Academia.eduAcademia.edu

Outline

Gold-carbon nanotube nanocomposites: synthesis and applications

Abstract

Nanocomposites are combinations of nanomaterials with other molecules or nanoscaled materials, such as nanoparticles or nanotubes. In general, these novel nanocomposites have different physical and chemical properties from the constituent particles or wires, and will thus allow new kinds of applications. Among these nanocomposites, gold-carbon nanotube (Au-CNT) composites are of particular interests, due to their easy fabrication protocols and broad potential applications. Au-CNT nanocomposites commonly refer to gold nanoparticles deposited on carbon nanotubes. To obtain Au-CNT nanocomposites, different methods have been developed, including direct and linked deposition of gold nanoparticles on CNT. Au-CNT nanocomposites combine the excellent physical and chemical properties of both gold nanoparticles and carbon nanotubes. The easy modification surface of gold nanoparticle and the excellent conductivity of carbon nanotube as well the high surface area, point towards a broad range of applications, such as biosensing, gas sensing, and electrochemistry. This paper reviews the recent progress of different kinds of Au-CNT nanocomposites and their synthesis and applications. properties of nanomaterials and on the developments of instruments such as the combination of scanning probe microscopes with transmission electron microscopes.

FAQs

sparkles

AI

What unique properties do Au-CNT nanocomposites offer compared to other materials?add

Au-CNT nanocomposites combine high conductivity and large surface area, enhancing sensor responsiveness and sensitivity. Their multifunctionality increases application potential across biosensors, optics, and medical fields.

What methods are used for the synthesis of Au-CNT nanocomposites?add

Au-CNT nanocomposites are synthesized predominantly through direct deposition methods, including both physical (e.g., thermal and electron-beam deposition) and wet chemical methods. Recent studies highlight improved methods for better uniformity of gold particles on carbon nanotubes.

What advantages do covalently linked Au-CNT nanocomposites provide?add

Covalently linked Au-CNT nanocomposites ensure stronger bonding between the gold nanoparticles and carbon nanotubes, which enhances stability under extreme conditions. Techniques such as using 2-aminoethanethiol for functionalization have yielded nanoparticles resistant to detachment.

How effective are Au-CNT nanocomposites in glucose biosensing applications?add

Recent glucose sensors based on Au-CNT nanocomposites achieved a linear range of 20 mM and detection limits down to 25 µM. This progression improves the sensitivity and operational range significantly compared to conventional sensor methods.

What are the emerging applications of Au-CNT nanocomposites beyond sensing?add

Emerging applications of Au-CNT nanocomposites include drug delivery systems and toxicant sensors, achieving low detection limits for arsenic and mercury. Their versatility also allows novel structures for fuel cells and gas storage solutions.

References (125)

  1. Alexeyeva, N. and Tammeveski, K. (2008) 'Electroreduction of oxygen on gold nanoparticle/PDDA-MWCNT nanocomposites in acid solution', Analytica Chimica Acta, Vol. 618, No. 2, pp.140-146.
  2. Alexeyeva, N., Laaksonen, T., Kontturi, K., Mirkhalaf, F., Schiffrin, D.J. and Tammeveski, K. (2006) 'Oxygen reduction on gold nanoparticle/multi-walled carbon nanotubes modified glassy carbon electrodes in acid solution', Electrochemistry Communications, Vol. 8, No. 9, pp.1475-1480.
  3. Azamian, B.R., Coleman, K.S., Davis, J.J., Hanson, N. and Hreen, M.L. (2002) 'Directly observed covalent coupling of quantum dots to single-wall carbon nanotubes', Chemical Communications, pp.366-367.
  4. Banerjee, S. and Wong, S.S. (2002) 'Synthesis and characterization of carbon nanotube-nnocrystal heterostructures', Nano Letters, Vol. 2, No. 3, pp.195-200.
  5. Banerjee, S., Hemraj-Benny, T. and Wong, S.S. (2005) 'Covalent surface chemistry of single-walled carbon nanotubes', Advanced Materials, Vol. 17, No. 1, pp.17-29.
  6. Bielinska, A., Eichman, J., Lee, I., Baker, J. and Balogh, L. (2002) 'Imaging {Au0-PAMAM} gold-dendrimer nanocomposites in cells', Journal of Nanoparticle Research, Vol. 4, No. 5, pp.395-403.
  7. Bittencourt, C., Felten, A., Douhard, B., Ghijsen, J., Johnson, R., Drube, W. and Pireaux, J. (2006) 'Photoemission studies of gold clusters thermally evaporated on multiwall carbon nanotubes', Chemical Physics, Vol. 328, Nos. 1-3, pp.385-391.
  8. Breuer, O. and Sundararaj, U. (2004) 'Big returns from small fibers: a review of polymer/carbon nanotube composites', Polymer Composites, Vol. 25, No. 6, pp.630-645.
  9. Cao, W., Wei, C., Hu, J. and Li, Q. (2008) 'Direct electrochemistry and electrocatalysis of myoglobin immobilized on gold nanoparticles/carbon nanotubes nanohybrid film', Electroanalysis, Vol. 20, No. 17, pp.1925-1931.
  10. Chen, J., Hamon, M.A., Hu, H., Chen, Y.S., Rao, A.M., Eklund, P.C. and Haddon, R.C. (1998) 'Solution properties of single-walled carbon nanotubes', Science, Vol. 282, pp.95-98.
  11. Chen, R.J., Bangsaruntip, S., Drouvalakis, K.A., Wong, N., Kam, S., Shim, M., Li, Y., Kim, W., Utz, P.J. and Dai, H. (2003) 'Noncovalent functionalization of carbon nanotubes for highly specific electronic biosensors', Proceedings of the National Academy of Sciences of the United States of America, Vol. 100, No. 9, pp.4984-4989.
  12. Chen, R.J., Zhang, Y.G., Wang, D.W. and Dai, H.J. (2001) 'Noncovalent sidewall functionalization of single-walled carbon nanotubes for protein immobilization', Journal of the American Chemical Society, Vol. 123, No. 16, pp.3838-3839.
  13. Chen, S., Yuan, R., Chai, Y., Zhang, L., Wang, N. and Li, X. (2007) 'Amperometric third-generation hydrogen peroxide biosensor based on the immobilization of hemoglobin on multiwall carbon nanotubes and gold colloidal nanoparticles', Biosensors & Bioelectronics, Vol. 22, No. 7, pp.1268-1274.
  14. Chen, W., Lu, Z. and Li, C.M. (2008) 'Sensitive human interleukin 5 impedimetric sensor based on polypyrrole-pyrrolepropylic acid-gold nanocomposite', Analytical Chemistry, Vol. 80, No. 22, pp.8485-8492.
  15. Cheng, S., Wei, Y., Feng, Q.W., Qiu, K., Pang, J., Jansen, S.A., Yin, R. and Ong, K. (2003) 'Facile synthesis of mesoporous gold-silica nanocomposite materials via sol-gel process with nonsurfactant templates', Chemistry of Materials, Vol. 15, No. 7, pp.1560-1566.
  16. Choi, H.C., Shim, M., Bangsaruntip, S. and Dai, H. (2002) 'Spontaneous reduction of metal ions on the sidewalls of carbon nanotubes', Journal of the American Chemical Society, Vol. 124, No. 31, pp.9058-9059.
  17. Coleman, K.S., Bailey, S.R., Fogden, S. and Green, M.L. (2003) 'Functionalization of single-walled carbon nanotubes via the Bingel reaction', Journal of the American Chemical Society, Vol. 125, No. 29, pp.8722-8723.
  18. Corbierre, M.K., Cameron, N.S., Sutton, M., Laaziri, K. and Lennox, R.B. (2005) 'Gold nanoparticle/polymer nanocomposites: dispersion of nanoparticles as a function of capping agent molecular weight and grafting density', Langmuir, Vol. 21, No. 13, pp.6063-6072.
  19. Cui, J.B., Daghlian, C.P. and Gibson, U.J. (2005) 'Gold nanoparticle mediated formation of aligned nanotube composite films', J. Phys. Chem. B, Vol. 109, No. 23, pp.11456-11460.
  20. Daniel, M. and Astruc, D. (2004) 'Gold nanoparticles: assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology', Chemical Reviews, Vol. 104, No. 1, pp.293-346.
  21. Datta, K.K.R., Eswaramoorthy, M. and Rao, C.N.R. (2007) 'Water-solubilized aminoclay-metal nanoparticle composites and their novel properties', J. Mater. Chem., Vol. 17, No. 7, pp.613-615.
  22. de Oliveira Marques, P.R., Lermo, A., Campoy, S., Yamanaka, H., Barbé, J., Alegret, S. and Pividori, M.I. (2009) 'Double-tagging polymerase chain reaction with a thiolated primer and electrochemical genosensing based on gold nanocomposite sensor for food safety', Analytical Chemistry, Vol. 81, No. 4, pp.1332-1339.
  23. Ding, L., Hao, C., Xue, Y. and Ju, H. (2007) 'A bio-inspired support of gold nanoparticles-chitosan nanocomposites gel for immobilization and electrochemical study of K562 leukemia cells', Biomacromolecules, Vol. 8, No. 4, pp.1341-1346.
  24. Dresselhaus, M.S., Dresselhaus, G. and Jorio, A. (2004) 'Unusual properties and structure of carbon nanotubes', Annu. Rev. Mater. Res., Vol. 34, pp.247-278.
  25. Du, D., Wang, M., Cai, J., Qin, Y. and Zhang, A. (2010) 'One-step synthesis of multiwalled carbon nanotubes-gold nanocomposites for fabricating amperometric acetylcholinesterase biosensor', Sensors and Actuators B: Chemical, Vol. 143, No. 2, pp.524-529.
  26. Ellis, A.V., Vijayamohanan, K., Goswami, R., Chakrapani, N., Ramanathan, L.S., Ajayan, P.M. and Ramanath, G. (2003) 'Hydrophobic anchoring of monolayer-protected gold nanoclusters to carbon nanotubes', Nano Letters, Vol. 3, No. 3, pp.279-282.
  27. Faraday, M. (1857) 'The Bakerian lecture: experimental relations of gold (and other metals) to light', Philosophical Transactions of the Royal Society of London, Vol. 147, pp.145-181.
  28. Felten, A., Bittencourt, C. and Pireaux, J.J. (2006) 'Gold clusters on oxygen plasma functionalized carbon nanotubes: XPS and TEM studies', Nanotechnology, Vol. 12, pp.1954-1959.
  29. Frens, G. (1973) 'Controlled nucleation for the regulation of the particle size in monodisperse gold suspensions', Nature Phys. Sci., Vol. 241, pp.20-22.
  30. Gao, R.F. and Zheng, J.B. (2009) 'Amine-terminated ionic liquid functionalized Au-CNT nanoparticles for investigating the direct electron transfer of glucose oxidase', Electrochemistry Communications, Vol. 11, No. 3, pp.608-611.
  31. Georgakilas, V., Gournis, D., Tzitzios, V., Pasquato, L., Guldi, D.M. and Prato, M. (2007) 'Decorating carbon nanotubes with metal or semiconductor nanoparticles', Journal of Materials Chemistry, Vol. 17, No. 26, pp.2679-2694.
  32. Ghosh, S.K. and Pal, T. (2007) 'Interparticle coupling effect on the surface plasmon resonance of gold nanoparticles: from theory to applications', Chemical Reviews, Vol. 107, No. 11, pp.4797-862.
  33. Gingery, D. and Buhlmann, P. (2008) 'Formation of gold nanoparticles on multiwalled carbon nanotubes by thermal evaporation', Carbon, Vol. 46, No. 14, pp.1966-1972.
  34. Gu, C.P., Huang, J.R., Wang, J.H., Wang, C.J., Li, M.Q. and Liu, J.H. (2007) 'Enhanced electrochemical detection of DNA hybridization based on Au/MWCNTs nanocomposites', Analytical Letters, Vol. 40, No. 17, pp.3159-3169.
  35. Guo, S. and Wang, E. (2007) 'Synthesis and electrochemical applications of gold nanoparticles', Analytica Chimica Acta, Vol. 598, No. 2, pp.181-192.
  36. Guo, Y., Guo, S., Fang, Y. and Dong, S. (2010) 'Gold nanoparticle/carbon nanotube hybrids as an enhanced material for sensitive amperometric determination of tryptophan', Electrochimica Acta, Vol. 55, No. 12, pp.3927-3931.
  37. Han, L., Wu, W., Kirk, F.L., Luo, J., Maye, M.M., Kariuki, N.N., Lin, Y., Wang, C. and Zhong, C. (2004) 'A direct route toward assembly of nanoparticle-carbon nanotube composite materials', Langmuir, Vol. 20, No. 14, pp.6019-6025.
  38. Hu, J.P., Shi, J.H., Li, S.P., Qin, Y.J., Guo, Z., Song, Y.L. and Zhu, D.B. (2005) 'Efficient method to functionalize carbon nanotubes with thiol groups and fabricate gold nanocomposites', Chemical Physics Letters, Vol. 401, Nos. 4-6, pp.352-356.
  39. Hu, M., Chen, J., Li, Z., Au, L., Hartland, G.V., Li, X., Marquez, M. and Xia, Y. (2006a) 'Gold nanostructures: engineering their plasmonic properties for biomedical applications', Chemical Society Reviews, Vol. 35, No. 11, pp.1084-1094.
  40. Hu, X., Wang, T., Qu, X. and Dong, S. (2006b) 'In situ synthesis and characterization of multiwalled carbon nanotube/Au nanoparticle composite materials', The Journal of Physical Chemistry B, Vol. 110, No. 2, pp.853-857.
  41. Huang, X., Jain, P.K., El-Sayed, I.H. and El-Sayed, M.A. (2007) 'Gold nanoparticles: interesting optical properties and recent applications in cancer diagnostics and therapy', Nanomedicine, Vol. 2, No. 5, pp.681-93.
  42. Iijima, S. (1991) 'Helical microtubules of graphitic carbon', Nature, Vol. 354, pp.56-58.
  43. Ispasoiu, R.G., Balogh, L., Varnavski, O.P. and Tomalia, D.A. (2000) 'Large optical limiting from novel metal-dendrimer nanocomposite materials', Journal of the American Chemical Society, Vol. 122, No. 44, pp.11005-11006.
  44. Jeong, G., Suzuki, S. and Kobayashi, Y. (2009) 'Synthesis and characterization of Au-attached single-walled carbon nanotube bundles', Nanotechnology, Vol. 20, No. 28, p.285708.
  45. Jia, F., Shan, C., Li, F. and Niu, L. (2008) 'Carbon nanotube/gold nanoparticles/polyethylenimine- functionalized ionic liquid thin film composites for glucose biosensing', Biosensors & Bioelectronics, Vol. 24, No. 4, pp.951-956.
  46. Jiang, K., Eitan, A., Schadler, L.S., Ajayan, P.M., Siegel, R.W., Grobert, N., Mayne, M., Reyes-Reyes, M., Terrones, H. and Terrones, M. (2003) 'Selective attachment of gold nanoparticles to nitrogen-doped carbon nanotubes', Nano Letters, Vol. 3, No. 3, pp.275-277.
  47. Kariuki, J.K. and McDermott, M.T. (1999) 'Nucleation and growth of functionalized aryl films on graphite electrodes', Langmuir, Vol. 15, pp.6534-6540.
  48. Kim, B. and Sigmund, W. (2004) 'Functionalized multiwall carbon nanotube/gold nanoparticle composites', Langmuir, Vol. 20, No. 19, pp.8239-8242.
  49. Kim, D.S., Lee, T. and Geckeler, K.E. (2005) 'Hole-doped single-walled carbon nanotubes: ornamenting with gold nanoparticles in water', Angewandte Chemie International, in English, Vol. 45, No. 1, pp.104-147.
  50. Kim, T., Kim, D., Lee, J., Lee, Y. and Oh, S. (2008) 'Preparation of gold-silica heterogeneous nanocomposite particles by alcohol-reduction method', Materials Research Bulletin, Vol. 43, No. 5, pp.1126-1134.
  51. Kinoshita, T., Seino, S., Maruyama, H., Otome, Y., Okitsu, K., Nakayama, T., Niihara, K., Nakagawa, T. and Yamamoto, T.A. (2004) 'Influence of size distribution on the magnetocaloric effect of superparamagnetic gold-magnetite nanocomposite', Journal of Alloys and Compounds, Vol. 365, Nos. 1-2, pp.281-285.
  52. Kulak, A., Davis, S.A., Dujardin, E. and Mann, S. (2003) 'Controlled assembly of nanoparticle-containing gold and silica microspheres and silica/gold nanocomposite spheroids with complex form', Chemistry of Materials, Vol. 15, No. 2, pp.528-535.
  53. Lee, J., Yang, J., Ko, H., Oh, S., Kang, J., Son, J., Lee, K., Lee, S., Yoon, H., Suh, J., Huh, Y. and Haam, S. (2008) 'Multifunctional magnetic gold nanocomposites: human epithelial cancer detection via magnetic resonance imaging and localized synchronous therapy', Advanced Functional Materials, Vol. 18, No. 2, pp.258-264.
  54. Li, D., He, Q. and Li, J. (2009a) 'Smart core/shell nanocomposites: intelligent polymers modified gold nanoparticles', Advances in Colloid and Interface Science, Vol. 149, Nos. 1-2, pp.28-38.
  55. Li, F., Wang, Z., Shan, C., Song, J., Han, D. and Niu, L. (2009b) 'Preparation of gold nanoparticles/functionalized multiwalled carbon nanotube nanocomposites and its glucose biosensing application', Biosensors & Bioelectronics, Vol. 24, No. 6, pp.1765-1770.
  56. Lin, J.H., He, C.Y., Zhang, L.J. and Zhang, S.S. (2009) 'Sensitive amperometric immunosensor for alpha-fetoprotein based on carbon nanotube/gold nanoparticle doped chitosan film', Analytical Biochemistry, Vol. 384, No. 1, pp.130-135.
  57. Liu, L.Q., Wang, T.X., Li, J.X., Guo, Z., Dai, L.M., Zhang, D.Q. and Zhu, D.B. (2003) 'Self-assembly of gold nanoparticles to carbon nanotubes using a thiol-terminated pyrene as interlinker', Chemical Physics Letters, Vol. 367, Nos. 5-6, pp.747-752.
  58. Liu, Y., Wang, M., Zhao, F., Guo, Z., Chen, H. and Dong, S. (2005) 'Direct electron transfer and electrocatalysis of microperoxidase immobilized on nanohybrid film', Journal of Electroanalytical Chemistry, Vol. 581, No. 1, pp.1-10.
  59. Liu, Y., Wu, S., Ju, H. and Xu, L. (2007) 'Amperometric glucose biosensing of gold nanoparticles and carbon nanotube multilayer membranes', Electroanalysis, Vol. 19, No. 9, pp.986-992.
  60. Ma, H.Y., Zhang, L.P., Pan, Y., Zhang, K.Y. and Zhang, Y.Z. (2008) 'A novel electrochemical DNA biosensor fabricated with layer-by-layer covalent attachment of multiwalled carbon nanotubes and gold nanoparticles', Electroanalysis, Vol. 20, No. 11, pp.1220-1226.
  61. Mandal, T.K., Fleming, M.S. and Walt, D.R. (2002) 'Preparation of polymer coated gold nanoparticles by surface-confined living radical polymerization at ambient temperature', Nano Lett., Vol. 2, pp.3-7.
  62. Manso, J., Mena, M., Yáñez-Sedeño, P. and Pingarrón, J. (2007) 'Electrochemical biosensors based on colloidal gold-carbon nanotubes composite electrodes', Journal of Electroanalytical Chemistry, Vol. 603, No. 1, pp.1-7.
  63. Manso, J., Mena, M., Yanezsedeno, P. and Pingarron, J. (2008) 'Alcohol dehydrogenase amperometric biosensor based on a colloidal gold-carbon nanotubes composite electrode', Electrochimica Acta, Vol. 53, No. 11, pp.4007-4012.
  64. Marsh, D.H., Rance, G.A., Whitby, R.J., Giustiniano, F. and Khlobystov, A.N. (2008) 'Assembly, structure and electrical conductance of carbon nanotube-gold nanoparticle 2D heterostructures', Journal of Materials Chemistry, Vol. 18, No. 19, Vol. 2249-pp.2256.
  65. Mishra, Y.K., Mohapatra, S., Avasthi, D.K., Kabiraj, D., Lalla, N.P., Pivin, J.C., Sharma, H., Kar, R. and Singh, N. (2007) 'Gold-silica nanocomposites for the detection of human ovarian cancer cells: a preliminary study', Nanotechnology, Vol. 18, No. 34, p.345606.
  66. Nooney, R.I., Dhanasekaran, T., Chen, Y.M., Josephs, R. and Ostafin, A.E. (2002) 'Self-assembled highly ordered spherical silica, mesoporous nanocomposites', Advanced Materials, Vol. 14, No. 7, pp.529-532.
  67. Ou, Y. and Huang, M.H. (2006) 'High-density assembly of gold nanoparticles on multiwalled carbon nanotubes using 1-pyrenemethylamine as interlinker', J. Phys. Chem. B, Vol. 110, No. 5, pp.2031-2036.
  68. Park, J.H., Lim, Y.T., Park, O.O., Kim, J.K., Yu, J. and Kim, Y.C. (2004) 'Polymer/gold nanoparticle nanocomposite light-emitting diodes: enhancement of electroluminescence stability and quantum efficiency of blue-light-emitting polymers', Chemistry of Materials, Vol. 16, No. 4, pp.688-692.
  69. Park, S.Y. and Stroud, D. (2003) 'Structure formation, melting, and optical properties of gold/DNA nanocomposites: effects of relaxation time', Physical Review B, Vol. 68, No. 22, pp.1-11.
  70. Pérez-Juste, J., Rodríguez-González, B., Mulvaney, P. and Liz-Marzán, L.M. (2005) 'Optical control and patterning of gold-nanorod-poly(vinyl alcohol) nanocomposite films', Advanced Functional Materials, Vol. 15, No. 7, pp.1065-1071.
  71. Qi, Z., Honma, I., Ichihara, M. and Zhou, H. (2006) 'Layer-by-layer fabrication and characterization of gold-nanoparticle/myoglobin nanocomposite films', Advanced Functional Materials, Vol. 16, No. 3, pp.377-386.
  72. Qi, Z., Wei, M., Honma, I. and Zhou, H. (2007) 'Thin films composed of multiwalled carbon nanotubes, gold nanoparticles and myoglobin for humidity detection at room temperature', Chemphyschem: A European Journal of Chemical Physics and Physical Chemistry, Vol. 8, No. 2, pp.264-269.
  73. Qu, S.L., Song, Y.L., Du, C.M., Wang, Y.X., Gao, Y.C., Liu, S.T., Li, Y.L. and Zhu, D.B. (2001) 'Nonlinear optical properties in three novel nanocomposites with gold nanoparticles', Optics Communications, Vol. 196, Nos. 1-6, pp.317-323.
  74. Rabbani, M.M., Ko, C.H., Bae, J., Yeum, J.H., Kim, I.S. and Oh, W. (2009) 'Comparison of some gold/carbon nanotube composites prepared by control of electrostatic interaction', Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 336, Nos. 1-3, pp.183-186.
  75. Raghuveer, M.S., Agrawal, S., Bishop, N. and Ramanath, G. (2006) 'Microwave-assisted single-step functionalization and in situ derivatization of carbon nanotubes with gold nanoparticles', Chemistry of Materials, Vol. 18, No. 6, pp.1390-1393.
  76. Richard, C., Balavoine, F., Schultz, P., Ebbesen, T.W. and Mioskowski, C. (2003) 'Supramolecular self-assembly of lipid derivatives on carbon nanotubes', Science, Vol. 300, pp.775-778.
  77. Rosi, N.L. and Mirkin, C.A. (2005) 'Nanostructures in biodiagnostics', Chemical Reviews, Vol. 105, No. 4, pp.1547-1562.
  78. Sainsbury, T. and Fitzmaurice, D. (2004) 'Pseudorotaxane-formation-driven gold nanowire self-assembly', Chemistry of Materials, Vol. 16, No. 11, pp.2174-2179.
  79. Sainsbury, T., Stolarczyk, J. and Fitzmaurice, D. (2005) 'An experimental and theoretical study of the self-assembly of gold nanoparticles at the surface of functionalized multiwalled carbon nanotubes', Journal of Physical Chemistry B, Vol. 109, No. 24, pp.16310-16325.
  80. Shi, J., Wang, Z. and Li, H. (2006) 'Self-assembly of gold nanoparticles onto the surface of multiwall carbon nanotubes functionalized with mercaptobenzene moieties', Journal of Nanoparticle Research, Vol. 8, No. 5, pp.743-747.
  81. Shi, Y., Yang, R.Z. and Yuet, P.K. (2009) 'Easy decoration of carbon nanotubes with well dispersed gold nanoparticles and the use of the material as an electrocatalyst', Carbon, Vol. 47, No. 4, pp.1146-1151.
  82. Shimada, T., Ookubo, K., Komuro, N., Shimizu, T. and Uehara, N. (2007) 'Blue-to-red chromatic sensor composed of gold nanoparticles conjugated with thermoresponsive copolymer for Thiol sensing', Langmuir, Vol. 23, No. 22, pp.11225-11232.
  83. Shipway, A., Katz, E. and Willner, I. (2000) 'Nanoparticle arrays on surfaces for electronic, optical, and sensor applications', ChemPhysChem, Vol. 1, No. 1, pp.18-52.
  84. Song, J., Lee, U., Lee, H., Suh, M. and Kwon, Y. (2009) 'Gold-titania nanocomposite films with a periodic 3D nanostructure', Thin Solid Films, Vol. 517, No. 19, pp.5705-5709.
  85. Streeter, I., Xiao, L., Wildgoose, G. and Compton, R. (2008) 'Gold nanoparticle-modified carbon nanotubes-modified electrodes. Using voltammetry to measure the total length of the nanotubes', J. Phys. Chem. C, Vol. 112, No. 6, pp.1933-1937.
  86. Subramanian, V., Wolf, E.E. and Kamat, P.V. (2004) 'Catalysis with TiO2/gold nanocomposites. effect of metal particle size on the Fermi level equilibration', Journal of the American Chemical Society, Vol. 126, No. 15, pp.4943-4950.
  87. Tai, Y., Watanabe, M., Kaneko, K., Tanemura, S., Miki, T., Murakami, J. and Tajiri, K. (2001) 'Preparation of gold cluster/silica nanocomposite aerogel via spontaneous wet-gel formation', Advanced Materials, Vol. 13, No. 21, pp.1611-1614.
  88. Tello, A., Cardenas, G., Häberle, P. and Segura, R.A. (2008) 'The synthesis of hybrid nanostructures of gold nanoparticles and carbon nanotubes and their transformation to solid carbon nanorods', Carbon, Vol. 46, No. 6, pp.884-889.
  89. Terrones, M. (2004) 'Carbon nanotubes: synthesis and properties, electronic devices and other emerging applications', Int. Mater. Rev., Vol. 49, pp.325-377.
  90. Thomas, K.G. and Kamat, P.V. (2003) 'Chromophore-functionalized gold nanoparticles', Accounts of Chemical Research, Vol. 36, No. 12, pp.888-898.
  91. Tsai, M. and Chen, P. (2008) 'Voltammetric study and electrochemical detection of hexavalent chromium at gold nanoparticle-electrodeposited indium tinoxide (ITO) electrodes in acidic media', Talanta, Vol. 76, No. 3, pp.533-539.
  92. Turkevich, J., Stevenson, P.C. and Hillier, J. (1951) 'A study of the nucleation and growth processes in the synthesis of colloidal gold', Discuss. Faraday Soc., Vol. 11, pp.55-75.
  93. Umasankar, Y., Yogeswaran, U., Thiagarajan, S. and Chen, S. (2007) 'Nanocomposite of functionalized multiwall carbon nanotubes with nafion, nano platinum, and nano gold biosensing film for simultaneous determination of ascorbic acid, epinephrine, and uric acid', Analytical Biochemistry, Vol. 365, No. 1, pp.122-131.
  94. Voevodin, A.A., Hu, J.J., Jones, J.G., Fitz, T.A. and Zabinski, J.S. (2001) 'Growth and structural characterization of yttria-stabilized zirconia-gold nanocomposite films with improved toughness', Thin Solid Films, Vol. 401, Nos. 1-2, pp.187-195.
  95. Voggu, R., Pal, S., Pati, S.K. and Rao, C.N. (2008) 'Semiconductor to metal transition in SWNTs caused by interaction with gold and platinum nanoparticles', Journal of Physics: Condensed Matter, Vol. 20, No. 21, p.215211.
  96. Wang, J. (2007) 'Nanoparticle-based electrochemical bioassays of proteins', Electroanalysis, Vol. 19, Nos. 7-8, pp.769-776.
  97. Wang, T.X., Zhang, D.Q., Xu, W., Yang, J.L. and Zhu, D.B. (2002) 'Preparation, characterization, and photophysical properties of alkanethiols with pyrene units-capped gold nanoparticles: unusual fluorescence enhancement for the aged solutions of these gold nanoparticles', Langmuir, Vol. 18, pp.1840-1848.
  98. Wang, C., Wang, G. and Fang, B. (2008a) 'Electrocatalytic oxidation of bilirubin at ferrocenecarboxamide modified MWCNT-gold nanocomposite electrodes', Microchimica Acta, Vol. 164, No. 1-2, pp.113-118.
  99. Wang, Z., Li, M., Su, P., Zhang, Y., Shen, Y., Han D., Ivaska, A. and Niu, L. (2008b) 'Direct electron transfer of horseradish peroxidase and its electrocatalysis based on carbon nanotube/thionine/gold composites', Electrochemistry Communications, Vol. 10, No. 2, pp.306-310.
  100. Wang, Z.J., Li, M.Y., Zhang, Y.J., Yuan, J.H., Shen, Y.F., Niu, L. and Ivaska, A. (2007) 'Thionine-interlinked multi-walled carbon nanotube/gold nanoparticle composites', Carbon, Vol. 45, No. 10, pp.2111-2115.
  101. Welch, C.M. and Compton, R.G. (2006) 'The use of nanoparticles in electroanalysis: a review', Analytical and Bioanalytical Chemistry, Vol. 384, No. 3, pp.601-619.
  102. Wildgoose, G.G., Banks, C.E. and Compton, R.G. (2006) 'Metal nanoparticles and related materials supported on carbon nanotubes: methods and applications', Small, Vol. 2, No. 2, pp.182-193.
  103. Xiao, L., Wildgoose, G.G. and Compton, R.G. (2008) 'Sensitive electrochemical detection of arsenic (III) using gold nanoparticle modified carbon nanotubes via anodic stripping voltammetry', Analytica Chimica Acta, Vol. 620, Nos. 1-2, pp.44-49.
  104. Xu, H., Zeng, L.P., Xing, S.J., Shi, G.Y., Xian, Y.Z. and Jin, L.T. (2008) 'Microwave-radiated synthesis of gold nanoparticles/carbon nanotubes composites and its application to voltammetric detection of trace mercury (II)', Electrochemistry Communications, Vol. 10, No. 12, pp.1839-1843.
  105. Yagci, Y., Sangermano, M. and Rizza, G. (2008) 'In situ synthesis of gold-cross-linked poly(ethylene glycol) nanocomposites by photoinduced electron transfer and free radical polymerization processes', Chemical Communications, No. 24, pp.2771-2773.
  106. Yao, Y. and Shiu, K. (2008) 'Direct electrochemistry of glucose oxidase at carbon nanotube/gold colloid modified electrode with poly(diallyldimethylammonium chloride) coating', Electroanalysis, Vol. 20, No. 14, pp.1542-1548.
  107. Yogeswaran, U., Thiagarajan, S. and Chen, S. (2007) 'Pinecone shape hydroxypropyl-- cyclodextrin on a film of multi-walled carbon nanotubes coated with gold particles for the simultaneous determination of tyrosine, guanine, adenine and thymine', Carbon, Vol. 45, No. 14, pp.2783-2796.
  108. Zanella, R., Basiuk, E., Santiago, P., Basiuk, V., Mireles, E., Puente-Lee, I. and Saniger, J.M. (2005) 'Deposition of gold nanoparticles onto thiol-functionalized multiwalled carbon nanotubes', J. Phys. Chem. B, Vol. 109, No. 34, pp.16290-16295.
  109. Zhang, J.J., Cheng, F.F., Zheng, T.T. and Zhu, J.J. (2010a) 'Design and implementation of electrochemical cytosensor for evaluation of cell surface carbohydrate and glycoprotein', Analytical Chemistry, Vol. 82, No. 9, pp.3547-3555.
  110. Zhang, R.Y., Hummelgård, M. and Olin, H. (2010b) 'Carbon nanocages grown by gold templating', Carbon, Vol. 48, No. 2, pp.424-430.
  111. Zhang, R.Y., Hummelgård, M. and Olin, H. (2010c) 'Simple synthesis of clay-gold nanocomposites with tunable color', Langmuir, Vol. 26, pp.5823-5828.
  112. Zhang, J.J., Gu, M.M., Zheng, T.T. and Zhu, J.J. (2009a) 'Synthesis of gelatin-stabilized gold nanoparticles and assembly of carboxylic single-walled carbon nanotubes/Au composites for cytosensing and drug uptake', Analytical Chemistry, Vol. 81, No. 16, pp.6641-6648.
  113. Zhang, R.Y., Hummelgård, M. and Olin, H. (2009b) 'Simple and efficient gold nanoparticles deposition on carbon nanotubes with controllable particle sizes', Materials Science and Engineering: B, Vol. 158, Nos. 1-3, pp.48-52.
  114. Zhang, Y., Kang, T., Wan, Y. and Chen, S. (2009c) 'Gold nanoparticles-carbon nanotubes modified sensor for electrochemical determination of organophosphate pesticides', Microchimica Acta, Vol. 165, Nos. 3-4, pp.307-311.
  115. Zhang, M., Su, L. and Mao, L. (2006a) 'Surfactant functionalization of carbon nanotubes (CNTs) for layer-by-layer assembling of CNT multi-layer films and fabrication of gold nanoparticle/CNT nanohybrid', Carbon, Vol. 44, No. 2, pp.276-283.
  116. Zhang, R.Y., Song, M., Li, X.M., Guan, Z.Q. and Wang, X.M. (2006b) 'In situ electrochemical contact angle study of hemoglobin and hemoglobin-Fe3O4 nanocomposites', Analytical and Bioanalytical Chemistry, Vol. 386, Nos. 7-8, pp.2075-2079.
  117. Zhang, R.L., Wang, Q.F., Zhang, L., Yang, S.C., Yang, Z.M. and Ding, B.J. (2008) 'The growth of uncoated gold nanoparticles on multiwalled carbon nanotubes', Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 312, Nos. 2-3, pp.136-141.
  118. Zhang, R.Y. and Wang, X.M. (2007) 'One step synthesis of multiwalled carbon nanotube/gold nanocomposites for enhancing electrochemical response', Chemistry of Materials, Vol. 19, No. 28, pp.976-978.
  119. Zhang, R.Y. and Wang, X.M. (2010) 'Selective enhanced electrochemical response of DNA bases on Au-CNT nanocomposites modified gold electrode', Physica Status Solidi (a), In press, DOI: 10.1002/pssa.201026094.
  120. Zhang, S., Huang, F., Liu, B., Ding, J., Xu, X. and Kong, J. (2007) 'A sensitive impedance immunosensor based on functionalized gold nanoparticle-protein composite films for probing apolipoprotein A-I', Talanta, Vol. 71, No. 2, pp.874-881.
  121. Zhang, Y., Franklin, N. W., Chen, R. J. and Dai, H. (2000) 'Metal coating on suspended carbon nanotubes and its implication to metal-tube interaction', Chemical Physics Letters, Vol. 331, pp.35-41.
  122. Zhou, R.J., Shi, M.M., Chen, X.Q., Wang, M., Yang, Y., Zhang, X.B. and Chen, H.Z. (2007) 'Water-soluble and highly fluorescent hybrids of multi-walled carbon nanotubes with uniformly arranged gold nanoparticles', Nanotechnology, Vol. 18, p.485603.
  123. Zhu, H., Lu, X., Li, M., Shao, Y. and Zhu, Z. (2009) 'Nonenzymatic glucose voltammetric sensor based on gold nanoparticles/carbon nanotubes/ionic liquid nanocomposite', Talanta, Vol. 79, No. 5, pp.1446-1453.
  124. Zhu, J., Xu, J., Hu, Z. and Chen, H. (2005) 'Reagentless electrochemical biosensor based on the multi-wall carbon nanotubes and nanogold particles particles composite', Frontiers in Bioscience, Vol. 10, pp.521-529.
  125. Zijlstra, P., Chon, J.W. and Gu, M. (2007) 'Effect of heat accumulation on the dynamic range of a gold nanorod doped polymer nanocomposite for optical laser writing and patterning', Optics Express, Vol. 15, No. 19, pp.12151-12160.