CN102703196A - Environment-friendly water-based metal cutting fluid - Google Patents
Environment-friendly water-based metal cutting fluid Download PDFInfo
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- CN102703196A CN102703196A CN201210177089XA CN201210177089A CN102703196A CN 102703196 A CN102703196 A CN 102703196A CN 201210177089X A CN201210177089X A CN 201210177089XA CN 201210177089 A CN201210177089 A CN 201210177089A CN 102703196 A CN102703196 A CN 102703196A
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- water
- cutting fluid
- based metal
- sodium
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 239000002173 cutting fluid Substances 0.000 title claims abstract description 24
- 229910052751 metal Inorganic materials 0.000 title abstract description 8
- 239000002184 metal Substances 0.000 title abstract description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 17
- WUGCLPOLOCIDHW-UHFFFAOYSA-N 2-aminoethanol;benzoic acid Chemical compound [NH3+]CCO.[O-]C(=O)C1=CC=CC=C1 WUGCLPOLOCIDHW-UHFFFAOYSA-N 0.000 claims abstract description 9
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 9
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 9
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 3
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims abstract description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 21
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 14
- 239000012530 fluid Substances 0.000 claims description 14
- 238000005555 metalworking Methods 0.000 claims description 13
- 239000005543 nano-size silicon particle Substances 0.000 claims description 10
- 150000002148 esters Chemical class 0.000 claims description 9
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 claims description 8
- -1 Polyoxyethylene Polymers 0.000 claims description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- 229910052796 boron Inorganic materials 0.000 claims description 7
- 235000011187 glycerol Nutrition 0.000 claims description 7
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 7
- 235000006408 oxalic acid Nutrition 0.000 claims description 7
- 235000019353 potassium silicate Nutrition 0.000 claims description 7
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims description 2
- 229960004418 trolamine Drugs 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- BDOYKFSQFYNPKF-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetic acid;sodium Chemical compound [Na].[Na].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O BDOYKFSQFYNPKF-UHFFFAOYSA-N 0.000 abstract 1
- GVSNQMFKEPBIOY-UHFFFAOYSA-N 4-methyl-2h-triazole Chemical compound CC=1C=NNN=1 GVSNQMFKEPBIOY-UHFFFAOYSA-N 0.000 abstract 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 235000015393 sodium molybdate Nutrition 0.000 abstract 1
- 239000011684 sodium molybdate Substances 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 8
- 238000005520 cutting process Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 6
- 238000005987 sulfurization reaction Methods 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 238000011161 development Methods 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 235000010288 sodium nitrite Nutrition 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 239000006061 abrasive grain Substances 0.000 description 2
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 231100000957 no side effect Toxicity 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- MHKWSJBPFXBFMX-UHFFFAOYSA-N iron magnesium Chemical compound [Mg].[Fe] MHKWSJBPFXBFMX-UHFFFAOYSA-N 0.000 description 1
- 239000010808 liquid waste Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention discloses an environment-friendly water-based metal cutting fluid. The cutting fluid consists of the following components in part by weight: 10 to 12 parts of triethanolamine, 3 to 4 parts of glycerol, 5 to 7 parts of polyethylene glycol, 3 to 5 parts of nanometer silicon dioxide, 1.5 to 2.5 parts of isopropanol, 5 to 7 parts of sodium molybdate, 2 to 3 parts of sodium benzoate, 3 to 5 parts of monoethanolamine benzoate, 5 to 7 parts of ethylene diamine tetraacetic acid disodium, 7 to 8 parts of water-soluble borate, 1.5 to 2 parts of sodium silicate, 1.5 to 2.5 parts of methyl triazole and 70 to 80 parts of water.
Description
Technical field
The present invention relates to the metal cutting processing technique field, relate in particular to a kind of environment protection water-based metal working fluid.
Background technology
Cutting fluid is widely used in the metal cutting process, and it act as the cooling of metal parts, lubricated, cleaning, antirust etc.The cutting fluid that China's machinery industry is used is to form from the formula development that the FSU introduces, and for the oil base emulsion, belongs to mixed aqueous solution, contains Sodium Nitrite in its composition more or less, and the user is had certain toxic side effect; Be prone in the use take place to go bad, smell is serious, contaminate environment.Continuous progress and development along with mechanical industry; The cutting speed of metal cutting equipment improves constantly; The development of machinery is had higher requirement to indexs such as the precision of mechanical component, performances simultaneously, and dimensional precision, surfaceness, anti-attrition abrasion resistance and the surperficial diamagnetism etc. of final component are also had higher requirement.Both at home and abroad some enterprises and the novel cutting fluid of the numerous and confused development of R&D institution, " a kind of water-base nondrip cutting liquid " (number of patent application 86102438) of inventing of Beijing first Machine Tools Plant for example, this invention is a kind of water-base nondrip cutting liquid that is used for mechanical workout.It is characterized in that not containing any MO and vegetables oil in the prescription, cost is low, preparation is simple, pollute very little, odorless, tasteless, still exist do not grow duration of service and lubricate, problem such as rustless property difference; " long lifetime centrallubrication synthesis type cutting fluid " (number of patent application 91105163.5) of Technology Inst., No.1 Automobile Manufacturing Factory and Dongliao County, Jilin Province oil in water emulsion factory joint research and development; This cutting fluid is a kind of boride that contains; The additive of fungicide mixture and carboxylic acid and salt thereof, and do not contain the synthesis type cutting fluid of MO.Be applicable to the centralized lubrication system of the multiple form processing of materials such as steel, cast iron, magnesium iron and aluminium, owing to have fungicide mixture to exist, thereby certain toxic side effect is arranged; Number of patent application is 94108478.7 " sulfurized aqueous machining fluid composition "; The water-based cutting fluid composite that this invention provides; Particularly water-based metal working fluid compsn demonstrates improved frictional force reduction and the reduction of improved pressure in the mechanical-moulded of metal and the nonmetal work package of solid and processing.These compsns comprise a) water; B) sulfuration organic substance, this material is selected from by the sulfuration unsaturated aliphatic carboxylic acid and the salt thereof that contain 6-22 carbon atom, contains the sulfuration unsaturated ester of the aliphatic carboxylic acid of 1-22 carbon atom; Sulfuration polymerization unsaturated fatty acids and salt and ester; And their group that mixture constituted, c) sulfuration hydrocarbon and d) aliphatic ester of dialkyldithiocarbamacompositions, owing to there is the existence of sulfuration hydrocarbon influential to environment more or less; " aqueous composition, the water-base cutting fluid that uses this compsn, its method of manufacture and use the cutting process of this cutting fluid " (number of patent application 99800279.8) of the common development of Japan Shinetsu Handotai KK and Ohtomo Chemical Ins Corp. provides a kind of impact that can suppress operating environment and global environment, has the water-base cutting fluid that the abrasive material polymolecularity also can prevent the throw out hard caking simultaneously.Abrasive grain G is dispersed in the aqueous composition that siliceous colloid particle P stable dispersion is formed in the dispersion agent M that contains oleophilicity multicomponent alcoholics compounds such as wetting ability multicomponent alcoholics compound, Ucar 35 such as terepthaloyl moietie and water; Dispersion agent M is odorless and flame retardant resistance; Even between the abrasive grain G through the time sedimentation can closely not contact yet, so the throw out hard caking free, can be with its redispersion and utilize again.Because the original viscosity of this water-base cutting fluid is low, sneaks into and cause that viscosity increases phenomenon and relaxes long service life so moisture is sneaked into reduce effect and the smear metal that cause viscosity; Can wash work piece; Because dispersion agent M is the low molecular weight organic compound with Biodegradable, can also must carry out liquid waste disposal with active sludge.
Summary of the invention
The objective of the invention is to propose a kind of environment protection water-based metal working fluid, this cutting fluid can overcome the defective of above-mentioned prior art, has no side effect, do not have discharging, pollution-free, and antirust, lubricated, cooling effect is excellent.
For reaching this purpose, the present invention adopts following technical scheme:
A kind of environment protection water-based metal working fluid, described cutting fluid is made up of following component in weight part: trolamine 10-12 part, glycerine 3-4 part, polyoxyethylene glycol 5-7 part; Nano silicon 3-5 part, Virahol 1.5-2.5 part, Sodium orthomolybdate 5-7 part, Sodium Benzoate 2-3 part; Phenylformic acid monoethanolamine 3-5 part, oxalic acid tetraacethyl disodium 5-7 part, water-soluble boron acid esters 7-8 part; Water glass 1.5-2 part, methyl benzotriazole 1.5-2.5 part, water 70-80 part.
Preferably, the granularity of said nano silicon is the 30-80 nanometer.
The present invention has following beneficial effect with respect to prior art:
1) the present invention does not contain Sodium Nitrite and muriate, has no side effect, do not have discharging, pollution-free.
2) the employing nano silicon substitutes conventional borax, has good antifriction and wear-resistant effect, and comparatively excellent extreme pressure property, can significantly improve the lubricity of metal working fluid.
3) combination of adopting Sodium Benzoate and phenylformic acid monoethanolamine is as antirust component, and on the basis of a large amount of experiments, the adding proportion of the two that confirm makes that the rust-proof effect of cutting fluid is excellent, and a series of problems of having avoided Sodium Nitrite to bring.
4) added an amount of antimicrobial composition, methyl benzotriazole prolongs the life cycle of cutting fluid greatly.
Embodiment
Embodiment one
A kind of environment protection water-based metal working fluid, described cutting fluid is made up of following component in weight part: 10 parts of trolamines, 4 parts of glycerine, 5 parts of polyoxyethylene glycol; 5 parts of nano silicons, the granularity of said nano silicon are the 30-80 nanometer, 1.5 parts of Virahols, 7 parts of Sodium orthomolybdates; 2 parts of Sodium Benzoates, 5 parts of phenylformic acid monoethanolamines, 5 parts of oxalic acid tetraacethyl disodiums, 8 parts of water-soluble boron acid esters; 1.5 parts of water glass, 2.5 parts of methyl benzotriazoles, 70 parts in water.
Embodiment two
A kind of environment protection water-based metal working fluid, described cutting fluid is made up of following component in weight part: 12 parts of trolamines, 3 parts of glycerine, 7 parts of polyoxyethylene glycol; 3 parts of nano silicons, the granularity of said nano silicon are the 30-80 nanometer, 2.5 parts of Virahols, 5 parts of Sodium orthomolybdates; 3 parts of Sodium Benzoates, 3 parts of phenylformic acid monoethanolamines, 7 parts of oxalic acid tetraacethyl disodiums, 7 parts of water-soluble boron acid esters; 2 parts of water glass, 1.5 parts of methyl benzotriazoles, 80 parts in water.
Embodiment three
A kind of environment protection water-based metal working fluid, described cutting fluid is made up of following component in weight part: 10.5 parts of trolamines, 3.8 parts of glycerine, 5.5 parts of polyoxyethylene glycol; 4.5 parts of nano silicons, the granularity of said nano silicon are the 30-80 nanometer, 1.8 parts of Virahols, 6.5 parts of Sodium orthomolybdates; 2.2 parts of Sodium Benzoates, 4.5 parts of phenylformic acid monoethanolamines, 5.5 parts of oxalic acid tetraacethyl disodiums, 7.8 parts of water-soluble boron acid esters; 1.6 parts of water glass, 2.3 parts of methyl benzotriazoles, 72 parts in water.
Embodiment four
A kind of environment protection water-based metal working fluid, described cutting fluid is made up of following component in weight part: 11.5 parts of trolamines, 3.2 parts of glycerine, 6.5 parts of polyoxyethylene glycol; 3.5 parts of nano silicons, the granularity of said nano silicon are the 30-80 nanometer, 2.3 parts of Virahols, 5.5 parts of Sodium orthomolybdates; 2.8 parts of Sodium Benzoates, 3.5 parts of phenylformic acid monoethanolamines, 6.5 parts of oxalic acid tetraacethyl disodiums, 7.3 parts of water-soluble boron acid esters; 1.8 parts of water glass, 1.8 parts of methyl benzotriazoles, 78 parts in water.
Embodiment five
A kind of environment protection water-based metal working fluid, described cutting fluid is made up of following component in weight part: 11 parts of trolamines, 3.5 parts of glycerine, 6 parts of polyoxyethylene glycol; 4 parts of nano silicons, the granularity of said nano silicon are the 30-80 nanometer, 2 parts of Virahols, 6 parts of Sodium orthomolybdates; 2.5 parts of Sodium Benzoates, 4 parts of phenylformic acid monoethanolamines, 6 parts of oxalic acid tetraacethyl disodiums, 7.5 parts of water-soluble boron acid esters; 1.8 parts of water glass, 2 parts of methyl benzotriazoles, 75 parts in water.
Claims (2)
1. an environment protection water-based metal working fluid is characterized in that, described cutting fluid is made up of following component in weight part: trolamine 10-12 part, glycerine 3-4 part; Polyoxyethylene glycol 5-7 part, nano silicon 3-5 part, Virahol 1.5-2.5 part, Sodium orthomolybdate 5-7 part; Sodium Benzoate 2-3 part, phenylformic acid monoethanolamine 3-5 part, oxalic acid tetraacethyl disodium 5-7 part, water-soluble boron acid esters 7-8 part; Water glass 1.5-2 part, methyl benzotriazole 1.5-2.5 part, water 70-80 part.
2. a kind of environment protection water-based metal working fluid as claimed in claim 1 is characterized in that the granularity of said nano silicon is the 30-80 nanometer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210177089.XA CN102703196B (en) | 2012-05-31 | 2012-05-31 | Environment-friendly water-based metal cutting fluid |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210177089.XA CN102703196B (en) | 2012-05-31 | 2012-05-31 | Environment-friendly water-based metal cutting fluid |
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| Publication Number | Publication Date |
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| CN102703196A true CN102703196A (en) | 2012-10-03 |
| CN102703196B CN102703196B (en) | 2014-11-26 |
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| CN201210177089.XA Expired - Fee Related CN102703196B (en) | 2012-05-31 | 2012-05-31 | Environment-friendly water-based metal cutting fluid |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103468386A (en) * | 2013-08-24 | 2013-12-25 | 天长市康和金属材料有限公司 | Copper wire high-speed filament lubricant |
| CN103602474A (en) * | 2013-11-18 | 2014-02-26 | 青岛广联达精密机械有限公司 | Novel high-viscosity-temperature-characteristic lubricating oil |
| CN104277900A (en) * | 2014-09-25 | 2015-01-14 | 巢湖广丰金属制品有限公司 | High-antiwear cutting fluid |
| CN106047463A (en) * | 2016-06-23 | 2016-10-26 | 苏州洪河金属制品有限公司 | Water-based cutting liquid for metals |
| CN106118839A (en) * | 2016-06-23 | 2016-11-16 | 苏州洪河金属制品有限公司 | Metalworking fluid that a kind of water based lubrication is antirust and preparation method thereof |
| CN106190478A (en) * | 2016-07-13 | 2016-12-07 | 天长市润达金属防锈助剂有限公司 | A kind of safe antirust, anti-corrosive metalworking fluid |
| CN106221882A (en) * | 2016-08-10 | 2016-12-14 | 天长市润达金属防锈助剂有限公司 | A kind of rust preventive cutting fluid |
| CN106281612A (en) * | 2016-08-10 | 2017-01-04 | 天长市润达金属防锈助剂有限公司 | A kind of semi-synthetic cutting fluid |
| CN106337186A (en) * | 2016-08-10 | 2017-01-18 | 天长市润达金属防锈助剂有限公司 | Sterilizing water-based antirust liquid and preparation method thereof |
| CN107118840A (en) * | 2017-03-31 | 2017-09-01 | 苏州亚思科精密数控有限公司 | A kind of green cutting fluid and preparation method thereof |
| CN109136954A (en) * | 2018-08-03 | 2019-01-04 | 天津普罗米新材料有限公司 | A kind of metal Environment-friendlywater-base water-base rust inhibitor |
| CN109810769A (en) * | 2017-11-21 | 2019-05-28 | 常州市好利莱光电科技有限公司 | A kind of preparation method of aqueous cutting fluid |
| CN109810749A (en) * | 2019-03-04 | 2019-05-28 | 富莱德科技(浙江)有限公司 | A fully synthetic cutting fluid |
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| US20100043301A1 (en) * | 2007-02-26 | 2010-02-25 | Kangnung National University Industrial Academy Corporation Group | Water-based cutting fluid having ceramic powder |
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2012
- 2012-05-31 CN CN201210177089.XA patent/CN102703196B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100043301A1 (en) * | 2007-02-26 | 2010-02-25 | Kangnung National University Industrial Academy Corporation Group | Water-based cutting fluid having ceramic powder |
| CN101613634A (en) * | 2009-07-28 | 2009-12-30 | 武汉玻尔科技有限公司 | A kind of high-property water-based emulsion cutting fluid composite |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103468386A (en) * | 2013-08-24 | 2013-12-25 | 天长市康和金属材料有限公司 | Copper wire high-speed filament lubricant |
| CN103602474A (en) * | 2013-11-18 | 2014-02-26 | 青岛广联达精密机械有限公司 | Novel high-viscosity-temperature-characteristic lubricating oil |
| CN104277900A (en) * | 2014-09-25 | 2015-01-14 | 巢湖广丰金属制品有限公司 | High-antiwear cutting fluid |
| CN106047463A (en) * | 2016-06-23 | 2016-10-26 | 苏州洪河金属制品有限公司 | Water-based cutting liquid for metals |
| CN106118839A (en) * | 2016-06-23 | 2016-11-16 | 苏州洪河金属制品有限公司 | Metalworking fluid that a kind of water based lubrication is antirust and preparation method thereof |
| CN106190478A (en) * | 2016-07-13 | 2016-12-07 | 天长市润达金属防锈助剂有限公司 | A kind of safe antirust, anti-corrosive metalworking fluid |
| CN106221882A (en) * | 2016-08-10 | 2016-12-14 | 天长市润达金属防锈助剂有限公司 | A kind of rust preventive cutting fluid |
| CN106281612A (en) * | 2016-08-10 | 2017-01-04 | 天长市润达金属防锈助剂有限公司 | A kind of semi-synthetic cutting fluid |
| CN106337186A (en) * | 2016-08-10 | 2017-01-18 | 天长市润达金属防锈助剂有限公司 | Sterilizing water-based antirust liquid and preparation method thereof |
| CN107118840A (en) * | 2017-03-31 | 2017-09-01 | 苏州亚思科精密数控有限公司 | A kind of green cutting fluid and preparation method thereof |
| CN109810769A (en) * | 2017-11-21 | 2019-05-28 | 常州市好利莱光电科技有限公司 | A kind of preparation method of aqueous cutting fluid |
| CN109136954A (en) * | 2018-08-03 | 2019-01-04 | 天津普罗米新材料有限公司 | A kind of metal Environment-friendlywater-base water-base rust inhibitor |
| CN109810749A (en) * | 2019-03-04 | 2019-05-28 | 富莱德科技(浙江)有限公司 | A fully synthetic cutting fluid |
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