CN106479704A - Greasy dirt emulsifying agent and preparation method thereof - Google Patents
Greasy dirt emulsifying agent and preparation method thereof Download PDFInfo
- Publication number
- CN106479704A CN106479704A CN201610778437.7A CN201610778437A CN106479704A CN 106479704 A CN106479704 A CN 106479704A CN 201610778437 A CN201610778437 A CN 201610778437A CN 106479704 A CN106479704 A CN 106479704A
- Authority
- CN
- China
- Prior art keywords
- emulsifying agent
- greasy dirt
- dirt emulsifying
- polyoxyethylene ether
- caustic soda
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000003995 emulsifying agent Substances 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 45
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 18
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 18
- 239000007787 solid Substances 0.000 claims abstract description 17
- 235000011121 sodium hydroxide Nutrition 0.000 claims abstract description 15
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000292 calcium oxide Substances 0.000 claims abstract description 11
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 11
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 8
- 239000003960 organic solvent Substances 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 30
- 238000006243 chemical reaction Methods 0.000 claims description 23
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 18
- 239000003921 oil Substances 0.000 claims description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- 239000012043 crude product Substances 0.000 claims description 16
- 239000013067 intermediate product Substances 0.000 claims description 16
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- XQSFXFQDJCDXDT-UHFFFAOYSA-N hydroxysilicon Chemical compound [Si]O XQSFXFQDJCDXDT-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- 238000005292 vacuum distillation Methods 0.000 claims description 7
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 5
- -1 polyoxy Polymers 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 150000001336 alkenes Chemical class 0.000 claims 1
- 229940059574 pentaerithrityl Drugs 0.000 claims 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical group OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 6
- 230000001804 emulsifying effect Effects 0.000 abstract description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract description 2
- 238000005238 degreasing Methods 0.000 abstract description 2
- 239000006185 dispersion Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 8
- 239000010865 sewage Substances 0.000 description 5
- 239000010779 crude oil Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 238000004807 desolvation Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- CIBMHJPPKCXONB-UHFFFAOYSA-N propane-2,2-diol Chemical compound CC(C)(O)O CIBMHJPPKCXONB-UHFFFAOYSA-N 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/82—Compounds containing silicon
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention discloses a kind of greasy dirt emulsifying agent, belong to chemical material field.It is made up of following components：Polyoxyethylene ether 30～50%；Siliceous end-capping reagent 5～20%；Solid caustic soda 5～15%；Calcium oxide 1～5%；Organic solvent 10～30%.Introduce silane chain in this emulsifier molecules structure, obtain the greasy dirt emulsifying agent showing that activity is higher；This preparation method is simple, and showing that the high siliceous greasy dirt emulsifying agent of activity can reduce the tension force of greasy surfaces, surface tension is less, the more easy emulsified dispersion of greasy dirt, the emulsifying capacity making greasy dirt emulsifying agent strengthens, and consumption can reach preferable degreasing result less.The invention also discloses the preparation method of above-mentioned greasy dirt emulsifying agent.
Description
Technical field
The present invention relates to a kind of emulsifying agent, it is especially a kind of for processing to oil field equipment, pipeline and greasy dirt articles for use
Greasy dirt emulsifying agent and preparation method thereof, belongs to chemical material field.
Background technology
Oilfield exploitation enters tertiary phase at present, generally carries out the displacement of reservoir oil using the mode of reinjected water, in the process,
Requirement for reinjected water is higher, also makes Produced Liquid contain large amount of sewage simultaneously.When these sewage are via pipeline, due to
Gravitational difference reason meeting natural subsidence is out.And more or less all can carry some crude oil in sewage, when processing these sewage,
Wherein a small amount of crude oil will be attached to equipment or pipe surface it is more difficult to clear up.When crude oil flows in pipeline, if temperature is relatively low
Or viscosity of crude is larger, if not checked to pipeline it is also possible to be caused the blocking of pipeline for a long time, affect the normal of oil field
Produce.Some oil fields are to be transported using groove tank car for the mode of movement of Produced Liquid, are readily formed oil reservoir in groove tank
Pile up, such as clear up not in time, the volume of tank car can be caused to reduce, increase cost of transportation.If in addition, removing not in time in reinjected water
A small amount of crude oil of remaining also can affect the normal operation to sewage disposal in oil field.Therefore, cleaning greasy dirt becomes oil field life in time
An important link in product.Traditional method has the method using vapour cooking, is made a return journey using high temperature and degreases, but this
The high cost of method, and high temperature is also relatively unsafe for operator；Later, there is also greasy dirt on the market
Emulsifying agent, but mostly there is the shortcomings of emulsifying effectiveness is not good, consumption is many, functional group is single, and current market exists simultaneously
Greasy dirt emulsifier is less, and less for emulsifier for oil fields, therefore, greasy dirt emulsifying agent provided by the present invention is for oil field
The greasy dirt such as equipment pipe removal significant.
Content of the invention
The technical problem to be solved is to overcome prior art defect, provides a kind of surface activity height, emulsifying
Greasy dirt effect is good and consumption is low, preparation process simple greasy dirt emulsifying agent and preparation method thereof.
In order to solve above-mentioned technical problem, the greasy dirt emulsifying agent that the present invention provides, by weight percentage, it is by with the following group
Divide and make：
Polyoxyethylene ether 30～50%；
Siliceous end-capping reagent 5～20%；
Solid caustic soda 5～15%；
Calcium oxide 1～5%；
Organic solvent 10～30%.
Further, described polyoxyethylene ether be polyoxyethylene pentaerythritol, octadecanol polyoxyethylene ether, nonyl phenol gather
The mixture of one or more of oxygen vinyl Ether.
Further, described siliceous end-capping reagent is the hydroxy silicon oil of molecular weight 100～1000.
Further, described solid caustic soda is the mixture of one or more of sodium hydroxide, potassium hydroxide.
Further, described solid caustic soda mean diameter is in 60～425 mesh.
Further, described solvent is the mixture of one or more of methanol, ethanol, isopropanol.
Present invention also offers the preparation method of above-mentioned greasy dirt emulsifying agent is it is characterised in that comprise the following steps：
1) polyoxyethylene ether, solid caustic soda and calcium oxide are added in reactor, under 60～120 DEG C of temperature conditionss, stir
Mix reaction 1～3 hour, obtain intermediate product；
2) in step 2) be obtained intermediate product in the siliceous end-capping reagent of Deca, dropwise reaction 1 hour, after completion of dropping continue
Stirring reaction obtains emulsifying agent crude product in 2～4 hours；
3) add organic solvent dissolving crude product, stirring stood after 1～2 hour, solids removed by filtration material, then steaming of reducing pressure
Evaporate desolvation and obtain greasy dirt emulsifying agent.
Having the beneficial effects that with respect to prior art：By in the basic conditions, by the hydroxyl of siliceous end-capping reagent
There is etherification reaction with the terminal hydroxy group of polyoxyethylene ether in base, introduce silane chain in molecular structure, obtains and shows that activity is higher
Greasy dirt emulsifying agent；This preparation method is simple, and shows that the high siliceous greasy dirt emulsifying agent of activity can reduce the tension force of greasy surfaces,
Surface tension is less, and the more easy emulsified dispersion of greasy dirt is so that the emulsifying capacity of greasy dirt emulsifying agent strengthens, and consumption is few permissible
Reach preferable degreasing result.
Specific embodiment
With reference to specific embodiment, the present invention is elaborated.
Embodiment 1
1) by 40 grams of industrial polyoxyethylene ether (NJ-301, Jurong Ningwu new material limited company product), i.e. 400
Eight carbon polyoxyethylenated alcohol, 4 grams of sodium hydroxide, 5 grams of potassium hydroxide, 1 gram of calcium oxide add with stirring, Dropping feeder and condensation
In the reactor of pipe, reaction under 80 DEG C of stirring conditions obtains intermediate product in 2 hours.
2) in above-mentioned intermediate product, Deca 20 gram-molecular weight is 466 hydroxy silicon oil, and dropwise reaction 1 hour drips
Continue stirring reaction after finishing and obtain crude product in 3 hours.
3) 30 grams of ethanol are added to dissolve crude product, stirring stood after 1 hour, filtered off solid matter, then vacuum distillation removing
Solvent obtains greasy dirt emulsifying agent.
Embodiment 2
1) by 50 grams of industrial polyoxyethylene ether (NJ-303, Jurong Ningwu new material limited company product), i.e. 50 seasons
Penta 4 polyoxyethylenated alcohol, 5 grams of sodium hydroxide and 5 grams of calcium oxide add the reactor with stirring, Dropping feeder and condensing tube
In, reaction under 60 DEG C of stirring conditions obtains intermediate product in 3 hours.
2) in above-mentioned intermediate product, Deca 15 gram-molecular weight is 326 hydroxy silicon oil, and dropwise reaction 1 hour drips
Continue stirring reaction after finishing and obtain crude product in 3 hours.
3) 25 grams of ethanol are added to dissolve crude product, stirring stood after 1 hour, filtered off solid matter, then vacuum distillation removing
Solvent obtains greasy dirt emulsifying agent.
Embodiment 3
1) by 30 grams of industrial polyoxyethylene ether (NJ-306, Jurong Ningwu new material limited company product), i.e. 30 grams
NPE, 15 grams of potassium hydroxide and 5 grams of calcium oxide add the reactor with stirring, Dropping feeder and condensing tube
In, reaction under 120 DEG C of stirring conditions obtains intermediate product in 1 hour.
2) in above-mentioned intermediate product, Deca 20 gram-molecular weight is 758 hydroxy silicon oil, and dropwise reaction 1 hour drips
Continue stirring reaction after finishing and obtain crude product in 4 hours.
3) 15 grams of ethanol and 15 grams of isopropanols are added to dissolve crude product, stirring stood after 2 hours, filtered off solid matter,
Vacuum distillation desolvation obtains greasy dirt emulsifying agent again.
Embodiment 4
1) by 50 grams of industrial polyoxyethylene ether (NJ-303, Jurong Ningwu new material limited company product), i.e. 50 grams
Polyoxyethylene pentaerythritol, 15 grams of potassium hydroxide and 5 grams of calcium oxide add the reaction with stirring, Dropping feeder and condensing tube
In device, reaction under 100 DEG C of stirring conditions obtains intermediate product in 2 hours.
2) in above-mentioned intermediate product, Deca 20 gram-molecular weight is 980 hydroxy silicon oil, and dropwise reaction 1 hour drips
Continue stirring reaction after finishing and obtain crude product in 2 hours.
3) 10 grams of methanol are added to dissolve crude product, stirring stood after 1 hour, filtered off solid matter, then vacuum distillation removing
Solvent obtains greasy dirt emulsifying agent.
Embodiment 5
1) by 25 grams of industrial polyoxyethylene ether (NJ-301, Jurong Ningwu new material limited company product) and 20 grams
Industrial polyoxyethylene ether (NJ-303, Jurong Ningwu new material limited company product), i.e. 25 octadecanol polyoxyethylene ether
And 20 grams of polyoxyethylene pentaerythritols, 15 grams of sodium hydroxide, 5 grams of calcium oxide add with stirring, Dropping feeder and condensation
In the reactor of pipe, reaction under 80 DEG C of stirring conditions obtains intermediate product in 2 hours.
2) in above-mentioned intermediate product, Deca 5 gram-molecular weight is 1000 hydroxy silicon oil, and dropwise reaction 1 hour drips
Continue stirring reaction after finishing and obtain crude product in 3 hours.
3) 30 grams of ethanol are added to dissolve crude product, stirring stood after 1 hour, filtered off solid matter, then vacuum distillation removing
Solvent obtains greasy dirt emulsifying agent.
Embodiment 6
1) by 40 grams of industrial polyoxyethylene ether (NJ-301, Jurong Ningwu new material limited company product), i.e. 400
Eight carbon polyoxyethylenated alcohol, 6 grams of sodium hydroxide, 6 grams of potassium hydroxide, 3 grams of calcium oxide add with stirring, Dropping feeder and condensation
In the reactor of pipe, reaction under 80 DEG C of stirring conditions obtains intermediate product in 2 hours.
2) in above-mentioned intermediate product, Deca 20 gram-molecular weight is 100 hydroxy silicon oil, and dropwise reaction 1 hour drips
Continue stirring reaction after finishing and obtain crude product in 3 hours.
3) 25 grams of isopropanol alcohol are added to dissolve crude product, stirring stood after 1 hour, filtered off solid matter, then vacuum distillation
Desolvation obtains greasy dirt emulsifying agent.
The above is only the preferred embodiment of the present invention it is noted that ordinary skill people for the art
For member, on the premise of without departing from the technology of the present invention principle, some improvement and modification can also be made, these improve and modification
Also should be regarded as protection scope of the present invention.
Claims (7)
1. it is characterised in that by weight percentage, it is made up a kind of greasy dirt emulsifying agent of following components：
Polyoxyethylene ether 30～50%；
Siliceous end-capping reagent 5～20%；
Solid caustic soda 5～15%；
Calcium oxide 1～5%；
Organic solvent 10～30%.
2. greasy dirt emulsifying agent according to claim 1 it is characterised in that：Described polyoxyethylene ether is tetramethylolmethane polyoxy second
The mixture of one or more of alkene ether, octadecanol polyoxyethylene ether, NPE.
3. greasy dirt emulsifying agent according to claim 1 and 2 it is characterised in that：Described siliceous end-capping reagent be molecular weight 100～
1000 hydroxy silicon oil.
4. greasy dirt emulsifying agent according to claim 3 it is characterised in that：Described solid caustic soda is sodium hydroxide, in potassium hydroxide
The mixture of one or more.
5. greasy dirt emulsifying agent according to claim 4 it is characterised in that：The mean diameter of described solid caustic soda is in 60～425
Mesh.
6. greasy dirt emulsifying agent according to claim 5 it is characterised in that：Described solvent is methanol, ethanol, in isopropanol
The mixture of one or more.
7. the preparation method of the greasy dirt emulsifying agent described in claim 1 is it is characterised in that comprise the following steps：
1) polyoxyethylene ether, solid caustic soda and calcium oxide are added in reactor, under 60～120 DEG C of temperature conditionss, stirring is anti-
Answer 1～3 hour, obtain intermediate product；
2) in step 2) the siliceous end-capping reagent of Deca in the intermediate product that is obtained, continues stirring reaction 2～4 hours after completion of dropping
Emulsifying agent crude product；
3) add organic solvent dissolving crude product, stirring stood after 1～2 hour, solids removed by filtration material, then vacuum distillation takes off
Except solvent obtains greasy dirt emulsifying agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610778437.7A CN106479704A (en) | 2016-08-30 | 2016-08-30 | Greasy dirt emulsifying agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610778437.7A CN106479704A (en) | 2016-08-30 | 2016-08-30 | Greasy dirt emulsifying agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106479704A true CN106479704A (en) | 2017-03-08 |
Family
ID=58273345
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610778437.7A Pending CN106479704A (en) | 2016-08-30 | 2016-08-30 | Greasy dirt emulsifying agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106479704A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114850621A (en) * | 2022-06-13 | 2022-08-05 | 张炜 | Method for welding oil stain welding part |
| CN115612564A (en) * | 2022-10-24 | 2023-01-17 | 句容宁武高新技术发展有限公司 | A kind of water-soluble oil emulsifier and its synthetic method |
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| CN1539884A (en) * | 2003-04-23 | 2004-10-27 | 上海西利康高新技术合作公司 | Non-ion type latex of hydroxy silicone oil and preparation method |
| CN1565431A (en) * | 2003-06-12 | 2005-01-19 | 中国医学科学院血液学研究所 | 3,4-dihydroxylbenzaldehyde pharmaceutical use |
| WO2007101059A2 (en) * | 2006-02-24 | 2007-09-07 | Lubrizol Advanced Materials, Inc. | Polymers containing silicone copolyol macromers and personal care compositions containing same |
-
2016
- 2016-08-30 CN CN201610778437.7A patent/CN106479704A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1539884A (en) * | 2003-04-23 | 2004-10-27 | 上海西利康高新技术合作公司 | Non-ion type latex of hydroxy silicone oil and preparation method |
| CN1565431A (en) * | 2003-06-12 | 2005-01-19 | 中国医学科学院血液学研究所 | 3,4-dihydroxylbenzaldehyde pharmaceutical use |
| WO2007101059A2 (en) * | 2006-02-24 | 2007-09-07 | Lubrizol Advanced Materials, Inc. | Polymers containing silicone copolyol macromers and personal care compositions containing same |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114850621A (en) * | 2022-06-13 | 2022-08-05 | 张炜 | Method for welding oil stain welding part |
| CN115612564A (en) * | 2022-10-24 | 2023-01-17 | 句容宁武高新技术发展有限公司 | A kind of water-soluble oil emulsifier and its synthetic method |
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| C06 | Publication | ||
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Application publication date: 20170308 |