CN105771144A - Preparation method of high-molecular thickening forest fire extinguishing agent - Google Patents
Preparation method of high-molecular thickening forest fire extinguishing agent Download PDFInfo
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- CN105771144A CN105771144A CN201610147242.2A CN201610147242A CN105771144A CN 105771144 A CN105771144 A CN 105771144A CN 201610147242 A CN201610147242 A CN 201610147242A CN 105771144 A CN105771144 A CN 105771144A
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0028—Liquid extinguishing substances
- A62D1/0035—Aqueous solutions
- A62D1/0042—"Wet" water, i.e. containing surfactant
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Abstract
本发明提供了一种高分子增稠森林灭火剂的制备方法,其配方为硫酸铵75‑100份,尿素175‑200份,高分子增稠剂0.5‑1.5份,水475‑550份。制备步骤为先将硫酸铵以及尿素溶于水中,高分子增稠剂单独溶解于水,然后两种水溶液混合搅拌0.5h‑1h至粘稠状。本发明的优点在于用高分子试剂做增稠剂可以使得灭火剂稳定性好、有效粘度高并且又耐储存,增稠后的森林灭火剂可以提高从树冠到地表可燃物的渗透能力,保持更长的阻滞火焰蔓延时间,而且可以在较高的喷洒作业高度下进行喷洒,对灭火人员而言更加安全。The invention provides a preparation method of a macromolecular thickening forest fire extinguishing agent, the formula of which is 75-100 parts of ammonium sulfate, 175-200 parts of urea, 0.5-1.5 parts of a polymer thickener and 475-550 parts of water. The preparation steps are as follows: dissolving ammonium sulfate and urea in water first, dissolving the polymer thickener in water alone, and then mixing and stirring the two aqueous solutions for 0.5h-1h until viscous. The present invention has the advantages of using a polymer reagent as a thickening agent to make the fire extinguishing agent good in stability, high in effective viscosity and resistant to storage, and the thickened forest fire extinguishing agent can improve the penetration ability from tree crowns to surface combustibles and keep more stable. It has a long flame retardation time and can be sprayed at a higher spraying height, which is safer for firefighters.
Description
技术领域 technical field
本发明属于消防用品消防材料领域,具体涉及一种高分子增稠森林灭火剂的制备方法。 The invention belongs to the field of fire-fighting materials for fire-fighting supplies, and in particular relates to a preparation method of a polymer-thickened forest fire-extinguishing agent.
背景技术 Background technique
目前市场上森林灭火剂按作用时间长短可分为短效灭火剂和长效灭火剂两种。短效灭火剂包括纯水、增稠水、泡沫灭火剂等,当其水完全蒸发后就不具备阻火和灭火能力;而像磷酸氢二铵、硫酸铵、碳酸铵、硫酸铵等水溶液即使水分被蒸发后仍然具有阻火和灭火能力,故而这种灭火剂被称为长效灭火剂。灭火剂使用方法一般为喷射或者空中喷洒,但是有一个及其严重的缺点,在使用时尤其是进行空中喷洒时,灭火剂在降落过程中,受到风的剪切力后呈雾状然后随风飘散,导致能够到达地面的灭火剂大大减少,甚至在一定高度时灭火剂根本到达不了地面。故对灭火剂进行增稠是必不可少的,目前灭火剂增稠剂主要分为两种,一种是黏土(如皂土)做增稠剂,但是也存在随风飘散的缺点;第二种是以树胶作为增稠剂(如藻朊酸胶、果胶、瓜尔胶等),但该类天然材料价格比较昂贵,且存在稳定性不好,易受微生物降解等问题,对灭火剂储存非常不利。所以高分子增稠剂的应用,能够生产一种稳定性好、有效粘度高又耐储存的森林灭火剂,该灭火剂在空中飘散损失和蒸发损失少,地面覆盖率高,灭火效率将会大大增加。 At present, forest fire extinguishing agents on the market can be divided into short-acting fire extinguishing agents and long-acting fire extinguishing agents according to the length of action. Short-acting fire extinguishing agents include pure water, thickened water, foam fire extinguishing agents, etc. When the water is completely evaporated, they will not have the ability to prevent and extinguish fire; while aqueous solutions such as diammonium hydrogen phosphate, ammonium sulfate, ammonium carbonate, and ammonium sulfate After the water is evaporated, it still has the ability to block and extinguish fire, so this kind of fire extinguishing agent is called long-acting fire extinguishing agent. The use of fire extinguishing agent is generally spraying or spraying in the air, but there is a serious disadvantage. When using it, especially when spraying in the air, the fire extinguishing agent will be in the form of mist after being sheared by the wind during the landing process and then blown by the wind. As a result, the fire extinguishing agent that can reach the ground is greatly reduced, and even at a certain height, the fire extinguishing agent cannot reach the ground at all. Therefore, it is essential to thicken the fire extinguishing agent. At present, there are mainly two types of fire extinguishing agent thickeners. One is clay (such as bentonite) as a thickener, but it also has the disadvantage of drifting with the wind; the second is One is to use gum as a thickener (such as alginate gum, pectin, guar gum, etc.), but this type of natural material is relatively expensive, and has problems such as poor stability and easy microbial degradation. Storage is very unfavorable. Therefore, the application of a polymer thickener can produce a forest fire extinguishing agent with good stability, high effective viscosity and storage resistance. The fire extinguishing agent has less loss in the air and less evaporation loss, high ground coverage, and high fire extinguishing efficiency. Increase.
发明内容 Contents of the invention
本发明针对森林灭火剂在进行空中喷洒时会严重损失的问题,提供了一种高分子增稠的稳定性好、有效粘度高又耐储存的森林灭火剂。该灭火剂在空中飘散损失和蒸发损失少,地面覆盖率高,灭火性能高。 The invention aims at the problem that the forest fire extinguishing agent will be seriously lost when it is sprayed in the air, and provides a forest fire extinguishing agent with good polymer thickening stability, high effective viscosity and storage resistance. The fire extinguishing agent has less floating loss and evaporation loss in the air, high ground coverage and high fire extinguishing performance.
本发明技术方案为,一种高分子增稠森林灭火剂的制备方法按以下各材料重量百分比组成:硫酸铵75-100份,尿素175-200份,高分子增稠剂0.5-1.5份,水475-550份。按照本发明配方制备增稠森林灭火剂时,必须按照以下投料顺序进行:先将硫酸铵以及尿素溶于水中,高分子增稠剂单独溶解于水,然后两种水溶液混合搅拌0.5h-1h至粘稠状。 The technical scheme of the present invention is that a preparation method of a polymer thickening forest fire extinguishing agent is composed of the following materials in weight percent: 75-100 parts of ammonium sulfate, 175-200 parts of urea, 0.5-1.5 parts of polymer thickener, water 475-550 copies. When preparing thickened forest fire extinguishing agent according to the formula of the present invention, it must be carried out according to the following feeding sequence: first dissolve ammonium sulfate and urea in water, dissolve the polymer thickener in water alone, and then mix and stir the two aqueous solutions for 0.5h-1h to Viscous.
本发明制备的增稠森林灭火剂,灭火主剂采用硫酸铵和尿素,其水溶液为中性,对一些对pH敏感的高分子增稠剂无影响,而高分子增稠剂的加入能够增强灭火剂的粘稠性,在喷洒使用时形成大的云雾滴大大减少了灭火剂在空中的飘散损失和蒸发损失,从而使对地面上的覆盖率大大增加,提高灭火性能。本发明制备的增稠森林灭火剂有以下优点:增稠的灭火剂可以提高从树冠到地表可燃物的渗透能力,保持更长的阻滞火焰蔓延时间,而且可以在较高的喷洒作业高度下进行喷洒,对灭火人员而言更加安全。 The thickened forest fire extinguishing agent prepared by the present invention uses ammonium sulfate and urea as the main fire extinguishing agent, and its aqueous solution is neutral, which has no effect on some polymer thickeners sensitive to pH, and the addition of polymer thickeners can enhance fire extinguishing Due to the viscosity of the agent, large cloud droplets are formed during spraying, which greatly reduces the drift loss and evaporation loss of the fire extinguishing agent in the air, thereby greatly increasing the coverage on the ground and improving the fire extinguishing performance. The thickened forest fire extinguishing agent prepared by the present invention has the following advantages: the thickened fire extinguishing agent can improve the penetration ability from the crown of the tree to the surface combustibles, keep a longer retarding flame spread time, and can be used at a higher spraying height It is safer for fire fighters to spray.
具体实施方式 detailed description
具体实施方式一:一种高分子增稠森林灭火剂制备方法,按以下配方进行制备,硫酸铵85份,尿素190份,聚丙烯酰胺1份,水500份。现将硫酸铵与尿素溶解于水溶,另将聚丙烯酰胺溶于少量水,然后将两种水溶液混合搅拌0.5h至粘稠状。 Embodiment 1: A method for preparing a polymer thickened forest fire extinguishing agent, which is prepared according to the following formula: 85 parts of ammonium sulfate, 190 parts of urea, 1 part of polyacrylamide, and 500 parts of water. Now dissolve ammonium sulfate and urea in water, and dissolve polyacrylamide in a small amount of water, then mix and stir the two aqueous solutions for 0.5h until viscous.
具体实施方式二:一种高分子增稠森林灭火剂制备方法,按以下配方进行制备,硫酸铵85份,尿素190份,聚乙烯吡咯烷酮1份,水500份。现将硫酸铵与尿素溶解于水溶,另将聚乙烯吡咯烷酮溶于少量水,然后将两种水溶液混合搅拌0.5h至粘稠状。 Embodiment 2: A method for preparing a polymer thickened forest fire extinguishing agent, which is prepared according to the following formula: 85 parts of ammonium sulfate, 190 parts of urea, 1 part of polyvinylpyrrolidone, and 500 parts of water. Now dissolve ammonium sulfate and urea in water, and dissolve polyvinylpyrrolidone in a small amount of water, then mix and stir the two aqueous solutions for 0.5h until viscous.
具体实施方式三:一种高分子增稠森林灭火剂制备方法,按以下配方进行制备,硫酸铵85份,尿素190份,聚氧化乙烯1份,水500份。现将硫酸铵与尿素溶解于水溶,另将聚氧化乙烯溶于少量水,然后将两种水溶液混合搅拌0.5h至粘稠状。 Specific embodiment three: a method for preparing a polymer thickened forest fire extinguishing agent, which is prepared according to the following formula: 85 parts of ammonium sulfate, 190 parts of urea, 1 part of polyethylene oxide, and 500 parts of water. Now dissolve ammonium sulfate and urea in water, and dissolve polyethylene oxide in a small amount of water, then mix and stir the two aqueous solutions for 0.5h until viscous.
具体实施方式四:一种高分子增稠森林灭火剂制备方法,按以下配方进行制备,硫酸铵85份,尿素190份,改性石蜡树脂1份,水500份。现将硫酸铵与尿素溶解于水溶,另将改性石蜡树脂溶于少量水,然后将两种水溶液混合搅拌0.5h至粘稠状。 Embodiment 4: A method for preparing a polymer thickened forest fire extinguishing agent, which is prepared according to the following formula: 85 parts of ammonium sulfate, 190 parts of urea, 1 part of modified paraffin resin, and 500 parts of water. Now dissolve the ammonium sulfate and urea in water, and dissolve the modified paraffin resin in a small amount of water, then mix and stir the two aqueous solutions for 0.5h until viscous.
本发明并不限于上述实施方式,凡采用与本发明相同或相似方法及结构来实现本发明的所有技术方案,均应在本发明的保护范围内。 The present invention is not limited to the above-mentioned embodiments, and all technical solutions that implement the present invention by using the same or similar methods and structures as the present invention shall fall within the protection scope of the present invention.
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| CN107050699A (en) * | 2016-12-30 | 2017-08-18 | 李小波 | A kind of application of alkali swollen thickener and its application apparatus |
| CN107638653A (en) * | 2017-10-10 | 2018-01-30 | 深圳国信利纾消防设备科技有限公司 | Water-based extinguishing agent preparation method |
| CN108079473A (en) * | 2016-11-21 | 2018-05-29 | 南京消防器材股份有限公司 | Intelligent Monitor fire extinguishing system and its extinguishing chemical |
| CN110917553A (en) * | 2019-12-06 | 2020-03-27 | 国网湖南省电力有限公司 | Temperature-sensitive evaporation-preventing water-based extinguishing agent |
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Cited By (5)
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| CN108079473A (en) * | 2016-11-21 | 2018-05-29 | 南京消防器材股份有限公司 | Intelligent Monitor fire extinguishing system and its extinguishing chemical |
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| CN110917553B (en) * | 2019-12-06 | 2021-06-15 | 国网湖南省电力有限公司 | Temperature-sensitive evaporation-preventing water-based extinguishing agent |
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