective date of registration: 20210427 Address after: 100124 room 950, 9th floor, building 10, huashanyuan Cultural Media Industrial Park, 1376 folk culture street, Gaobeidian village, Gaobeidian Township, Chaoyang District, Beijing Patentee after: BEIJING ZHONGQINGYUAN ENGINEERING TECHNOLOGY Co.,Ltd. Address before: 200434, room 2, zone 2, zone 249, West Cen street, No. 216, Qingpu District, Shanghai, Patentee before: SHANGHAI PURPLE-BOX BIOLOGICAL TECHNOLOGY Co.,Ltd. |
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