CN106543714A - A kind of glass fiber reinforced PA66 electric armour clamp material of weather-resistance flame-retardant and preparation method thereof - Google Patents
A kind of glass fiber reinforced PA66 electric armour clamp material of weather-resistance flame-retardant and preparation method thereof Download PDFInfo
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- CN106543714A CN106543714A CN201610959153.8A CN201610959153A CN106543714A CN 106543714 A CN106543714 A CN 106543714A CN 201610959153 A CN201610959153 A CN 201610959153A CN 106543714 A CN106543714 A CN 106543714A
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- 239000000463 material Substances 0.000 title claims abstract description 46
- 239000003365 glass fiber Substances 0.000 title claims abstract description 33
- 239000003063 flame retardant Substances 0.000 title claims abstract description 19
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003610 charcoal Substances 0.000 claims abstract description 11
- 239000002131 composite material Substances 0.000 claims abstract description 11
- 229920002635 polyurethane Polymers 0.000 claims abstract description 11
- 239000004814 polyurethane Substances 0.000 claims abstract description 11
- 239000010458 rotten stone Substances 0.000 claims abstract description 11
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 10
- 239000004917 carbon fiber Substances 0.000 claims abstract description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 10
- -1 polypropylene Polymers 0.000 claims abstract description 10
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 10
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 9
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 9
- 241001330002 Bambuseae Species 0.000 claims abstract description 9
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 9
- 239000004743 Polypropylene Substances 0.000 claims abstract description 9
- 239000011425 bamboo Substances 0.000 claims abstract description 9
- 239000011248 coating agent Substances 0.000 claims abstract description 9
- 238000000576 coating method Methods 0.000 claims abstract description 9
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 9
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 9
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002048 multi walled nanotube Substances 0.000 claims abstract description 9
- 229920001155 polypropylene Polymers 0.000 claims abstract description 9
- 229920002379 silicone rubber Polymers 0.000 claims abstract description 9
- 108091003079 Bovine Serum Albumin Proteins 0.000 claims abstract description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 8
- 229940098773 bovine serum albumin Drugs 0.000 claims abstract description 8
- 239000013078 crystal Substances 0.000 claims abstract description 8
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004945 silicone rubber Substances 0.000 claims abstract description 8
- 239000012948 isocyanate Substances 0.000 claims abstract description 7
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 7
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 6
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 5
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 5
- 238000005253 cladding Methods 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims abstract description 5
- 239000012757 flame retardant agent Substances 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 239000000243 solution Substances 0.000 claims description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 7
- 238000000498 ball milling Methods 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 238000009990 desizing Methods 0.000 claims description 6
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- 238000001291 vacuum drying Methods 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
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- 239000007924 injection Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 238000011068 loading method Methods 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
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- 239000012467 final product Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
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- 239000000047 product Substances 0.000 claims description 3
- 238000002791 soaking Methods 0.000 claims description 3
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- FEWFXBUNENSNBQ-UHFFFAOYSA-N 2-hydroxyacrylic acid Chemical compound OC(=C)C(O)=O FEWFXBUNENSNBQ-UHFFFAOYSA-N 0.000 claims description 2
- 241000283690 Bos taurus Species 0.000 claims description 2
- 108010071390 Serum Albumin Proteins 0.000 claims description 2
- 102000007562 Serum Albumin Human genes 0.000 claims description 2
- 239000003792 electrolyte Substances 0.000 claims description 2
- 229910052738 indium Inorganic materials 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 abstract description 4
- 229910002804 graphite Inorganic materials 0.000 abstract description 4
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- 238000010521 absorption reaction Methods 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
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- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 238000005452 bending Methods 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000003483 aging Methods 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000004067 bulking agent Substances 0.000 description 2
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229940005657 pyrophosphoric acid Drugs 0.000 description 2
- 238000004017 vitrification Methods 0.000 description 2
- 229910014033 C-OH Inorganic materials 0.000 description 1
- 229910014570 C—OH Inorganic materials 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 206010051246 Photodermatosis Diseases 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- OMUGFZNEOIWQOD-UHFFFAOYSA-N boric acid;zinc Chemical compound [Zn].OB(O)O OMUGFZNEOIWQOD-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002135 nanosheet Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000008845 photoaging Effects 0.000 description 1
- 239000002990 reinforced plastic Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000009955 starching Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/58—Component parts, details or accessories; Auxiliary operations
- B29B7/72—Measuring, controlling or regulating
- B29B7/726—Measuring properties of mixture, e.g. temperature or density
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/76—Measuring, controlling or regulating
- B29C45/78—Measuring, controlling or regulating of temperature
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2945/00—Indexing scheme relating to injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould
- B29C2945/76—Measuring, controlling or regulating
- B29C2945/76494—Controlled parameter
- B29C2945/76531—Temperature
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2377/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2475/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2475/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The invention discloses a kind of glass fiber reinforced PA66 electric armour clamp material of weather-resistance flame-retardant, and its preparation technology, characterized in that, with PA66, glass fibre, melamine cyanurate, Firebrake ZB, hypo-aluminum orthophosphate, bamboo charcoal, carbon fiber, silicone rubber, aqueous polyurethane, maleic anhydride inoculated polypropylene, bovine serum albumin solution, crystal whisker of hexa potassium titanate, graphene oxide, multi-walled carbon nano-tubes, Hydroxylated acrylic resin, tripoli, aliphatic polymeric isocyanate etc. as raw material.The present invention is coated to melamine cyanurate using Firebrake ZB, obtains composite flame-retardant agent；With bovine serum albumin modified glass-fiber surface, the glass fiber compound material of graphite oxide cladding is prepared using electrostatic absorption principle；The acroleic acid polyurethane composite coating containing tripoli is prepared for, is sprayed on PA66 and is formed coating, with more preferable corrosion resistance, good mechanical property；Obtain a kind of glass fiber reinforced PA66 electric armour clamp material of weather-resistance flame-retardant.
Description
Technical field
The present invention relates to electric armour clamp Material Field, and in particular to a kind of glass fiber reinforced PA66 electric armour clamp of weather-resistance flame-retardant
Material, and its preparation technology.
Background technology
Gold utensil is the vitals during power transmission, for the purpose of energy-saving and emission-reduction, develops new easy processing, recyclable
Plastics electric armour clamp material there is important practical significance.Glass fiber reinforced PA66 composite has good mechanical performance, ratio
Little, electrical insulation capability is superior and many merits such as easy processing molding for weight, but in view of gold utensil is used for outdoor high-altitude, use environment is disliked
It is bad, and nylon is degradable in the presence of long-term water, illumination and heat.
Chao Fen is in paper《The preparation and performance study of novel plastic electric armour clamp material》In, make functional agglomerate by oneself, improve
The long-term resistant to hydrolysis of glass fiber reinforced PA66 material and ageing-resistant performance, so as to obtain the novel plastic electric power for meeting use requirement
Gold utensil material.PA66 and other auxiliary agents are added to be sufficiently mixed in homogenizer by different proportion respectively and obtains premix material, will
Particle from the main charge door and side loading mouth blanking extruding pelletization of double screw extruder, is subsequently put into by premix material and glass respectively
4h is dried in 120 DEG C in baking oven, then sample is injected into injection machine.But the material weatherability for obtaining is not enough, and does not possess
Fire resistance.
The present invention with hypo-aluminum orthophosphate as fire retardant, with bamboo charcoal as synergist, using Firebrake ZB to melamine cyanurate
Coated, obtained composite flame-retardant agent；With maleic anhydride inoculated polypropylene as bulking agent, the silicone rubber with nucleocapsid structure is as toughness reinforcing
Agent, fibre reinforced PA66 have excellent mechanical property, self lubricity and electric conductivity；With bovine serum albumin modified glass
Fiber surface, prepares the glass fiber compound material of graphite oxide cladding using electrostatic absorption principle；Multi-walled carbon nano-tubes plus
Enter to improve the mechanical property and vitrification point of PA66 fibers；The acroleic acid polyurethane composite coating containing tripoli is prepared for,
It is sprayed on PA66 and forms coating, with more preferable corrosion resistance, good mechanical property；Obtain a kind of glass of weather-resistance flame-retardant
Reinforced plastic PA66 electric armour clamp material.
The content of the invention
The invention mainly solves the technical problem of providing a kind of glass fiber reinforced PA66 electric armour clamp material of weather-resistance flame-retardant
And its preparation technology, there is light weight, weather-proof, fire-retardant premium properties according to the electric armour clamp material of technique making.
The technical problem to be solved is realized using following technical scheme：
PA66 30-40, glass fibre 15-25, melamine cyanurate 3-6, Firebrake ZB 2-4, hypophosphorous acid
Aluminum 2-5, bamboo charcoal 1-3, carbon fiber 4-8, silicone rubber 2-5, aqueous polyurethane 1-4, maleic anhydride inoculated polypropylene 2-5, cattle
Serum albumin solution 1-3, crystal whisker of hexa potassium titanate 2-3, graphene oxide 1-2, multi-walled carbon nano-tubes 3-5, hydroxy acrylic acid tree
Fat 2-4, tripoli 1-3, aliphatic polymeric isocyanate 1-2, NaOH solution, NH4HCO3, acetone, HCl solution, appropriate dimethylbenzene.
The preparation method of the glass fiber reinforced PA66 electric armour clamp material of a kind of weather-resistance flame-retardant, it is characterised in that by following step
Suddenly carry out：
A. add NaOH solution in melamine cyanurate, stir, add Firebrake ZB, 60-90 DEG C of reaction 1- of intensification
2h, obtains thick white product, and sucking filtration, washing 3-5 time are dried 1-2h in 110-160 DEG C；By hypo-aluminum orthophosphate, bamboo charcoal in 100-140
DEG C drying 1-2h after, mix with the former, superfine grinding obtains composite flame-retardant agent；
B. carbon fiber is placed in desizing furnace, under nitrogen protection, high temperature desizing process is carried out in 400-600 DEG C, is subsequently placed in
Electrolyte NH4HCO3In, be electrolysed 90-150s at 50-90 DEG C, wash 3-5 time, 90-130 DEG C is dried 1-2h, then with silicone rubber, water
Property polyurethane mixing；Maleic anhydride inoculated polypropylene is dried after 1-2 h in 70-90 DEG C of vacuum drying oven, is mixed with the former
Ball milling 1-2h is stand-by；
C. by glass fibre, soaking and washing processes 0.5-1h in acetone, and in HCl solution, hydroxylating processes 1-2h, washes 3-5
Secondary, the submergence 0.5-1h in bovine serum albumin solution is washed 3-5 time, adds dividing for crystal whisker of hexa potassium titanate and graphene oxide
Dispersion liquid, uniform stirring, ultrasonic disperse adjust pH value of solution 3-6, stand 0.5-1h, rinse 3-5 time, and 60-90 DEG C of drying obtains Graphene
The glass fiber compound material of cladding；
D. in PA66 being dried 1-2h, with multi-walled carbon nano-tubes and a, b in 70-90 DEG C of vacuum drying oven, resulting material is added
Premix material is sufficiently mixed to obtain in homogenizer, by resulting material in premix material and c respectively from the main charging of double screw extruder
Mouth and side loading mouth blanking, in 250-280 DEG C of extruding pelletization, are subsequently put into particle in baking oven and are dried 2-4h in 110-130 DEG C,
Then sample is injected in 260-290 DEG C with injection machine；
E. tripoli will be added under high speed dispersion condition during Hydroxylated acrylic resin 10: 3-5 adds dimethylbenzene, ball milling 1-2h, with
Aliphatic polymeric isocyanate mix homogeneously, using the resulting surface of material prepares coating in d of aerial spraying mode, room temperature is dried in the air
It is dry, obtain final product a kind of glass fiber reinforced PA66 electric armour clamp material of weather-resistance flame-retardant.
The present invention reaction mechanism and have the beneficial effect that：
（1）Hypo-aluminum orthophosphate (AHP) has the advantages that phosphorus content height, good flame retardation effect, and the addition of synergist bamboo charcoal can promote AHP
Degraded generates phosphoric acid and pyrophosphoric acid, and in solid phase, phosphoric acid and pyrophosphoric acid can promote what PA66 was produced after being degraded into charcoal, and degraded
Fine and close layer of charcoal can prevent oxygen and heat transfer to inside polymeric matrix, be conducive to improving the fire resistance of material；Tripolycyanamide
Cyanurate（MCA）It is a kind of typical nitrogen system bittern-free fire retardant, odorless, tasteless, decomposition temperature are high, low-smoke low-toxicity, using boric acid
Zinc is controlled to MCA, makes Firebrake ZB dispersed deposition on MCA surfaces, MCA is coated, be separated into less independent reaction
System so that the viscosity of reaction system remains at a relatively low level.
（2）Fibre reinforced PA66 has excellent mechanical property, self lubricity and electric conductivity, first carries out carbon fiber
Electrochemical surface treatment, introduces active group such as-C-OH and-COOH in carbon fiber surface, then with aqueous polyurethane to carbon
Fiber carries out starching process, possesses more preferable interfacial combined function after process with PA66, and prepared composite also possesses more
High mechanical property, with maleic anhydride inoculated polypropylene as bulking agent, the silicone rubber with nucleocapsid structure is as toughener.
（3）With bovine serum albumin modified glass-fiber surface, graphite oxide cladding is prepared using electrostatic absorption principle
Glass fiber compound material, with excellent flexible and heat stability.Crystal whisker of hexa potassium titanate hardness is low, it is not easy to wear to flour milling,
The compatibility with organic polymer matrix is projected, the good dispersion in polymeric matrix.
（4）The addition of multi-walled carbon nano-tubes improves the mechanical property and vitrification point of PA66 fibers；Tripoli has micro-
Rice-shaped silicon oxide and the kaolinic combinative structure of nano-sheet, advantageously improve permeability resistance and mechanical property, are prepared for containing
There is the acroleic acid polyurethane composite coating of tripoli, be sprayed on PA66 and form coating, with more preferable corrosion resistance, good power
Learn performance.
Specific embodiment
In order that technological means, creation characteristic, reached purpose and effect that the present invention is realized are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further.
Embodiment
A kind of glass fiber reinforced PA66 electric armour clamp material of weather-resistance flame-retardant, is obtained by the raw material of following weight parts (g)：
PA6640, glass fibre 25, melamine cyanurate 3, Firebrake ZB 2, hypo-aluminum orthophosphate 5, bamboo charcoal 1, carbon fiber 4, silicon rubber
Glue 2, aqueous polyurethane 1, maleic anhydride inoculated polypropylene 5, bovine serum albumin solution 3, crystal whisker of hexa potassium titanate 2, graphite oxide
Alkene 1, multi-walled carbon nano-tubes 3, Hydroxylated acrylic resin 2, tripoli 1, aliphatic polymeric isocyanate 1, NaOH solution, NH4HCO3, third
Ketone, HCl solution, appropriate dimethylbenzene.
The preparation method of the glass fiber reinforced PA66 electric armour clamp material of a kind of weather-resistance flame-retardant, it is characterised in that by following step
Suddenly carry out：
A. add NaOH solution in melamine cyanurate, stir, add Firebrake ZB, heat up 80 DEG C of reaction 1h, obtains white
Color viscous product, sucking filtration, washing 3 times, is dried 1h in 130 DEG C；It is after hypo-aluminum orthophosphate, bamboo charcoal are dried 1h at 120 DEG C, mixed with the former
Close, superfine grinding obtains composite flame-retardant agent；
B. carbon fiber is placed in desizing furnace, under nitrogen protection, high temperature desizing process is carried out in 550 DEG C, electrolysis is subsequently placed in
Liquid NH4HCO3In, 150s is electrolysed at 70 DEG C, wash 3 times, 120-130 DEG C is dried 1h, then is mixed with silicone rubber, aqueous polyurethane；
It is after maleic anhydride inoculated polypropylene is dried 1h in 80-90 DEG C of vacuum drying oven, stand-by with the former mixing and ball milling 1h；
C. by glass fibre, soaking and washing processes 0.5h in acetone, and in HCl solution, hydroxylating processes 1h, washes 3 times,
Submergence 0.5h in bovine serum albumin solution, washes 3 times, adds the dispersion liquid of crystal whisker of hexa potassium titanate and graphene oxide, uniformly
PH value of solution 5 is adjusted in stirring, ultrasonic disperse, stands 0.5h, is rinsed 3 times, and 80-90 DEG C of drying obtains the glass fibre of graphene coated
Composite；
D. in PA66 being dried 1h, with multi-walled carbon nano-tubes and a, b in 70-80 DEG C of vacuum drying oven, resulting material adds height
Premix material is sufficiently mixed to obtain in fast blender, by resulting material in premix material and c respectively from the main charge door of double screw extruder
With side loading mouth blanking, in 270-280 DEG C of extruding pelletization, subsequently particle is put in baking oven and 2h is dried in 120-130 DEG C, then
Sample is injected in 280-290 DEG C with injection machine；
E. Hydroxylated acrylic resin 10: 3 is added in dimethylbenzene, under high speed dispersion condition, adds tripoli, ball milling 1h, with fat
Adoption isocyanates mix homogeneously, using the resulting surface of material prepares coating in d of aerial spraying mode, room temperature is dried,
Obtain final product a kind of glass fiber reinforced PA66 electric armour clamp material of weather-resistance flame-retardant.
A kind of performance test results of the glass fiber reinforced PA66 electric armour clamp material of weather-resistance flame-retardant prepared by above-described embodiment
It is as follows：
Jing hydrolytic resistances（Ethylene glycol, 135 DEG C, 48h）After test, tensile strength rate of change is 40%, and bending strength rate of change is
45%, impact strength rate of change is 130%, and weight rate is 10%；Bending property loss rate ＜ 50%, meets use requirement；
Jing heat ageings（150 DEG C, 2000h）Test, tensile strength rate of change are 15%, and bending strength rate of change is 10%, and impact is strong
Degree rate of change is 9%, meets the requirement of loss rate ＜ 25%；
Jing photoaging（2000h）Test, tensile strength rate of change are 18%, and bending strength rate of change is 14%, impact strength change
Rate is 8%, meets the requirement of loss rate ＜ 30%.
Claims (2)
1. the glass fiber reinforced PA66 electric armour clamp material of a kind of weather-resistance flame-retardant, it is characterised in that by the raw material system of following weight parts
：
PA66 30-40, glass fibre 15-25, melamine cyanurate 3-6, Firebrake ZB 2-4, hypophosphorous acid
Aluminum 2-5, bamboo charcoal 1-3, carbon fiber 4-8, silicone rubber 2-5, aqueous polyurethane 1-4, maleic anhydride inoculated polypropylene 2-5, cattle
Serum albumin solution 1-3, crystal whisker of hexa potassium titanate 2-3, graphene oxide 1-2, multi-walled carbon nano-tubes 3-5, hydroxy acrylic acid tree
Fat 2-4, tripoli 1-3, aliphatic polymeric isocyanate 1-2, NaOH solution, NH4HCO3, acetone, HCl solution, appropriate dimethylbenzene.
2. the preparation method of the glass fiber reinforced PA66 electric armour clamp material of a kind of weather-resistance flame-retardant according to claim 1, its
It is characterised by, carries out according to the following steps：
A. add NaOH solution in melamine cyanurate, stir, add Firebrake ZB, 60-90 DEG C of reaction 1- of intensification
2h, obtains thick white product, and sucking filtration, washing 3-5 time are dried 1-2h in 110-160 DEG C；By hypo-aluminum orthophosphate, bamboo charcoal in 100-140
DEG C drying 1-2h after, mix with the former, superfine grinding obtains composite flame-retardant agent；
B. carbon fiber is placed in desizing furnace, under nitrogen protection, high temperature desizing process is carried out in 400-600 DEG C, is subsequently placed in
Electrolyte NH4HCO3In, be electrolysed 90-150s at 50-90 DEG C, wash 3-5 time, 90-130 DEG C is dried 1-2h, then with silicone rubber, water
Property polyurethane mixing；Maleic anhydride inoculated polypropylene is dried after 1-2 h in 70-90 DEG C of vacuum drying oven, is mixed with the former
Ball milling 1-2h is stand-by；
C. by glass fibre, soaking and washing processes 0.5-1h in acetone, and in HCl solution, hydroxylating processes 1-2h, washes 3-5
Secondary, the submergence 0.5-1h in bovine serum albumin solution is washed 3-5 time, adds dividing for crystal whisker of hexa potassium titanate and graphene oxide
Dispersion liquid, uniform stirring, ultrasonic disperse adjust pH value of solution 3-6, stand 0.5-1h, rinse 3-5 time, and 60-90 DEG C of drying obtains Graphene
The glass fiber compound material of cladding；
D. in PA66 being dried 1-2h, with multi-walled carbon nano-tubes and a, b in 70-90 DEG C of vacuum drying oven, resulting material is added
Premix material is sufficiently mixed to obtain in homogenizer, by resulting material in premix material and c respectively from the main charging of double screw extruder
Mouth and side loading mouth blanking, in 250-280 DEG C of extruding pelletization, are subsequently put into particle in baking oven and are dried 2-4h in 110-130 DEG C,
Then sample is injected in 260-290 DEG C with injection machine；
E. tripoli will be added under high speed dispersion condition during Hydroxylated acrylic resin 10: 3-5 adds dimethylbenzene, ball milling 1-2h, with
Aliphatic polymeric isocyanate mix homogeneously, using the resulting surface of material prepares coating in d of aerial spraying mode, room temperature is dried in the air
It is dry, obtain final product a kind of glass fiber reinforced PA66 electric armour clamp material of weather-resistance flame-retardant.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019100592A1 (en) * | 2017-11-22 | 2019-05-31 | 江苏利思德新材料有限公司 | Halogen-free flame retardant compound system for glass fiber reinforced nylon and application thereof in halogen-free flame retardant glass fiber reinforced nylon material |
| CN112442282A (en) * | 2019-09-01 | 2021-03-05 | 南京航空航天大学 | Graphene-coated glass wool felt resin composite plate and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103044912A (en) * | 2012-11-28 | 2013-04-17 | 江苏金发科技新材料有限公司 | Halogen-free flame retardant continuous long glass fiber reinforced polyamide 66 composite material and preparation method thereof |
| CN103194023A (en) * | 2013-03-19 | 2013-07-10 | 深圳市亚塑科技有限公司 | Glass fiber reinforced PP/PA6 (Polypropylene/Polyamide6) composite material and preparation method and application thereof |
-
2016
- 2016-11-04 CN CN201610959153.8A patent/CN106543714A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103044912A (en) * | 2012-11-28 | 2013-04-17 | 江苏金发科技新材料有限公司 | Halogen-free flame retardant continuous long glass fiber reinforced polyamide 66 composite material and preparation method thereof |
| CN103194023A (en) * | 2013-03-19 | 2013-07-10 | 深圳市亚塑科技有限公司 | Glass fiber reinforced PP/PA6 (Polypropylene/Polyamide6) composite material and preparation method and application thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019100592A1 (en) * | 2017-11-22 | 2019-05-31 | 江苏利思德新材料有限公司 | Halogen-free flame retardant compound system for glass fiber reinforced nylon and application thereof in halogen-free flame retardant glass fiber reinforced nylon material |
| CN112442282A (en) * | 2019-09-01 | 2021-03-05 | 南京航空航天大学 | Graphene-coated glass wool felt resin composite plate and preparation method thereof |
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Application publication date: 20170329 |