CN100342068C - Electrostatic spinning method of waste polystyrene foam - Google Patents
Electrostatic spinning method of waste polystyrene foam Download PDFInfo
- Publication number
- CN100342068C CN100342068C CNB2005100148828A CN200510014882A CN100342068C CN 100342068 C CN100342068 C CN 100342068C CN B2005100148828 A CNB2005100148828 A CN B2005100148828A CN 200510014882 A CN200510014882 A CN 200510014882A CN 100342068 C CN100342068 C CN 100342068C
- Authority
- CN
- China
- Prior art keywords
- polystyrene foam
- waste polystyrene
- electrospinning
- waste
- limonene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920006327 polystyrene foam Polymers 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title claims abstract description 22
- 239000002699 waste material Substances 0.000 title claims abstract description 21
- 238000010041 electrostatic spinning Methods 0.000 title abstract description 11
- 238000001523 electrospinning Methods 0.000 claims abstract description 19
- 239000000835 fiber Substances 0.000 claims abstract description 12
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 claims abstract description 11
- 239000008204 material by function Substances 0.000 claims abstract 3
- 229920002223 polystyrene Polymers 0.000 claims description 17
- 239000004793 Polystyrene Substances 0.000 claims description 15
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 3
- 239000006096 absorbing agent Substances 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 2
- 229910021426 porous silicon Inorganic materials 0.000 claims description 2
- 239000004033 plastic Substances 0.000 abstract description 30
- 229920003023 plastic Polymers 0.000 abstract description 30
- 239000000463 material Substances 0.000 abstract description 11
- 239000002904 solvent Substances 0.000 abstract description 11
- 241000196324 Embryophyta Species 0.000 abstract description 5
- 239000002121 nanofiber Substances 0.000 abstract description 5
- 241000207199 Citrus Species 0.000 abstract description 2
- 235000020971 citrus fruits Nutrition 0.000 abstract description 2
- 230000008569 process Effects 0.000 description 8
- 239000003960 organic solvent Substances 0.000 description 7
- 238000004090 dissolution Methods 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 240000008866 Ziziphus nummularia Species 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000014171 carbonated beverage Nutrition 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229940112822 chewing gum Drugs 0.000 description 1
- 235000015218 chewing gum Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000007968 orange flavor Substances 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
Landscapes
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Artificial Filaments (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
本发明公开了一种废旧聚苯乙烯泡沫塑料的静电纺丝方法。其包括将经过粉碎的聚苯乙烯泡沫塑料和d-柠檬烯以91～53∶9～47的重量比在常温下进行混合而将聚苯乙烯泡沫塑料溶解成溶液；将上述溶液直接或加入特殊功能材料并利用静电纺丝装置制成直径为400nm～3.0μm的特种纤维。本发明提供的废旧聚苯乙烯泡沫塑料的静电纺丝方法是利用从天然植物中提取的d-柠檬烯作为溶剂来溶解废旧聚苯乙烯泡沫塑料，然后直接或加入特殊功能材料制成纳米纤维。由于d-柠檬烯是从柑桔及荆介穗等天然植物中提取而制成，因而来源丰富，并且具有天然降解性，因而对环境无害，所以不会对环境造成污染。The invention discloses an electrostatic spinning method of waste polystyrene foam plastics. It includes mixing the pulverized polystyrene foam plastic and d-limonene at a weight ratio of 91-53:9-47 at room temperature to dissolve the polystyrene foam plastic into a solution; directly or adding the above solution materials and use an electrospinning device to make special fibers with a diameter of 400nm to 3.0μm. The electrospinning method of waste polystyrene foam provided by the invention is to use d-limonene extracted from natural plants as a solvent to dissolve waste polystyrene foam, and then directly or add special functional materials to make nanofibers. Since d-limonene is extracted from natural plants such as citrus and jingsuke, it has abundant sources and is naturally degradable, so it is harmless to the environment, so it will not pollute the environment.
Description
Technical field
The present invention relates to a kind of electrospinning process of waste and old polystyrol foamed plastic, particularly relate to a kind of natural botanical extraction liquid that utilizes and the waste and old polystyrol foamed plastic is dissolved into solution, add the specific function material then and utilize electrostatic spinning technique to spin electrospinning process with waste old polystyrene foamed plastic of nanometer stage material as solvent.
Background technology
Polystyrene foam plastics is applied in the every field as a kind of packaging material usually because of having characteristics such as big, the in light weight and proportion of volume is little, but the shortcoming of this material is not decompose, thus with the back if it is discarded contaminated environment seriously.At present the recovery method major part of waste old polystyrene foamed plastic all is to utilize organic solvent its dissolving to be prepared the material of other purposes such as coating, because the organic solvent that this recovery method uses can bring secondary pollution to environment, so be unfavorable for promoting.Therefore seek that a kind of can not cause secondary pollution and waste old polystyrene foamed plastic recovery method easy and simple to handle be the direction that the research worker makes great efforts always.
Summary of the invention
In order to address the above problem, the object of the present invention is to provide a kind of with natural botanical extraction liquid as solvent, thereby can not cause secondary pollution, and the electrospinning process of waste old polystyrene foamed plastic easy and simple to handle to environment.
In order to achieve the above object, the electrospinning process of waste old polystyrene foamed plastic provided by the invention comprises:
(1) will be through the polystyrene foam plastics pulverized and d-citrene with 91～53: 9～47 weight ratio be mixed at normal temperatures and polystyrene foam plastics is dissolved into the clear solution of thickness;
(2) above-mentioned soln using electrostatic spinning apparatus is made the styroflex that diameter is 400nm～3.0 μ m, or added the specific function material, and utilize electrostatic spinning apparatus to make the special fibre of diameter for 400nm～3.0 μ m at above-mentioned solution.
Described specific function material comprises radar wave absorbing agent, carbon black, SnO
2, TiO
2Or porous silicon.
The dissolution time of described polystyrene foam plastics is 1～20 minute.
Described d-citrene is 100% concentrate.
Described electrostatic spinning voltage is 15KV～24KV, and receiving range is 4cm～15cm.
The electrospinning process of waste old polystyrene foamed plastic provided by the invention is to utilize the d-citrene concentrate extract from natural plants to dissolve waste old polystyrene foamed plastic as solvent, adds the specific function material then in this solution and makes the fiber that diameter is 400nm～3.0 μ m.Owing to the d-citrene is to extract to make from plants such as citrus and sour jujube Jie fringe, thereby its source is abundant, and this solvent has Natural Degradation, thereby to environment and body harmless, so can not cause secondary pollution to environment.In addition, the present invention also has and can keep original mechanical strength of polystyrene and advantage such as easy and simple to handle.
The specific embodiment
Be elaborated below in conjunction with the electrospinning process of specific embodiment to waste old polystyrene foamed plastic provided by the invention.
Embodiment 1
To mix at normal temperatures with 85: 15 weight ratio and polystyrene foam plastics will be dissolved into the clear solution of thickness through the polystyrene foam plastics pulverized and d-citrene, dissolution time is 2 minutes, then above-mentioned solution is joined in the electrostatic spinning apparatus, and be 20KV at voltage, and receiving range is to make the polystyrene non-woven fibre that diameter is 400nm under the condition of 5cm, and this fiber can be used as the raw material of filter membranes such as medical science, biotechnology and industrial wastewater.
Embodiment 2
To mix at normal temperatures with 85: 15 weight ratio and polystyrene foam plastics will be dissolved into the clear solution of thickness through the polystyrene foam plastics pulverized and d-citrene, dissolution time is 2 minutes, in above-mentioned solution, add radar wave absorbing agent then, and be 20KV at voltage, and receiving range is to utilize electrostatic spinning apparatus to make diameter under the condition of 5cm to absorb nanofiber for the radar wave of 500nm.The electrical conductivity of this fiber is 10
-3～10
-1S/cm, its millimeter wave to 26.5～40GHz has absorption preferably, and mechanism is similar to the electrical loss type.
Embodiment 3
To mix at normal temperatures with 75: 25 weight ratio and polystyrene foam plastics is dissolved into the clear solution of thickness through the polystyrene foam plastics pulverized and d-citrene, dissolution time be 6 minutes, adds carbon black, SnO then in above-mentioned solution
2Or TiO
2In any conductive material, and be 20KV, and receiving range is to utilize electrostatic spinning apparatus to make the conductive fiber of diameter about for 600nm under the condition of 5cm at voltage.This conductive fiber can be used as semiconductor devices, electromagnetic wave shielding and antistatic material.
Embodiment 4
To mix at normal temperatures with 60: 40 weight ratio and polystyrene foam plastics will be dissolved into the clear solution of thickness through the polystyrene foam plastics pulverized and d-citrene, dissolution time is 20 minutes, in above-mentioned solution, add porous silica material then, and be 20KV at voltage, and receiving range is to utilize electrostatic spinning apparatus to make the non-electric light source nanofiber of diameter for 800nm under the condition of 5cm.This light source nanofiber can be used as sensing element, sensor and illuminating material.
The solvent that the present invention uses is the d-citrene concentrate of 100% concentration extracted from natural plants, and this solution can be used as food additives and uses, as the spices of orange flavor carbonated drink or chewing gum etc., and also can replace organic solvent etc.Detect the small white mouse LD of this solvent through the diseases prevention and control center
50＞5.0g/kgBW belongs to actual nontoxic, so it belongs to the environment-friendly type solvent, thereby to human body and environmentally friendly.In addition, because the citrene molecular structure in this solvent is similar to the polystyrene molecular structure, and solubility parameter is close, thereby it at room temperature just can be dissolved into the polystyrene foam plastics after pulverizing the clear solution of thickness, and dissolution velocity is identical with organic solvent toluene and benzene, and prove that by technology for detection this solvent does not change the molecular weight and the molecular weight distribution of polystyrene, promptly can keep the original mechanical strength of polystyrene.In addition, utilize this natural solvent to come replace organic solvent not only can solve " white pollution " problem that polystyrene foam plastics itself forms, but also can solve the secondary pollution problem that causes with organic solvent processing polystyrene foam plastics, and be difficult to reach for present traditional solution electrostatic spinning technique without organic solvent processing polystyrene foam plastics.The nanofiber made from electrospinning process provided by the invention has bigger specific area and surface-to-volume ratio, this fiber has the absorption affinity of very strong bearing certain pressure and good filterability, barrier, cohesiveness and heat insulating ability, therefore can be applicable to the aspects such as filtration of submicron particle, its filter effect can improve greatly than the conventional filtration material efficiency.
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100148828A CN100342068C (en) | 2005-08-29 | 2005-08-29 | Electrostatic spinning method of waste polystyrene foam |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100148828A CN100342068C (en) | 2005-08-29 | 2005-08-29 | Electrostatic spinning method of waste polystyrene foam |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1743518A CN1743518A (en) | 2006-03-08 |
| CN100342068C true CN100342068C (en) | 2007-10-10 |
Family
ID=36139036
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100148828A Expired - Fee Related CN100342068C (en) | 2005-08-29 | 2005-08-29 | Electrostatic spinning method of waste polystyrene foam |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100342068C (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2381022B1 (en) * | 2009-01-14 | 2013-11-20 | Japan Vilene Company, Ltd. | Inorganic fiber structure and process for producing same |
| CN102926021A (en) * | 2012-11-07 | 2013-02-13 | 北京化工大学 | Method using emulsion electricity texture to prepare beaded filaments |
| CN107428987A (en) * | 2014-11-26 | 2017-12-01 | 印度海得拉巴理工学院 | There is the method for the fiber of the hydrophobic oleophilic oil arranged of the sub-micron of controllable geometry using citrus bark extract as solvent by waste polystyrene manufacture |
| CN106435805B (en) * | 2016-10-05 | 2019-06-07 | 桂林理工大学 | A kind of preparation method of polystyrene electrostatic spinning solution |
| CN111270420A (en) * | 2020-03-25 | 2020-06-12 | 合肥巧织纺织科技有限公司 | Preparation method of high-strength non-woven fabric |
| CN113403852A (en) * | 2021-05-19 | 2021-09-17 | 兰义忠 | Ultrathin waterproof fabric and preparation method thereof |
| CN116061341A (en) * | 2021-10-29 | 2023-05-05 | 中国石油化工股份有限公司 | Method for separating waste plastics |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5223543A (en) * | 1992-10-19 | 1993-06-29 | Claudia Iovino | Reduction in polystyrene with activated agent |
| JPH06220724A (en) * | 1993-01-26 | 1994-08-09 | Nagoya Yuka Kk | Treatment method for polystyrene foam waste |
-
2005
- 2005-08-29 CN CNB2005100148828A patent/CN100342068C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5223543A (en) * | 1992-10-19 | 1993-06-29 | Claudia Iovino | Reduction in polystyrene with activated agent |
| JPH06220724A (en) * | 1993-01-26 | 1994-08-09 | Nagoya Yuka Kk | Treatment method for polystyrene foam waste |
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| Publication number | Publication date |
|---|---|
| CN1743518A (en) | 2006-03-08 |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20071010 Termination date: 20100829 |