CN105232392A - Preparation method of ultraviolet protecting agent for electrical workers - Google Patents
Preparation method of ultraviolet protecting agent for electrical workers Download PDFInfo
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Abstract
本发明公开了一种电力作业人员紫外防护剂制备方法,以纳米金红石溶胶、纳米二氧化铈溶胶、磷酸盐缓冲溶液、明胶、芦荟、姜黄根、紫草、丹参、十二烷基硫酸钠、对羟基苯甲酸甲酯、蜜蜡、蛇油、维生素E、香精、聚乙二醇-1000、羟苯甲酮、抗氧化剂BHA、防腐剂卡松为原料,该防护剂清凉舒爽,防紫外效果好。The invention discloses a method for preparing an ultraviolet protective agent for electric workers. Nano rutile sol, nano cerium dioxide sol, phosphate buffer solution, gelatin, aloe vera, turmeric root, comfrey, salvia miltiorrhiza, sodium lauryl sulfate, Methylparaben, beeswax, snake oil, vitamin E, essence, macrogol-1000, oxybenzone, antioxidant BHA, and preservative Kathon are used as raw materials. The protective agent is cool and refreshing, and anti-ultraviolet The effect is good.
Description
技术领域technical field
本发明属于防护剂领域,特别涉及一种电力作业人员紫外防护剂及其制备方法。The invention belongs to the field of protective agents, in particular to an ultraviolet protective agent for electric workers and a preparation method thereof.
背景技术Background technique
电力作业的工作人员,属于经常需要户外工作的人员,长期需要暴露在阳光下,从而会容易造成紫外线对于皮肤乃至身体的损伤。在长时间暴露于阳光下而又未采取任何保护措施的情况下,皮肤将会发炎,出现红色素沉着的晒伤(太阳红斑)。太阳红斑小则导致皮肤暂时性不适和起皮,甚至引起严重的长期损伤以致皮肤的组织坏死。皮肤在没有保护措施的情况下受日光照射后,如不进行适当处理,后果也会十分严重。其表现为皮肤老化、出现斑点、失水和血管扩张,更严重者导致皮肤发生癌变。Electricity workers are those who often need to work outdoors. They need to be exposed to the sun for a long time, which will easily cause damage to the skin and even the body by ultraviolet rays. After prolonged exposure to the sun without any protection, the skin becomes inflamed and develops a red hyperpigmented sunburn (solar erythema). Small solar erythema can cause temporary discomfort and peeling of the skin, and even cause serious long-term damage to the necrosis of skin tissue. Skin exposed to the sun without protection can have serious consequences if not properly treated. It is manifested as skin aging, spots, dehydration and blood vessel expansion, and more serious cases lead to skin cancer.
随着工业的发展,且随着人们对于紫外线损伤皮肤的了解加强以及深入,各种类型的紫外线防护品也应运而生,不过关于电力作业人员的紫外防护剂的研究颇少。With the development of industry, and as people's understanding of UV damage to the skin is strengthened and deepened, various types of UV protective products have also emerged as the times require, but there are few studies on UV protective agents for electric workers.
发明内容Contents of the invention
本发明的目的是针对上述问题,研制出一种清凉舒爽,防紫外效果好的电力作业人员紫外防护剂及其制备方法。The purpose of the present invention is to address the above problems, to develop a cool and comfortable, good UV protection effect of electric workers ultraviolet protective agent and its preparation method.
一种电力作业人员紫外防护剂,该防护剂由如下重量份物质组成:An ultraviolet protective agent for electric workers, the protective agent is composed of the following materials in parts by weight:
纳米金红石溶胶10-20份;Nano rutile sol 10-20 parts;
纳米二氧化铈溶胶10-20份;10-20 parts of nano ceria sol;
明胶10-20份;10-20 parts of gelatin;
芦荟5-10份;Aloe 5-10 parts;
姜黄根5-10份;5-10 parts of turmeric root;
紫草5-10份;Comfrey 5-10 parts;
丹参5-10份;Salvia 5-10 parts;
十二烷基硫酸钠5-10份;5-10 parts of sodium lauryl sulfate;
对羟基苯甲酸甲酯5-10份;5-10 parts of methyl p-hydroxybenzoate;
蜜蜡5-10份;5-10 parts of beeswax;
蛇油5-10份;5-10 parts of snake oil;
维生素E5-10份;Vitamin E5-10 parts;
香精5-10份5-10 copies of essence
聚乙二醇-10005-10份;Polyethylene glycol-10005-10 parts;
羟苯甲酮5-10份;5-10 parts of oxybenzone;
抗氧化剂1-3份;Antioxidant 1-3 parts;
防腐剂1-3份;1-3 parts of preservatives;
磷酸盐缓冲溶液1-3份;1-3 parts of phosphate buffer solution;
水适量。Appropriate amount of water.
作为优选,所述抗氧化剂为BHA。Preferably, the antioxidant is BHA.
作为优选,所述防腐剂为卡松。Preferably, the preservative is Kathon.
作为优选,该防护剂由如下重量份物质组成:Preferably, the protective agent consists of the following parts by weight:
纳米金红石溶胶15份;15 parts of nanometer rutile sol;
纳米二氧化铈溶胶15份;15 parts of nano ceria sol;
明胶15份;15 parts gelatin;
芦荟7份;7 parts of aloe vera;
姜黄根7份;7 parts turmeric root;
紫草7份;7 parts of comfrey;
丹参7份;7 parts of Danshen;
十二烷基硫酸钠7份;7 parts of sodium lauryl sulfate;
对羟基苯甲酸甲酯7份;7 parts of methyl p-hydroxybenzoate;
蜜蜡7份;7 parts beeswax;
蛇油7份;7 parts snake oil;
维生素E7份;7 parts of vitamin E;
香精7份7 servings of essence
聚乙二醇-10007份;Polyethylene glycol - 10007 parts;
羟苯甲酮7份;7 parts of oxybenzone;
抗氧化剂BHA2份;Antioxidant BHA 2 parts;
防腐剂卡松2份;Preservative Kason 2 parts;
磷酸盐缓冲溶液2份;2 parts of phosphate buffer solution;
水适量。Appropriate amount of water.
一种制备上述电力作业人员紫外防护剂的方法,包括如下步骤:A method for preparing the above-mentioned ultraviolet protective agent for electric workers, comprising the steps of:
(1)按照紫外防护剂的组成进行配料;(1) batching is carried out according to the composition of ultraviolet protective agent;
(2)将纳米金红石溶胶和纳米二氧化铈溶胶加入至水中,随后加入磷酸盐缓冲溶液,搅拌均匀;随后加入明胶、芦荟、姜黄根、紫草、丹参和十二烷基硫酸钠,搅拌均匀,得到混合物A;(2) Add nano rutile sol and nano ceria sol to water, then add phosphate buffer solution, stir well; then add gelatin, aloe vera, turmeric root, comfrey, salvia miltiorrhiza and sodium lauryl sulfate, stir well , to obtain mixture A;
(3)将混合物A升温至70摄氏度,加入对羟基苯甲酸甲酯、蜜蜡、蛇油、维生素E、香精、聚乙二醇-1000、羟苯甲酮、抗氧化剂BHA、防腐剂卡松,搅拌10min。(3) Heat mixture A to 70 degrees Celsius, add methyl paraben, beeswax, snake oil, vitamin E, essence, macrogol-1000, oxybenzone, antioxidant BHA, preservative Cathone , stirred for 10 min.
(4)停止加热,搅拌至冷凝,即可获得电力作业人员紫外防护剂。(4) Stop heating, stir until it condenses, and you can get the UV protection agent for electric workers.
本发明的有益效果:Beneficial effects of the present invention:
(1)采用纳米金红石溶胶、纳米二氧化铈溶胶作为防护剂的主要成分,纳米溶胶具有很强的紫外屏蔽能力,低紫外光催化活性强,粘附力强,颗粒尺寸小,且不改变底色等优点。(1) Nano rutile sol and nano ceria sol are used as the main components of the protective agent. Nano sol has strong ultraviolet shielding ability, strong low ultraviolet photocatalytic activity, strong adhesion, small particle size, and does not change the bottom color and other advantages.
(2)为了进一步提高防护剂的抗紫外性能,本发明通过将中草药芦荟、姜黄根、紫草和丹参添加到防护剂中,该中草药具有较强的抗氧化、遮光效果,如姜黄根由于含有姜黄素,从而能够抗炎,抗增殖,可清除羟自由基,从而抵抗紫外辐射诱导的DNA损伤。同时,中草药成分还可以促使该防护剂清凉舒爽。(2) In order to further improve the anti-ultraviolet performance of the protective agent, the present invention adds Chinese herbal medicine aloe vera, turmeric root, comfrey and salvia miltiorrhiza to the protective agent. Curcumin, which can be anti-inflammatory, anti-proliferative, can scavenge hydroxyl free radicals, thereby resisting DNA damage induced by ultraviolet radiation. At the same time, Chinese herbal ingredients can also make the protective agent cool and refreshing.
(3)本发明除了主要成分外,还通过选择合适的辅助成分,其中不乏对于紫外防护起到重要作用的成分,如对羟基苯甲酸甲酯具有较强的抗菌效果,从而防止紫外损伤伤口的进一步恶化;又如维生素E是人类抗氧化防御系统的主要成分之一,也是人类皮脂的重要组成部分。UVR照射后维生素E明显耗竭是外界氧化作用的最早、最敏感的指标。局部外用维生素E可拮抗UVR诱导的免疫抑制、慢性皮肤损伤;最重要的是本发明各组分之间的协同作用,如磷酸盐缓冲溶液,可以使得纳米溶胶在混合过程中依旧保持好的分散状态,不至于快速的聚集,影响防护效果。(3) The present invention is also by selecting suitable auxiliary components except the main components, wherein there is no shortage of components that play an important role in UV protection, such as methyl p-hydroxybenzoate, which has a strong antibacterial effect, thereby preventing UV damage to the wound. Further deterioration; Another example is vitamin E, which is one of the main components of the human antioxidant defense system and an important component of human sebum. Significant vitamin E depletion after UVR irradiation is the earliest and most sensitive indicator of external oxidation. Topical vitamin E can antagonize UVR-induced immunosuppression and chronic skin damage; the most important thing is the synergistic effect between the components of the present invention, such as phosphate buffer solution, which can make the nano-sol still maintain good dispersion during the mixing process state, so as not to gather quickly and affect the protective effect.
(4)该防护剂制备工艺简单,易于工业化,原料来源广泛,非常适合应用于生产。(4) The protective agent has a simple preparation process, is easy to industrialize, and has a wide range of raw material sources, and is very suitable for production.
具体实施方式detailed description
下面结合具体的实施例,并参照数据进一步详细描述本发明。应理解,这些实施例只是为了举例说明本发明,而非以任何方式限制本发明的范围。The present invention will be further described in detail below in conjunction with specific examples and with reference to data. It should be understood that these examples are only for illustration of the present invention, but not to limit the scope of the present invention in any way.
实施例1:Example 1:
一种电力作业人员紫外防护剂,该防护剂由如下重量份物质组成:An ultraviolet protective agent for electric workers, the protective agent is composed of the following materials in parts by weight:
纳米金红石溶胶15份;15 parts of nanometer rutile sol;
纳米二氧化铈溶胶15份;15 parts of nano ceria sol;
明胶15份;15 parts gelatin;
芦荟7份;7 parts of aloe vera;
姜黄根7份;7 parts turmeric root;
紫草7份;7 parts of comfrey;
丹参7份;7 parts of Danshen;
十二烷基硫酸钠7份;7 parts of sodium lauryl sulfate;
对羟基苯甲酸甲酯7份;7 parts of methyl p-hydroxybenzoate;
蜜蜡7份;7 parts beeswax;
蛇油7份;7 parts snake oil;
维生素E7份;7 parts of vitamin E;
香精7份7 servings of essence
聚乙二醇-10007份;Polyethylene glycol - 10007 parts;
羟苯甲酮7份;7 parts of oxybenzone;
抗氧化剂BHA2份;Antioxidant BHA 2 parts;
防腐剂卡松2份;Preservative Kason 2 parts;
磷酸盐缓冲溶液2份;2 parts of phosphate buffer solution;
水适量。Appropriate amount of water.
一种制备上述电力作业人员紫外防护剂的方法,包括如下步骤:A method for preparing the above-mentioned ultraviolet protective agent for electric workers, comprising the steps of:
(1)按照紫外防护剂的组成进行配料;(1) batching is carried out according to the composition of ultraviolet protective agent;
(2)将纳米金红石溶胶和纳米二氧化铈溶胶加入至水中,随后加入磷酸盐缓冲溶液,搅拌均匀;随后加入明胶、芦荟、姜黄根、紫草、丹参和十二烷基硫酸钠,搅拌均匀,得到混合物A;(2) Add nano rutile sol and nano ceria sol to water, then add phosphate buffer solution, stir well; then add gelatin, aloe vera, turmeric root, comfrey, salvia miltiorrhiza and sodium lauryl sulfate, stir well , to obtain mixture A;
(3)将混合物A升温至70摄氏度,加入对羟基苯甲酸甲酯、蜜蜡、蛇油、维生素E、香精、聚乙二醇-1000、羟苯甲酮、抗氧化剂BHA、防腐剂卡松,搅拌10min。(3) Heat mixture A to 70 degrees Celsius, add methyl paraben, beeswax, snake oil, vitamin E, essence, macrogol-1000, oxybenzone, antioxidant BHA, preservative Cathone , stirred for 10 min.
(4)停止加热,搅拌至冷凝,即可获得电力作业人员紫外防护剂。(4) Stop heating, stir until it condenses, and you can get the UV protection agent for electric workers.
实施例2:Example 2:
一种电力作业人员紫外防护剂,该防护剂由如下重量份物质组成:An ultraviolet protective agent for electric workers, the protective agent is composed of the following materials in parts by weight:
纳米金红石溶胶10份;10 parts of nanometer rutile sol;
纳米二氧化铈溶胶10份;10 parts of nano ceria sol;
明胶10份;10 parts gelatin;
芦荟5份;5 parts aloe;
姜黄根5份;5 parts turmeric root;
紫草5份;5 parts comfrey;
丹参5份;Salvia 5 parts;
十二烷基硫酸钠5份;5 parts of sodium lauryl sulfate;
对羟基苯甲酸甲酯5份;5 parts of methyl p-hydroxybenzoate;
蜜蜡5份;5 parts beeswax;
蛇油5份;5 parts snake oil;
维生素E5份;5 parts of vitamin E;
香精5份5 servings of essence
聚乙二醇-10005份;Polyethylene glycol - 10005 parts;
羟苯甲酮5份;5 parts of oxybenzone;
抗氧化剂BHA2份;Antioxidant BHA 2 parts;
防腐剂卡松2份;Preservative Kason 2 parts;
磷酸盐缓冲溶液2份;2 parts of phosphate buffer solution;
水适量。Appropriate amount of water.
一种制备上述电力作业人员紫外防护剂的方法,包括如下步骤:A method for preparing the above-mentioned ultraviolet protective agent for electric workers, comprising the steps of:
(1)按照紫外防护剂的组成进行配料;(1) batching is carried out according to the composition of ultraviolet protective agent;
(2)将纳米金红石溶胶和纳米二氧化铈溶胶加入至水中,随后加入磷酸盐缓冲溶液,搅拌均匀;随后加入明胶、芦荟、姜黄根、紫草、丹参和十二烷基硫酸钠,搅拌均匀,得到混合物A;(2) Add nano rutile sol and nano ceria sol to water, then add phosphate buffer solution, stir well; then add gelatin, aloe vera, turmeric root, comfrey, salvia miltiorrhiza and sodium lauryl sulfate, stir well , to obtain mixture A;
(3)将混合物A升温至70摄氏度,加入对羟基苯甲酸甲酯、蜜蜡、蛇油、维生素E、香精、聚乙二醇-1000、羟苯甲酮、抗氧化剂BHA、防腐剂卡松,搅拌10min。(3) Heat mixture A to 70 degrees Celsius, add methyl paraben, beeswax, snake oil, vitamin E, essence, macrogol-1000, oxybenzone, antioxidant BHA, preservative Cathone , stirred for 10 min.
(4)停止加热,搅拌至冷凝,即可获得电力作业人员紫外防护剂。(4) Stop heating, stir until it condenses, and you can get the UV protection agent for electric workers.
实施例3:Example 3:
一种电力作业人员紫外防护剂,该防护剂由如下重量份物质组成:An ultraviolet protective agent for electric workers, the protective agent is composed of the following materials in parts by weight:
纳米金红石溶胶20份;20 parts of nanometer rutile sol;
纳米二氧化铈溶胶20份;20 parts of nano ceria sol;
明胶20份;20 parts gelatin;
芦荟10份;10 parts of aloe vera;
姜黄根10份;10 parts turmeric root;
紫草10份;10 parts of comfrey;
丹参10份;10 parts of Danshen;
十二烷基硫酸钠10份;10 parts of sodium lauryl sulfate;
对羟基苯甲酸甲酯10份;10 parts of methyl p-hydroxybenzoate;
蜜蜡10份;10 parts beeswax;
蛇油10份;10 parts snake oil;
维生素E10份;10 parts of vitamin E;
香精10份10 parts of essence
聚乙二醇-100010份;Polyethylene glycol - 100010 parts;
羟苯甲酮10份;10 parts of oxybenzone;
抗氧化剂BHA2份;Antioxidant BHA 2 parts;
防腐剂卡松2份;Preservative Kason 2 parts;
磷酸盐缓冲溶液2份;2 parts of phosphate buffer solution;
水适量。Appropriate amount of water.
一种制备上述电力作业人员紫外防护剂的方法,包括如下步骤:A method for preparing the above-mentioned ultraviolet protective agent for electric workers, comprising the steps of:
(1)按照紫外防护剂的组成进行配料;(1) batching is carried out according to the composition of ultraviolet protective agent;
(2)将纳米金红石溶胶和纳米二氧化铈溶胶加入至水中,随后加入磷酸盐缓冲溶液,搅拌均匀;随后加入明胶、芦荟、姜黄根、紫草、丹参和十二烷基硫酸钠,搅拌均匀,得到混合物A;(2) Add nano rutile sol and nano ceria sol to water, then add phosphate buffer solution, stir well; then add gelatin, aloe vera, turmeric root, comfrey, salvia miltiorrhiza and sodium lauryl sulfate, stir well , to obtain mixture A;
(3)将混合物A升温至70摄氏度,加入对羟基苯甲酸甲酯、蜜蜡、蛇油、维生素E、香精、聚乙二醇-1000、羟苯甲酮、抗氧化剂BHA、防腐剂卡松,搅拌10min。(3) Heat mixture A to 70 degrees Celsius, add methyl paraben, beeswax, snake oil, vitamin E, essence, macrogol-1000, oxybenzone, antioxidant BHA, preservative Cathone , stirred for 10 min.
(4)停止加热,搅拌至冷凝,即可获得电力作业人员紫外防护剂。(4) Stop heating, stir until it condenses, and you can get the UV protection agent for electric workers.
实施例4:Example 4:
一种电力作业人员紫外防护剂,该防护剂由如下重量份物质组成:An ultraviolet protective agent for electric workers, the protective agent is composed of the following materials in parts by weight:
纳米金红石溶胶15份;15 parts of nanometer rutile sol;
纳米二氧化铈溶胶15份;15 parts of nano ceria sol;
明胶15份;15 parts gelatin;
芦荟10份;10 parts of aloe vera;
姜黄根10份;10 parts turmeric root;
紫草10份;10 parts of comfrey;
丹参10份;10 parts of Danshen;
十二烷基硫酸钠10份;10 parts of sodium lauryl sulfate;
对羟基苯甲酸甲酯10份;10 parts of methyl p-hydroxybenzoate;
蜜蜡10份;10 parts beeswax;
蛇油10份;10 parts snake oil;
维生素E10份;10 parts of vitamin E;
香精10份10 parts of essence
聚乙二醇-100010份;Polyethylene glycol - 100010 parts;
羟苯甲酮10份;10 parts of oxybenzone;
抗氧化剂BHA1份;Antioxidant BHA 1 part;
防腐剂卡松1份;1 part of preservative Kasong;
磷酸盐缓冲溶液1份;1 part of phosphate buffer solution;
水适量。Appropriate amount of water.
一种制备上述电力作业人员紫外防护剂的方法,包括如下步骤:A method for preparing the above-mentioned ultraviolet protective agent for electric workers, comprising the steps of:
(1)按照紫外防护剂的组成进行配料;(1) batching is carried out according to the composition of ultraviolet protective agent;
(2)将纳米金红石溶胶和纳米二氧化铈溶胶加入至水中,随后加入磷酸盐缓冲溶液,搅拌均匀;随后加入明胶、芦荟、姜黄根、紫草、丹参和十二烷基硫酸钠,搅拌均匀,得到混合物A;(2) Add nano rutile sol and nano ceria sol to water, then add phosphate buffer solution, stir well; then add gelatin, aloe vera, turmeric root, comfrey, salvia miltiorrhiza and sodium lauryl sulfate, stir well , to obtain mixture A;
(3)将混合物A升温至70摄氏度,加入对羟基苯甲酸甲酯、蜜蜡、蛇油、维生素E、香精、聚乙二醇-1000、羟苯甲酮、抗氧化剂BHA、防腐剂卡松,搅拌10min。(3) Heat mixture A to 70 degrees Celsius, add methyl paraben, beeswax, snake oil, vitamin E, essence, macrogol-1000, oxybenzone, antioxidant BHA, preservative Cathone , stirred for 10 min.
(4)停止加热,搅拌至冷凝,即可获得电力作业人员紫外防护剂。(4) Stop heating, stir until it condenses, and you can get the UV protection agent for electric workers.
该防护剂可适用于涂抹在电力作业人员裸露的皮肤表层。The protective agent can be applied to the exposed skin surface of electric workers.
对于本领域技术人员而言,显然本发明不限于上述示范性实施例的细节,而且在不背离本发明的精神或基本特征的情况下,能够以其他的具体形式实现本发明。因此,无论从哪一点来看,均应将实施例看作是示范性的,而且是非限制性的,本发明的范围由所附权利要求而不是上述说明限定,因此旨在将落在权利要求的等同要件的含义和范围内的所有变化囊括在本发明内。It will be apparent to those skilled in the art that the invention is not limited to the details of the above-described exemplary embodiments, but that the invention can be embodied in other specific forms without departing from the spirit or essential characteristics of the invention. Accordingly, the embodiments should be regarded in all points of view as exemplary and not restrictive, the scope of the invention being defined by the appended claims rather than the foregoing description, and it is therefore intended that the scope of the invention be defined by the appended claims rather than by the foregoing description. All changes within the meaning and range of equivalents of the elements are embraced in the present invention.
此外,应当理解,虽然本说明书按照实施方式加以描述,但并非每个实施方式仅包含一个独立的技术方案,说明书的这种叙述方式仅仅是为清楚起见,本领域技术人员应当将说明书作为一个整体,各实施例中的技术方案也可以经适当组合,形成本领域技术人员可以理解的其他实施方式。In addition, it should be understood that although this specification is described according to implementation modes, not each implementation mode only contains an independent technical solution, and this description in the specification is only for clarity, and those skilled in the art should take the specification as a whole , the technical solutions in the various embodiments can also be properly combined to form other implementations that can be understood by those skilled in the art.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1598056A1 (en) * | 1998-05-27 | 2005-11-23 | Isis Innovation Limited | Ultraviolet light screening compositions |
| CN101092246A (en) * | 2007-05-18 | 2007-12-26 | 广东省生态环境与土壤研究所 | Method for preparing Nano sol as ultraviolet protective agent |
| CN102018637A (en) * | 2009-09-17 | 2011-04-20 | 天津科技大学 | Preparation of novel sunscreen and moisturizing cream |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1598056A1 (en) * | 1998-05-27 | 2005-11-23 | Isis Innovation Limited | Ultraviolet light screening compositions |
| CN101092246A (en) * | 2007-05-18 | 2007-12-26 | 广东省生态环境与土壤研究所 | Method for preparing Nano sol as ultraviolet protective agent |
| CN102018637A (en) * | 2009-09-17 | 2011-04-20 | 天津科技大学 | Preparation of novel sunscreen and moisturizing cream |
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Application publication date: 20160113 |