CN105007887B - Hair mousse composition - Google Patents

Abstract

The present invention hair mousse composition include：0.1 mass % or more, the 10 mass % particles (ingredient A) below in the group being made of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicates, magnesium silicate, alumina silicate and magnesium hydroxide；Clay mineral (ingredient B)；And select polymer (ingredient C) in the group that free polymer (ingredient C1) and polymer (ingredient C2) form, the polymer (ingredient C1) is obtained using the two or more monomers in the group being made of (methyl) acrylic acid and (methyl) alkyl acrylate, the polymer (ingredient C2) is using the monomer in the group being made of (methyl) acrylic acid and (methyl) alkyl acrylate, with selected from by (methyl) acrylic acid polyoxyethylene alkyl ether, what the monomer in the group of itaconic acid polyoxyethylene alkyl ether and vinyl neodecanoate composition obtained.

Description

hair conditioner composition

technical field

The present invention relates to a hair dressing composition suitable for use as a hair dressing for conditioning hair.

Background technique

Hair dressing compositions in various forms, such as liquid, gel, cream and solid, are used for hair conditioning. Conventionally, in order to impart the hair styling power which is the main function to a hair dressing composition, a film-forming polymer is often used. However, if an effective amount of a coating-forming polymer is compounded, although the initial hair-styling power immediately after hair-styling is improved, on the other hand, the extensibility and fusion properties of the hair-styling composition on the hair are deteriorated, or sticky problem. In addition, in the hair dressing composition using a film-forming polymer, after hair styling, a film is formed on the surface of the hair from the film-forming polymer. Therefore, it is difficult to groom the hair in a natural state, and when the hair is stimulated with hands or a comb after the hair styling, the coating is peeled off from the surface of the hair (so-called flaking occurs), and the hair styling force tends to be greatly reduced.

In order to solve such a problem, it has been studied to improve the flexibility of a film formed from a film-forming polymer. In Patent Document 1 below, the use of silicones as a plasticizer in a hair dressing composition containing a film-forming polymer has been studied.

In addition, a method different from the method of using a film-forming polymer has been studied, specifically, the use of a powder for imparting hair styling power to a hair dressing composition has also been studied.

Patent Document 2 below discloses a hair cosmetic (hair dressing composition) comprising 0.1% by mass to 10% by mass of fine particle powder having a specific surface area of 50 m ² /g or more. In Patent Document 2, it is described that by using the above-mentioned specific fine particle powder at a specific above-mentioned content, a good touch can be obtained, excellent hair styling power can be obtained, and the good touch can be sustained for a long time, and can Excellent restyling properties are obtained.

prior art literature

patent documents

Patent Document 1: Japanese Patent Laid-Open No. 2001-240519

Patent Document 2: Japanese Unexamined Patent Publication No. 2003-342130

Contents of the invention

The problem to be solved by the invention

In the hair dressing composition described in Patent Document 1, the flexibility of the coating formed from the coating-forming polymer is improved to some extent. As a result, the usability of the hair dressing composition improves to some extent. However, there is a problem that the function of maintaining the hair-styled state for a long time decreases as the flexibility of the coating increases. That is, when hair styling is performed using the hair dressing composition described in Patent Document 1, the hair styling holding power may not become sufficiently high.

In addition, as described in Patent Document 2, when hair is styled using a hair dressing composition containing fine particle powder, the hair style holding power may not be sufficiently high.

In addition, the viscosity of the composition may not be sufficiently increased, resulting in reduced applicability of the composition during hair styling, separation of powder and liquid components in the composition, or reduction in storage stability.

An object of the present invention is to provide a hair dressing composition excellent in hair styling retention, applicability, and storage stability.

Solution to the problem

The hair dressing composition of the present invention is a hair dressing composition comprising the following component (A), the following component (B), and the following component (C1) and the following component (C2) The content of the component (C) of the polymer in the composition group and the above-mentioned component (A) is 0.1% by mass or more and 10% by mass or less.

Ingredient (A): Particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide

Ingredient (B): Clay Minerals

Component (C1): A polymer obtained by using two or more monomers selected from the group consisting of (meth)acrylic acid and alkyl (meth)acrylate as essential monomer components

Component (C2): A monomer selected from the group consisting of (meth)acrylic acid and alkyl (meth)acrylate, and a monomer selected from the group consisting of (meth)acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyl A polymer obtained from the group consisting of vinyl alkyl ether and vinyl neodecanoate as an essential monomer component

In the hair dressing composition of this invention, it is preferable that the total amount of content of the said component (B) and content of the said component (C) is 0.2 mass % or more and 10 mass % or less.

In the hair dressing composition of this invention, it is preferable that the mass ratio of content of the said component (B) and content of the said component (C) is 0.1:1-30:1.

It is preferable that the hair dressing composition of this invention contains the following component (D) further.

Component (D): a compound selected from the group consisting of polyoxyalkylene alkyl glucoside and polyoxyalkylene glycerol fatty acid ester

It is preferable that the hair dressing composition of this invention contains the following component (E) further.

Ingredient (E): Polyethylene Glycol

The effect of the invention

The hair dressing composition of the present invention contains specific components (A), (B), and (C), and the content of component (A) is within a specific range, so the applicability at the time of hair styling is good, and the Afterwards, it can exert excellent hair holding power. In addition, excellent storage stability can be exhibited.

Detailed ways

Hereinafter, the present invention will be described in detail.

Using two or more types of monomers selected from the group consisting of (meth)acrylic acid and alkyl (meth)acrylates as essential monomer components, the obtained polymer is used as a first polymer. A monomer selected from the group consisting of (meth)acrylic acid and alkyl (meth)acrylate, and a monomer selected from the group consisting of (meth)acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether, and The monomers in the group consisting of vinyl neodecanoate were used as essential monomer components, and the obtained polymer was used as a second polymer.

The hair dressing composition of the present invention comprises: the particles in; clay mineral; and a polymer selected from the group consisting of the above-mentioned first polymer and the above-mentioned second polymer.

In this specification, the above-mentioned "selected from the group consisting of silicon dioxide, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide is sometimes used. Particles" are referred to as "ingredient (A)". In addition, the said "clay mineral" may be called "component (B)". In addition, in this specification, said "polymer selected from the group which consists of a 1st polymer and a 2nd polymer" may be called "component (C)". In addition, the above-mentioned "first polymer" may be called "component (C1)", and the above-mentioned "second polymer" may be called "component (C2)". In addition, "(meth)acryl" means one or both of acryl and methacryl.

The hair dressing composition of the present invention preferably further contains a compound selected from the group consisting of polyoxyalkylene alkyl glucoside and polyoxyalkylene glycerin fatty acid ester.

In this specification, the above "compound selected from the group consisting of polyoxyalkylene alkyl glucoside and polyoxyalkylene glycerin fatty acid ester" may be referred to as "component (D)". Moreover, said "polyoxyalkylene alkyl glucoside" may be called "component (D1)", and said "polyoxyalkylene glycerol fatty acid ester" may be called "component (D2)".

The hair dressing composition of the present invention preferably further contains polyethylene glycol. In this specification, the above-mentioned "polyethylene glycol" may be referred to as "component (E)".

That is, the hair dressing composition of this invention contains a component (A), a component (B) and a component (C) at least. The hair dressing composition of the present invention preferably further contains a component (at least one component) selected from the group consisting of a component (D) and a component (E). Among these, it is preferable that the hair dressing composition of this invention contains all component (A), component (B), component (C), component (D), and component (E). The hair dressing composition of the present invention may further contain other components. The above-mentioned components, for example, component (A), component (B), component (C), component (D), component (E), and other components may be used alone or in combination of two or more.

In addition, the said component (C) is a polymer (at least 1 type of polymer) selected from the group which consists of a component (C1) and a component (C2). In addition, the above-mentioned component (D) is a compound (at least one kind of compound) selected from the group consisting of a component (D1) and a component (D2). The said component (C1), component (C2), component (D1), and component (D2) may use only 1 type, respectively, and may use 2 or more types.

Hereinafter, the detail of each component used for the hair dressing composition of this invention is demonstrated.

(ingredient (A))

The above component (A) is particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide. The above-mentioned component (A) mainly has the effect of suppressing stickiness and improving initial hair styling power and hair styling retention power (especially hair styling retention power). Moreover, by using the above-mentioned component (A), compared with the case of using a coating-forming polymer, it becomes easy to perform hair styling again after hair styling once, and hair restyling property can also be improved.

Among them, the component (A) is preferably selected from the group consisting of silica, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide from the viewpoint of improving hair styling performance. The particles (at least one kind of particle) in the group consisting of, more preferably the particles (at least one kind of particle) selected from the group consisting of silicon dioxide and magnesium hydroxide. The said component (A) may use only 1 type, and may use 2 or more types.

<Silica>

Well-known and commonly used silica (silicic acid anhydride) can be used as said silica. The aforementioned silica may be silicic anhydride that has not been hydrophobized (hydrophilic silica) or hydrophobized silicic anhydride. In addition, the aforementioned silica may be silica surface-treated with amino acid, ester, lecithin, or the like. In addition, the above-mentioned silica may be so-called easily disintegrable silica particles. The above-mentioned silicas may be used alone or in combination of two or more.

The above-mentioned hydrophobized silicic anhydride is obtained by hydrophobizing silicic anhydride (for example, untreated silicic anhydride). Examples of the treatment agent used in the hydrophobization treatment include organosilyl compounds, silicone compounds, and the like. Examples of the organosilyl compound include methyltrichlorosilane, dimethyldichlorosilane, trimethylchlorosilane, hexamethyldisilazane, methyltrialkoxysilane, dimethyl Dialkoxysilane, Trimethylalkoxysilane, Ethyltrichlorosilane, Propyltrichlorosilane, Hexyltrichlorosilane, Long Chain Alkyltrichlorosilane, Ethyltrialkoxysilane, Propyltrichlorosilane Alkoxysilane, hexyltrialkoxysilane, long-chain alkyltrialkoxysilane, methacrylic silane, fluoroalkylsilane and perfluoroalkylsilane, etc. Examples of the aforementioned silicone compound include dimethylpolysiloxane (silicone oil), methylphenylpolysiloxane, methylhydrogenpolysiloxane, and amino-modified silicone. As the method of the above-mentioned hydrophobization treatment, known methods can be employed. Examples of the method of the hydrophobizing treatment include a liquid phase method, a gas phase method, and an autoclave method.

Preferred examples of the aforementioned hydrophobized silicic anhydride include dimethylsiloxylated silicic anhydride, trimethylsiloxylated silicic anhydride, octylsiloxylated silicic anhydride, silicone oil-treated silicic anhydride, and Methacrylate siloxylated silicic anhydride, etc.

The above-mentioned easily disintegrable silica particles are particles formed by aggregating a plurality of primary silica particles. It does not specifically limit as said silica primary particle, For example, a spherical silica particle, a scaly silica particle, an amorphous silica particle, etc. are mentioned. The average particle diameter of the above-mentioned silica primary particles is not particularly limited.

In addition, the easily disintegrable silica particles may contain components other than silica. Components other than the aforementioned silica (hereinafter sometimes referred to as "contained components") are not particularly limited, and examples thereof include surfactants, polyhydric alcohols, higher alcohols, sugar alcohols, silicone oils, chelating agents, antioxidants, plant Extracts, pigments, pigments, fragrances, humectants, vitamins, amino acids and cooling agents, etc. Among them, amino acids, silicone oils, and vitamins are preferable. The above-mentioned amino acids are not particularly limited, and examples thereof include bis(laurylaminoglutamine)lysine Na (for example, manufactured by Asahi Kasei Chemical Co., Ltd., trade name "pellicer"), trimethylglycine, and glutamic acid. By making the above-mentioned easily disintegrable silica particles contain the above-mentioned contained components, when the above-mentioned easily disintegrable silica particles are disintegrated during hair styling, the contained components are released, and the types of the contained components can be exhibited. corresponding effect. For example, when amino acids are included in the easily disintegrable silica particles, the hair damage care function can be exhibited.

The method for producing the easily disintegrable silica particles is not particularly limited, and known methods can be used.

The oil absorption of the above-mentioned silica is preferably 100 mL/100 g or more, more preferably 150 mL/100 g or more, still more preferably 200 mL/100 g or more, preferably 1000 mL/100 g or less, more preferably 800 mL/100 g or less, still more preferably 700 mL/100 g or more. Below 100g. When the oil absorption of the silica is more than the above-mentioned lower limit and not more than the above-mentioned upper limit, the initial hair-styling power, hair-styling retention power, and hair restyling property become better. The above oil absorption is measured according to the method described in JIS K5101.

Commercially available products of the aforementioned silica include, for example, silicic anhydrides manufactured by Fuji Silysia Chemical under the trade name "Sylysia 320", the trade name "Sylysia 310P", the trade name "Sylysia 250", and the trade name "Sylysia 250N". , the trade name "Sylysia 350", the trade name "Sylysia 370", the trade name "Sylysia380", the trade name "Sylysia 420", the trade name "Sylysia 430", the trade name "Sylysia 440", the trade name "Sylysia 450" and the trade name The name "Sylysia 470"; the product name "AEROSIL 50", the product name "AEROSIL 90G", the product name "AEROSIL 130", the product name "AEROSIL 150", the product name "AEROSIL 200", the product "AEROSIL 300", trade name "AEROSIL 380", trade name "AEROSIL 200V" and trade name "AEROSIL OX50"; the trade name "Sunsphere H-31", trade name "Sunsphere H-31", trade name " Sunsphere H-51", trade name "Sunsphere H-121", trade name "Sunsphere H-201", trade name "Sunsphere H-32", trade name "Sunsphere H-52", trade name "Sunsphere H-122" , product name "Sunsphere H-33" and product name "Sunsphere H-53"; product name "AEROSIL R972", product name "AEROSIL R974" and product The name "AEROSILR9200"; the trade name "AEROSILRX200", the trade name "AEROSIL R8200", the trade name "AEROSIL RX300" and the trade name "AEROSIL R812S" manufactured by NIPPON AEROSIL Corporation as trimethylsiloxylated silicic anhydride; The trade name "AEROSIL R805" manufactured by NIPPON AEROSIL Co., Ltd. of octylsiloxylated silicic anhydride; the trade name "AEROSIL R202", the trade name "AEROSIL RY200", the trade name " AEROSIL RY200S" and trade name "AEROSIL RY300"; as methacrylic siloxylated silicic anhydride The trade name "AEROSIL R711" manufactured by NIPPON AEROSIL; the trade name "Silica Beads SB-705" manufactured by Miyoshi Chemical Co., Ltd. as the above-mentioned disintegrating silica; The trade name "God Ball SF-16C", the trade name "God Ball AF-6C", the trade name "God Ball AF-16C" etc. manufactured by Yuyusha.

<calcium carbonate>

The aforementioned calcium carbonate is represented by, for example, the INCI name "CALCIUM CARBONATE". The said calcium carbonate may use only 1 type, and may use 2 or more types. As a commercial item of the said calcium carbonate, the brand name "Calmaru SCS M5" by Sakai Chemical Industry Co., Ltd.; the brand name "FUWACAL" by Shiraishi Calcium Co., Ltd. etc. are mentioned, for example.

<magnesium carbonate>

The aforementioned magnesium carbonate is represented by, for example, the INCI name "MAGNESIUM CARBONATE". The said magnesium carbonate may use only 1 type, and may use 2 or more types. As a commercial item of the said magnesium carbonate, the Tomita Pharmaceutical Co., Ltd. make, a brand name "light magnesium carbonate", etc. are mentioned, for example.

<Hydroxyapatite>

The aforementioned hydroxyapatite is represented by, for example, the INCI name "HYDROXYAPATITE". The said hydroxyapatite may be used only by 1 type, and may use 2 or more types.

The hydroxyapatite is not particularly limited, and examples thereof include spherical hydroxyapatite, sheet-like hydroxyapatite, and amorphous hydroxyapatite. Among these, spherical hydroxyapatite is preferable from the viewpoint of exhibiting high hair styling performance. Examples of commercially available hydroxyapatite include Taihei Chemical Industry Co., Ltd.'s trade name "flaky HAP", trade name "spherical HAP", trade name "HAP-100", trade name "HAP-200 " and the trade name "HAP-300", etc.

<Titanium dioxide>

The aforementioned titanium dioxide is represented by, for example, the INCI name "TITANIUM DIOXIDE". The aforementioned titanium dioxide is not particularly limited, and may be, for example, fine particle titanium dioxide or pigment titanium. The said titanium dioxide may use only 1 type, and may use 2 or more types. As a commercial item of the said titanium dioxide, the brand name "TTO-55(A)" and the brand name "CR-50" etc. which are made by Ishihara Sangyo Co., Ltd. are mentioned, for example.

<Zinc Oxide>

The aforementioned zinc oxide is represented by, for example, the INCI name "ZINC OXIDE". The above-mentioned zinc oxides may be used alone or in combination of two or more. As a commercial item of the said zinc oxide, the Sakai Chemical Industry Co., Ltd. product name "FINEX-30S-LP2" etc. are mentioned, for example.

<Calcium silicate>

The aforementioned calcium silicate is represented by, for example, the INCI name "CALCIUM SILICATE". The said calcium silicate may use only 1 type, and may use 2 or more types. As commercially available products of the above-mentioned calcium silicate, for example, the product name "FLORITE R" manufactured by Tomita Pharmaceutical Co., Ltd.; the product name "xonotlite powder XJ" manufactured by JAPAN INSULATION CO., LTD. wollastonite powder TK", etc.

<Magnesium silicate>

The aforementioned magnesium silicate is represented by, for example, the INCI name "MAGNESIUM SILICATE". The said magnesium silicate may use only 1 type, and may use 2 or more types. As a commercial item of the said magnesium silicate, the Tomita Pharmaceutical Co., Ltd. make, a brand name "magnesium silicate (light weight)", etc. are mentioned, for example.

<aluminum silicate>

The aforementioned aluminum silicate is represented by, for example, the INCI name "ALUMINUM SILICATE". The said aluminum silicate may use only 1 type, and may use 2 or more types. Although it does not specifically limit as aluminum silicate, Synthetic aluminum silicate is preferable. As a synthesis method, for example, a method of adding Na ₂ SiO ₃ to alum and drying the resulting precipitate; a method of producing a silicic acid sol by electrodialysis to form a gel; and adding Na 2 SiO 3 to water glass Aqueous solutions of aluminum salts; etc. As a commercial item of the said aluminum silicate, the Tomita Pharmaceutical Co., Ltd. make, a brand name "synthetic aluminum silicate (heavy weight)" etc. are mentioned, for example.

<magnesium hydroxide>

The aforementioned magnesium hydroxide is represented by, for example, the INCI name "MAGNESIUM HYDROXIDE". The said magnesium hydroxide may use only 1 type, and may use 2 or more types. As a commercial item of the said magnesium hydroxide, the brand name "magnesium hydroxide (heavy weight)" etc. by the Tomita Pharmaceutical Co., Ltd. product are mentioned, for example.

In 100% by mass of the hair dressing composition of the present invention, the content of the above component (A) is at least 0.1% by mass, preferably at least 0.4% by mass, more preferably at least 1% by mass, and at most 10% by mass, preferably 7% by mass. mass % or less, more preferably 5 mass % or less. When content of the said component (A) is more than the said minimum, hair styling retention power can be improved more, and stickiness can be further suppressed further. Storage stability (stability at the time of long-term storage) can be improved more because content of the said component (A) is below the said upper limit. In addition, the feel after hair styling becomes better. Content of the said component (A) is the total amount of content of all the components (A) in the hair dressing composition of this invention. In addition, in 100% by mass of the hair dressing composition of the present invention, the content of silicon dioxide, and the content of silicon dioxide, and calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicate, magnesium silicate, silicon The content (total content) of the particles in the group consisting of acid aluminum and magnesium hydroxide is 0.1% by mass or more, preferably 0.4% by mass or more, more preferably 1% by mass or more, 10% by mass or less, preferably 7% by mass. mass % or less, more preferably 5 mass % or less.

(ingredient (B))

The above-mentioned component (B) is a clay mineral. By using the above-mentioned component (B), especially by using the above-mentioned component (B) and the above-mentioned component (C) in combination, the hair dressing composition thickens moderately, so the dispersibility of the above-mentioned component (A) becomes better, and the storage stability becomes better. better. In addition, the applicability at the time of hair styling becomes better. The said component (B) may use only 1 type, and may use 2 or more types.

The above-mentioned component (B) may be a natural product or a synthetic product. The above-mentioned component (B) is not particularly limited, and examples thereof include clay minerals of the kaolin group, clay minerals of the pyrophyllite group, clay minerals of the pyrophyllite group, clay minerals of the mica group, clay minerals of the smectite group, and clay minerals of the vermiculite group. Clay minerals, chlorite group clay minerals and organically modified clay minerals, etc.

Examples of the above-mentioned kaolin group clay minerals include kaolin, nacrite, dickite, and seyonite. Examples of the above-mentioned antigorite group clay minerals include antigorite, magnesite, and greenstone. Pyrophyllite, talc (talc), etc. are mentioned as said pyrophyllite group clay mineral. Illite, glauconite, chrysophyte, sericite, mica (mica), muscovite, chrome muscovite, biotite, etc. are mentioned as said mica group clay mineral. Bentonite, montmorillonite, beidellite, nontronite, saponite, hectorite, synthetic hectorite (Lucentite) etc. are mentioned as said smectite group clay mineral. Vermiculite etc. are mentioned as said vermiculite group clay mineral. Chlorite (chlorite) etc. are mentioned as said chlorite group clay mineral. Examples of the above-mentioned organically modified clay minerals include organically modified clay minerals subjected to organic modification treatment, such as smectite group clay minerals and vermiculite group clay minerals. It is suitable to use quaternary ammonium salt type cationic surfactant in organic modification treatment. Examples of the above-mentioned quaternary ammonium salt type cationic surfactant include the above-mentioned alkyltrimethylammonium chloride, dialkyldimethylammonium chloride, benzalkonium chloride, and the like.

The component (B) is preferably a clay mineral selected from the group consisting of synthetic silicates and derivatives thereof from the viewpoint of further improving storage stability and usability of the hair dressing composition. The above-mentioned synthetic silicates and their derivatives are not silicate minerals mainly composed of natural magnesium silicate or silicic acid (sodium/magnesium) containing many impurities, but silicate minerals obtained through synthesis. and silicate derivatives.

As above-mentioned synthetic silicates and derivatives thereof, for example, there can be mentioned INCI name (International Cosmetic Ingredient Dictionary and Handbook (International Cosmetic Ingredient Dictionary and Handbook), 14th Edition, Volume 2, CTFA, 2012, p.3076 ): SODIUM MAGNESIUM SILICATE (sodium magnesium silicate) synthetic silicic acid (sodium/magnesium), INCI name (International Dictionary and Handbook of Cosmetic Raw Materials, 14th Edition, Volume 2, CTFA, 2012, p.1793) : MAGNESIUM FLUOROSILICATE (magnesium fluorosilicate), with INCI name (International Dictionary and Handbook of Cosmetic Raw Materials, 14th Edition, Volume 2, CTFA, 2012, p.3076): SODIUMMAGNESIUM FLUOROSILICATE (fluorosilicon Fluorosilicic acid (sodium/magnesium) represented by INCI name (International Dictionary and Handbook of Cosmetic Raw Materials, 14th Edition, Volume 2, CTFA, 2012, p.1799): MAGNESIUMPOTASSIUM FLUOROSILICATE (fluorosilicic acid Fluorosilicic acid (magnesium/potassium) expressed in INCI name (International Dictionary and Handbook of Cosmetic Raw Materials, 14th Edition, Volume 2, CTFA, 2012, p.1800): MAGNESIUMSODIUM FLUOROSILICATE (Sodium Fluorosilicate Fluorosilicic acid (magnesium/sodium) expressed by magnesium), expressed by INCI name (International Dictionary and Handbook of Cosmetic Raw Materials, 14th Edition, Volume 1, CTFA, 2012, p.156): ALUMINUMSILICATE (aluminum silicate) Synthetic aluminum silicate, etc.

As the above-mentioned component (B), among them, clay minerals (at least one kind) selected from the group consisting of synthetic silicic acid (sodium/magnesium), fluorosilicate (sodium/magnesium) and fluorosilicate (sodium/magnesium) are particularly preferred. Clay minerals).

As a commercial item of the said component (B), the Rockwood company make, a brand name "synthetic hectorite XLG", a brand name "synthetic hectorite XL21", etc. are mentioned, for example.

The content of the above-mentioned component (B) in 100% by mass of the hair dressing composition of the present invention is preferably at least 0.1% by mass, more preferably at least 0.3% by mass, still more preferably at least 0.5% by mass, and preferably at most 10% by mass. , more preferably 5% by mass or less, still more preferably 3% by mass or less. Storage stability and applicability of a hair dressing composition will become more favorable as content of the said component (B) is more than the said minimum. In addition, hair styling becomes better. The applicability of a hair dressing composition agent becomes more favorable that content of the said component (B) is below the said upper limit. Content of the said component (B) is the total amount of content of all the components (B) in the hair dressing composition of this invention.

(ingredient (C))

The above-mentioned component (C) is at least one kind of polymer selected from the group consisting of the above-mentioned component (C1) and the above-mentioned component (C2). By using the above-mentioned component (C), the hair styling retention becomes better. In addition, the hair dressing composition becomes difficult to separate, and storage stability becomes better. Moreover, since the hair dressing composition thickens moderately by using the said component (C) and the said component (B) together, the dispersibility of the said component (A) becomes better, and storage stability becomes more favorable. Moreover, the said component (C) may use only 1 type, and may use 2 or more types. In addition, the said component (C1) and the said component (C2) may use only 1 type, respectively, and may use 2 or more types.

As the above-mentioned component (C), either one of the above-mentioned component (C1) and the above-mentioned component (C2) may be used alone, or the above-mentioned component (C1) and the above-mentioned component (C2) may be used in combination.

The monomer component for obtaining the polymer of the said component (C1) contains at least 2 or more monomers selected from the group which consists of (meth)acrylic acid and an alkyl (meth)acrylate. That is, the above-mentioned component (C1) is a polymer containing at least two or more structural units selected from the group consisting of structural units derived from (meth)acrylic acid and structural units derived from alkyl (meth)acrylates. In addition, in this specification, the polymer which can correspond to both the said component (C1) and the said component (C2) is not a component (C1), but a component (C2).

The above-mentioned component (C1) is not particularly limited, but is preferably expressed as "ACRYLATES COPOLYMER (acrylic acid ( ester) copolymer)" compounds.

As a commercial item of the said component (C1), the Dow chemical company make, a brand name "Aculyn33" and a brand name "Aculyn 33A"; the SEPPIC company make a brand name "SepiMAX ZEN", etc. are mentioned, for example.

The above-mentioned component (C1) is not particularly limited, but is preferably neutralized with an alkaline substance or used after neutralization with an alkaline substance. Examples of the basic substance include alkanolamines such as triethanolamine and monoethanolamine; inorganic alkali compounds such as ammonia, sodium hydroxide, and potassium hydroxide; and basic amino acids such as arginine. In addition, the amount of the above-mentioned basic substance to be added is the amount to achieve sufficient neutralization of the component (C1), or the amount sufficient to neutralize the above-mentioned component (C1), as long as the above-mentioned component (C1) and the above-mentioned basic substance The type of and the amount of the above-mentioned component (C1) can be properly mixed.

The monomer component of the polymer used to obtain the above component (C2) contains at least one monomer component (c2a) selected from the group consisting of (meth)acrylic acid and alkyl (meth)acrylate, and At least one monomer component (c2b) selected from the group consisting of polyoxyethylene alkyl ether (meth)acrylate, polyoxyethylene alkyl ether itaconic acid, and vinyl neodecanoate. That is, the above-mentioned component (C2) is a polymer containing at least a structural unit derived from the above-mentioned monomer component (c2a) and a structural unit derived from the above-mentioned monomer component (c2b). The said monomer component (c2a) and the said monomer component (c2b) may use only 1 type, respectively, and may use 2 or more types.

The above-mentioned component (C2) is not particularly limited, but it is preferably expressed as "ACRYLATES/STEARETH-20 METHACRYLATECOPOLYMER (acrylic acid (esters) / stearyl ether-20 methacrylate copolymer)" compound; under the name of INCI (International Dictionary and Handbook of Cosmetic Raw Materials, 14th Edition, Volume 1, CTFA, 2012, p.67) Compounds expressed as "ACRYLATES/STEARETH-20 METHACRYLATECROSSPOLYMER (Acrylates/Steareth-20 Methacrylate Crosspolymer)"; , 14th Edition, Volume 1, CTFA, 2012, p.57) expressed as "ACRYLATES/BEHENETH-25 METHACRYLATE COPOLYMER (acrylic acid (ester) type/beheneth-25 methacrylate copolymer)" Compounds; expressed as "ACRYLATES/VINYLNEODECANOATE CROSSPOLYMER (acrylic acid (ester) class/new decanoic acid Vinyl ester crosslinked polymer)" compound; in INCI name (International Dictionary and Handbook of Cosmetic Raw Materials, 14th Edition, Volume 1, CTFA, 2012, p.66) as "ACRYLATES/STEARETH-20 ITACONATECOPOLYMER (acrylic acid (esters/steareth-20 itaconate copolymer)"; with INCI name (International Dictionary and Handbook of Cosmetic Raw Materials, 14th Edition, Volume 1, CTFA, 2012, p.60 ) a compound represented by "ACRYLATES/CETETH-20ITACONATECOPOLYMER (acrylic acid (ester) type/ceteth-20 itaconate copolymer)", etc.

Examples of commercially available products of the above-mentioned component (C2) include trade names "Aculyn 22", "Aculyn 88", "Aculyn 28" and "Aculyn 38" manufactured by The Dow Chemical Company; Akzo Nobel The trade name "STRUCTURE 2001" and the trade name "STRUCTURE 3001" manufactured by the company.

The above-mentioned component (C2) is not particularly limited, but is preferably neutralized with an alkaline substance or used after neutralization with an alkaline substance. Examples of the basic substance at this time include the above-mentioned basic substances. In addition, the amount of the above-mentioned basic substance to be added is the amount to achieve the fully neutralized component (C2), or the amount sufficient to neutralize the above-mentioned component (C2), as long as the above-mentioned component (C2) and the above-mentioned basic substance The type of and the amount of the above-mentioned component (C2) can be properly mixed.

The content of the above component (C) in 100% by mass of the hair dressing composition of the present invention is preferably at least 0.01% by mass, more preferably at least 0.1% by mass, preferably at most 5% by mass, more preferably at most 2% by mass . Storage stability and applicability of a hair dressing composition will become more favorable as content of the said component (C) is more than the said minimum. When content of the said component (C) is below the said upper limit, applicability will improve more, and the texture of hair will become more favorable. Content of the said component (C) is the total amount of content of all the components (C) in the hair dressing composition of this invention.

In 100% by mass of the hair dressing composition of the present invention, from the viewpoint of further improving the applicability of the hair dressing composition, the total amount of the content of the above-mentioned component (B) and the content of the above-mentioned component (C) (i.e. The total content) is preferably 0.2% by mass or more, more preferably 0.4% by mass or more, even more preferably 0.6% by mass or more, preferably 10% by mass or less, more preferably 8% by mass or less, and even more preferably 5% by mass or less. When the content of the total of the component (B) and the component (C) is more than the above lower limit, the harsh feeling due to the component (A) at the time of application of the hair dressing composition is further suppressed, and applicability is further improved. In addition, since thixomodification can be imparted to the hair dressing composition, the viscosity at the time of application is low, and better applicability can be exhibited, and the viscosity after application increases, so the hair style retention property is further improved. The storage stability of a hair dressing composition becomes more favorable as the total amount of content of the said component (B) and content of the said component (C) is below the said upper limit.

The mass ratio of the above-mentioned component (B) to the above-mentioned component (C) (content of the above-mentioned component (B) : content of the above-mentioned component (C)) is preferably 0.1:1 to 30:1, more preferably 0.2:1 to 20: 1. More preferably 0.5:1 to 10:1. If the above-mentioned mass ratio is satisfied, the separation of the hair dressing composition can be more effectively suppressed, and the storage stability of the hair dressing composition (stability during long-term storage), especially the storage stability during long-term storage becomes better. better.

(ingredient (D))

The above-mentioned component (D) is at least one compound selected from the group consisting of the above-mentioned component (D1) and the above-mentioned component (D2). Use of the component (D) further suppresses flaking, improves wash-off property after hair styling, and imparts a good feel to hair after hair styling while maintaining high initial hair styling power. In addition, even in a state in which the hair dressing composition is applied to the hair and the hair is sufficiently styled, the uncomfortable feeling due to the adhesion of the hair dressing composition can be suppressed, and the hair can be styled in a natural state. The said component (D) may use only 1 type, and may use 2 or more types. In addition, the said component (D1) and the said component (D2) may use only 1 type, respectively, and may use 2 or more types.

As the above-mentioned component (D), either one of the above-mentioned component (D1) and the above-mentioned component (D2) may be used alone, or the above-mentioned component (D1) and the above-mentioned component (D2) may be used in combination.

The above-mentioned component (D1) is a polyoxyalkylene alkyl glucoside. Examples of the oxyalkylene group in the component (D1) include an oxyethylene group, an oxypropylene group, and the like. The average added mole number of oxyalkylene groups in the component (D1) is not particularly limited, but is preferably 5 or more, and preferably 40 or less. The number of carbon atoms of the alkyl group in the component (D1) is preferably 1-4, more preferably 1-3. The alkyl group in the above component (D1) is preferably a methyl group or an ethyl group.

It does not specifically limit as said component (D1), Polyoxyethylene methyl glucoside, polyoxyethylene ethyl glucoside, polyoxypropylene methyl glucoside, polyoxypropylene ethyl glucoside, etc. are mentioned.

The above-mentioned component (D1) is preferably polyoxyethylene methyl glucoside from the viewpoint of providing a better texture to the hair after hair styling while maintaining a high initial hair styling power.

The above-mentioned component (D2) is a polyoxyalkylene glycerin fatty acid ester. The number of carbon atoms of the fatty acid in the component (D2) is preferably 8 or more, preferably 22 or less. Examples of the oxyalkylene group in the component (D2) include an oxyethylene group, an oxypropylene group, and the like. The average number of added moles of the oxyalkylene groups in the component (D2) is preferably 5 or more, preferably 40 or less.

The fatty acid in the component (D2) is preferably a branched chain fatty acid, and the component (D2) is preferably a polyoxyalkylene glycerin from the viewpoint of imparting a better feel to the hair after styling while maintaining a high initial hair styling power. Branched-chain fatty acid esters.

From the viewpoint of imparting a better feel to the hair after hair styling while maintaining a high initial hair styling power, the number of carbon atoms of the branched fatty acid in the polyoxyalkylene glycerin branched fatty acid ester is preferably 8 or more, preferably under 16. Examples of the branched fatty acid in the polyoxyalkylene glycerin branched fatty acid ester include 2-ethylhexanoic acid, isononanoic acid, isopalmitic acid, and isostearic acid.

As the polyoxyalkylene glycerin branched fatty acid ester, polyoxyethylene glyceryl isostearate is particularly preferable.

As a commercial product of the above-mentioned component (D1), for example, the product name "MACBIOBRIDEMG-10P" manufactured by NOF Corporation; the product name "GLUCAM E-10" and "GLUCAM E-20" manufactured by Noveon Corporation; Amerchol's product name "GLUCAM P-10" etc.

As a commercial product of the above-mentioned component (D2), for example, the trade name "Noigen GIS-125" manufactured by Daiichi Kogyo Pharmaceutical Co., Ltd.; the trade name "EMALEX GWIS-115" manufactured by NIHON EMULSION; 120", trade name "EMALEX GWIS-125" and trade name "EMALEX GWIS-130", etc.

The content of the above component (D) in 100% by mass of the hair dressing composition of the present invention is preferably at least 0.5% by mass, more preferably at least 1% by mass, preferably at most 20% by mass, more preferably at most 10% by mass . When content of the said component (D) is more than the said minimum, peeling is suppressed further, and the washability after hair styling becomes better, and a better texture can be provided to the hair after hair styling. Stickiness is further reduced as content of the said component (D) is below the said upper limit. Content of the said component (D) is the total amount of content of all the components (D) in the hair dressing composition of this invention.

In the above-mentioned hair dressing composition, the mass ratio of the content of the above-mentioned component (A) to the content of the above-mentioned component (D) (the content of the above-mentioned component (A) : the content of the above-mentioned component (D)) is preferably 1:0.2-1 :20, more preferably 1:1 to 1:10. When there are relatively many contents of the said component (A), hair styling power becomes better. When the content of the above-mentioned component (D) is relatively large, the texture of the hair and the wash-off property at the time of shampooing the hair conditioner become better. The mass ratio of the content of silicon dioxide to the content of the above-mentioned component (D), and the selected from calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and hydroxide The mass ratio of the content of the particles (total content) in the magnesium group to the content of the component (D) is preferably 1:0.2 to 1:20, more preferably 1:1 to 1:10.

(ingredient (E))

The above component (E) is polyethylene glycol. By using the above-mentioned component (E), it is possible to provide a favorable texture to the hair after hair styling while maintaining high hair styling properties. The said component (E) may use only 1 type, and may use 2 or more types.

The number average molecular weight of the component (E) is preferably 800 or more, more preferably 900 or more, and preferably 2000 or less, more preferably 1700 or less, from the viewpoint of further enhancing the effect of imparting a good feel to hair.

In 100% by mass of the hair dressing composition of the present invention, the content of the component (E) is at least 0.3% by mass, preferably at least 0.5% by mass, more preferably at least 1% by mass, preferably at most 15% by mass, and more preferably at least 15% by mass. Preferably it is 10 mass % or less. When content of the said component (E) is more than the said minimum, the effect of providing a favorable texture to hair will improve more. Hair styling property improves more because content of the said component (E) is below the said upper limit. Content of the said component (E) is the total amount of content of all the components (E) in the hair dressing composition of this invention.

(other ingredients)

The hair dressing composition of the present invention is not particularly limited, but preferably contains water. The water is not particularly limited as long as it is used in cosmetics, but pure water is preferred. The content of water in 100% by mass of the hair dressing composition of the present invention is preferably at least 30% by mass, more preferably at least 40% by mass, preferably at most 95% by mass, more preferably at most 90% by mass.

In addition, the hair dressing composition of the present invention is not particularly limited, but preferably contains a lower alcohol having 2 to 5 carbon atoms (especially ethanol). The content of lower alcohol (especially ethanol) in 100% by mass of the hair dressing composition of the present invention is preferably at least 2% by mass, more preferably at least 5% by mass, preferably at most 50% by mass, more preferably 30% by mass %the following.

In the hair dressing composition of the present invention, surfactants such as nonionic surfactants, cationic surfactants, and amphoteric surfactants may also be contained within the range that does not inhibit the effects of the present invention; glycerin, 1,3 -Butanediol, propylene glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol and other polyols; Higher alcohols with 12 to 18 carbon atoms such as lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, isostearyl alcohol, cetearyl alcohol and oleyl alcohol; sorbitol, maltitol and trehalose, etc. Sugar alcohols; xanthan gum, carrageenan, guar gum, gellan gum and other polysaccharide compounds; silicone oil; chelating agents; antioxidants; plant extracts; pigments; pigments; pH regulators; fragrances; preservatives; solvents, etc.

(Additional details of hair dressing composition)

The property of the hair dressing composition of this invention is not specifically limited, For example, a liquid form, a gel form, a paste form, a solid form, etc. are mentioned. In particular, it is preferable that the said hair dressing composition is liquid or gel.

The viscosity at 25° C. of the hair dressing composition is preferably 1000 mPa·s or more, more preferably 2000 mPa·s or more, preferably 100000 mPa·s or less, more preferably 50000 mPa·s or less. When the viscosity is not less than the above lower limit and not more than the above upper limit, applicability is further improved, the occurrence of peeling and stickiness are further suppressed, and the initial hair styling power and hair styling retention power are further improved. In the above-mentioned hair dressing composition, the above-mentioned viscosity is not more than the above-mentioned upper limit, even if the fluidity is high, the generation of flaking and stickiness can be suppressed, and the initial hair styling power and hair styling retention power can be improved.

The above-mentioned viscosity was measured with a viscometer using a No. 4 spindle under the conditions of a rotation speed of 12 rpm and a rotation time of 1 minute. As the above-mentioned viscometer, TV-22 type viscometer manufactured by Toki Sangyo Co., Ltd. can be used.

The manufacturing method of the hair dressing composition of this invention is not specifically limited, As a manufacturing method of the hair dressing composition of this invention, the manufacturing method of a well-known hair dressing composition can be used. The method for producing the hair dressing composition of the present invention is not particularly limited, and examples include a method in which component (A) and component (C) and water are stirred with a disperser, and then replaced with a paddle mixer. Mix and homogenize the other ingredients while stirring.

The hair dressing composition of this invention contains a component (A), a component (B) and a component (C) at least. Component (A) enables the hair dressing composition of the present invention to exhibit excellent hair styling retention power. In addition, when only the component (A) is used, the roughness of the applied hair can be solved, and the applicability can be improved. In addition, by using the component (B) and the component (C) in combination, it is estimated that the crosslinked structure of the component (B) and the component (C) can be formed, but the hair dressing composition thickens moderately. In addition, the hair dressing composition exhibits thixotropy, and the viscosity decreases under shear stress. Thereby, sedimentation and aggregation of a component (A) are hard to generate|occur|produce, and the storage stability at the time of storing a hair dressing composition for a long time improves. In addition, applicability improves. By making the compounding ratio of a component (B) and a component (C) into a specific preferable range, the said effect improves further. In addition, by using the component (B) and the component (C) together, it is presumed that the water retention effect of the component (C) is exhibited, but the separation of the hair dressing composition (chaotropic liquid components) can be suppressed, and the storage stability is further improved. improve.

In addition, by blending the component (D), the hair styling power and the effect of suppressing flaking are further improved, and furthermore, the effect of imparting luster to the hair after hair styling and the rinse-off property are improved.

It is preferable that the hair dressing composition of this invention contains a component (E) further. By using the component (E), it is possible to provide a favorable texture to the hair after hair styling while maintaining high hair styling properties. In addition, stickiness occurs when only component (E) is used, but by using component (A) and component (E) together, the above-mentioned effect can be exhibited while suppressing stickiness.

As described above, when the hair dressing composition of the present invention is used, not only can the hair be styled well, but also the state of the hair style can be maintained well for a long time. Moreover, the storage stability of the hair dressing composition of this invention is also excellent.

The hair dressing composition of the present invention is not particularly limited, and can be used, for example, in a form filled in a container.

As said container, a bottle container, a can container, a tube container, etc. are mentioned. The aforementioned container is preferably a bottle container or a tube container.

Hereinafter, the present invention will be specifically described with reference to Examples and Comparative Examples. The present invention is not limited to the following examples.

(Example)

The following components were used in Examples and Comparative Examples.

(ingredient (A))

Product name "Sylysia 320": Silicon dioxide, manufactured by Fuji Silysia Chemical Co., Ltd.

Product name "AEROSIL 200": Silica, manufactured by NIPPON AEROSIL

Trade name "Spherical HAP": Hydroxyapatite (manufactured by Taihei Chemical Industry Co., Ltd.)

Product name "FLORITE R": Calcium silicate (manufactured by Tomita Pharmaceutical Co., Ltd.)

Trade name "synthetic aluminum silicate (heavy)": aluminum silicate (manufactured by Tomita Pharmaceutical Co., Ltd.)

Trade name "magnesium hydroxide (heavy)": Magnesium hydroxide (manufactured by Tomita Pharmaceutical Co., Ltd.)

(ingredient (B))

Trade name "synthetic hectorite XL21": fluosilicic acid (sodium/magnesium), manufactured by Rockwood

Trade name "Synthetic Hectorite XLG": Synthetic silicic acid (sodium/magnesium), manufactured by Rockwood

(ingredient (C))

Trade name "Aculyn 22": Alkyl acrylate/alkyl methacrylate/polyoxyethylene stearyl ether methacrylate (20E.O.) copolymer emulsion, manufactured by The Dow Chemical Company, 30% by mass aqueous solution

Trade name "Aculyn 28": Alkyl acrylate/alkyl methacrylate/polyoxyethylene behenyl ether (25E.O.) copolymer emulsion, manufactured by The Dow Chemical Company, 20% by mass aqueous solution

Trade name "Aculyn 33A": Alkyl acrylate copolymer emulsion, manufactured by The Dow Chemical Company, 28% by mass aqueous solution

Trade name "Aculyn 38": Alkyl acrylate-vinyl neodecanoate crosspolymer, manufactured by The Dow Chemical Company, 29% by mass aqueous solution

(ingredient (D))

Product name "Noigen GIS-125": polyoxyethylene glyceryl isostearate, manufactured by Daiichi Kogyo Pharmaceutical Co., Ltd.

Product name "MACBIOBRIDE MG-10P": polyoxypropylene methyl glucoside, manufactured by NOF Corporation

(ingredient (E))

Product name "PEG#1000": polyethylene glycol 1000, manufactured by LION Corporation

(Examples 1-42 and Comparative Examples 1-9)

The compounding components shown to following Tables 1-6 were compounded (the compounding unit is mass %), and the hair dressing composition was prepared. The properties of the hair dressing compositions obtained in Examples 1 to 42 were all gel-like. In addition, the compounding quantity in a table is shown by the actual compounding quantity (commodity compounding quantity).

The obtained hair dressing composition was filled in a plastic container.

(Test Example 1: Evaluation of Storage Stability)

The said hair dressing composition was filled in the transparent glass container with a volume of 60 mL, and it preserve|saved for 1 month in the thermostat maintained at 40 degreeC. The hair dressing composition in the said transparent glass container after storage for 1 month was observed visually, and "storage stability" was evaluated based on the following evaluation criteria.

<Evaluation criteria for storage stability>

○ (quite good): Occurrence of aggregation and sedimentation and separation of the hair dressing composition were not confirmed in any of them

Δ (good): At least one change in the occurrence of aggregation and sedimentation and separation of the hair dressing composition was slightly confirmed

× (poor): At least one change in occurrence of aggregation and sedimentation and separation of hair dressing composition was clearly confirmed

(Test Example 2: Evaluation of Coatability)

20 professional judges apply the above-mentioned hair dressing composition evenly to the hair of a wig (practice mannequin: manufactured by YUKARI Japan Co., Ltd.), comb the hair from front to back along the shape of the wig to perform hair styling, and then answer the application ease. In addition, it judged that it was easy to apply|coat when hair styling and a rough feeling were not felt. Based on the above answers, applicability was evaluated in accordance with the following criteria.

<Evaluation Criteria for Coatability>

○ (quite good): 16 or more out of 20 respondents answered that it is easy to apply

△ (Good): 10 to 15 out of 20 respondents answered that it was easy to apply

× (poor): Less than 9 out of 20 respondents answered that it was easy to apply

(Test Example 3: Evaluation of Hair Retaining Power)

20 professional judges observed the hair of the hair-styled wig 6 hours after the above-mentioned Test Example 2 (evaluation of coating properties), and answered whether there was hair-setting retention. In addition, when the shape of the hair after hair styling of the test example 2 was maintained continuously, it was judged that it had hair styling retention power. Based on the above answers, hair styling retention power was evaluated according to the following criteria.

<Evaluation Criteria for Hair Retaining Power>

○ (pretty good): 16 or more out of 20 respondents answered that they have hair holding power

△ (Good): 10 to 15 out of 20 respondents answered that they have hair holding power

× (poor): Less than 9 out of 20 respondents answered that hair holding power was maintained

The results are shown in Tables 1 to 6 below. The total of the compounding components in each Example and each comparative example of Tables 1-6 is 100 mass %.

[Table 1]

[Table 2]

[table 3]

[Table 4]

[table 5]

[Table 6]

In addition, about the hair dressing composition obtained in Example 1, Example 20, Example 22, and Example 41, the following peeling and wash-off evaluations were also performed.

(Test Example 4: Evaluation of Peeling)

After the above-mentioned Test Example 3 (evaluation of hair holding power), 20 professional judges combed the hair of the wig from the root to the tip of the wig 5 times in a row with fingertips, and asked whether there was any peeling. In addition, when it seems that white powder adhered to the hair, it was judged that there was peeling. Based on the above answers, peeling was evaluated according to the following criteria.

<Evaluation criteria for peeling>

○ (quite good): 16 or more out of 20 respondents answered that there was no peeling

△ (good): 10 to 15 out of 20 respondents answered that there was no peeling

× (poor): 9 or less out of 20 respondents answered that there was no peeling

(Test Example 5: Evaluation of Washability)

After the above-mentioned Test Example 4 (evaluation of peeling), 20 professional judges washed the hair of the wig with warm water using shampoo (trade name "LUCIDOshampoo", manufactured by Mandansha Co., Ltd.), dried it, and asked whether the wash-off property was good. In addition, when the hair after shampooing does not have rough feeling and sticky feeling, it is evaluated that the wash-off property is good. Based on the above answers, the wash-off property was evaluated according to the following criteria.

<Evaluation Criteria for Washability>

○ (very good): 16 or more out of 20 respondents answered that the wash-off property is good

△ (good): 10 to 15 out of 20 respondents answered that the wash-off property was good

× (poor): Less than 9 out of 20 respondents answered that the wash-off property was good

Regarding the evaluation results, the evaluation results of the hair dressing compositions obtained in Example 1 and Example 22 were all "◯ (quite good)" in terms of peeling and rinsing properties. On the other hand, the evaluation results of the hair dressing compositions obtained in Example 20 and Example 41 were all "Δ (good)" in terms of peeling and rinsing properties.

Claims (2)

1. a kind of hair mousse composition, it includes following compositions A, following compositions B, as selected from by following compositions C1 and it is following at Divide the ingredient C and ingredient D of the polymer in the group of C2 compositions,

The content of the ingredient A is 0.1 mass % or more, 10 mass % hereinafter, the content of the ingredient B and containing for the ingredient C The total amount of amount be 0.2 mass % or more, 10 mass % hereinafter, and the content of the content of the ingredient B and the ingredient C matter Amount is than being 0.1：1~30：1

Ingredient A：Selected from by silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicates, silicic acid Particle in the group of magnesium, alumina silicate and magnesium hydroxide composition；

Ingredient B：Clay mineral；

Ingredient C1：Using two or more in the group being made of (methyl) acrylic acid and (methyl) alkyl acrylate Monomer is as polymer obtained from necessary monomer component；

Ingredient C2：Using in the group being made of (methyl) acrylic acid and (methyl) alkyl acrylate monomer and choosing Freely in the group of (methyl) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether and vinyl neodecanoate composition Monomer as polymer obtained from necessary monomer component；

Ingredient D：Polyoxyalkylene glycerine side chain fatty acid ester.

2. hair mousse composition as described in claim 1, further includes following compositions E,

Ingredient E：Polyethylene glycol.