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Adsorption study of mango peel activated carbon as iron removal for batik waste industry Nugroho, Agung; Amanah, Nur Layli; Firdaus, Revo Gilang
Jurnal Rekayasa Proses Vol 16 No 1 (2022): Volume 16, Number 1, 2022
Publisher : Jurnal Rekayasa Proses

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/jrekpros.69404

Abstract

Mango peel waste which has a carbon functional group was converted to activated carbon. The as-synthesized activated carbon (AC) was then utilized as an adsorbent for batik waste which contains heavy metal substances such as Fe2+. The purpose of this study was to determine the optimum process variation in absorbing heavy metal ion Fe contained in batik waste. Four variation methods of activated carbon synthesis were explored to determine the most suitable method of AC synthesis. The results showed that the sample synthesized using a combination physical-chemical-physical process was the best process variation resulting in percentage removal of Fe2+ of 84.81%. FTIR showed that the functional groups in mango peel were visible for all variations of the process, namely hydroxyl (-OH) derived from cellulose and hemicellulose and carboxyl (-COOH) derived from pectin. The adsorption study showed that the most suitable isotherm for all process variations was Langmuir with an R2 value of 0.9999 for the MPAC-4 sample. The adsorption mechanism is physisorption with a value of E < 8 kJ/mol based on the D-R isotherm and has the largest adsorption capacity of Qmax 8.2 mg/g.
Acid Treatment on Carbonate Rock: An Effect of HCL Concentration on Rock Properties and Fluid Flowrates Nugroho, Agung; Amanah, Nur Layli; Kamal, Hary Perdana; Angkasa, Syahreza
Journal of Emerging Supply Chain, Clean Energy, and Process Engineering Vol 1 No 1 (2022): Journal of Emerging Supply Chain, Clean Energy, and Process Engineering
Publisher : Universitas Pertamina

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.57102/jescee.v1i1.2

Abstract

A series of analyses techniques were performed to study the influence of different acid concentrations on the rock properties during the acidizing process. Based on the Thin section and Routine Core Analysis (RCA), the calcite content have effect on the reservoir quality from the aspect of rock-fluid properties. In this paper, the physical and mineralogical responses to rock acidizing of carbonate rock are evaluated. This study found that calcite content decreases approximately 25% from the total calcite content of rock samples after the addition of HCl. Scanning Electron Microscope (SEM) Analysis show that samples treated using HCl 15% provide a wider pore size distribution, resulting in the increasing permeability fluid flow rate
Study of Efficiency and Reaction Rates Dechlorination of Nata De Coco Wastewater Using Sodium Thiosulfate Sari, Alifiana Permata; Rhamadani, Fadila Arum; Amanah, Nur Layli; Nugroho, Agung
Journal of Emerging Supply Chain, Clean Energy, and Process Engineering Vol 1 No 2 (2022): Journal of Emerging Supply Chain, Clean Energy, and Process Engineering
Publisher : Universitas Pertamina

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.57102/jescee.v1i2.17

Abstract

Chemical reduction with sodium thiosulfate is commonly used to dechlorinate chlorinated waste. U.S. Environmental Protection Agency recommends sodium thiosulfate (Na2S2O3) as a dechlorinating agent for waste samples containing residual chlorine before being released into the environment or entering the distribution system. However, sodium thiosulfate's efficiency and chlorination kinetics at different concentrations are still unknown due to a lack of information on chlorination kinetics. The study was conducted by determining the number of efficient doses of sodium thiosulfate and observing chlorination kinetics using sodium thiosulfate as a dechlorination agent observed at different stoichiometric ratios (1x, 1.5x, and 2x). Sodium thiosulfate at a stoichiometric dose of 2x can reduce chlorine residue by up to 0.4 ppm. The regression analysis of and constant rate are used in the kinetic analysis of sodium thiosulfate dechlorination processes. The kinetics of the chlorination process employing sodium thiosulfate is first order to the total concentration of chlorine in solution at a stoichiometric dosage of 2x, according to the findings.